Highly Active and Stable Graphene Tubes Decorated with FeCoNi Alloy Nanoparticles via a Template-Free Graphitization for Bifunctional Oxygen Reduction and Evolution

Gupta, Shiva; Qiao, Liang; Zhao, Shuai; Xu, Hui; Lin, Ye; Devaguptapu, Surya V.; Wang, Xianliang; Swihart, Mark T.; Wu, Gang

doi:10.1002/aenm.201601198

Title: Highly Active and Stable Graphene Tubes Decorated with FeCoNi Alloy Nanoparticles via a Template-Free Graphitization for Bifunctional Oxygen Reduction and Evolution

Journal Article · Tue Aug 23 00:00:00 EDT 2016 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201601198· OSTI ID:1533063

Gupta, Shiva ^[1]; Qiao, Liang ^[1]; Zhao, Shuai ^[2]; Xu, Hui ^[2]; Lin, Ye ^[3]; Devaguptapu, Surya V. ^[1]; Wang, Xianliang ^[1]; Swihart, Mark T. ^[1]; Wu, Gang ^[1]

University at Buffalo, State University of New York, Buffalo, NY (United States)
Giner Inc, Newton, MA (United States)
University of South Carolina, Columbia, SC (United States)

Development of highly active and stable bifunctional oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) catalysts from earth–abundant elements remains a grand challenge for highly demanded reversible fuel cells and metal–air batteries. Carbon catalysts have many advantages over others due to their low cost, excellent electrical conductivity, high surface area, and easy functionalization. However, they typically cannot withstand the highly oxidative OER environment. Here, a new class of bifunctional electrocatalyst is reported, consisting of ultralarge sized nitrogen doped graphene tubes (N–GTs) (>500 nm) decorated with FeCoNi alloy particles. These tubes are prepared from an inexpensive precursor, dicyandiamide, via a template–free graphitization process. The ORR/OER activity and the stability of these graphene tube catalysts depend strongly on the transition metal precursors. The best performing FeCoNi–derived N–GT catalyst exhibits excellent ORR and OER activity along with adequate electrochemical durability over a wide potential window (0–1.9 V) in alkaline media. Here, the measured OER current is solely due to desirable O₂ evolution, rather than carbon oxidation. Extensive electrochemical and physical characterization indicated that high graphitization degree, thicker tube walls, proper nitrogen doping, and presence of FeCoNi alloy particles are vital for high bifunctional activity and electrochemical durability of tubular carbon catalysts.

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Research Organization:: Giner, Inc., Newton, MA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Fuel Cell Technologies Office; USDOE

Grant/Contract Number:: EE0006960

OSTI ID:: 1533063

Alternate ID(s):: OSTI ID: 1464414

Journal Information:: Advanced Energy Materials, Vol. 6, Issue 22; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 210 works

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Electronic reconfiguration of Co ₂ P induced by Cu doping enhancing oxygen reduction reaction activity in zinc–air batteries Diao, Lechen; Yang, Tao; Chen, Biao Journal of Materials Chemistry A, Vol. 7, Issue 37 https://doi.org/10.1039/c9ta07652b	journal	January 2019
Ternary MnO/CoMn alloy@N-doped graphitic composites derived from a bi-metallic pigment as bi-functional electrocatalysts Deng, Chen; Wu, Kuang-Hsu; Scott, Jason Journal of Materials Chemistry A, Vol. 7, Issue 36 https://doi.org/10.1039/c9ta08016c	journal	January 2019
Enhanced electrolytic oxygen evolution by the synergistic effects of trimetallic FeCoNi boride oxides immobilized on polypyrrole/reduced graphene oxide Mao, Hui; Guo, Xi; Fu, Yuanlin Journal of Materials Chemistry A, Vol. 8, Issue 4 https://doi.org/10.1039/c9ta10756h	journal	January 2020
Platinum Nanoparticle Inclusion into a Carbonized Polymer of Intrinsic Microporosity: Electrochemical Characteristics of a Catalyst for Electroless Hydrogen Peroxide Production Adamik, Robert; Hernández-Ibáñez, Naiara; Iniesta, Jesus Nanomaterials, Vol. 8, Issue 7 https://doi.org/10.3390/nano8070542	journal	July 2018
Functional Electrocatalysts Derived from Prussian Blue and its Analogues for Metal‐Air Batteries: Progress and Prospects Deng, Chen; Wang, Da‐Wei Batteries & Supercaps, Vol. 2, Issue 4 https://doi.org/10.1002/batt.201800116	journal	February 2019
Stable and Efficient Nitrogen-Containing Carbon-Based Electrocatalysts for Reactions in Energy-Conversion Systems Wang, Sicong; Teng, Zhengyuan; Wang, Chengyin ChemSusChem, Vol. 11, Issue 14 https://doi.org/10.1002/cssc.201800509	journal	June 2018
3D self-supported Ni nanoparticle@N-doped carbon nanotubes anchored on NiMoN pillars for the hydrogen evolution reaction with high activity and anti-oxidation ability Gong, Yi; Wang, Linan; Xiong, Hailang Journal of Materials Chemistry A, Vol. 7, Issue 22 https://doi.org/10.1039/c9ta03473k	journal	January 2019
N,P-coordinated fullerene-like carbon nanostructures with dual active centers toward highly-efficient multi-functional electrocatalysis for CO ₂ RR, ORR and Zn-air battery Xue, Xiaoyi; Yang, Hui; Yang, Tao Journal of Materials Chemistry A, Vol. 7, Issue 25 https://doi.org/10.1039/c9ta03828k	journal	January 2019
Ultrafast X-ray Absorption Studies of the Structural Dynamics of Molecular and Biological Systems in Solution Milne, Christopher J.; Van der Veen, Renske M.; Pham, Van-Thai CHIMIA International Journal for Chemistry, Vol. 65, Issue 5 https://doi.org/10.2533/chimia.2011.303	journal	May 2011
Sr, Fe Co-doped Perovskite Oxides With High Performance for Oxygen Evolution Reaction Guo, Qiang; Li, Xiang; Wei, Haifei Frontiers in Chemistry, Vol. 7 https://doi.org/10.3389/fchem.2019.00224	journal	April 2019

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