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Title: Improving Quantum Yield of Upconverting Nanoparticles in Aqueous Media via Emission Sensitization

Journal Article · · Nano Letters
ORCiD logo [1];  [2];  [1]; ORCiD logo [3];  [1];  [1]
  1. Stanford Univ., Stanford, CA (United States)
  2. Stanford Univ., Stanford, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
  3. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States); Kavli Energy NanoScience Institute, Berkeley, CA (United States)

We demonstrate a facile method to improve upconversion quantum yields in Yb,Er-based nanoparticles via emission dye-sensitization. Using the commercially available dye ATTO 542, chosen for its high radiative rate and significant spectral overlap with the green emission of Er3+, we decorate the surfaces of sub-25 nm hexagonal-phase Na(Y/Gd/Lu)0.8F4:Yb0.18Er0.02 upconverting nanoparticles with varying dye concentrations. Upconversion photoluminescence and absorption spectroscopy provide experimental confirmation of energy transfer to and emission from the dye molecules. Upconversion quantum yield is observed to increase with dye sensitization, with the highest enhancement measured for the smallest particles investigated (10.9 nm in diameter); specifically, these dye-decorated particles are more than 2× brighter than are unmodified, organic-soluble nanoparticles and more than 10× brighter than are water-soluble nanoparticles. We also observe 3× lifetime reductions with dye adsorption, confirming the quantum yield enhancement to result from the high radiative rate of the dye. As a result, the approach detailed in this work is widely implementable, renders the nanoparticles water-soluble, and most significantly improves sub-15 nm nanoparticles, making our method especially attractive for biological imaging applications.

Research Organization:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Energy Frontier Research Centers (EFRC) (United States). Light-Material Interactions in Energy Conversion (LMI)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC02-05CH11231; SC0001293
OSTI ID:
1532309
Journal Information:
Nano Letters, Vol. 18, Issue 4; ISSN 1530-6984
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 51 works
Citation information provided by
Web of Science

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Optical tuning in lanthanide-based nanostructures journal November 2019
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Towards Utilising Photocrosslinking of Polydiacetylenes for the Preparation of “Stealth” Upconverting Nanoparticles journal October 2018
Modulation of lanthanide luminescence via an electric field journal January 2019
Mechanism of upconversion luminescence enhancement in Yb 3+ /Er 3+ co-doped Y 2 O 3 through Li + incorporation journal January 2020
Physical Manipulation of Lanthanide‐Activated Photoluminescence journal May 2019
Future and challenges for hybrid upconversion nanosystems journal October 2019
Are lanthanide-doped upconversion materials good candidates for photocatalysis? journal January 2019
Recent Progress of Rare‐Earth Doped Upconversion Nanoparticles: Synthesis, Optimization, and Applications journal September 2019
Upconversion of low-energy photons in semiconductor nanostructures for solar energy harvesting journal January 2018
UCN–SiO 2 –GO: a core shell and conjugate system for controlling delivery of doxorubicin by 980 nm NIR pulse journal January 2018
Strong upconversion emission in CsPbBr 3 perovskite quantum dots through efficient BaYF 5 :Yb,Ln sensitization journal January 2019
Towards Utilising Photocrosslinking of Polydiacetylenes for the Preparation of “Stealth” Upconverting Nanoparticles journal December 2018