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Title: Stepped gradient fuel electrode and method for making the same

Patent ·
OSTI ID:1531618

The present invention provides for a method of depositing a stepped-gradient fuel electrode onto a fuel cell support 2 and the resulting fuel cell, that comprises placing a solid oxide fuel cell support that has at least an air electrode layer 4 and an electrolyte layer 6 into an atmospheric plasma spraying chamber and measuring spray parameters of an atmospheric plasma spray to obtain reactive oxides, conductive metal and graphite phases. Then spraying the spray parameters onto the solid oxide fuel cell support to produce multiple sub-layers 8 on the solid oxide fuel cell support, and adjusting a hydrogen usage of the atmospheric plasma spray. The adjusting of the hydrogen usage comprises using high hydrogen levels for the initial spraying of the sub-layers producing a first gradient region, and a lower hydrogen level for subsequent spraying of the sub-layers, producing a second gradient region.

Research Organization:
Siemens Energy, Inc., Orlando, FL (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FC26-97FT34139
Assignee:
Siemens Energy, Inc. (Orlando, FL)
Patent Number(s):
7,637,967
Application Number:
11/298,321
OSTI ID:
1531618
Resource Relation:
Patent File Date: 2005-12-08
Country of Publication:
United States
Language:
English

References (12)

Carrier substrate for an electrode layer of a fuel cell and method for the production thereof patent-application September 2005
Method for manufacturing fuel cells, and articles made therewith patent-application December 2003
Solid oxide fuel cell components and method of manufacture thereof patent-application January 2004
A study of Ni + 8YSZ/8YSZ/LaSrCoO ITSOFC fabricated by atmospheric plasma spraying journal February 2005
Multi-stage fuel cell arrangement patent January 1998
Sealing structure for a fuel cell, as well as a method for producing it, and a fuel cell with the sealing structure patent-application October 2004
Standard package design for both atmospheric and pressurized SOFC power generation system patent July 2004
Fuel cell patent-application October 2004
High power density solid oxide fuel cell having a graded anode patent May 2001
Low-cost atmospheric SOFC power generation system patent December 2003
Method for operating a fuel cell assembly patent December 1998
Method for modifying the surface of a thermal barrier coating by plasma-heating patent August 2000

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