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Title: Method for creating a corrosion-resistant surface on aluminum alloys having a high copper content

Patent ·
OSTI ID:1531421

A method for treating the surface of aluminum alloys having a relatively high copper content is provided which includes the steps of removing substantially all of the copper from the surface, contacting the surface with a first solution containing cerium, electrically charging the surface while contacting the surface in an aqueous molybdate solution, and contacting the surface with a second solution containing cerium. The copper is substantially removed from the surface in the first step either by (i) contacting the surface with an acidic chromate solution or by (ii) contacting the surface with an acidic nitrate solution while subjecting the surface to an electric potential. The corrosion-resistant surface resulting from the invention is excellent, consistent and uniform throughout the surface. Surfaces treated by the invention may often be certified for use in salt-water services.

Research Organization:
Univ. of Southern California, Los Angeles, CA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
N00014-91-J-1041
Assignee:
University of Southern California (Los Angeles, CA)
Patent Number(s):
5,582,654
Application Number:
08/247,147
OSTI ID:
1531421
Resource Relation:
Patent File Date: 1994-05-20
Country of Publication:
United States
Language:
English

References (16)

Chrome-Free Deoxidizing and Desmutting Composition and Method patent April 1973
Surface treatment chemical and bath for aluminum and its alloy patent February 1991
Corrosion protection of high copper aluminium alloys by surface modification journal January 1994
Method of inhibiting corrosion of zirconium or its alloy patent September 1986
Rare earth coating process for aluminum alloys patent November 1994
Chromium-free method and composition to protect aluminum patent March 1993
Method for creating a corrosion-resistant aluminum surface patent March 1993
Corrosion inhibition with rare earth metal salts journal March 1992
Rare earth metal rinse for metal coatings patent July 1976
Surface modification of Al alloys and Al-based metal matrix composites by chemical passivation journal August 1989
Cationic-Film-Forming Inhibitors for the Protection of the AA 7075 Aluminum Alloy Against Corrosion in Aqueous Chloride Solution journal January 1989
Method of improving the corrosion resistance of chemical conversion coated aluminum patent May 1984
Treatment of Magnesium and Magnesium Base Alloys to Increase Their Resistance to Corrosion patent June 1950
Coating process for aluminum and aluminum alloy patent June 1976
Corrosion resistant aluminum coating composition patent January 1991
Corrosion Protection of Al Alloys and Al-Based Metal Matrix Composites by Chemical Passivation journal August 1989

Cited By (11)

Non-toxic corrosion-protection conversion coats based on cobalt patent November 2007
Use of rare earth metal salt solutions for sealing or anodized aluminum for corosion protection and paint adhesion patent June 2001
Corrosion resistant metallate compositions patent May 2016
Electrolytic and electroless process for treating metallic surfaces and products formed thereby patent June 2004
Corrosion resistant conversion coatings patent November 2008
Non-carcinogenic corrosion inhibiting additive patent March 2003
Apparatus and method for TV broadcast copy protection patent February 2003
Compound, non-chromium conversion coatings for aluminum alloys patent September 2003
Chromium-free conversion coating patent September 2002
Non-toxic corrosion-protection conversion coats based on rare earth elements patent August 2008
Non-toxic corrosion-protection rinses and seals based on rare earth elements patent September 2008

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