Ultrafine Pt Nanoparticle-Decorated Pyrite-Type CoS 2 Nanosheet Arrays Coated on Carbon Cloth as a Bifunctional Electrode for Overall Water Splitting

Han, Xiaopeng; Wu, Xiaoyu; Deng, Yida; Liu, Jian; Lu, Jun; Zhong, Cheng; Hu, Wenbin

doi:10.1002/aenm.201800935

Title: Ultrafine Pt Nanoparticle-Decorated Pyrite-Type CoS ₂ Nanosheet Arrays Coated on Carbon Cloth as a Bifunctional Electrode for Overall Water Splitting

Journal Article · Mon Jul 02 00:00:00 EDT 2018 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201800935· OSTI ID:1526674

Han, Xiaopeng ^[1]; Wu, Xiaoyu ^[1]; Deng, Yida ^[1]; Liu, Jian ^[2]; Lu, Jun ^[3];

^[1]; Hu, Wenbin ^[1]

Tianjin Univ. (China)
Shandong Univ., Jinan (China)
Argonne National Lab. (ANL), Lemont, IL (United States)

To improve the utilization efficiency of precious metals, metal-supported materials provide a direction for fabricating highly active and stable heterogeneous catalysts. Here, carbon cloth (CC)-supported Earth-abundant CoS₂ nanosheet arrays (CoS₂/CC) are presented as ideal substrates for ultrafine Pt deposition (Pt-CoS₂/CC) to achieve remarkable performance toward the hydrogen and oxygen evolution reactions (HER/OER) in alkaline solutions. Notably, the Pt-CoS₂/CC hybrid delivers an overpotential of 24 mV at 10 mA cm^–2 and a mass activity of 3.89 A Ptmg^–1, which is 4.7 times higher than that of commercial Pt/C, at an overpotential of 130 mV for catalyzing the HER. An alkali-electrolyzer using Pt-CoS₂/CC as a bifunctional electrode enables a water-splitting current density of 10 mA cm^–2 at a low voltage of 1.55 V and can sustain for more than 20 h, which is superior to that of the state-of-the-art Pt/C+RuO₂ catalyst. Further experimental and theoretical simulation studies demonstrate that strong electronic interaction between Pt and CoS₂ synergistically optimize hydrogen adsorption/desorption behaviors and facilitate the in situ generation of OER active species, enhancing the overall water-splitting performance. This research highlights the regulation of interfacial and electronic synergy in pursuit of highly efficient and durable supported catalysts for hydrogen and oxygen electrocatalytic applications.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Natural Science Foundation of China (NSFC); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1526674

Journal Information:: Advanced Energy Materials, Vol. 8, Issue 24; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 286 works

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