Selective Benzyl Alcohol Oxidation over Pd Catalysts

Chan-Thaw, Carine Edith; Savara, Aditya; Villa, Alberto

doi:10.3390/catal8100431

Title: Selective Benzyl Alcohol Oxidation over Pd Catalysts

Journal Article · Sun Sep 30 00:00:00 EDT 2018 · Catalysts

DOI:https://doi.org/10.3390/catal8100431· OSTI ID:1513407

Chan-Thaw, Carine Edith ^[1]; Savara, Aditya ^[2];

^[3]

Univ. d'Antananarivo, Antananarivo (Madagascar)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. degli Studi di Milano, Milano (Italy)

In the last decades, the selective liquid phase oxidation of alcohols to the corresponding carbonyl compounds has been a subject of growing interest. Research has focused on green methods that use “clean” oxidants such as O₂ in combination with supported metal nanoparticles as the catalyst. Among the alcohols, benzyl alcohol is one of the most studied substrates. Indeed, benzyl alcohol can be converted to benzaldehyde, largely for use in the pharmaceutical and agricultural industries. This conversion serves as model reaction in testing new potential catalysts, that can then be applied to other systems. Pd based catalysts have been extensively studied as active catalytic metals for alcohol oxidation for their high activity and selectivity to the corresponding aldehyde. Several catalytic materials obtained by careful control of the morphology of Pd nanoparticles, (including bimetallic systems) and by tuning the support properties have been developed. Moreover, reaction conditions, including solvent, temperature, pressure and alcohol concentration have been investigated to tune the selectivity to the desired products. Different reaction mechanisms and microkinetic models have been proposed. The aim of this review is to provide a critical description of the recent advances on Pd catalyzed benzyl alcohol oxidation.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1513407

Journal Information:: Catalysts, Vol. 8, Issue 10; ISSN 2073-4344

Publisher:: MDPICopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 38 works

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