Transient Nonlinear Response of Dynamically Decoupled Ionic Conductors

Wieland, Felix; Sokolov, Alexei P.; Böhmer, Roland; Gainaru, Catalin

doi:10.1103/PhysRevLett.121.064503

Title: Transient Nonlinear Response of Dynamically Decoupled Ionic Conductors

Journal Article · Thu Aug 09 00:00:00 EDT 2018 · Physical Review Letters

DOI:https://doi.org/10.1103/PhysRevLett.121.064503· OSTI ID:1510586

Wieland, Felix ^[1];

^[2]; Böhmer, Roland ^[1]; Gainaru, Catalin ^[1]

Technische Univ. Dortmund, Dortmund (Germany)
Univ. of Tennessee, Knoxville, TN (United States)

The present study demonstrates that large electric fields progressively enhance the conductivity of ionic systems up to timescales corresponding to those on which their structural rearrangements take place. Here, in many ionic materials, some regarded as candidates for electrical energy storage applications, the structural relaxation process can be tremendously slower than (or highly decoupled from) the charge fluctuations. Consequently, nonlinear dielectric spectroscopy may be employed to access rheological information in dynamically decoupled ionic conductors, whereas the combination of large electric power density and good mechanical stability, both technologically highly desired, imposes specific experimental constraints to reliably determine the steady-state conductivity of such materials.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1510586

Alternate ID(s):: OSTI ID: 1463761

Journal Information:: Physical Review Letters, Vol. 121, Issue 6; ISSN 0031-9007

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 13 works

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Local and global dynamics of the viscous ion conductors 2Ca(NO ₃ ) ₂ -3KNO ₃ and 2Ca(NO ₃ ) ₂ -3RbNO ₃ probed by ⁸⁷ Rb nuclear magnetic resonance and shear rheology Beerwerth, Joachim; Bierwirth, S. Peter; Adam, Jens The Journal of Chemical Physics, Vol. 150, Issue 19 https://doi.org/10.1063/1.5093973	journal	May 2019
Structure and dynamics of short-chain polymerized ionic liquids Wieland, F.; Bocharova, V.; Münzner, P. The Journal of Chemical Physics, Vol. 151, Issue 3 https://doi.org/10.1063/1.5109228	journal	July 2019

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