Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd3Bi7 and Sm3Bi7

Ovchinnikov, Alexander; Makongo, Julien P.  A.; Bobev, Svilen

doi:10.1039/c8cc02563k

Title: Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd₃Bi₇ and Sm₃Bi₇

Journal Article · Mon Jun 04 00:00:00 EDT 2018 · ChemComm

DOI:https://doi.org/10.1039/c8cc02563k· OSTI ID:1504902

^[1]; Makongo, Julien P. A. ^[1];

^[1]

Univ. of Delaware, Newark, DE (United States)

The binary bismuthides Nd₃Bi₇ and Sm₃Bi₇ were synthesized and structurally characterized for the first time. Here, the results from the calorimetric analysis show that both compounds are stable only up to about 500 °C, which may explain why they were overlooked during the original assessment of the corresponding phase diagrams.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Univ. of Delaware, Newark, DE (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0008885

OSTI ID:: 1504902

Alternate ID(s):: OSTI ID: 1441062

Journal Information:: ChemComm, Vol. 54, Issue 51; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 12 works

Citation information provided by
Web of Science

References (31)

Permanent magnets: Plugging the gap Coey, J. M. D. Scripta Materialia, Vol. 67, Issue 6 https://doi.org/10.1016/j.scriptamat.2012.04.036	journal	September 2012
Preparation and Crystal Structure of the Ternary Uranium Rare Earth Antimonides (U _2/3 R _1/3 )Sb ₂ and (U _1/2 R _1/2 ) ₃ Sb ₇ with Mixed U/ R Occupancy of the Metal Sites and a Variety of Antimony Polyanions Schmidt, Tobias; Jeitschko, Wolfgang Inorganic Chemistry, Vol. 40, Issue 25 https://doi.org/10.1021/ic010564j	journal	December 2001
Ternary pnictides MNi2−xPn2 (M ≡ Sr and rare earth metals, Pn ≡ Sb, Bi) with defect CaBe2Ge2 and defect ThCr2Si2 structures Hofmann, W. K.; Jeitschko, W. Journal of the Less Common Metals, Vol. 138, Issue 2 https://doi.org/10.1016/0022-5088(88)90119-1	journal	March 1988
Rare-earth bismuthides Yoshihara, K.; Taylor, J. B.; Calvert, L. D. Journal of the Less Common Metals, Vol. 41, Issue 2 https://doi.org/10.1016/0022-5088(75)90038-7	journal	July 1975
Catalytic Properties of Ceria and CeO ₂ -Containing Materials Trovarelli, Alessandro Catalysis Reviews, Vol. 38, Issue 4 https://doi.org/10.1080/01614949608006464	journal	November 1996
On the effect of Ga and In substitutions in the Ca ₁₁ Bi ₁₀ and Yb ₁₁ Bi ₁₀ bismuthides crystallizing in the tetragonal Ho ₁₁ Ge ₁₀ structure type Ovchinnikov, Alexander; Bobev, Svilen Acta Crystallographica Section C Structural Chemistry, Vol. 74, Issue 3 https://doi.org/10.1107/S2053229618001596	journal	February 2018
Weak Interactions under Pressure: hp -CuBi and Its Analogues Guo, Kai; Akselrud, Lev; Bobnar, Matej Angewandte Chemie International Edition, Vol. 56, Issue 20 https://doi.org/10.1002/anie.201700712	journal	April 2017
Superconductivity in iron compounds Stewart, G. R. Reviews of Modern Physics, Vol. 83, Issue 4 https://doi.org/10.1103/RevModPhys.83.1589	journal	December 2011
Anisotropic magnetization and resistivity of single crystalline RNi1−xBi2±y (R=La–Nd, Sm, Gd–Dy) Lin, Xiao; Straszheim, Warren E.; Bud’ko, Sergey L. Journal of Alloys and Compounds, Vol. 554 https://doi.org/10.1016/j.jallcom.2012.11.138	journal	March 2013
Yb ₁₄ MnSb ₁₁ : New High Efficiency Thermoelectric Material for Power Generation Brown, Shawna R.; Kauzlarich, Susan M.; Gascoin, Franck Chemistry of Materials, Vol. 18, Issue 7 https://doi.org/10.1021/cm060261t	journal	April 2006
Low Temperature Magnetic Properties of CeTBi ₂ (T: Ni, Cu and Ag) Single Crystals Thamizhavel, Arumugam; Galatanu, Andrei; Yamamoto, Etsuji Journal of the Physical Society of Japan, Vol. 72, Issue 10 https://doi.org/10.1143/JPSJ.72.2632	journal	October 2003
Lanthanide-Based Luminescent Hybrid Materials Binnemans, Koen Chemical Reviews, Vol. 109, Issue 9 https://doi.org/10.1021/cr8003983	journal	September 2009
Synthesis and crystal structure of EuBi2 Sun, Zhong-Ming; Mao, Jiang-Gao Journal of Solid State Chemistry, Vol. 177, Issue 10 https://doi.org/10.1016/j.jssc.2004.07.006	journal	October 2004
Synthesis and crystal structures of La3MgBi5 and LaLiBi2 Pan, Da-Chun; Sun, Zhong-Ming; Mao, Jiang-Gao Journal of Solid State Chemistry, Vol. 179, Issue 4 https://doi.org/10.1016/j.jssc.2005.12.030	journal	April 2006
Crystal chemistry and magnetic properties of the solid solutions Ca _14−x RE _x MnBi ₁₁ (RE = La–Nd, Sm, and Gd–Ho; x ≈ 0.6–0.8) Ovchinnikov, Alexander; Prakash, Jai; Bobev, Svilen Dalton Transactions, Vol. 46, Issue 46 https://doi.org/10.1039/C7DT03715E	journal	January 2017
Structure and properties of the transition-metal zintl compounds: A14MnBi11 (A = Ca, Sr, Ba) Kuromoto, Traci Y.; Kauzlarich, Susan M.; Webb, David J. Chemistry of Materials, Vol. 4, Issue 2 https://doi.org/10.1021/cm00020a036	journal	March 1992
Undistorted linear Bi chains with hypervalent bonding in La ₃ TiBi ₅ from single-crystal X-ray diffraction Ovchinnikov, Alexander; Bobev, Svilen Acta Crystallographica Section C Structural Chemistry, Vol. 74, Issue 5 https://doi.org/10.1107/S205322961800565X	journal	April 2018
Skutterudites as thermoelectric materials: revisited Rull-Bravo, M.; Moure, A.; Fernández, J. F. RSC Advances, Vol. 5, Issue 52 https://doi.org/10.1039/C5RA03942H	journal	January 2015
The single crystal structure determination of Ln6MnSb15 (Ln=La, Ce), Ln6Mn1−xZnxSb15 (x~0.5), and Ln6ZnSb15 (Ln=La–Pr) Benavides, Katherine A.; McCandless, Gregory T.; Chan, Julia Y. Zeitschrift für Kristallographie - Crystalline Materials, Vol. 232, Issue 7-9 https://doi.org/10.1515/zkri-2016-2025	journal	January 2017
Magnetic and transport properties of the antiferromagnetic Kondo-lattice compound ${CeNiBi}_{2}$ Jung, M. H.; Lacerda, A. H.; Takabatake, T. Physical Review B, Vol. 65, Issue 13 https://doi.org/10.1103/PhysRevB.65.132405	journal	March 2002
Rare Earths in Magnesium Alloys Suseelan Nair, K.; Mittal, M. C. Materials Science Forum, Vol. 30 https://doi.org/10.4028/www.scientific.net/MSF.30.89	journal	January 1991
The Ternary Alkaline-Earth Metal Manganese Bismuthides Sr ₂ MnBi ₂ and Ba ₂ Mn _{1– x} Bi ₂ ( x ≈ 0.15) Ovchinnikov, Alexander; Saparov, Bayrammurad; Xia, Sheng-Qing Inorganic Chemistry, Vol. 56, Issue 20 https://doi.org/10.1021/acs.inorgchem.7b01851	journal	October 2017
Structures and Physical Properties of Rare-Earth Zinc Antimonides Pr ₆ Zn _{1+ x} Sb _{14+ y} and RE ₆ Zn _{1+ x} Sb ₁₄ ( RE = Sm, Gd−Ho) Liu, Yi; Chen, Ling; Li, Long-Hua Inorganic Chemistry, Vol. 47, Issue 24 https://doi.org/10.1021/ic800524d	journal	December 2008
Building up Complexity from Strips and Sheets: The Electronic Structure of the La12Mn2Sb30Alloy Papoian, Garegin; Hoffmann, Roald Journal of Solid State Chemistry, Vol. 139, Issue 1 https://doi.org/10.1006/jssc.1998.7773	journal	August 1998
Crystal Structure and Magnetism of Ternary CompoundsRE6MSb15,RE= La, Ce andM= Mn, Cu, Zn Sologub, O.; Vybornov, M.; Rogl, P. Journal of Solid State Chemistry, Vol. 122, Issue 2 https://doi.org/10.1006/jssc.1996.0112	journal	March 1996
Hypervalent Bonding in One, Two, and Three Dimensions: Extending the Zintl-Klemm Concept to Nonclassical Electron-Rich Networks A. Papoian, Garegin; Hoffmann, Roald Angewandte Chemie International Edition, Vol. 39, Issue 14 https://doi.org/10.1002/1521-3773(20000717)39:14<2408::AID-ANIE2408>3.0.CO;2-U	journal	July 2000
Ce6ZnBi14 and Pr6InSb15: Ternary rare-earth intermetallics with extended pnicogen ribbons Tkachuk, Andriy V.; Tam, Thomas; Mar, Arthur Chemistry of Metals and Alloys, Vol. 1, Issue 1 https://doi.org/10.30970/cma1.0008	journal	January 2008
Magnetism and magnetic materials: by J.M.D. Coey, Cambridge, Cambridge University Press, 2018, 617 pp., £59.99 (paperback), ISBN 9781108717519. Scope: review. Level: advanced undergraduate, postgraduate, early career researcher, researcher. Howard, Eric Contemporary Physics, Vol. 60, Issue 4 https://doi.org/10.1080/00107514.2019.1709555	journal	October 2019
Synthesis and Crystal Structures of La3MgBi5 and LaLiBi2. Pan, Da-Chun; Sun, Zhong-Ming; Mao, Jiang-Gao ChemInform, Vol. 37, Issue 27 https://doi.org/10.1002/chin.200627005	journal	July 2006
Magnetism and Magnetic Materials Sucksmith, W. Physics Bulletin, Vol. 10, Issue 10 https://doi.org/10.1088/0031-9112/10/10/012	journal	October 1959
Superconductivity in Iron Compounds Stewart, G. R. arXiv https://doi.org/10.48550/arxiv.1106.1618	text	January 2011

Cited By (2)

Exploration of Multi-Component Vanadium and Titanium Pnictides Using Flux Growth and Conventional High-Temperature Methods Ovchinnikov, Alexander; Bobev, Svilen Frontiers in Chemistry, Vol. 7 https://doi.org/10.3389/fchem.2019.00909	journal	January 2020
Exploratory Work in the Quaternary System of Ca–Eu–Cd–Sb: Synthesis, Crystal, and Electronic Structures of New Zintl Solid Solutions Ovchinnikov, Alexander; Darone, Gregory; Saparov, Bayrammurad Materials, Vol. 11, Issue 11 https://doi.org/10.3390/ma11112146	journal	October 2018

Figures / Tables (4)

Similar Records

New rare-earth metal germanides with bismuth substitution. Synthesis, structural variations, and magnetism of the RE[Bi{sub x}Ge{sub 1-x}]{sub 2} (RE=Y, Pr, Nd, Sm, Gd-Tm, Lu) compounds

Journal Article · Sat Dec 15 00:00:00 EST 2012 · Journal of Solid State Chemistry · OSTI ID:1504902

Zhang, Jiliang; Hmiel, Benjamin; Antonelli, Anthony; +6 more

Rare-earth transition-metal chalcogenides Ln{sub 3}MGaS{sub 7} (Ln=Nd, Sm, Dy, Er; M=Co, Ni) and Ln{sub 3}MGaSe{sub 7} (Ln=Nd, Sm, Gd, Dy, M=Co; Ln=Nd, Gd, Dy, M=Ni)

Journal Article · Thu May 01 00:00:00 EDT 2014 · Journal of Solid State Chemistry · OSTI ID:1504902

Yin, Wenlong; Shi, Youguo; Kang, Bin; +3 more

Antiferromagnetic ordering in superconducting and oxygen-deficient nonsuperconducting R Ba sub 2 Cu sub 3 O sub 7 minus. delta. compounds ( R =Nd and Sm)

Journal Article · Fri Dec 01 00:00:00 EST 1989 · Physical Review (Section) B: Condensed Matter; (USA) · OSTI ID:1504902

Yang, K N; Ferreira, J M; Lee, B W; +4 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
36 MATERIALS SCIENCE

CSD 1833009: Experimental Crystal Structure Determination Ovchinnikov, Alexander; Makongo, Julien P. A.; Bobev, Svilen https://doi.org/10.25505/fiz.icsd.cc1zjdb7 The current record is supplemented by this dataset	dataset	January 2018
CSD 1833010: Experimental Crystal Structure Determination Ovchinnikov, Alexander; Makongo, Julien P. A.; Bobev, Svilen https://doi.org/10.25505/fiz.icsd.cc1zjdc8 The current record is supplemented by this dataset	dataset	January 2018

Title: Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd3Bi7 and Sm3Bi7

Citation Formats