Impact of Synthesis Method on Phase Transformations of Layered Lithium Vanadium Oxide upon Electrochemical (De)lithiation

Zhang, Qing; Yue, Shiyu; Quilty, Calvin D.; Li, Jing; Zou, Shihui; Stach, Eric A.; Dooryhee, Eric; Takeuchi, Kenneth J.; Takeuchi, Esther S.; Wong, Stanislaus S.; Marschilok, Amy C.

doi:10.1149/2.1101904jes

Title: Impact of Synthesis Method on Phase Transformations of Layered Lithium Vanadium Oxide upon Electrochemical (De)lithiation

Journal Article · Sat Mar 09 00:00:00 EST 2019 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/2.1101904jes· OSTI ID:1503509

Zhang, Qing ^[1]; Yue, Shiyu ^[2]; Quilty, Calvin D. ^[2]; Li, Jing ^[1]; Zou, Shihui ^[2]; Stach, Eric A. ^[3]; Dooryhee, Eric ^[4];

^[5];

^[6]; Wong, Stanislaus S. ^[2];

^[6]

Stony Brook Univ., NY (United States). Dept. of Materials Science and Chemical Engineering
Stony Brook Univ., NY (United States). Dept. of Chemistry
Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials
Brookhaven National Lab. (BNL), Upton, NY (United States). Energy and Photon Sciences Directorate
Stony Brook Univ., NY (United States). Dept. of Materials Science and Chemical Engineering. Dept. of Chemistry
Stony Brook Univ., NY (United States). Dept. of Materials Science and Chemical Engineering. Dept. of Chemistry; Brookhaven National Lab. (BNL), Upton, NY (United States). Energy and Photon Sciences Directorate

Li_1.1V₃O₈ (LVO) has shown promise as a cathode material for lithium-based batteries due to its high theoretical capacity (360 mAh^.g^-1) and good rate capability; however, LVO batteries suffer from capacity fade upon extended cycling. The impact of synthetic material control on electrochemistry and capacity retention was explored here through solvothermal synthesis of LVO fibers and sol-gel synthesis of LVO rhombohedrons. Cyclic voltammetry (CV) of the two materials revealed key differences where lithiation of the solvothermal-derived LVO material resulted in less β phase formation as compared with the sol-gel-derived material. Structural evolution of the materials during lithiation was characterized through in situ XRD which revealed that the α→β phase conversion is essentially complete in the sol-gel product with only partial conversion in the solvothermal product. Under galvanostatic cycling, the sol-gel product delivered higher capacity but displayed more capacity fade as compared to the solvothermal product as foretold by both CV and XRD findings. When cycled within the α phase region, improved preservation of both energy delivery and structural integrity was observed. These findings substantiate the proposed cause of capacity degradation as originating from an α→β structural change and illustrate the possibility of minimizing β phase formation through synthetic control of LVO.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2mt); Brookhaven National Lab. (BNL), Upton, NY (United States); Stony Brook Univ., NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704; SC0012673

OSTI ID:: 1503509

Report Number(s):: BNL-211465-2019-JAAM

Journal Information:: Journal of the Electrochemical Society, Vol. 166, Issue 4; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 9 works

Citation information provided by
Web of Science

References (36)

The Origin of Capacity Fading upon Lithium Cycling in Li[sub 1.1]V[sub 3]O[sub 8] Jouanneau, S.; Le Gal La Salle, A.; Verbaere, A. Journal of The Electrochemical Society, Vol. 152, Issue 8 https://doi.org/10.1149/1.1945687	journal	January 2005
Energy Dispersive X-ray Diffraction (EDXRD) of Li _1.1 V ₃ O ₈ Electrochemical Cell Zhang, Qing; Bruck, Andrea M.; Bock, David C. MRS Advances, Vol. 2, Issue 7 https://doi.org/10.1557/adv.2017.54	journal	January 2017
Carbon nanotube–metal oxide composite electrodes for secondary lithium-based batteries Marschilok, Amy C.; Schaffer, Corey P.; Takeuchi, Kenneth J. Journal of Composite Materials, Vol. 47, Issue 1 https://doi.org/10.1177/0021998312446827	journal	June 2012
Synthesis, Structural Characterization, and Growth Mechanism of Li _{1+ x} V ₃ O ₈ Submicron Fibers for Lithium-Ion Batteries Yue, Shiyu; Li, Jing; Wang, Lei Crystal Growth & Design, Vol. 18, Issue 4 https://doi.org/10.1021/acs.cgd.7b01522	journal	February 2018
Surface modification of LiV3O8 nanosheets via layer-by-layer self-assembly for high-performance rechargeable lithium batteries Mo, Runwei; Du, Ying; Zhang, Naiqing Journal of Power Sources, Vol. 257 https://doi.org/10.1016/j.jpowsour.2014.01.125	journal	July 2014
High capacity lithium-ion battery cathode using LiV3O8 nanorods Sarkar, Sudeep; Banda, Harish; Mitra, Sagar Electrochimica Acta, Vol. 99 https://doi.org/10.1016/j.electacta.2013.03.083	journal	June 2013
Influence of heat-treatment temperature on crystal structure, morphology and electrochemical properties of LiV3O8 prepared by hydrothermal reaction Xu, Jiaqiang; Zhang, Hailin; Zhang, Tao Journal of Alloys and Compounds, Vol. 467, Issue 1-2 https://doi.org/10.1016/j.jallcom.2007.11.113	journal	January 2009
Structural characterization of Li1+xV3O8 insertion electrodes by single-crystal X-ray diffraction Depicciotto, L.; Adendorff, K.; Liles, D. Solid State Ionics, Vol. 62, Issue 3-4 https://doi.org/10.1016/0167-2738(93)90386-H	journal	August 1993
High Rate, Long Lifespan LiV ₃ O ₈ Nanorods as a Cathode Material for Lithium-Ion Batteries Chen, Zhongxue; Xu, Fei; Cao, Shunan Small, Vol. 13, Issue 18 https://doi.org/10.1002/smll.201603148	journal	March 2017
Improvement of the lithium insertion properties of Li1.1V3O8 Jouanneau, S.; Verbaere, A.; Lascaud, S. Solid State Ionics, Vol. 177, Issue 3-4 https://doi.org/10.1016/j.ssi.2005.10.034	journal	January 2006
Effect of different treatment methods on the electrochemical properties of LiV3O8 at elevated temperatures Zhong, Changrong; Su, Xunjia; Hou, Genliang Ceramics International, Vol. 43, Issue 1 https://doi.org/10.1016/j.ceramint.2016.09.174	journal	January 2017
A soft chemistry synthesis and electrochemical properties of LiV3O8 as cathode material for lithium secondary batteries Liu, Qiaoyun; Liu, Haowen; Zhou, Xinwen Solid State Ionics, Vol. 176, Issue 17-18 https://doi.org/10.1016/j.ssi.2005.04.040	journal	May 2005
Super-thin LiV3O8 nanosheets/graphene sandwich-like nanostructures with ultrahigh lithium ion storage properties Zhang, Rui-Zhi; Luo, Jian-Zhe; Lu, Pei-Jie Ceramics International, Vol. 45, Issue 3 https://doi.org/10.1016/j.ceramint.2018.09.309	journal	February 2019
GSAS-II : the genesis of a modern open-source all purpose crystallography software package Toby, Brian H.; Von Dreele, Robert B. Journal of Applied Crystallography, Vol. 46, Issue 2 https://doi.org/10.1107/S0021889813003531	journal	March 2013
Phase Transition, Electrochemistry, and Structural Studies of High Rate Li _x V ₃ O ₈ Cathode with Nanoplate Morphology Sarkar, S.; Bhowmik, Arghya; Dixit Bharadwaj, Mridula Journal of The Electrochemical Society, Vol. 161, Issue 1 https://doi.org/10.1149/2.006401jes	journal	October 2013
Facile synthesis of cookies-shaped LiV3O8 cathode materials with good cycling performance for lithium-ion batteries Huang, S.; Wang, X. L.; Lu, Y. Journal of Alloys and Compounds, Vol. 584 https://doi.org/10.1016/j.jallcom.2013.09.034	journal	January 2014
Novel chemical method for synthesis of LiV3O8 nanorods as cathode materials for lithium ion batteries Xu, Hai Yan; Wang, Hao; Song, Zhi Qiang Electrochimica Acta, Vol. 49, Issue 2 https://doi.org/10.1016/j.electacta.2003.08.017	journal	January 2004
High Rate and Stable Li-Ion Insertion in Oxygen-Deficient LiV ₃ O ₈ Nanosheets as a Cathode Material for Lithium-Ion Battery Song, Huanqiao; Luo, Mingsheng; Wang, Aimei ACS Applied Materials & Interfaces, Vol. 9, Issue 3 https://doi.org/10.1021/acsami.6b13814	journal	January 2017
Lithium Vanadium Oxide (Li _1.1 V ₃ O ₈ ) Coated with Amorphous Lithium Phosphorous Oxynitride (LiPON): Role of Material Morphology and Interfacial Structure on Resulting Electrochemistry Zhang, Qing; Kercher, Andrew K.; Veith, Gabriel M. Journal of The Electrochemical Society, Vol. 164, Issue 7 https://doi.org/10.1149/2.0881707jes	journal	January 2017
LiV ₃ O ₈ /Polydiphenylamine Composites with Significantly Improved Electrochemical Behavior as Cathode Materials for Rechargeable Lithium Batteries Zhu, Limin; Xie, Lingling; Cao, Xiaoyu ACS Applied Materials & Interfaces, Vol. 10, Issue 13 https://doi.org/10.1021/acsami.8b00364	journal	March 2018
Structure of V ₂ O ₅ · n H ₂ O Xerogel Solved by the Atomic Pair Distribution Function Technique Petkov, Valeri; Trikalitis, Pantelis N.; Bozin, Emil S. Journal of the American Chemical Society, Vol. 124, Issue 34 https://doi.org/10.1021/ja026143y	journal	August 2002
Large-scale synthesis of Li1.2V3O8 as a cathode material for lithium secondary battery via a soft chemistry route Cao, Xiaoyu; Xie, Lingling; Zhan, Hui Materials Research Bulletin, Vol. 44, Issue 2 https://doi.org/10.1016/j.materresbull.2008.06.008	journal	February 2009
Ultradispersed Nanoarchitecture of LiV3O8 Nanoparticle/Reduced Graphene Oxide with High-Capacity and Long-Life Lithium-Ion Battery Cathodes Mo, Runwei; Du, Ying; Rooney, David Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep19843	journal	January 2016
Material Design Strategies to Achieve Simultaneous High Power and High Energy Density Wu, Qiyuan; Quilty, Calvin D.; Takeuchi, Kenneth J. MRS Advances, Vol. 3, Issue 22 https://doi.org/10.1557/adv.2018.325	journal	January 2018
Hydrothermal Synthesis of Nanostructured Vanadium Oxides Livage, Jacques Materials, Vol. 3, Issue 8 https://doi.org/10.3390/ma3084175	journal	August 2010
Mo-doped LiV ₃ O ₈ nanorod-assembled nanosheets as a high performance cathode material for lithium ion batteries Song, Huanqiao; Liu, Yaguang; Zhang, Cuiping Journal of Materials Chemistry A, Vol. 3, Issue 7 https://doi.org/10.1039/C4TA05616G	journal	January 2015
Sol Gel Synthesis of Li ₁₊ _α V ₃ O ₈ . 1. From Precursors to Xerogel Dubarry, Matthieu; Gaubicher, Joël; Guyomard, Dominique Chemistry of Materials, Vol. 17, Issue 9 https://doi.org/10.1021/cm047845k	journal	May 2005
Correlating Lithium Hydroxyl Accumulation with Capacity Retention in V ₂ O ₅ Aerogel Cathodes Wangoh, Linda W.; Huang, Yiqing; Jezorek, Ryan L. ACS Applied Materials & Interfaces, Vol. 8, Issue 18 https://doi.org/10.1021/acsami.6b02759	journal	April 2016
Novel Method for Synthesis of γ-Lithium Vanadium Oxide as Cathode Materials in Lithium Ion Batteries Dai, Jinxiang; Li, Sam F. Y.; Gao, Zhiqiang Chemistry of Materials, Vol. 11, Issue 11 https://doi.org/10.1021/cm9901461	journal	November 1999
Vanadium-based nanostructure materials for secondary lithium battery applications Tan, Hui Teng; Rui, Xianhong; Sun, Wenping Nanoscale, Vol. 7, Issue 35 https://doi.org/10.1039/C5NR04126K	journal	January 2015
Investigation of Structural Evolution of Li _1.1 V ₃ O ₈ by In Situ X-ray Diffraction and Density Functional Theory Calculations Zhang, Qing; Brady, Alexander B.; Pelliccione, Christopher J. Chemistry of Materials, Vol. 29, Issue 5 https://doi.org/10.1021/acs.chemmater.7b00096	journal	February 2017
Electrochemical Properties of Li Metal Batteries with P(PEGMA)-Coated Lithium Trivanadate Cathode and Li Powder Anode Cho, Sung Ho; Hwang, Sun Woo; Kim, Byung Hyuk Journal of Nanoscience and Nanotechnology, Vol. 16, Issue 10 https://doi.org/10.1166/jnn.2016.13204	journal	October 2016
Graphene-nanosheet-wrapped LiV3O8 nanocomposites as high performance cathode materials for rechargeable lithium-ion batteries Wang, Zong-Kai; Shu, Jie; Zhu, Qian-Cheng Journal of Power Sources, Vol. 307 https://doi.org/10.1016/j.jpowsour.2016.01.005	journal	March 2016
Correlating Titania Nanostructured Morphologies with Performance as Anode Materials for Lithium-Ion Batteries Lewis, Crystal S.; Li, Yue Ru; Wang, Lei ACS Sustainable Chemistry & Engineering, Vol. 4, Issue 12 https://doi.org/10.1021/acssuschemeng.6b00763	journal	October 2016
Holy Grails in Chemistry: Investigating and Understanding Fast Electron/Cation Coupled Transport within Inorganic Ionic Matrices Smith, Paul F.; Takeuchi, Kenneth J.; Marschilok, Amy C. Accounts of Chemical Research, Vol. 50, Issue 3 https://doi.org/10.1021/acs.accounts.6b00540	journal	March 2017
An amorphous wrapped nanorod LiV3O8 electrode with enhanced performance for lithium ion batteries Shi, Qian; Liu, Jiangwen; Hu, Renzong RSC Advances, Vol. 2, Issue 18 https://doi.org/10.1039/c2ra20769a	journal	January 2012

Similar Records

Crystal Chemistry of Electrochemically and Chemically Lithiated Layered α_I-LiVOPO₄

Journal Article · Mon Sep 14 00:00:00 EDT 2015 · Chemistry of Materials · OSTI ID:1503509

He, Guang; Bridges, Craig A.; Manthiram, Arumugam

CTAB-assisted sol-gel synthesis of Li{sub 4}Ti{sub 5}O{sub 12} and its performance as anode material for Li-ion batteries

Journal Article · Fri Jul 15 00:00:00 EDT 2011 · Materials Research Bulletin · OSTI ID:1503509

Prakash, A. S.; Ramesha, K.; Sathiya, M.

Co-sputtering of lithium vanadium oxide thin films with variable lithium content to enable advanced solid-state batteries

Journal Article · Mon May 23 00:00:00 EDT 2022 · Journal of Materials Chemistry. A · OSTI ID:1503509

Ferrari, Victoria C.; Kim, Nam S.; Lee, Sang Bok; +2 more

Related Subjects

25 ENERGY STORAGE
batteries - lithium
energy storage
battery
lithium vanadium oxide
solvothermal

Title: Impact of Synthesis Method on Phase Transformations of Layered Lithium Vanadium Oxide upon Electrochemical (De)lithiation

Citation Formats

References (36)

Similar Records

Related Subjects