Probing enhanced lithium-ion transport kinetics in 2D holey nanoarchitectured electrodes
Abstract
Nanostructuring has been proved effective towards improving many energy storage and conversion devices, and is feasible for a wide range of materials. In particular, secondary nanoarchitectured materials exhibit collective advantages compared with nano-sized primary building blocks. Despite the manifold efforts in designed nanoarchitectures and synthetic routes, the underlying ion diffusion kinetics and phase transformation behaviours within nanoarchitectures still remain less explored. Herein, we probed enhanced lithium-ion transport behaviours using 2D holey zinc ferrite (ZFO) nanosheets as a model material, to demonstrate how self-assembled 2D holey nanoarchitectured electrodes can feature efficient ion diffusion channels, robust yet continuous electron transfer framework, and enlarged surface area, contributing to the superior performance over the ZFO nanoparticles without secondary structures. By revealing kinetic parameters through combined spectroscopic measurements and electrochemical techniques, our study manifests increased lithium-ion diffusion coefficients, higher capacitive charge storage contribution and reduced charge transfer impedance in holey nanosheets compared to randomly aggregated nanoparticles. Furthermore, our results promote deeper understanding of significantly enhanced electrochemical energy storage properties of these 2D holey nanoarchitectured electrodes resulted from more uniform and complete phase transformation and better active material utilization.
- Authors:
-
- Univ. of Texas at Austin, Austin, TX (United States)
- SUNY-Stony Brook Univ., Stony Brook, NY (United States)
- Univ. of Pennsylvania, Philadelphia, PA (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- SUNY-Stony Brook Univ., Stony Brook, NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2mt); Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1498276
- Report Number(s):
- BNL-211322-2019-JAAM
Journal ID: ISSN 2399-1984
- Grant/Contract Number:
- SC0012704
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Nano Futures
- Additional Journal Information:
- Journal Volume: 2; Journal Issue: 3; Journal ID: ISSN 2399-1984
- Publisher:
- IOP Science
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; Li-ion battery; transport kinetics; nanostructuring; 2D holey nanosheet; energy storage
Citation Formats
Zhang, Xiao, Bruck, Andrea M., Zhu, Yue, Peng, Lele, Li, Jing, Stach, Eric, Zhu, Yimei, Takeuchi, Kenneth J., Takeuchi, Esther S., Marschilok, Amy C., and Yu, Guihua. Probing enhanced lithium-ion transport kinetics in 2D holey nanoarchitectured electrodes. United States: N. p., 2018.
Web. doi:10.1088/2399-1984/aada90.
Zhang, Xiao, Bruck, Andrea M., Zhu, Yue, Peng, Lele, Li, Jing, Stach, Eric, Zhu, Yimei, Takeuchi, Kenneth J., Takeuchi, Esther S., Marschilok, Amy C., & Yu, Guihua. Probing enhanced lithium-ion transport kinetics in 2D holey nanoarchitectured electrodes. United States. https://doi.org/10.1088/2399-1984/aada90
Zhang, Xiao, Bruck, Andrea M., Zhu, Yue, Peng, Lele, Li, Jing, Stach, Eric, Zhu, Yimei, Takeuchi, Kenneth J., Takeuchi, Esther S., Marschilok, Amy C., and Yu, Guihua. 2018.
"Probing enhanced lithium-ion transport kinetics in 2D holey nanoarchitectured electrodes". United States. https://doi.org/10.1088/2399-1984/aada90. https://www.osti.gov/servlets/purl/1498276.
@article{osti_1498276,
title = {Probing enhanced lithium-ion transport kinetics in 2D holey nanoarchitectured electrodes},
author = {Zhang, Xiao and Bruck, Andrea M. and Zhu, Yue and Peng, Lele and Li, Jing and Stach, Eric and Zhu, Yimei and Takeuchi, Kenneth J. and Takeuchi, Esther S. and Marschilok, Amy C. and Yu, Guihua},
abstractNote = {Nanostructuring has been proved effective towards improving many energy storage and conversion devices, and is feasible for a wide range of materials. In particular, secondary nanoarchitectured materials exhibit collective advantages compared with nano-sized primary building blocks. Despite the manifold efforts in designed nanoarchitectures and synthetic routes, the underlying ion diffusion kinetics and phase transformation behaviours within nanoarchitectures still remain less explored. Herein, we probed enhanced lithium-ion transport behaviours using 2D holey zinc ferrite (ZFO) nanosheets as a model material, to demonstrate how self-assembled 2D holey nanoarchitectured electrodes can feature efficient ion diffusion channels, robust yet continuous electron transfer framework, and enlarged surface area, contributing to the superior performance over the ZFO nanoparticles without secondary structures. By revealing kinetic parameters through combined spectroscopic measurements and electrochemical techniques, our study manifests increased lithium-ion diffusion coefficients, higher capacitive charge storage contribution and reduced charge transfer impedance in holey nanosheets compared to randomly aggregated nanoparticles. Furthermore, our results promote deeper understanding of significantly enhanced electrochemical energy storage properties of these 2D holey nanoarchitectured electrodes resulted from more uniform and complete phase transformation and better active material utilization.},
doi = {10.1088/2399-1984/aada90},
url = {https://www.osti.gov/biblio/1498276},
journal = {Nano Futures},
issn = {2399-1984},
number = 3,
volume = 2,
place = {United States},
year = {Fri Aug 31 00:00:00 EDT 2018},
month = {Fri Aug 31 00:00:00 EDT 2018}
}
Web of Science
Works referenced in this record:
Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries
journal, September 2000
- Poizot, P.; Laruelle, S.; Grugeon, S.
- Nature, Vol. 407, Issue 6803, p. 496-499
Structural Engineering of 2D Nanomaterials for Energy Storage and Catalysis
journal, February 2018
- Zhu, Yue; Peng, Lele; Fang, Zhiwei
- Advanced Materials, Vol. 30, Issue 15
Metallic Transition Metal Selenide Holey Nanosheets for Efficient Oxygen Evolution Electrocatalysis
journal, September 2017
- Fang, Zhiwei; Peng, Lele; Lv, Haifeng
- ACS Nano, Vol. 11, Issue 9
Lithium diffusivity in antimony-based intermetallic and FeSb–TiC composite anodes as measured by GITT
journal, January 2015
- Allcorn, Eric; Kim, Sang Ok; Manthiram, Arumugam
- Physical Chemistry Chemical Physics, Vol. 17, Issue 43
Mixed Transition-Metal Oxides: Design, Synthesis, and Energy-Related Applications
journal, January 2014
- Yuan, Changzhou; Wu, Hao Bin; Xie, Yi
- Angewandte Chemie International Edition, Vol. 53, Issue 6
Metal Oxides and Oxysalts as Anode Materials for Li Ion Batteries
journal, March 2013
- Reddy, M. V.; Subba Rao, G. V.; Chowdari, B. V. R.
- Chemical Reviews, Vol. 113, Issue 7
Probing the Li Insertion Mechanism of ZnFe 2 O 4 in Li-Ion Batteries: A Combined X-Ray Diffraction, Extended X-Ray Absorption Fine Structure, and Density Functional Theory Study
journal, May 2017
- Zhang, Yiman; Pelliccione, Christopher J.; Brady, Alexander B.
- Chemistry of Materials, Vol. 29, Issue 10
Pseudocapacitive oxide materials for high-rate electrochemical energy storage
journal, January 2014
- Augustyn, Veronica; Simon, Patrice; Dunn, Bruce
- Energy & Environmental Science, Vol. 7, Issue 5
Insight into Lithium Diffusion in Conversion-Type Iron Oxide Negative Electrode
journal, December 2014
- Tian, Bingbing; Światowska, Jolanta; Maurice, Vincent
- The Journal of Physical Chemistry C, Vol. 119, Issue 2
Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide
journal, June 2007
- Stankovich, Sasha; Dikin, Dmitriy A.; Piner, Richard D.
- Carbon, Vol. 45, Issue 7, p. 1558-1565
Recent Developments and Understanding of Novel Mixed Transition-Metal Oxides as Anodes in Lithium Ion Batteries
journal, February 2016
- Zhao, Yang; Li, Xifei; Yan, Bo
- Advanced Energy Materials, Vol. 6, Issue 8
Probing the Additional Capacity and Reaction Mechanism of the RuO 2 Anode in Lithium Rechargeable Batteries
journal, June 2015
- Kim, Yunok; Muhammad, Shoaib; Kim, Hyunchul
- ChemSusChem, Vol. 8, Issue 14
Insights into Ionic Transport and Structural Changes in Magnetite during Multiple-Electron Transfer Reactions
journal, March 2016
- Zhang, Wei; Bock, David C.; Pelliccione, Christopher J.
- Advanced Energy Materials, Vol. 6, Issue 10
High-Quality Metal Oxide Core/Shell Nanowire Arrays on Conductive Substrates for Electrochemical Energy Storage
journal, May 2012
- Xia, Xinhui; Tu, Jiangping; Zhang, Yongqi
- ACS Nano, Vol. 6, Issue 6
Determination of the Kinetic Parameters of Mixed-Conducting Electrodes and Application to the System Li[sub 3]Sb
journal, January 1977
- Weppner, W.
- Journal of The Electrochemical Society, Vol. 124, Issue 10
Visualization and Quantification of Electrochemical and Mechanical Degradation in Li Ion Batteries
journal, October 2013
- Ebner, M.; Marone, F.; Stampanoni, M.
- Science, Vol. 342, Issue 6159
Self-assembled porous MoO2/graphene microspheres towards high performance anodes for lithium ion batteries
journal, February 2015
- Palanisamy, Kowsalya; Kim, Yunok; Kim, Hansu
- Journal of Power Sources, Vol. 275
High-rate electrochemical energy storage through Li+ intercalation pseudocapacitance
journal, April 2013
- Augustyn, Veronica; Come, Jérémy; Lowe, Michael A.
- Nature Materials, Vol. 12, Issue 6
Conversion Reaction-Based Oxide Nanomaterials for Lithium Ion Battery Anodes
journal, December 2015
- Yu, Seung-Ho; Lee, Soo Hong; Lee, Dong Jun
- Small, Vol. 12, Issue 16
Dual Tuning of Ni–Co–A (A = P, Se, O) Nanosheets by Anion Substitution and Holey Engineering for Efficient Hydrogen Evolution
journal, April 2018
- Fang, Zhiwei; Peng, Lele; Qian, Yumin
- Journal of the American Chemical Society, Vol. 140, Issue 15
Two-Dimensional Holey Nanoarchitectures Created by Confined Self-Assembly of Nanoparticles via Block Copolymers: From Synthesis to Energy Storage Property
journal, December 2017
- Peng, Lele; Fang, Zhiwei; Li, Jing
- ACS Nano, Vol. 12, Issue 1
Nanostructured materials for advanced energy conversion and storage devices
journal, May 2005
- Aricò, Antonino Salvatore; Bruce, Peter; Scrosati, Bruno
- Nature Materials, Vol. 4, Issue 5, p. 366-377
Construction of Complex Co 3 O 4 @Co 3 V 2 O 8 Hollow Structures from Metal-Organic Frameworks with Enhanced Lithium Storage Properties
journal, November 2017
- Lu, Yan; Yu, Le; Wu, Minghong
- Advanced Materials, Vol. 30, Issue 1
Ultrathin-Nanosheet-Induced Synthesis of 3D Transition Metal Oxides Networks for Lithium Ion Battery Anodes
journal, January 2017
- Zhu, Shan; Li, Jiajun; Deng, Xiaoyang
- Advanced Functional Materials, Vol. 27, Issue 9
Multidimensional materials and device architectures for future hybrid energy storage
journal, September 2016
- Lukatskaya, Maria R.; Dunn, Bruce; Gogotsi, Yury
- Nature Communications, Vol. 7, Issue 1
Conductive porous vanadium nitride/graphene composite as chemical anchor of polysulfides for lithium-sulfur batteries
journal, March 2017
- Sun, Zhenhua; Zhang, Jingqi; Yin, Lichang
- Nature Communications, Vol. 8, Issue 1
α-Fe2O3/single-walled carbon nanotube hybrid films as high-performance anodes for rechargeable lithium-ion batteries
journal, November 2013
- Cao, Zeyuan; Wei, Bingqing
- Journal of Power Sources, Vol. 241
Intercalation Pseudocapacitance in Ultrathin VOPO 4 Nanosheets: Toward High-Rate Alkali-Ion-Based Electrochemical Energy Storage
journal, December 2015
- Zhu, Yue; Peng, Lele; Chen, Dahong
- Nano Letters, Vol. 16, Issue 1
Three-Dimensional Architectures Constructed from Transition-Metal Dichalcogenide Nanomaterials for Electrochemical Energy Storage and Conversion
journal, December 2017
- Yun, Qinbai; Lu, Qipeng; Zhang, Xiao
- Angewandte Chemie International Edition, Vol. 57, Issue 3
General Facet-Controlled Synthesis of Single-Crystalline {010}-Oriented LiMPO 4 (M = Mn, Fe, Co) Nanosheets
journal, November 2017
- Peng, Lele; Zhang, Xiao; Fang, Zhiwei
- Chemistry of Materials, Vol. 29, Issue 24
Revealing the Conversion Mechanism of Transition Metal Oxide Electrodes during Lithiation from First-Principles
journal, October 2017
- Yao, Zhenpeng; Kim, Soo; Aykol, Muratahan
- Chemistry of Materials, Vol. 29, Issue 21
Holey two-dimensional transition metal oxide nanosheets for efficient energy storage
journal, April 2017
- Peng, Lele; Xiong, Pan; Ma, Lu
- Nature Communications, Vol. 8, Issue 1
Hierarchical Structures Based on Two-Dimensional Nanomaterials for Rechargeable Lithium Batteries
journal, January 2017
- Cong, Lina; Xie, Haiming; Li, Jinghong
- Advanced Energy Materials, Vol. 7, Issue 12
Holy Grails in Chemistry: Investigating and Understanding Fast Electron/Cation Coupled Transport within Inorganic Ionic Matrices
journal, March 2017
- Smith, Paul F.; Takeuchi, Kenneth J.; Marschilok, Amy C.
- Accounts of Chemical Research, Vol. 50, Issue 3
Investigating the Complex Chemistry of Functional Energy Storage Systems: The Need for an Integrative, Multiscale (Molecular to Mesoscale) Perspective
journal, April 2016
- Abraham, Alyson; Housel, Lisa M.; Lininger, Christianna N.
- ACS Central Science, Vol. 2, Issue 6
Holey 2D Nanomaterials for Electrochemical Energy Storage
journal, December 2017
- Peng, Lele; Fang, Zhiwei; Zhu, Yue
- Advanced Energy Materials, Vol. 8, Issue 9
Morphology-controlled hydrothermal synthesis of acanthosphere FeCO3 as an excellent performance anode material for lithium ion batteries
journal, September 2016
- Feng, Xiaoyu; Shen, Qiang; Shi, Yuanchang
- Ceramics International, Vol. 42, Issue 12
New approaches to the lithiation kinetics in reaction-limited battery electrodes through electrochemical impedance spectroscopy
journal, January 2018
- Vicente, Nuria; Haro, Marta; Garcia-Belmonte, Germà
- Chemical Communications, Vol. 54, Issue 9
Size dependent behavior of Fe 3 O 4 crystals during electrochemical (de)lithiation: an in situ X-ray diffraction, ex situ X-ray absorption spectroscopy, transmission electron microscopy and theoretical investigation
journal, January 2017
- Bock, David C.; Pelliccione, Christopher J.; Zhang, Wei
- Physical Chemistry Chemical Physics, Vol. 19, Issue 31
EIS and GITT studies on oxide cathodes, O2-Li(2/3)+x(Co0.15Mn0.85)O2 (x=0 and 1/3)
journal, August 2003
- Shaju, K. M.; Subba Rao, G. V.; Chowdari, B. V. R.
- Electrochimica Acta, Vol. 48, Issue 18, p. 2691-2703
Nanocrystalline iron oxide based electroactive materials in lithium ion batteries: the critical role of crystallite size, morphology, and electrode heterostructure on battery relevant electrochemistry
journal, January 2016
- Bruck, Andrea M.; Cama, Christina A.; Gannett, Cara N.
- Inorganic Chemistry Frontiers, Vol. 3, Issue 1
A first principles study of spinel ZnFe 2 O 4 for electrode materials in lithium-ion batteries
journal, January 2017
- Guo, Haoyue; Zhang, Yiman; Marschilok, Amy C.
- Physical Chemistry Chemical Physics, Vol. 19, Issue 38
Works referencing / citing this record:
Ultrafast Intercalation Enabled by Strong Solvent–Host Interactions: Understanding Solvent Effect at the Atomic Level
journal, November 2019
- Zhu, Yue; Ji, Yujin; Ju, Zhengyu
- Angewandte Chemie, Vol. 131, Issue 48
Evaporation‐Induced Vertical Alignment Enabling Directional Ion Transport in a 2D‐Nanosheet‐Based Battery Electrode
journal, January 2020
- Zhu, Yue; Ju, Zhengyu; Zhang, Xiao
- Advanced Materials, Vol. 32, Issue 10
Ultrafast Intercalation Enabled by Strong Solvent-Host Interactions: Understanding Solvent Effect at the Atomic Level
journal, October 2019
- Zhu, Yue; Ji, Yujin; Ju, Zhengyu
- Angewandte Chemie International Edition, Vol. 58, Issue 48