Hyperelastic binder for printed, stretchable electronics

Wang, Joseph; Kumar, Rajan; Meng, Ying Shirley; Shin, Jae Wook; Yin, Lu

Title: Hyperelastic binder for printed, stretchable electronics

Patent · Tue Nov 27 00:00:00 EST 2018

OSTI ID:1495043

Wang, Joseph; Kumar, Rajan; Meng, Ying Shirley; Shin, Jae Wook; Yin, Lu

Disclosed are compositions, devices, systems and fabrication methods for stretchable composite materials and stretchable electronics devices. In some aspects, an elastic composite material for a stretchable electronics device includes a first material having a particular electrical, mechanical or optical property; and a multi-block copolymer configured to form a hyperelastic binder that creates contact between the first material and the multi-block copolymer, in which the elastic composite material is structured to stretch at least 500% in at least one direction of the material and to exhibit the particular electrical, mechanical or optical property imparted from the first material. In some aspects, the stretchable electronics device includes a stretchable battery, biofuel cell, sensor, supercapacitor or other device able to be mounted to skin, clothing or other surface of a user or object.

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Research Organization:: Univ. of California, Oakland, CA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AR0000535

Assignee:: The Regents of the University of California (Oakland, CA)

Patent Number(s):: 10,143,081

Application Number:: 15/820,284

OSTI ID:: 1495043

Resource Relation:: Patent File Date: 2017 Nov 21

Country of Publication:: United States

Language:: English

References (76)

Highly stretchable electric circuits from a composite material of silver nanoparticles and elastomeric fibres Park, Minwoo; Im, Jungkyun; Shin, Minkwan Nature Nanotechnology, Vol. 7, Issue 12 https://doi.org/10.1038/nnano.2012.206	journal	November 2012
Flexible and Stretchable Electronics Paving the Way for Soft Robotics Lu, Nanshu; Kim, Dae-Hyeong Soft Robotics, Vol. 1, Issue 1 https://doi.org/10.1089/soro.2013.0005	journal	March 2014
Soft Conductive Elastomer Materials for Stretchable Electronics and Voltage Controlled Artificial Muscles Stoyanov, Hristiyan; Kollosche, Matthias; Risse, Sebastian Advanced Materials, Vol. 25, Issue 4 https://doi.org/10.1002/adma.201202728	journal	October 2012
Materials and Fractal Designs for 3D Multifunctional Integumentary Membranes with Capabilities in Cardiac Electrotherapy Xu, Lizhi; Gutbrod, Sarah R.; Ma, Yinji Advanced Materials, Vol. 27, Issue 10 https://doi.org/10.1002/adma.201405017	journal	January 2015
Conductive Nanomaterials for Printed Electronics Kamyshny, Alexander; Magdassi, Shlomo Small, Vol. 10, Issue 17 https://doi.org/10.1002/smll.201303000	journal	January 2014
Stretchable GaAs Photovoltaics with Designs That Enable High Areal Coverage Lee, Jongho; Wu, Jian; Shi, Mingxing Advanced Materials, Vol. 23, Issue 8 https://doi.org/10.1002/adma.201003961	journal	January 2011
Printable elastic conductors by in situ formation of silver nanoparticles from silver flakes Matsuhisa, Naoji; Inoue, Daishi; Zalar, Peter Nature Materials, Vol. 16, Issue 8 https://doi.org/10.1038/nmat4904	journal	May 2017
All‐Printed Stretchable Electrochemical Devices Bandodkar, Amay J.; Nuñez‐Flores, Rogelio; Jia, Wenzhao Advanced Materials, Vol. 27, Issue 19 https://doi.org/10.1002/adma.201500768	journal	April 2015
Stretchable batteries with self-similar serpentine interconnects and integrated wireless recharging systems Xu, Sheng; Zhang, Yihui; Cho, Jiung Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms2553	journal	February 2013
Balloon-Embedded Sensors Withstanding Extreme Multiaxial Stretching and Global Bending Mechanical Stress: Towards Environmental and Security Monitoring Cánovas, Rocío; Parrilla, Marc; Mercier, Patrick Advanced Materials Technologies, Vol. 1, Issue 5 https://doi.org/10.1002/admt.201600061	journal	May 2016
Intrinsically stretchable and rechargeable batteries for self-powered stretchable electronics Kettlgruber, Gerald; Kaltenbrunner, Martin; Siket, Christian M. Journal of Materials Chemistry A, Vol. 1, Issue 18 https://doi.org/10.1039/c3ta00019b	journal	January 2013
Soft, stretchable, fully implantable miniaturized optoelectronic systems for wireless optogenetics Park, Sung Il; Brenner, Daniel S.; Shin, Gunchul Nature Biotechnology, Vol. 33, Issue 12 https://doi.org/10.1038/nbt.3415	journal	November 2015
Photo-oxidative enhancement of polymeric molecular sieve membranes Song, Qilei; Cao, Shuai; Zavala-Rivera, Paul Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms2942	journal	May 2013
Ultraflexible organic photonic skin Yokota, Tomoyuki; Zalar, Peter; Kaltenbrunner, Martin Science Advances, Vol. 2, Issue 4 https://doi.org/10.1126/sciadv.1501856	journal	April 2016
Kirigami-based stretchable lithium-ion batteries Song, Zeming; Wang, Xu; Lv, Cheng Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep10988	journal	June 2015
Elastomeric polymer light-emitting devices and displays Liang, Jiajie; Li, Lu; Niu, Xiaofan Nature Photonics, Vol. 7, Issue 10 https://doi.org/10.1038/nphoton.2013.242	journal	September 2013
Wearable Electricity Generators Fabricated Utilizing Transparent Electronic Textiles Based on Polyester/Ag Nanowires/Graphene Core–Shell Nanocomposites Wu, Chaoxing; Kim, Tae Whan; Li, Fushan ACS Nano, Vol. 10, Issue 7 https://doi.org/10.1021/acsnano.5b08137	journal	June 2016
An epidermal alkaline rechargeable Ag–Zn printable tattoo battery for wearable electronics Berchmans, Sheela; Bandodkar, Amay J.; Jia, Wenzhao J. Mater. Chem. A, Vol. 2, Issue 38 https://doi.org/10.1039/C4TA03256J	journal	January 2014
Wearable Flexible and Stretchable Glove Biosensor for On-Site Detection of Organophosphorus Chemical Threats Mishra, Rupesh K.; Hubble, Lee J.; Martín, Aida ACS Sensors, Vol. 2, Issue 4 https://doi.org/10.1021/acssensors.7b00051	journal	March 2017
A wearable chemical–electrophysiological hybrid biosensing system for real-time health and fitness monitoring Imani, Somayeh; Bandodkar, Amay J.; Mohan, A. M. Vinu Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11650	journal	May 2016
Mechanics of ultra-stretchable self-similar serpentine interconnects Zhang, Yihui; Fu, Haoran; Su, Yewang Acta Materialia, Vol. 61, Issue 20, p. 7816-7827 https://doi.org/10.1016/j.actamat.2013.09.020	journal	December 2013
Highly Flexible, Printed Alkaline Batteries Based on Mesh-Embedded Electrodes Gaikwad, Abhinav M.; Whiting, Gregory L.; Steingart, Daniel A. Advanced Materials, Vol. 23, Issue 29 https://doi.org/10.1002/adma.201100894	journal	June 2011
Two-dimensional digital image correlation for in-plane displacement and strain measurement: a review Pan, Bing; Qian, Kemao; Xie, Huimin Measurement Science and Technology, Vol. 20, Issue 6 https://doi.org/10.1088/0957-0233/20/6/062001	journal	April 2009
Free-standing nanocomposites with high conductivity and extensibility Chun, Kyoung-Yong; Kim, Shi Hyeong; Shin, Min Kyoon Nanotechnology, Vol. 24, Issue 16 https://doi.org/10.1088/0957-4484/24/16/165401	journal	March 2013
Stretchable biofuel cells as wearable textile-based self-powered sensors Jeerapan, Itthipon; Sempionatto, Juliane R.; Pavinatto, Adriana Journal of Materials Chemistry A, Vol. 4, Issue 47 https://doi.org/10.1039/C6TA08358G	journal	January 2016
Highly Stretchable Alkaline Batteries Based on an Embedded Conductive Fabric Gaikwad, Abhinav M.; Zamarayeva, Alla M.; Rousseau, Jamesley Advanced Materials, Vol. 24, Issue 37, p. 5071-5076 https://doi.org/10.1002/adma.201201329	journal	July 2012
Printable elastic conductors with a high conductivity for electronic textile applications Matsuhisa, Naoji; Kaltenbrunner, Martin; Yokota, Tomoyuki Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8461	journal	June 2015
Fractal design concepts for stretchable electronics Fan, Jonathan A.; Yeo, Woon-Hong; Su, Yewang Nature Communications, Vol. 5, Article No. 3266 (2014) https://doi.org/10.1038/ncomms4266	journal	February 2014
Wearable Fall Detector using Integrated Sensors and Energy Devices Jung, Sungmook; Hong, Seungki; Kim, Jaemin Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep17081	journal	November 2015
Flexible battery Lim, James Robert; Yeh, Yuting; Vaknine, Erik Avy https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/9502734 US Patent Document 9,502,734	patent	November 2016
A Wearable Electrochemical Platform for Noninvasive Simultaneous Monitoring of Ca ²⁺ and pH Nyein, Hnin Yin Yin; Gao, Wei; Shahpar, Ziba ACS Nano, Vol. 10, Issue 7 https://doi.org/10.1021/acsnano.6b04005	journal	July 2016
On-Demand Separation of Oil-Water Mixtures Kwon, Gibum; Kota, Arun. K.; Li, Yongxin Advanced Materials, Vol. 24, Issue 27 https://doi.org/10.1002/adma.201201364	journal	June 2012
Multiphase design of autonomic self-healing thermoplastic elastomers Chen, Yulin; Kushner, Aaron M.; Williams, Gregory A. Nature Chemistry, Vol. 4, Issue 6 https://doi.org/10.1038/nchem.1314	journal	April 2012
Tattoo-based potentiometric ion-selective sensors for epidermal pH monitoring Bandodkar, Amay J.; Hung, Vinci W. S.; Jia, Wenzhao The Analyst, Vol. 138, Issue 1 https://doi.org/10.1039/C2AN36422K	journal	January 2013
Multifunctional wearable devices for diagnosis and therapy of movement disorders Son, Donghee; Lee, Jongha; Qiao, Shutao Nature Nanotechnology, Vol. 9, Issue 5 https://doi.org/10.1038/nnano.2014.38	journal	March 2014
“Cut-and-Paste” Manufacture of Multiparametric Epidermal Sensor Systems Yang, Shixuan; Chen, Ying-Chen; Nicolini, Luke Advanced Materials, Vol. 27, Issue 41 https://doi.org/10.1002/adma.201502386	journal	September 2015
3D Printing of Highly Stretchable and Tough Hydrogels into Complex, Cellularized Structures Hong, Sungmin; Sycks, Dalton; Chan, Hon Fai Advanced Materials, Vol. 27, Issue 27 https://doi.org/10.1002/adma.201501099	journal	June 2015
Wearable Chemical Sensors: Present Challenges and Future Prospects Bandodkar, Amay J.; Jeerapan, Itthipon; Wang, Joseph ACS Sensors, Vol. 1, Issue 5 https://doi.org/10.1021/acssensors.6b00250	journal	March 2016
Recent Progress on Stretchable Electronic Devices with Intrinsically Stretchable Components Trung, Tran Quang; Lee, Nae-Eung Advanced Materials, Vol. 29, Issue 3, Article No. 1603167 https://doi.org/10.1002/adma.201603167	journal	November 2016
Stretchable Electronics: Materials Strategies and Devices Kim, Dae-Hyeong; Rogers, John A. Advanced Materials, Vol. 20, Issue 24, p. 4887-4892 https://doi.org/10.1002/adma.200801788	journal	December 2008
Stretchable Silver-Zinc Batteries Based on Embedded Nanowire Elastic Conductors Yan, Chaoyi; Wang, Xu; Cui, Mengqi Advanced Energy Materials, Vol. 4, Issue 5 https://doi.org/10.1002/aenm.201301396	journal	October 2013
All-Graphene Core-Sheath Microfibers for All-Solid-State, Stretchable Fibriform Supercapacitors and Wearable Electronic Textiles Meng, Yuning; Zhao, Yang; Hu, Chuangang Advanced Materials, Vol. 25, Issue 16 https://doi.org/10.1002/adma.201300132	journal	March 2013
Highly elastic binders integrating polyrotaxanes for silicon microparticle anodes in lithium ion batteries Choi, Sunghun; Kwon, Tae-woo; Coskun, Ali Science, Vol. 357, Issue 6348 https://doi.org/10.1126/science.aal4373	journal	July 2017
ABA triblock and diblock copolymers and methods of preparing the same Grubbs, Robert H.; Bielawski, Christopher W. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6410666 US Patent Document 6,410,666	patent	June 2002
Advances and Future Challenges in Printed Batteries Sousa, Ricardo E.; Costa, Carlos M.; Lanceros-Méndez, Senentxu ChemSusChem, Vol. 8, Issue 21 https://doi.org/10.1002/cssc.201500657	journal	September 2015
Smart bandage with wireless connectivity for uric acid biosensing as an indicator of wound status Kassal, Petar; Kim, Jayoung; Kumar, Rajan Electrochemistry Communications, Vol. 56 https://doi.org/10.1016/j.elecom.2015.03.018	journal	July 2015
All-Printed, Stretchable Zn-Ag ₂ O Rechargeable Battery via Hyperelastic Binder for Self-Powering Wearable Electronics Kumar, Rajan; Shin, Jaewook; Yin, Lu Advanced Energy Materials, Vol. 7, Issue 8 https://doi.org/10.1002/aenm.201602096	journal	December 2016
Advanced Materials for Printed Wearable Electrochemical Devices: A Review Kim, Jayoung; Kumar, Rajan; Bandodkar, Amay J. Advanced Electronic Materials, Vol. 3, Issue 1 https://doi.org/10.1002/aelm.201600260	journal	December 2016
Cable-Type Flexible Lithium Ion Battery Based on Hollow Multi-Helix Electrodes Kwon, Yo Han; Woo, Sang-Wook; Jung, Hye-Ran Advanced Materials, Vol. 24, Issue 38 https://doi.org/10.1002/adma.201202196	journal	August 2012
Stretchable Conductor, Method for Manufacturing Same, and Paste for Forming Stretchable Conductor Sekitani, Tsuyoshi; Someya, Takao; Matsuhisa, Naoji https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20170169914 US Patent Application 15/115974; 20170169914	patent-application	June 2017
Materials and Designs for Wireless Epidermal Sensors of Hydration and Strain Huang, Xian; Liu, Yuhao; Cheng, Huanyu Advanced Functional Materials, Vol. 24, Issue 25 https://doi.org/10.1002/adfm.201303886	journal	March 2014
Encapsulated, High-Performance, Stretchable Array of Stacked Planar Micro-Supercapacitors as Waterproof Wearable Energy Storage Devices Kim, Hyoungjun; Yoon, Jangyeol; Lee, Geumbee ACS Applied Materials & Interfaces, Vol. 8, Issue 25 https://doi.org/10.1021/acsami.6b03504	journal	June 2016
Stretchable and High-Performance Supercapacitors with Crumpled Graphene Papers Zang, Jianfeng; Cao, Changyong; Feng, Yaying Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep06492	journal	October 2014
An Effective Mixing for Lithium Ion Battery Slurries Liu, Darjen; Chen, Li-Chun; Liu, Ta-Jo Advances in Chemical Engineering and Science, Vol. 04, Issue 04 https://doi.org/10.4236/aces.2014.44053	journal	January 2014
Merging of Thin- and Thick-Film Fabrication Technologies: Toward Soft Stretchable “Island-Bridge” Devices Mohan, A. M. Vinu; Kim, NamHeon; Gu, Yue Advanced Materials Technologies, Vol. 2, Issue 4 https://doi.org/10.1002/admt.201600284	journal	February 2017
Stretchable Figures of Merit in Deformable Electronics Lipomi, Darren J. Advanced Materials, Vol. 28, Issue 22 https://doi.org/10.1002/adma.201504196	journal	November 2015
Fabrication of a High-Performance Flexible Silver-Zinc Wire Battery Zamarayeva, Alla M.; Gaikwad, Abhinav M.; Deckman, Igal Advanced Electronic Materials, Vol. 2, Issue 5 https://doi.org/10.1002/aelm.201500296	journal	March 2016
Direct Pen Writing of Adhesive Particle-Free Ultrahigh Silver Salt-Loaded Composite Ink for Stretchable Circuits Hu, Mingjun; Cai, Xiaobing; Guo, Qiuquan ACS Nano, Vol. 10, Issue 1 https://doi.org/10.1021/acsnano.5b05082	journal	December 2015
Deposition of ZnO on bismuth species towards a rechargeable Zn-based aqueous battery Shin, JaeWook; You, Jung-Min; Lee, Jungwoo Z. Physical Chemistry Chemical Physics, Vol. 18, Issue 38 https://doi.org/10.1039/C6CP04566A	journal	January 2016
Stretchable Organic Solar Cells Lipomi, Darren J.; Tee, Benjamin C. -K.; Vosgueritchian, Michael Advanced Materials, Vol. 23, Issue 15 https://doi.org/10.1002/adma.201004426	journal	February 2011
An analytical mechanics model for the island-bridge structure of stretchable electronics Li, Rui; Li, Ming; Su, Yewang Soft Matter, Vol. 9, Issue 35 https://doi.org/10.1039/c3sm51476e	journal	January 2013
In-Plane Deformation Mechanics for Highly Stretchable Electronics Su, Yewang; Ping, Xuecheng; Yu, Ki Jun Advanced Materials, Vol. 29, Issue 8 https://doi.org/10.1002/adma.201604989	journal	December 2016
Tattoo-Based Noninvasive Glucose Monitoring: A Proof-of-Concept Study Bandodkar, Amay J.; Jia, Wenzhao; Yardımcı, Ceren Analytical Chemistry, Vol. 87, Issue 1 https://doi.org/10.1021/ac504300n	journal	December 2014
A hierarchical computational model for stretchable interconnects with fractal-inspired designs Zhang, Yihui; Fu, Haoran; Xu, Sheng Journal of the Mechanics and Physics of Solids, Vol. 72 https://doi.org/10.1016/j.jmps.2014.07.011	journal	December 2014
Flexible Transducer Takahashi, Wataru; Yoshikawa, Hitoshi; Takamatsu, Shigeaki https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20150202656 US Patent Application 14/674231; 20150202656	patent-application	July 2015
A graphene-based electrochemical device with thermoresponsive microneedles for diabetes monitoring and therapy Lee, Hyunjae; Choi, Tae Kyu; Lee, Young Bum Nature Nanotechnology, Vol. 11, Issue 6 https://doi.org/10.1038/nnano.2016.38	journal	March 2016
A highly stretchable, transparent, and conductive polymer Wang, Yue; Zhu, Chenxin; Pfattner, Raphael Science Advances, Vol. 3, Issue 3 https://doi.org/10.1126/sciadv.1602076	journal	March 2017
Design of conductive composite elastomers for stretchable electronics Park, Minwoo; Park, Jaeyoon; Jeong, Unyong Nano Today, Vol. 9, Issue 2 https://doi.org/10.1016/j.nantod.2014.04.009	journal	April 2014
Highly Stretchable Fully-Printed CNT-Based Electrochemical Sensors and Biofuel Cells: Combining Intrinsic and Design-Induced Stretchability Bandodkar, Amay J.; Jeerapan, Itthipon; You, Jung-Min Nano Letters, Vol. 16, Issue 1 https://doi.org/10.1021/acs.nanolett.5b04549	journal	December 2015
Toward a Stretchable, Elastic, and Electrically Conductive Nanocomposite: Morphology and Properties of Poly[styrene- b- (ethylene- co -butylene)- b -styrene]/Multiwalled Carbon Nanotube Composites Fabricated by High-Shear Processing Li, Yongjin; Shimizu, Hiroshi Macromolecules, Vol. 42, Issue 7, p. 2587-2593 https://doi.org/10.1021/ma802662c	journal	April 2009
Recent developments and directions in printed nanomaterials Choi, Hyung Woo; Zhou, Tianlei; Singh, Madhusudan Nanoscale, Vol. 7, Issue 8 https://doi.org/10.1039/C4NR03915G	journal	January 2015
Stretchable, Skin-Mountable, and Wearable Strain Sensors and Their Potential Applications: A Review Amjadi, Morteza; Kyung, Ki-Uk; Park, Inkyu Advanced Functional Materials, Vol. 26, Issue 11 https://doi.org/10.1002/adfm.201504755	journal	February 2016
Stretchable Thermoelectric Material and Thermoelectric Device Including the Same Baik, Seunghyun; Suh, Daewoo; Lee, Dongmok https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20150342523 US Patent Application 14/724220; 20150342523	patent-application	December 2015
Stretchable Conductive Nanofibers, Stretchable Electrode Using the Same and Method of Producing the Stretchable Conductive Nanofibers Park, Jong-Jin; Im, Jung-Kyun; Kim, Sang-Won https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20150235731 US Patent Application 14/679112; 20150235731	patent-application	August 2015
Polythiophene Nanofibril Bundles Surface-Embedded in Elastomer: A Route to a Highly Stretchable Active Channel Layer Shin, Minkwan; Oh, Jin Young; Byun, Kyung-Eun Advanced Materials, Vol. 27, Issue 7 https://doi.org/10.1002/adma.201404602	journal	January 2015
Noninvasive Alcohol Monitoring Using a Wearable Tattoo-Based Iontophoretic-Biosensing System Kim, Jayoung; Jeerapan, Itthipon; Imani, Somayeh ACS Sensors, Vol. 1, Issue 8 https://doi.org/10.1021/acssensors.6b00356	journal	July 2016

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