Empirical profiling of cold hydrogen plumes formed from venting of LH₂ storage vessels

Journal Article · Tue Dec 04 00:00:00 EST 2018 · International Journal of Hydrogen Energy

DOI:https://doi.org/10.1016/j.ijhydene.2018.10.231· OSTI ID:1494733

Buttner, William J.  ^[1]; Ciotti, Michael ^[2]; Hartmann, Kevin ^[1]; Schmidt, Kara ^[1]; Wright, Hannah ^[1]; Weidner, Eveline ^[3]

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1. National Renewable Energy Lab. (NREL), Golden, CO (United States)
2. H2 Fueling and CIP Markets Engineering, Murray Hill, NJ (United States)
3. Joint Research Centre, Petten (Netherlands)

Liquid hydrogen (LH₂) storage is viewed as a viable approach to assure sufficient hydrogen capacity at commercial fuelling stations. Presently, LH₂ is produced at remote facilities and then transported to the end-use site by road vehicles (i.e., LH₂ tanker trucks). Venting of hydrogen to depressurize the transport storage tank is a routine part of the LH₂ delivery and site transfer process. The behavior of cold hydrogen plumes has not been well characterized because of the sparsity of empirical field data, which can lead to overly conservative safety requirements. Committee members of the National Fire Protection Association (NFPA) Standard 2 [1] formed the Hydrogen Storage Safety Task Group, which consists of hydrogen producers, safety experts, and computational fluid dynamics modellers, has identified the lack of understanding of hydrogen dispersion during LH₂ venting of storage vessels as a critical gap for establishing safety distances at LH₂ facilities, especially commercial hydrogen fuelling stations. To address this need, the National Renewable Energy Laboratory Sensor Laboratory, in collaboration with the NFPA Hydrogen Storage Task Group, developed a prototype Cold Hydrogen Plume Analyzer to empirically characterize the hydrogen plume formed during LH₂ storage tank venting. The prototype analyzer was field deployed during an actual LH₂ venting process. Critical findings included: hydrogen above the lower flammable limit (LFL) was detected as much as 2 m lower than the release point, which is not predicted by existing models; personal monitors detected hydrogen at ground level, although at levels below the LFL; a small but inconsistent correlation was found between oxygen depletion and the hydrogen concentration; a negligible to non-existent correlation was found between in-situ temperature measurements and the hydrogen concentration. The prototype analyzer is being upgraded for enhanced metrological capabilities, including improved real-time spatial and temporal profiling of hydrogen plumes and tracking of prevailing weather conditions. Additional deployments are planned to monitor plume behavior under different wind, humidity, and temperature conditions. The data will be shared with the Hydrogen Storage Task Group and ultimately will be used support theoretical models and code requirements prescribed in NFPA 2.

• Research Organization: National Renewable Energy Laboratory (NREL), Golden, CO (United States)
• Sponsoring Organization: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Hydrogen Fuel Cell Technologies Office
• Grant/Contract Number: AC36-08GO28308
• OSTI ID: 1494733
• Alternate ID(s): OSTI ID: 1812968
• Report Number(s): NREL/JA-5400-71678; MainId:12945; UUID:1aea543b-f764-e811-9c14-ac162d87dfe5; MainAdminID:1425
• Journal Information: International Journal of Hydrogen Energy, Vol. 46, Issue 64; ISSN 0360-3199
• Publisher: Elsevier
• Country of Publication: United States
• Language: English

Related Subjects

08 HYDROGEN
hydrogen sensors
hydrogen storage
HyWAM
LH2
NFPA2
safety
wide-area monitor