A tailored double perovskite nanofiber catalyst enables ultrafast oxygen evolution

Zhao, Bote; Zhang, Lei; Zhen, Dongxing; Yoo, Seonyoung; Ding, Yong; Chen, Dongchang; Chen, Yu; Zhang, Qiaobao; Doyle, Brian; Xiong, Xunhui; Liu, Meilin

doi:10.1038/ncomms14586

Title: A tailored double perovskite nanofiber catalyst enables ultrafast oxygen evolution

Journal Article · Mon Feb 27 00:00:00 EST 2017 · Nature Communications

DOI:https://doi.org/10.1038/ncomms14586· OSTI ID:1489289

Zhao, Bote ^[1]; Zhang, Lei ^[1]; Zhen, Dongxing ^[1]; Yoo, Seonyoung ^[1]; Ding, Yong ^[1]; Chen, Dongchang ^[1]; Chen, Yu ^[1]; Zhang, Qiaobao ^[1]; Doyle, Brian ^[1]; Xiong, Xunhui ^[2]; Liu, Meilin ^[1]

Georgia Inst. of Technology, Atlanta, GA (United States). School of Materials Science and Engineering
Georgia Inst. of Technology, Atlanta, GA (United States). School of Materials Science and Engineering; South China Univ. of Technology (SCUT), Guangzhou (China). School of Environment and Energy

Rechargeable metal–air batteries and water splitting are highly competitive options for a sustainable energy future, but their commercialization is hindered by the absence of cost-effective, highly efficient and stable catalysts for the oxygen evolution reaction. Here we report the rational design and synthesis of a double perovskite PrBa_0.5Sr_0.5Co_1.5Fe_0.5O_5+δ nanofiber as a highly efficient and robust catalyst for the oxygen evolution reaction. Co-doping of strontium and iron into PrBaCo₂O_5+δ is found to be very effective in enhancing intrinsic activity (normalized by the geometrical surface area, ~4.7 times), as validated by electrochemical measurements and first-principles calculations. Although, the nanofiber morphology enhances its mass activity remarkably (by ~20 times) as the diameter is reduced to ~20nm, attributed to the increased surface area and an unexpected intrinsic activity enhancement due possibly to a favourable eg electron filling associated with partial surface reduction, as unravelled from chemical titration and electron energy-loss spectroscopy.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1489289

Journal Information:: Nature Communications, Vol. 8; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 281 works

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Nanoporous gold supported chromium-doped NiFe oxyhydroxides as high-performance catalysts for the oxygen evolution reaction Sun, Jie-Song; Zhou, Yi-Tong; Yao, Rui-Qi Journal of Materials Chemistry A, Vol. 7, Issue 16 https://doi.org/10.1039/c9ta01027k	journal	January 2019
Boosting the oxygen evolution reaction activity of a perovskite through introducing multi-element synergy and building an ordered structure Sun, Hainan; Xu, Xiaomin; Hu, Zhiwei Journal of Materials Chemistry A, Vol. 7, Issue 16 https://doi.org/10.1039/c9ta01404g	journal	January 2019
Pyrite-type ruthenium disulfide with tunable disorder and defects enables ultra-efficient overall water splitting Zhu, Yinlong; Tahini, Hassan A.; Wang, Yang Journal of Materials Chemistry A, Vol. 7, Issue 23 https://doi.org/10.1039/c9ta04120f	journal	January 2019
Morphology, crystal structure and electronic state one-step co-tuning strategy towards developing superior perovskite electrocatalysts for water oxidation Zhang, Haijuan; Guan, Daqin; Gao, Xuechao Journal of Materials Chemistry A, Vol. 7, Issue 33 https://doi.org/10.1039/c9ta06020k	journal	January 2019
Selective acid leaching: a simple way to engineer cobalt oxide nanostructures for the electrochemical oxygen evolution reaction Yu, Mingquan; Belthle, Kendra Solveig; Tüysüz, Cengiz Journal of Materials Chemistry A, Vol. 7, Issue 40 https://doi.org/10.1039/c9ta07835e	journal	January 2019
Multimetallic metal-organic frameworks derived transition metal doped iron selenide arrays for efficient oxygen evolution reaction Wei, Xin; Xie, Yabo; Liu, Mingcheng APL Materials, Vol. 7, Issue 10 https://doi.org/10.1063/1.5119858	journal	October 2019
Hollow‐Structured Metal Oxides as Oxygen‐Related Catalysts Huang, Keke; Sun, Yu; Zhang, Yuan Advanced Materials, Vol. 31, Issue 38 https://doi.org/10.1002/adma.201801430	journal	July 2018
An Amorphous Nickel–Iron‐Based Electrocatalyst with Unusual Local Structures for Ultrafast Oxygen Evolution Reaction Chen, Gao; Zhu, Yanping; Chen, Hao Ming Advanced Materials, Vol. 31, Issue 28 https://doi.org/10.1002/adma.201900883	journal	May 2019
Earth-Abundant Silicon for Facilitating Water Oxidation over Iron-Based Perovskite Electrocatalyst Xu, Xiaomin; Chen, Yubo; Zhou, Wei Advanced Materials Interfaces, Vol. 5, Issue 11 https://doi.org/10.1002/admi.201701693	journal	February 2018
Advanced Architectures and Relatives of Air Electrodes in Zn-Air Batteries Pan, Jing; Xu, Yang Yang; Yang, Huan Advanced Science, Vol. 5, Issue 4 https://doi.org/10.1002/advs.201700691	journal	January 2018
Realizing Ultrafast Oxygen Evolution by Introducing Proton Acceptor into Perovskites She, Sixuan; Zhu, Yinlong; Chen, Yubo Advanced Energy Materials, Vol. 9, Issue 20 https://doi.org/10.1002/aenm.201900429	journal	April 2019
Double Perovskite LaFe _x Ni _{1− x} O ₃ Nanorods Enable Efficient Oxygen Evolution Electrocatalysis Wang, Huaping; Wang, Juan; Pi, Yecan Angewandte Chemie International Edition, Vol. 58, Issue 8 https://doi.org/10.1002/anie.201812545	journal	January 2019
Recent Progress on Transition Metal Oxides as Bifunctional Catalysts for Lithium‐Air and Zinc‐Air Batteries Pan, Jing; Tian, Xin Long; Zaman, Shahid Batteries & Supercaps, Vol. 2, Issue 4 https://doi.org/10.1002/batt.201800082	journal	October 2018
A Tailored Bifunctional Electrocatalyst: Boosting Oxygen Reduction/Evolution Catalysis via Electron Transfer Between N-Doped Graphene and Perovskite Oxides Bu, Yunfei; Nam, Gyutae; Kim, Seona Small, Vol. 14, Issue 48 https://doi.org/10.1002/smll.201802767	journal	September 2018
Oxygen Evolution Reaction Brouzgou, A. Methods for Electrocatalysis: Advanced Materials and Allied Applications, p. 149-169 https://doi.org/10.1007/978-3-030-27161-9_6	book	January 2020
A surface-modified antiperovskite as an electrocatalyst for water oxidation Zhu, Yanping; Chen, Gao; Zhong, Yijun Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04682-y	journal	June 2018
Crystal structure and surface characteristics of Sr-doped GdBaCo ₂ O _6−δ double perovskites: oxygen evolution reaction and conductivity Pramana, Stevin S.; Cavallaro, Andrea; Li, Cheng Journal of Materials Chemistry A, Vol. 6, Issue 13 https://doi.org/10.1039/c7ta06817d	journal	January 2018
Imidazolate-mediated assembled structures of Co-LDH sheets for efficient electrocatalytic oxygen evolution Chen, Liyong; Guo, Yuting; Wang, Huifang Journal of Materials Chemistry A, Vol. 6, Issue 11 https://doi.org/10.1039/c7ta11078b	journal	January 2018
A perovskite oxide with a tunable pore-size derived from a general salt-template strategy as a highly efficient electrocatalyst for the oxygen evolution reaction Yu, Haoran; Chu, Fuqiang; Zhou, Xiao Chemical Communications, Vol. 55, Issue 17 https://doi.org/10.1039/c8cc10181g	journal	January 2019
Protonic ceramic electrochemical cells for hydrogen production and electricity generation: exceptional reversibility, stability, and demonstrated faradaic efficiency Choi, Sihyuk; Davenport, Timothy C.; Haile, Sossina M. Energy & Environmental Science, Vol. 12, Issue 1 https://doi.org/10.1039/c8ee02865f	journal	January 2019
Reconstructing bimetallic carbide Mo ₆ Ni ₆ C for carbon interconnected MoNi alloys to boost oxygen evolution electrocatalysis Zu, Meng Yang; Wang, Chongwu; Zhang, Le Materials Horizons, Vol. 6, Issue 1 https://doi.org/10.1039/c8mh00664d	journal	January 2019
MA ₂ CoBr ₄ : lead-free cobalt-based perovskite for electrochemical conversion of water to oxygen Babu, Ramavath; Vardhaman, Anil Kumar; Dhavale, Vishal M. Chemical Communications, Vol. 55, Issue 47 https://doi.org/10.1039/c9cc00878k	journal	January 2019
Trinuclear Ni( ii ) oriented highly dense packing and π-conjugation degree of metal–organic frameworks for efficient water oxidation Zhai, Zhi-Min; Yang, Xiao-Gang; Yang, Zhao-Tong CrystEngComm, Vol. 21, Issue 39 https://doi.org/10.1039/c9ce00944b	journal	January 2019
Recent progress made in the mechanism comprehension and design of electrocatalysts for alkaline water splitting Hu, Congling; Zhang, Lei; Gong, Jinlong Energy & Environmental Science, Vol. 12, Issue 9 https://doi.org/10.1039/c9ee01202h	journal	January 2019
ZnO nanoconfined 3D porous carbon composite microspheres to stabilize lithium nucleation/growth for high-performance lithium metal anodes Tang, Linsheng; Zhang, Rui; Zhang, Xinyue Journal of Materials Chemistry A, Vol. 7, Issue 33 https://doi.org/10.1039/c9ta06401j	journal	January 2019
Exceptional oxygen evolution reactivities on CaCoO ₃ and SrCoO ₃ Li, Xiang; Wang, Hao; Cui, Zhiming Science Advances, Vol. 5, Issue 8 https://doi.org/10.1126/sciadv.aav6262	journal	August 2019
Co ₃ O ₄ Nanoparticles with Ultrasmall Size and Abundant Oxygen Vacancies for Boosting Oxygen Involved Reactions Li, Zhe; Zhang, Yan; Feng, Yi Advanced Functional Materials, Vol. 30, Issue 11 https://doi.org/10.1002/adfm.202000364	journal	March 2020
Preferential Cation Vacancies in Perovskite Hydroxide for the Oxygen Evolution Reaction Chen, Dawei; Qiao, Man; Lu, Ying-Rui Angewandte Chemie, Vol. 130, Issue 28 https://doi.org/10.1002/ange.201805520	journal	June 2018
Surface dual-oxidation induced metallic copper doping into NiFe electrodes for electrocatalytic water oxidation Ma, Yaming; Wang, Ke; Liu, Dongyu Journal of Materials Chemistry A, Vol. 7, Issue 40 https://doi.org/10.1039/c9ta08797d	journal	January 2019
The Synergistic Effect Accelerates the Oxygen Reduction/Evolution Reaction in a Zn-Air Battery Zhang, Yidan; Guo, Youmin; Liu, Tao Frontiers in Chemistry, Vol. 7 https://doi.org/10.3389/fchem.2019.00524	journal	July 2019

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