Engineering the solid oxide fuel cell electrocatalyst infiltration technique for industrial use

Dowd, Regis P.; Lee, Shiwoo; Fan, Yueying; Gerdes, Kirk

doi:10.1016/j.ijhydene.2016.06.015

Title: Engineering the solid oxide fuel cell electrocatalyst infiltration technique for industrial use

Journal Article · Fri Jul 15 00:00:00 EDT 2016 · International Journal of Hydrogen Energy

DOI:https://doi.org/10.1016/j.ijhydene.2016.06.015· OSTI ID:1480826

^[1]; Lee, Shiwoo ^[2]; Fan, Yueying ^[2]; Gerdes, Kirk ^[3]

National Energy Technology Lab. (NETL), Morgantown, WV (United States); Univ. of Kansas, Lawrence, KS (United States). Dept. of Chemical and Petroleum Engineering
National Energy Technology Lab. (NETL), Morgantown, WV (United States); AECOM, Morgantown, WV (United States)
National Energy Technology Lab. (NETL), Morgantown, WV (United States)

We explore various parameters for infiltrating La_0.6Sr_0.4CoO_3-δ (LSCo) into the La_0.6Sr_0.4Co_0.2Fe_0.8O_3-δ (LSCF) – Ce_0.8Sm_0.2O₂ (SDC) cathode of a planar solid oxide fuel cell (SOFC) using an automated solution dispensing technique for commercial deployment of infiltrated SOFCs by industry. Substrate temperature, chelating agent concentration, and surfactant type were explored to develop a 1-step infiltration process for delivering 8–10 weight percent of LSCo electrocatalyst to the cathode active layer. Finally, the results confirm increased fuel cell performance and durability by optimizing the infiltrate solution for increased transport into the cathode's microstructure.

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Research Organization:: National Energy Technology Lab. (NETL), Morgantown, WV (United States); AECOM, Morgantown, WV (United States)

Sponsoring Organization:: USDOE Office of Fossil Energy (FE)

Grant/Contract Number:: FE0004000

OSTI ID:: 1480826

Alternate ID(s):: OSTI ID: 1396450

Journal Information:: International Journal of Hydrogen Energy, Vol. 41, Issue 33; ISSN 0360-3199

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 20 works

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References (25)

Energy and exergy analyses of an integrated underground coal gasification with SOFC fuel cell system for multigeneration including hydrogen production Bicer, Yusuf; Dincer, Ibrahim International Journal of Hydrogen Energy, Vol. 40, Issue 39 https://doi.org/10.1016/j.ijhydene.2015.08.023	journal	October 2015
Exergy & economic analysis of biogas fueled solid oxide fuel cell systems Siefert, Nicholas S.; Litster, Shawn Journal of Power Sources, Vol. 272 https://doi.org/10.1016/j.jpowsour.2014.08.044	journal	December 2014
A review of wet impregnation—An alternative method for the fabrication of high performance and nano-structured electrodes of solid oxide fuel cells Jiang, San Ping Materials Science and Engineering: A, Vol. 418, Issue 1-2 https://doi.org/10.1016/j.msea.2005.11.052	journal	February 2006
Nanoscale and nano-structured electrodes of solid oxide fuel cells by infiltration: Advances and challenges Jiang, San Ping International Journal of Hydrogen Energy, Vol. 37, Issue 1 https://doi.org/10.1016/j.ijhydene.2011.09.067	journal	January 2012
SOFC anodes based on infiltration of tungsten bronzes Adijanto, Lawrence; Küngas, Rainer; Park, Jongsung International Journal of Hydrogen Energy, Vol. 36, Issue 24 https://doi.org/10.1016/j.ijhydene.2011.09.059	journal	December 2011
Highly active YSB infiltrated LSCF cathode for proton conducting solid oxide fuel cells Li, Geng; He, Beibei; Ling, Yihan International Journal of Hydrogen Energy, Vol. 40, Issue 39 https://doi.org/10.1016/j.ijhydene.2015.07.164	journal	October 2015
High performance solid oxide fuel cells with Co1.5Mn1.5O4 infiltrated (La,Sr)MnO3-yittria stabilized zirconia cathodes Zhang, Xiaomin; Liu, Li; Zhao, Zhe International Journal of Hydrogen Energy, Vol. 40, Issue 8 https://doi.org/10.1016/j.ijhydene.2015.01.040	journal	March 2015
Long-Term Stability of SOFC Composite Cathode Activated by Electrocatalyst Infiltration Lee, Shiwoo; Miller, Nicholas; Gerdes, Kirk Journal of The Electrochemical Society, Vol. 159, Issue 7 https://doi.org/10.1149/2.067207jes	journal	January 2012
Effect of Sr-Doped LaCoO3 and LaZrO3 Infiltration on the Performance of SDC-LSCF Cathode Lee, Shiwoo; Miller, Nicholas; Abernathy, Harry Journal of The Electrochemical Society, Vol. 158, Issue 6 https://doi.org/10.1149/1.3581026	journal	January 2011
Pr0.6Sr0.4CoO3−δ electrocatalyst for solid oxide fuel cell cathode introduced via infiltration Lee, Shiwoo; Miller, Nicholas; Staruch, Margo Electrochimica Acta, Vol. 56, Issue 27 https://doi.org/10.1016/j.electacta.2011.08.060	journal	November 2011
Performance of a commercial cathode-supported solid oxide fuel cells prepared by single-step infiltration of an ion-conducting electrocatalyst Li, Xue; Xu, Nansheng; Zhao, Xuan Journal of Power Sources, Vol. 199 https://doi.org/10.1016/j.jpowsour.2011.10.079	journal	February 2012
Enhanced electrochemical performance and stability of (La,Sr)MnO 3 –(Gd,Ce)O 2 oxygen electrodes of solid oxide electrolysis cells by palladium infiltration Chen, Kongfa; Ai, Na; Jiang, San Ping International Journal of Hydrogen Energy, Vol. 37, Issue 2 https://doi.org/10.1016/j.ijhydene.2011.10.015	journal	January 2012
Electrochemical stability of La0.6Sr0.4Co0.2Fe0.8O3−δ-infiltrated YSZ oxygen electrode for reversible solid oxide fuel cells Fan, Hui; Keane, Michael; Li, Na International Journal of Hydrogen Energy, Vol. 39, Issue 26 https://doi.org/10.1016/j.ijhydene.2014.05.149	journal	September 2014
The effect of electrode infiltration on the performance of tubular solid oxide fuel cells under electrolysis and fuel cell modes Hanifi, A. R.; Laguna-Bercero, M. A.; Etsell, T. H. International Journal of Hydrogen Energy, Vol. 39, Issue 15 https://doi.org/10.1016/j.ijhydene.2014.03.071	journal	May 2014
Performance of microtubular SOFCs with infiltrated electrodes under thermal cycling Howe, K. S.; Hanifi, A. R.; Kendall, K. International Journal of Hydrogen Energy, Vol. 38, Issue 2 https://doi.org/10.1016/j.ijhydene.2012.10.098	journal	January 2013
Microtubular solid oxide fuel cells with lanthanum strontium manganite infiltrated cathodes Laguna-Bercero, M. A.; Hanifi, A. R.; Etsell, T. H. International Journal of Hydrogen Energy, Vol. 40, Issue 15 https://doi.org/10.1016/j.ijhydene.2015.01.060	journal	April 2015
Fabrication of planar-type SOFC single cells by a novel vacuum dip-coating method and co-firing/infiltration techniques Zhou, Zhenyi; Han, Da; Wu, Hao International Journal of Hydrogen Energy, Vol. 39, Issue 5 https://doi.org/10.1016/j.ijhydene.2013.11.061	journal	February 2014
La[sub 0.85]Sr[sub 0.15]MnO[sub 3−δ] Infiltrated Y[sub 0.5]Bi[sub 1.5]O[sub 3] Cathodes for Intermediate-Temperature Solid Oxide Fuel Cells Jiang, Zhiyi; Xia, Changrong; Zhao, Fei Electrochemical and Solid-State Letters, Vol. 12, Issue 6 https://doi.org/10.1149/1.3099321	journal	January 2009
Aggregation and transport of nano-TiO2 in saturated porous media: Effects of pH, surfactants and flow velocity Godinez, Itzel G.; Darnault, Christophe J. G. Water Research, Vol. 45, Issue 2 https://doi.org/10.1016/j.watres.2010.09.013	journal	January 2011
Development of La0.6Sr0.4Co0.2Fe0.8O3−δ cathode with an improved stability via La0.8Sr0.2MnO3-film impregnation Zhu, Xingbao; Ding, Dong; Li, Yiqian International Journal of Hydrogen Energy, Vol. 38, Issue 13 https://doi.org/10.1016/j.ijhydene.2013.02.091	journal	May 2013
Capillary imbibition of surfactant solutions in porous media and thin capillaries: partial wetting case Starov, V. M.; Zhdanov, S. A.; Velarde, M. G. Journal of Colloid and Interface Science, Vol. 273, Issue 2 https://doi.org/10.1016/j.jcis.2004.02.033	journal	May 2004
LaCoO3 formation from precursors obtained by water-based sol–gel method with citric acid Predoana, Luminita; Malic, Barbara; Zaharescu, Maria Journal of Thermal Analysis and Calorimetry, Vol. 98, Issue 2 https://doi.org/10.1007/s10973-009-0315-x	journal	August 2009
Moderate concentration of citric acid for the formation of LaMnO3 and LaCoO3 nano-perovskites Ghiasi, Elham; Malekzadeh, Azim; Ghiasi, Mahnaz Journal of Rare Earths, Vol. 31, Issue 10 https://doi.org/10.1016/S1002-0721(13)60020-4	journal	October 2013
Mesoporous silica supported LaCoO3 perovskites as catalysts for methane oxidation Nguyen, S. V.; Szabo, V.; Trong On, D. Microporous and Mesoporous Materials, Vol. 54, Issue 1-2 https://doi.org/10.1016/S1387-1811(02)00340-2	journal	July 2002
Surface characterization of LaCoO3 synthesized using citric acid Taguchi, Hideki; Yamada, Sayuki; Nagao, Mahiko Materials Research Bulletin, Vol. 37, Issue 1 https://doi.org/10.1016/S0025-5408(01)00799-1	journal	January 2002

Cited By (3)

Temperature dependency of activity of nano-catalysts on La0.6Sr0.4Co0.2Fe0.8O3−δ cathode of solid oxide fuel cells Soltanizade, Ali; Babaei, Alireza; Ataie, Abolghasem Journal of Applied Electrochemistry, Vol. 49, Issue 11 https://doi.org/10.1007/s10800-019-01355-6	journal	September 2019
Inkjet Printing Functionalization of SOFC LSCF Cathodes Venezia, Eleonora; Viviani, Massimo; Presto, Sabrina Nanomaterials, Vol. 9, Issue 4 https://doi.org/10.3390/nano9040654	journal	April 2019
Inkjet Printing Functionalization of SOFC LSCF Cathodes. Venezia, Eleonora; Viviani, Massimo; Presto, Sabrina Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.41856	text	January 2019

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