Ultra-Stable and High-Cobalt-Loaded Cobalt@Ordered Mesoporous Carbon Catalysts: All-in-One Deoxygenation of Ketone into Alkylbenzene

Zhang, Pengfei; Chen, Nanqing; Chen, Dong; Yang, Shize; Liu, Xiaofei; Wang, Li; Wu, Peiwen; Phillip, Nathan; Yang, Guang; Dai, Sheng

doi:10.1002/cctc.201800358

Title: Ultra-Stable and High-Cobalt-Loaded Cobalt@Ordered Mesoporous Carbon Catalysts: All-in-One Deoxygenation of Ketone into Alkylbenzene

Journal Article · Mon Apr 23 00:00:00 EDT 2018 · ChemCatChem

DOI:https://doi.org/10.1002/cctc.201800358· OSTI ID:1479713

^[1]; Chen, Nanqing ^[2]; Chen, Dong ^[3]; Yang, Shize ^[4]; Liu, Xiaofei ^[5]; Wang, Li ^[5]; Wu, Peiwen ^[4]; Phillip, Nathan ^[4]; Yang, Guang ^[4]; Dai, Sheng ^[6]

Shanghai Jiao Tong Univ. (China). School of Chemistry and Chemical Engineering; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
Shanghai Jiao Tong Univ. (China). School of Chemistry and Chemical Engineering
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); East China Univ. of Science and Technology, Shanghai (China). Inst. of Industrial Catalysis
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry

Catalytic deoxygenation represents a straightforward and core methodology for fine-chemical production and biomass upgrading. Generally, the application of homogeneous metal complexes or heterogeneous noble-metal catalysts prevails in academia and the chemical industry. We introduce cobalt@ordered mesoporous carbon (Co@OMC) catalysts, which are constructed conveniently by a mechanochemical coordination self-assembly based on a renewable tannin precursor. Importantly, the Co@OMC catalysts with a high loading of in situ confined Co species promote the selective deoxygenation of various ketones, aldehydes, and alcohols efficiently into the corresponding alkanes under mild conditions. Therefore, a simple, inexpensive, and heterogeneous catalyst for selective deoxygenation can be expected, meanwhile the solid-state synthesis affords a green, rapid, and scalable pathway to Co@OMC catalysts.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States); Shanghai Jiao Tong Univ. (China)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); Shanghai Pujiang Program (China); National Natural Science Foundation of China (NSFC); Thousand Talent Program of China

Grant/Contract Number:: AC05-00OR22725; 17PJ1403500; 21776174

OSTI ID:: 1479713

Journal Information:: ChemCatChem, Vol. 10, Issue 15; ISSN 1867-3880

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 16 works

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Mechanochemical Synthesis of Ruthenium Cluster@Ordered Mesoporous Carbon Catalysts by Synergetic Dual Templates Wang, Li; Zhao, Jiahua; Zhang, Pengfei Chemistry – A European Journal, Vol. 25, Issue 36 https://doi.org/10.1002/chem.201901714	journal	May 2019
High-level nitrogen-doped, micro/mesoporous carbon as an efficient metal-free electrocatalyst for the oxygen reduction reaction: optimizing the reaction surface area by a solvent-free mechanochemical method Zhang, Wendu; Qi, Jiawei; Bai, Peiyao New Journal of Chemistry, Vol. 43, Issue 27 https://doi.org/10.1039/c9nj01997a	journal	January 2019

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Title: Ultra-Stable and High-Cobalt-Loaded Cobalt@Ordered Mesoporous Carbon Catalysts: All-in-One Deoxygenation of Ketone into Alkylbenzene

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