Frequency measurements and self-broadening of sub-Doppler transitions in the v1 + v3 band of C2H2

Twagirayezu, Sylvestre; Hall, Gregory E.; Sears, Trevor J.

doi:10.1063/1.5047410

Title: Frequency measurements and self-broadening of sub-Doppler transitions in the v1 + v3 band of C₂H₂

Journal Article · Fri Oct 19 00:00:00 EDT 2018 · Journal of Chemical Physics

DOI:https://doi.org/10.1063/1.5047410· OSTI ID:1473639

Twagirayezu, Sylvestre ^[1];

^[1]; Sears, Trevor J. ^[2]

Brookhaven National Lab. (BNL), Upton, NY (United States). Division of Chemistry, Department of Energy and Photon Sciences
Brookhaven National Lab. (BNL), Upton, NY (United States). Division of Chemistry, Department of Energy and Photon Sciences ; Stony Brook Univ., NY (United States). Dept. of Chemistry

Here, frequency comb-referenced measurements of sub-Doppler laser saturation dip absorption lines in the v1 + v3 band of acetylene near 1:5 μm are reported. These measurements include transitions involving higher rotational levels than previously frequency measured in this band. The accuracy of the measured frequencies is typically better than 10 kHz. Measurements of the observed sub-Doppler line widths as a function of pressure showed that the self pressure-broadening coefficients are about 3.5 times larger than those derived from conventional pressure broadening of unsaturated Doppler-limited spectra. This is attributed to the contribution of velocity-changing collisions to the total dephasing rate in the low pressure sub-Doppler measurements. At higher pressures, when the homogeneous broadening becomes comparable to the typical Doppler shift per elastic collision, the velocity changing collisions cease to contribute significantly to the incremental pressure broadening. Lastly, a time-dependent soft collision model is developed to illustrate the transition between low and high pressure regimes of sub-Doppler pressure-broadening.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division

Grant/Contract Number:: SC0012704

OSTI ID:: 1473639

Alternate ID(s):: OSTI ID: 1478275

Report Number(s):: BNL-209076-2018-JAAM

Journal Information:: Journal of Chemical Physics, Vol. 149, Issue 15; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 10 works

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