Creating Hierarchical Pores by Controlled Linker Thermolysis in Multivariate Metal–Organic Frameworks

Feng, Liang; Yuan, Shuai; Zhang, Liang-Liang; Tan, Kui; Li, Jia-Luo; Kirchon, Angelo; Liu, Ling-Mei; Zhang, Peng; Han, Yu; Chabal, Yves J.; Zhou, Hong-Cai

doi:10.1021/jacs.7b12916

Title: Creating Hierarchical Pores by Controlled Linker Thermolysis in Multivariate Metal–Organic Frameworks

Journal Article · Thu Jan 18 00:00:00 EST 2018 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.7b12916· OSTI ID:1470336

^[1]; Yuan, Shuai ^[1]; Zhang, Liang-Liang ^[1];

^[2]; Li, Jia-Luo ^[1]; Kirchon, Angelo ^[1]; Liu, Ling-Mei ^[3]; Zhang, Peng ^[1];

^[3];

^[2];

^[1]

Texas A & M Univ., College Station, TX (United States)
Univ. of Texas at Dallas, Richardson, TX (United States)
King Abdullah Univ. of Science and Technology, Thuwal (Saudi Arabia)

Sufficient pore size, appropriate stability, and hierarchical porosity are three prerequisites for open frameworks designed for drug delivery, enzyme immobilization, and catalysis involving large molecules. In this work, we report a powerful and general strategy, linker thermolysis, to construct ultrastable hierarchically porous metal–organic frameworks (HP-MOFs) with tunable pore size distribution. Linker instability, usually an undesirable trait of MOFs, was exploited to create mesopores by generating crystal defects throughout a microporous MOF crystal via thermolysis. The crystallinity and stability of HP-MOFs remain after thermolabile linkers are selectively removed from multivariate metal–organic frameworks (MTV-MOFs) through a decarboxylation process. A domain-based linker spatial distribution was found to be critical for creating hierarchical pores inside MTV-MOFs. Furthermore, linker thermolysis promotes the formation of ultrasmall metal oxide nanoparticles immobilized in an open framework that exhibits high catalytic activity for Lewis acid-catalyzed reactions. Lastly and most importantly, this work provides fresh insights into the connection between linker apportionment and vacancy distribution, which may shed light on probing the disordered linker apportionment in multivariate systems, a long-standing challenge in the study of MTV-MOFs.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS)

Sponsoring Organization:: USDOE Office of Fossil Energy (FE); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0001015; FG02-08ER46491; FE0026472

OSTI ID:: 1470336

Journal Information:: Journal of the American Chemical Society, Vol. 140, Issue 6; Related Information: CGS partners with University of California, Berkeley; University of California, Davis; Lawrence Berkeley National Laboratory; University of Minnesota; National Energy Technology Laboratory; Texas A&M University; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 233 works

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References (48)

Introduction to Metal–Organic Frameworks Zhou, Hong-Cai; Long, Jeffrey R.; Yaghi, Omar M. Chemical Reviews, Vol. 112, Issue 2, p. 673-674 https://doi.org/10.1021/cr300014x	journal	September 2011
Metal–organic framework materials as catalysts Lee, JeongYong; Farha, Omar K.; Roberts, John Chemical Society Reviews, Vol. 38, Issue 5, p. 1450-1459 https://doi.org/10.1039/b807080f	journal	January 2009
Selective gas adsorption and separation in metal–organic frameworks Li, Jian-Rong; Kuppler, Ryan J.; Zhou, Hong-Cai Chemical Society Reviews, Vol. 38, Issue 5, p. 1477-1504 https://doi.org/10.1039/b802426j	journal	January 2009
Metal–Organic Frameworks for Separations Li, Jian-Rong; Sculley, Julian; Zhou, Hong-Cai Chemical Reviews, Vol. 112, Issue 2, p. 869-932 https://doi.org/10.1021/cr200190s	journal	September 2011
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage Eddaoudi, Mohamed; Kim, Jaheon; Rosi, Nathaniel Science, Vol. 295, Issue 5554, p. 469-472 https://doi.org/10.1126/science.1067208	journal	January 2002
Topological Analysis of Metal–Organic Frameworks with Polytopic Linkers and/or Multiple Building Units and the Minimal Transitivity Principle Li, Mian; Li, Dan; O’Keeffe, Michael Chemical Reviews, Vol. 114, Issue 2 https://doi.org/10.1021/cr400392k	journal	November 2013
Synthesis of Metal-Organic Frameworks (MOFs): Routes to Various MOF Topologies, Morphologies, and Composites Stock, Norbert; Biswas, Shyam Chemical Reviews, Vol. 112, Issue 2 https://doi.org/10.1021/cr200304e	journal	September 2011
Chemical, thermal and mechanical stabilities of metal–organic frameworks Howarth, Ashlee J.; Liu, Yangyang; Li, Peng Nature Reviews Materials, Vol. 1, Issue 3 https://doi.org/10.1038/natrevmats.2015.18	journal	February 2016
Toward Design Rules for Enzyme Immobilization in Hierarchical Mesoporous Metal-Organic Frameworks Li, Peng; Modica, Justin A.; Howarth, Ashlee J. Chem, Vol. 1, Issue 1 https://doi.org/10.1016/j.chempr.2016.05.001	journal	July 2016
Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts Feng, Dawei; Gu, Zhi-Yuan; Li, Jian-Rong Angewandte Chemie International Edition, Vol. 51, Issue 41 https://doi.org/10.1002/anie.201204475	journal	August 2012
Stable metal-organic frameworks containing single-molecule traps for enzyme encapsulation Feng, Dawei; Liu, Tian-Fu; Su, Jie Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms6979	journal	January 2015
Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework Mondloch, Joseph E.; Bury, Wojciech; Fairen-Jimenez, David Journal of the American Chemical Society, Vol. 135, Issue 28, p. 10294-10297 https://doi.org/10.1021/ja4050828	journal	May 2013
Cooperative Template-Directed Assembly of Mesoporous Metal–Organic Frameworks Sun, Lin-Bing; Li, Jian-Rong; Park, Jinhee Journal of the American Chemical Society, Vol. 134, Issue 1 https://doi.org/10.1021/ja209698f	journal	December 2011
Hierarchically Micro- and Mesoporous Metal-Organic Frameworks with Tunable Porosity Qiu, Ling-Guang; Xu, Tao; Li, Zong-Qun Angewandte Chemie International Edition, Vol. 47, Issue 49 https://doi.org/10.1002/anie.200803640	journal	November 2008
Metal-Organic Framework Nanospheres with Well-Ordered Mesopores Synthesized in an Ionic Liquid/CO2/Surfactant System Zhao, Yueju; Zhang, Jianling; Han, Buxing Angewandte Chemie International Edition, Vol. 50, Issue 3 https://doi.org/10.1002/anie.201005314	journal	December 2010
Hierarchical bicontinuous porosity in metal–organic frameworks templated from functional block co-oligomer micelles Cao, Shuai; Gody, Guillaume; Zhao, Wei Chemical Science, Vol. 4, Issue 9 https://doi.org/10.1039/c3sc51336j	journal	January 2013
A Modulator-Induced Defect-Formation Strategy to Hierarchically Porous Metal-Organic Frameworks with High Stability Cai, Guorui; Jiang, Hai-Long Angewandte Chemie International Edition, Vol. 56, Issue 2 https://doi.org/10.1002/anie.201610914	journal	December 2016
An in situ self-assembly template strategy for the preparation of hierarchical-pore metal-organic frameworks Huang, Hongliang; Li, Jian-Rong; Wang, Keke Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9847	journal	November 2015
Copper Benzene Tricarboxylate Metal–Organic Framework with Wide Permanent Mesopores Stabilized by Keggin Polyoxometallate Ions Wee, Lik H.; Wiktor, Christian; Turner, Stuart Journal of the American Chemical Society, Vol. 134, Issue 26 https://doi.org/10.1021/ja302089w	journal	June 2012
Exploiting chemically selective weakness in solids as a route to new porous materials Morris, Russell E.; Čejka, Jiří Nature Chemistry, Vol. 7, Issue 5 https://doi.org/10.1038/nchem.2222	journal	April 2015
Zeolites with Continuously Tuneable Porosity Wheatley, Paul S.; Chlubná-Eliášová, Pavla; Greer, Heather Angewandte Chemie International Edition, Vol. 53, Issue 48 https://doi.org/10.1002/anie.201407676	journal	October 2014
Postsynthetic Methods for the Functionalization of Metal–Organic Frameworks Cohen, Seth M. Chemical Reviews, Vol. 112, Issue 2, p. 970-1000 https://doi.org/10.1021/cr200179u	journal	September 2011
Hydrolytic Transformation of Microporous Metal-Organic Frameworks to Hierarchical Micro- and Mesoporous MOFs Kim, Yonghwi; Yang, Tao; Yun, Gyeongwon Angewandte Chemie International Edition, Vol. 54, Issue 45 https://doi.org/10.1002/anie.201506391	journal	September 2015
Linker Installation: Engineering Pore Environment with Precisely Placed Functionalities in Zirconium MOFs Yuan, Shuai; Chen, Ying-Pin; Qin, Jun-Sheng Journal of the American Chemical Society, Vol. 138, Issue 28 https://doi.org/10.1021/jacs.6b04501	journal	July 2016
Sequential Linker Installation: Precise Placement of Functional Groups in Multivariate Metal–Organic Frameworks Yuan, Shuai; Lu, Weigang; Chen, Ying-Pin Journal of the American Chemical Society, Vol. 137, Issue 9 https://doi.org/10.1021/ja512762r	journal	March 2015
Perfluoroalkane Functionalization of NU-1000 via Solvent-Assisted Ligand Incorporation: Synthesis and CO₂ Adsorption Studies Deria, Pravas; Mondloch, Joseph E.; Tylianakis, Emmanuel Journal of the American Chemical Society, Vol. 135, Issue 45, p. 16801-16804 https://doi.org/10.1021/ja408959g	journal	October 2013
Synthesis Modulation as a Tool To Increase the Catalytic Activity of Metal–Organic Frameworks: The Unique Case of UiO-66(Zr) Vermoortele, Frederik; Bueken, Bart; Le Bars, Gaëlle Journal of the American Chemical Society, Vol. 135, Issue 31 https://doi.org/10.1021/ja405078u	journal	July 2013
Construction of hierarchically porous metal–organic frameworks through linker labilization Yuan, Shuai; Zou, Lanfang; Qin, Jun-Sheng Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15356	journal	May 2017
A Series of Isoreticular, Highly Stable, Porous Zirconium Oxide Based Metal-Organic Frameworks Guillerm, V.; Ragon, F.; Dan-Hardi, M. Angewandte Chemie International Edition, Vol. 51, Issue 37 https://doi.org/10.1002/anie.201204806	journal	August 2012
Isoreticular synthesis and modification of frameworks with the UiO-66 topology Garibay, Sergio J.; Cohen, Seth M. Chemical Communications, Vol. 46, Issue 41, p. 7700-7702 https://doi.org/10.1039/c0cc02990d	journal	January 2010
Synthesis and Stability of Tagged UiO-66 Zr-MOFs Kandiah, Mathivathani; Nilsen, Merete Hellner; Usseglio, Sandro Chemistry of Materials, Vol. 22, Issue 24 https://doi.org/10.1021/cm102601v	journal	December 2010
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851 https://doi.org/10.1021/ja8057953	journal	October 2008
Tuned to Perfection: Ironing Out the Defects in Metal–Organic Framework UiO-66 Shearer, Greig C.; Chavan, Sachin; Ethiraj, Jayashree Chemistry of Materials, Vol. 26, Issue 14 https://doi.org/10.1021/cm501859p	journal	July 2014
Metal–Organic Framework (MOF) Defects under Control: Insights into the Missing Linker Sites and Their Implication in the Reactivity of Zirconium-Based Frameworks Gutov, Oleksii V.; Hevia, Miguel González; Escudero-Adán, Eduardo C. Inorganic Chemistry, Vol. 54, Issue 17 https://doi.org/10.1021/acs.inorgchem.5b01053	journal	August 2015
Unusual and Highly Tunable Missing-Linker Defects in Zirconium Metal–Organic Framework UiO-66 and Their Important Effects on Gas Adsorption Wu, Hui; Chua, Yong Shen; Krungleviciute, Vaiva Journal of the American Chemical Society, Vol. 135, Issue 28 https://doi.org/10.1021/ja404514r	journal	May 2013
Correlated defect nanoregions in a metal–organic framework Cliffe, Matthew J.; Wan, Wei; Zou, Xiaodong Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5176	journal	June 2014
Bottom-up/top-down synthesis of stable zirconium hydroxide nanophases Ambrosi, Moira; Fratini, Emiliano; Canton, Patrizia Journal of Materials Chemistry, Vol. 22, Issue 44 https://doi.org/10.1039/c2jm34111e	journal	January 2012
Facile synthesis and characterization of ZrO ₂ nanoparticles prepared by the AOP/hydrothermal route Padovini, D. S. S.; Pontes, D. S. L.; Dalmaschio, C. J. RSC Adv., Vol. 4, Issue 73 https://doi.org/10.1039/C4RA04861J	journal	January 2014
Reversible Low-Temperature Metal Node Distortion during Atomic Layer Deposition of Al ₂ O ₃ and TiO ₂ on UiO-66-NH ₂ Metal–Organic Framework Crystal Surfaces Lemaire, Paul C.; Lee, Dennis T.; Zhao, Junjie ACS Applied Materials & Interfaces, Vol. 9, Issue 26 https://doi.org/10.1021/acsami.7b05214	journal	June 2017
Disclosing the Complex Structure of UiO-66 Metal Organic Framework: A Synergic Combination of Experiment and Theory Valenzano, Loredana; Civalleri, Bartolomeo; Chavan, Sachin Chemistry of Materials, Vol. 23, Issue 7, p. 1700-1718 https://doi.org/10.1021/cm1022882	journal	April 2011
Postsynthesis Annealing of MOF-5 Remarkably Enhances the Framework Structural Stability and CO ₂ Uptake Gadipelli, Srinivas; Guo, Zhengxiao Chemistry of Materials, Vol. 26, Issue 22 https://doi.org/10.1021/cm502399q	journal	November 2014
Mapping of Functional Groups in Metal-Organic Frameworks Kong, X.; Deng, H.; Yan, F. Science, Vol. 341, Issue 6148, p. 882-885 https://doi.org/10.1126/science.1238339	journal	July 2013
An In Situ One-Pot Synthetic Approach towards Multivariate Zirconium MOFs Sun, Yujia; Sun, Lixian; Feng, Dawei Angewandte Chemie International Edition, Vol. 55, Issue 22 https://doi.org/10.1002/anie.201602274	journal	April 2016
Tackling the Defect Conundrum in UiO-66: A Mixed-Linker Approach to Engineering Missing Linker Defects Bueken, Bart; Van Velthoven, Niels; Krajnc, Andraž Chemistry of Materials, Vol. 29, Issue 24 https://doi.org/10.1021/acs.chemmater.7b04128	journal	November 2017
Zr-TUD-1: A Lewis Acidic, Three-Dimensional, Mesoporous, Zirconium-Containing Catalyst Ramanathan, Anand; Castro Villalobos, M. Carmen; Kwakernaak, Cees Chemistry - A European Journal, Vol. 14, Issue 3 https://doi.org/10.1002/chem.200700725	journal	January 2008
Ionic liquid accelerates the crystallization of Zr-based metal–organic frameworks Sang, Xinxin; Zhang, Jianling; Xiang, Junfeng Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00226-y	journal	August 2017
Porous Zirconium-Phytic Acid Hybrid: a Highly Efficient Catalyst for Meerwein-Ponndorf-Verley Reductions Song, Jinliang; Zhou, Baowen; Zhou, Huacong Angewandte Chemie International Edition, Vol. 54, Issue 32 https://doi.org/10.1002/anie.201504001	journal	July 2015
Synergistic Catalysis by Lewis Acid and Base Sites on ZrO ₂ for Meerwein–Ponndorf–Verley Reduction Komanoya, Tasuku; Nakajima, Kiyotaka; Kitano, Masaaki The Journal of Physical Chemistry C, Vol. 119, Issue 47 https://doi.org/10.1021/acs.jpcc.5b08355	journal	November 2015

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Title: Creating Hierarchical Pores by Controlled Linker Thermolysis in Multivariate Metal–Organic Frameworks

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