Oxygen Reduction by Homogeneous Molecular Catalysts and Electrocatalysts

Pegis, Michael L.; Wise, Catherine F.; Martin, Daniel J.; Mayer, James M.

doi:10.1021/acs.chemrev.7b00542

Title: Oxygen Reduction by Homogeneous Molecular Catalysts and Electrocatalysts

Journal Article · Tue Feb 06 00:00:00 EST 2018 · Chemical Reviews

DOI:https://doi.org/10.1021/acs.chemrev.7b00542· OSTI ID:1470267

^[1]; Wise, Catherine F. ^[1]; Martin, Daniel J. ^[1];

^[1]

Yale Univ., New Haven, CT (United States)

The oxygen reduction reaction (ORR) is a key component of biological processes and energy technologies. This Review provides a comprehensive report of soluble molecular catalysts and electrocatalysts for the ORR. The precise synthetic control and relative ease of mechanistic study for homogeneous molecular catalysts, as compared to heterogeneous materials or surface-adsorbed species, enables a detailed understanding of the individual steps of ORR catalysis. Thus, the Review places particular emphasis on ORR mechanism and thermodynamics. First, the thermochemistry of oxygen reduction and the factors influencing ORR efficiency are described to contextualize the discussion of catalytic studies that follows. Reports of ORR catalysis are presented in terms of their mechanism, with separate sections for catalysis proceeding via initial outer- and inner-sphere electron transfer to O₂. The rates and selectivities (for production of H₂O₂ vs H₂O) of these catalysts are provided, along with suggested methods for accurately comparing catalysts of different metals and ligand scaffolds that were examined under different experimental conditions.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Molecular Electrocatalysis (CME)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1470267

Journal Information:: Chemical Reviews, Vol. 118, Issue 5; Related Information: CME partners with Pacific Northwest National Laboratory (lead); University of Illinois, Urbana-Champaign; Pennsylvania State University; University of Washington; University of Wyoming; ISSN 0009-2665

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 363 works

Citation information provided by
Web of Science

References (310)

Industrial Organic Chemistry Weissermel, Klaus; Arpe, Hans-Jürgen https://doi.org/10.1002/9783527616688		May 1997
Reaction Mechanism of Cytochrome c Oxidase Yoshikawa, Shinya; Shimada, Atsuhiro Chemical Reviews, Vol. 115, Issue 4 https://doi.org/10.1021/cr500266a	journal	January 2015
Dioxygen Activation at Mononuclear Nonheme Iron Active Sites: Enzymes, Models, and Intermediates Costas, Miquel; Mehn, Mark P.; Jensen, Michael P. Chemical Reviews, Vol. 104, Issue 2 https://doi.org/10.1021/cr020628n	journal	February 2004
Functional Analogues of Cytochrome c Oxidase, Myoglobin, and Hemoglobin Collman, James P.; Boulatov, Roman; Sunderland, Christopher J. Chemical Reviews, Vol. 104, Issue 2 https://doi.org/10.1021/cr0206059	journal	February 2004
Synthetic models for the oxygen-binding hemoproteins Collman, James P. Accounts of Chemical Research, Vol. 10, Issue 7 https://doi.org/10.1021/ar50115a006	journal	July 1977
Thermodynamics of oxygen binding in natural and synthetic dioxygen complexes Niederhoffer, Eric C.; Timmons, James H.; Martell, Arthur E. Chemical Reviews, Vol. 84, Issue 2 https://doi.org/10.1021/cr00060a003	journal	April 1984
Molecular Catalysis of Electrochemical Reactions. Mechanistic Aspects Savéant, Jean-Michel Chemical Reviews, Vol. 108, Issue 7, p. 2348-2378 https://doi.org/10.1021/cr068079z	journal	July 2008
Energy-Related Small Molecule Activation Reactions: Oxygen Reduction and Hydrogen and Oxygen Evolution Reactions Catalyzed by Porphyrin- and Corrole-Based Systems Zhang, Wei; Lai, Wenzhen; Cao, Rui Chemical Reviews, Vol. 117, Issue 4 https://doi.org/10.1021/acs.chemrev.6b00299	journal	November 2016
Hydrogen Peroxide Synthesis: An Outlook beyond the Anthraquinone Process Campos-Martin, Jose M.; Blanco-Brieva, Gema; Fierro, Jose L. G. Angewandte Chemie International Edition, Vol. 45, Issue 42 https://doi.org/10.1002/anie.200503779	journal	October 2006
Chemical and Technical Aspects of Propene Oxide Production via Hydrogen Peroxide (HPPO Process) Russo, V.; Tesser, R.; Santacesaria, E. Industrial & Engineering Chemistry Research, Vol. 52, Issue 3 https://doi.org/10.1021/ie3023862	journal	January 2013
Degradation of polymer electrolyte membranes Collier, A.; Wang, H.; Ziyuan, X. International Journal of Hydrogen Energy, Vol. 31, Issue 13 https://doi.org/10.1016/j.ijhydene.2006.05.006	journal	October 2006
Recent Advances in Electrocatalysts for Oxygen Reduction Reaction Shao, Minhua; Chang, Qiaowan; Dodelet, Jean-Pol Chemical Reviews, Vol. 116, Issue 6 https://doi.org/10.1021/acs.chemrev.5b00462	journal	February 2016
Metal-Free Catalysts for Oxygen Reduction Reaction Dai, Liming; Xue, Yuhua; Qu, Liangti Chemical Reviews, Vol. 115, Issue 11 https://doi.org/10.1021/cr5003563	journal	May 2015
Erratum: Design principles for oxygen-reduction activity on perovskite oxide catalysts for fuel cells and metal–air batteries Suntivich, Jin; Gasteiger, Hubert A.; Yabuuchi, Naoaki Nature Chemistry, Vol. 3, Issue 8 https://doi.org/10.1038/nchem.1093	journal	July 2011
Proton-Coupled Electron Transfer in Cytochrome Oxidase Kaila, Ville R. I.; Verkhovsky, Michael I.; Wikström, Mårten Chemical Reviews, Vol. 110, Issue 12 https://doi.org/10.1021/cr1002003	journal	December 2010
Direct, Electrocatalytic Oxygen Reduction by Laccase on Anthracene-2-methanethiol-Modified Gold Thorum, Matthew S.; Anderson, Cyrus A.; Hatch, Jeremy J. The Journal of Physical Chemistry Letters, Vol. 1, Issue 15 https://doi.org/10.1021/jz100745s	journal	July 2010
Enzymes as Working or Inspirational Electrocatalysts for Fuel Cells and Electrolysis Cracknell, James A.; Vincent, Kylie A.; Armstrong, Fraser A. Chemical Reviews, Vol. 108, Issue 7 https://doi.org/10.1021/cr0680639	journal	July 2008
Conformational Control of Intramolecular Hydrogen Bonding in Heme Models: Maximal CoII-O2 Binding in a C-Clamp Porphyrin Chang, C. K.; Liang, Ying; Aviles, Gladys Journal of the American Chemical Society, Vol. 117, Issue 14 https://doi.org/10.1021/ja00119a044	journal	April 1995
Standard Electrode Potentials and Temperature Coefficients in Water at 298.15 K Bratsch, Steven G. Journal of Physical and Chemical Reference Data, Vol. 18, Issue 1 https://doi.org/10.1063/1.555839	journal	January 1989
Experimental Methods for Quantifying the Activity of Platinum Electrocatalysts for the Oxygen Reduction Reaction Garsany, Yannick; Baturina, Olga A.; Swider-Lyons, Karen E. Analytical Chemistry, Vol. 82, Issue 15 https://doi.org/10.1021/ac100306c	journal	August 2010
Standard Reduction Potentials for Oxygen and Carbon Dioxide Couples in Acetonitrile and N , N -Dimethylformamide Pegis, Michael L.; Roberts, John A. S.; Wasylenko, Derek J. Inorganic Chemistry, Vol. 54, Issue 24 https://doi.org/10.1021/acs.inorgchem.5b02136	journal	December 2015
Direct Determination of Equilibrium Potentials for Hydrogen Oxidation/Production by Open Circuit Potential Measurements in Acetonitrile Roberts, John A. S.; Bullock, R. Morris Inorganic Chemistry, Vol. 52, Issue 7 https://doi.org/10.1021/ic302461q	journal	June 2012
Oxygen Reduction Catalysis at a Dicobalt Center: The Relationship of Faradaic Efficiency to Overpotential Passard, Guillaume; Ullman, Andrew M.; Brodsky, Casey N. Journal of the American Chemical Society, Vol. 138, Issue 9 https://doi.org/10.1021/jacs.5b12828	journal	February 2016
A Comprehensive Self-Consistent Spectrophotometric Acidity Scale of Neutral Brønsted Acids in Acetonitrile Kütt, Agnes; Leito, Ivo; Kaljurand, Ivari The Journal of Organic Chemistry, Vol. 71, Issue 7 https://doi.org/10.1021/jo060031y	journal	March 2006
Equilibrium acidities in dimethyl sulfoxide solution Bordwell, Frederick G. Accounts of Chemical Research, Vol. 21, Issue 12 https://doi.org/10.1021/ar00156a004	journal	December 1988
Electrochemical Reduction of Brønsted Acids by Glassy Carbon in Acetonitrile—Implications for Electrocatalytic Hydrogen Evolution McCarthy, Brian D.; Martin, Daniel J.; Rountree, Eric S. Inorganic Chemistry, Vol. 53, Issue 16 https://doi.org/10.1021/ic500770k	journal	July 2014
Determining the Overpotential for a Molecular Electrocatalyst Appel, Aaron M.; Helm, Monte L. ACS Catalysis, Vol. 4, Issue 2 https://doi.org/10.1021/cs401013v	journal	December 2013
H ₂ Evolution and Molecular Electrocatalysts: Determination of Overpotentials and Effect of Homoconjugation Fourmond, Vincent; Jacques, Pierre-André; Fontecave, Marc Inorganic Chemistry, Vol. 49, Issue 22 https://doi.org/10.1021/ic101187v	journal	November 2010
Kinetic Analysis of Competitive Electrocatalytic Pathways: New Insights into Hydrogen Production with Nickel Electrocatalysts Wiedner, Eric S.; Brown, Houston J. S.; Helm, Monte L. Journal of the American Chemical Society, Vol. 138, Issue 2 https://doi.org/10.1021/jacs.5b10853	journal	January 2016
Spectrophotometric Acidity Scale of Strong Neutral Brønsted Acids in Acetonitrile Leito, Ivo; Kaljurand, Ivari; Koppel, Ilmar A. The Journal of Organic Chemistry, Vol. 63, Issue 22 https://doi.org/10.1021/jo981124l	journal	October 1998
Reaction Pathways of Hydrogen-Evolving Electrocatalysts: Electrochemical and Spectroscopic Studies of Proton-Coupled Electron Transfer Processes Elgrishi, Noémie; McCarthy, Brian D.; Rountree, Eric S. ACS Catalysis, Vol. 6, Issue 6 https://doi.org/10.1021/acscatal.6b00778	journal	May 2016
A nickel–manganese catalyst as a biomimic of the active site of NiFe hydrogenases: a combined electrocatalytical and DFT mechanistic study Fourmond, Vincent; Canaguier, Sigolène; Golly, Benjamin Energy & Environmental Science, Vol. 4, Issue 7 https://doi.org/10.1039/c0ee00736f	journal	January 2011
Through-Space Charge Interaction Substituent Effects in Molecular Catalysis Leading to the Design of the Most Efficient Catalyst of CO ₂ -to-CO Electrochemical Conversion Azcarate, Iban; Costentin, Cyrille; Robert, Marc Journal of the American Chemical Society, Vol. 138, Issue 51 https://doi.org/10.1021/jacs.6b07014	journal	December 2016
Ferrocene as an internal standard for electrochemical measurements Gagne, Robert R.; Koval, Carl A.; Lisensky, George C. Inorganic Chemistry, Vol. 19, Issue 9 https://doi.org/10.1021/ic50211a080	journal	September 1980
The Decamethylferrocenium/Decamethylferrocene Redox Couple: A Superior Redox Standard to the Ferrocenium/Ferrocene Redox Couple for Studying Solvent Effects on the Thermodynamics of Electron Transfer Noviandri, Indra; Brown, Kylie N.; Fleming, Douglas S. The Journal of Physical Chemistry B, Vol. 103, Issue 32 https://doi.org/10.1021/jp991381+	journal	July 1999
Conversion constants for redox potentials measured versus different reference electrodes in acetonitrile solutions at 25°C Pavlishchuk, Vitaly V.; Addison, Anthony W. Inorganica Chimica Acta, Vol. 298, Issue 1 https://doi.org/10.1016/S0020-1693(99)00407-7	journal	January 2000
Chemical Redox Agents for Organometallic Chemistry Connelly, Neil G.; Geiger, William E. Chemical Reviews, Vol. 96, Issue 2 https://doi.org/10.1021/cr940053x	journal	January 1996
Anomalous solubility of oxygen in acetonitrile/water mixture containing tetra-n-butylammonium perchlorate supporting electrolyte; the solubility and diffusion coefficient of oxygen in anhydrous acetonitrile and aqueous mixtures Li, Qian; Batchelor-McAuley, Christopher; Lawrence, Nathan S. Journal of Electroanalytical Chemistry, Vol. 688 https://doi.org/10.1016/j.jelechem.2012.07.039	journal	January 2013
Solubility of Oxygen in Aqueous Solutions of KCl, K ₂ SO ₄ , and CaCl ₂ as a Function of Concentration and Temperature Millero, Frank J.; Huang, Fen Journal of Chemical & Engineering Data, Vol. 48, Issue 4 https://doi.org/10.1021/je034031w	journal	July 2003
A new generalized Henry-Setschenow equation for predicting the solubility of air gases (oxygen, nitrogen and argon) in seawater and saline solutions Valderrama, José O.; Campusano, Richard A.; Forero, Luis A. Journal of Molecular Liquids, Vol. 222 https://doi.org/10.1016/j.molliq.2016.07.110	journal	October 2016
Experimental Limiting Oxygen Concentrations for Nine Organic Solvents at Temperatures and Pressures Relevant to Aerobic Oxidations in the Pharmaceutical Industry Osterberg, Paul M.; Niemeier, Jeffry K.; Welch, Christopher J. Organic Process Research & Development, Vol. 19, Issue 11 https://doi.org/10.1021/op500328f	journal	August 2014
The Solubility of Oxygen and Ozone in Liquids Battino, Rubin; Rettich, Timothy R.; Tominaga, Toshihiro Journal of Physical and Chemical Reference Data, Vol. 12, Issue 2 https://doi.org/10.1063/1.555680	journal	April 1983
Effects of media and electrode materials on the electrochemical reduction of dioxygen Sawyer, Donald T.; Chiericato, Glaico.; Angelis, Charles T. Analytical Chemistry, Vol. 54, Issue 11 https://doi.org/10.1021/ac00248a014	journal	September 1982
Modified winkler determination of oxygen in dimethylformamide: oxygen solubility as a function of partial pressure James, Helen J.; Broman, R. F. Analytica Chimica Acta, Vol. 48, Issue 2 https://doi.org/10.1016/S0003-2670(01)85508-2	journal	December 1969
Thermochemistry of Proton-Coupled Electron Transfer Reagents and its Implications Warren, Jeffrey J.; Tronic, Tristan A.; Mayer, James M. Chemical Reviews, Vol. 110, Issue 12 https://doi.org/10.1021/cr100085k	journal	December 2010
Using combinations of oxidants and bases as PCET reactants: thermochemical and practical considerations Waidmann, Christopher R.; Miller, Alexander J. M.; Ng, Cheuk-Wa Angela Energy & Environmental Science, Vol. 5, Issue 7 https://doi.org/10.1039/c2ee03300c	journal	January 2012
Toward the rational benchmarking of homogeneous H ₂ -evolving catalysts Artero, Vincent; Saveant, Jean-Michel Energy Environ. Sci., Vol. 7, Issue 11 https://doi.org/10.1039/C4EE01709A	journal	January 2014
Turnover Numbers, Turnover Frequencies, and Overpotential in Molecular Catalysis of Electrochemical Reactions. Cyclic Voltammetry and Preparative-Scale Electrolysis Costentin, Cyrille; Drouet, Samuel; Robert, Marc Journal of the American Chemical Society, Vol. 134, Issue 27, p. 11235-11242 https://doi.org/10.1021/ja303560c	journal	June 2012
Homogenous Electrocatalytic Oxygen Reduction Rates Correlate with Reaction Overpotential in Acidic Organic Solutions Pegis, Michael L.; McKeown, Bradley A.; Kumar, Neeraj ACS Central Science, Vol. 2, Issue 11 https://doi.org/10.1021/acscentsci.6b00261	journal	October 2016
A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s^-1 for H₂ Production Helm, M. L.; Stewart, M. P.; Bullock, R. M. Science, Vol. 333, Issue 6044, p. 863-866 https://doi.org/10.1126/science.1205864	journal	August 2011
Production of H2 at fast rates using a nickel electrocatalyst in water–acetonitrile solutions Hoffert, Wesley A.; Roberts, John A. S.; Morris Bullock, R. Chemical Communications, Vol. 49, Issue 71 https://doi.org/10.1039/c3cc43203c	journal	January 2013
Benchmarking of Homogeneous Electrocatalysts: Overpotential, Turnover Frequency, Limiting Turnover Number Costentin, Cyrille; Passard, Guillaume; Savéant, Jean-Michel Journal of the American Chemical Society, Vol. 137, Issue 16 https://doi.org/10.1021/jacs.5b00914	journal	April 2015
Multielectron, Multistep Molecular Catalysis of Electrochemical Reactions: Benchmarking of Homogeneous Catalysts Costentin, Cyrille; Savéant, Jean-Michel ChemElectroChem, Vol. 1, Issue 7 https://doi.org/10.1002/celc.201300263	journal	June 2014
Electrocatalytic Oxygen Reduction by Iron Tetra-arylporphyrins Bearing Pendant Proton Relays Carver, Colin T.; Matson, Benjamin D.; Mayer, James M. Journal of the American Chemical Society, Vol. 134, Issue 12 https://doi.org/10.1021/ja211987f	journal	March 2012
Distant protonated pyridine groups in water-soluble iron porphyrin electrocatalysts promote selective oxygen reduction to water Matson, Benjamin D.; Carver, Colin T.; Von Ruden, Amber Chemical Communications, Vol. 48, Issue 90 https://doi.org/10.1039/c2cc35576k	journal	January 2012
Direct Comparison of Electrochemical and Spectrochemical Kinetics for Catalytic Oxygen Reduction Wasylenko, Derek J.; Rodríguez, Carlos; Pegis, Michael L. Journal of the American Chemical Society, Vol. 136, Issue 36 https://doi.org/10.1021/ja505667t	journal	August 2014
Evaluation of Homogeneous Electrocatalysts by Cyclic Voltammetry Rountree, Eric S.; McCarthy, Brian D.; Eisenhart, Thomas T. Inorganic Chemistry, Vol. 53, Issue 19 https://doi.org/10.1021/ic500658x	journal	September 2014
Mechanism of Four-Electron Reduction of Dioxygen to Water by Ferrocene Derivatives in the Presence of Perchloric Acid in Benzonitrile, Catalyzed by Cofacial Dicobalt Porphyrins Fukuzumi, Shunichi; Okamoto, Ken; Gros, Claude P. Journal of the American Chemical Society, Vol. 126, Issue 33 https://doi.org/10.1021/ja048403c	journal	August 2004
Proton-Coupled Electron-Transfer Reduction of Dioxygen Catalyzed by a Saddle-Distorted Cobalt Phthalocyanine Honda, Tatsuhiko; Kojima, Takahiko; Fukuzumi, Shunichi Journal of the American Chemical Society, Vol. 134, Issue 9 https://doi.org/10.1021/ja209978q	journal	February 2012
Temperature-Independent Catalytic Two-Electron Reduction of Dioxygen by Ferrocenes with a Copper(II) Tris[2-(2-pyridyl)ethyl]amine Catalyst in the Presence of Perchloric Acid Das, Dipanwita; Lee, Yong-Min; Ohkubo, Kei Journal of the American Chemical Society, Vol. 135, Issue 7 https://doi.org/10.1021/ja312523u	journal	February 2013
Effective Reversible Potential, Energy Loss, and Overpotential on Platinum Fuel Cell Cathodes Tian, Feng; Anderson, Alfred B. The Journal of Physical Chemistry C, Vol. 115, Issue 10 https://doi.org/10.1021/jp1100126	journal	February 2011
Functional Independent Scaling Relation for ORR/OER Catalysts Christensen, Rune; Hansen, Heine A.; Dickens, Colin F. The Journal of Physical Chemistry C, Vol. 120, Issue 43 https://doi.org/10.1021/acs.jpcc.6b09141	journal	October 2016
Examining the Linearity of Transition State Scaling Relations Plessow, Philipp N.; Abild-Pedersen, Frank The Journal of Physical Chemistry C, Vol. 119, Issue 19 https://doi.org/10.1021/acs.jpcc.5b02055	journal	May 2015
Tuning protein–protein interactions using cosolvents: specific effects of ionic and non-ionic additives on protein phase behavior Hansen, Jan; Platten, Florian; Wagner, Dana Physical Chemistry Chemical Physics, Vol. 18, Issue 15 https://doi.org/10.1039/C5CP07285A	journal	January 2016
Activity Descriptor Identification for Oxygen Reduction on Nonprecious Electrocatalysts: Linking Surface Science to Coordination Chemistry Ramaswamy, Nagappan; Tylus, Urszula; Jia, Qingying Journal of the American Chemical Society, Vol. 135, Issue 41 https://doi.org/10.1021/ja405149m	journal	October 2013
Theory of multiple proton–electron transfer reactions and its implications for electrocatalysis Koper, Marc T. M. Chemical Science, Vol. 4, Issue 7 https://doi.org/10.1039/c3sc50205h	journal	January 2013
In Situ Electrochemical Generation of Hydrogen Peroxide in Alkaline Aqueous Solution by using an Unmodified Gas Diffusion Electrode Barros, Willyam R. P.; Ereno, Thaís; Tavares, Ana C. ChemElectroChem, Vol. 2, Issue 5 https://doi.org/10.1002/celc.201402426	journal	February 2015
Identifying and Breaking Scaling Relations in Molecular Catalysis of Electrochemical Reactions Pegis, Michael L.; Wise, Catherine F.; Koronkiewicz, Brian Journal of the American Chemical Society, Vol. 139, Issue 32 https://doi.org/10.1021/jacs.7b05642	journal	August 2017
Metal ion-coupled and decoupled electron transfer Fukuzumi, Shunichi; Ohkubo, Kei Coordination Chemistry Reviews, Vol. 254, Issue 3-4 https://doi.org/10.1016/j.ccr.2009.10.020	journal	February 2010
Mechanisms of metal ion-coupled electron transfer Fukuzumi, Shunichi; Ohkubo, Kei; Morimoto, Yuma Physical Chemistry Chemical Physics, Vol. 14, Issue 24 https://doi.org/10.1039/c2cp40459a	journal	January 2012
Superoxide Ion: Generation and Chemical Implications Hayyan, Maan; Hashim, Mohd Ali; AlNashef, Inas M. Chemical Reviews, Vol. 116, Issue 5 https://doi.org/10.1021/acs.chemrev.5b00407	journal	February 2016
Reduction of oxygen by ruthenium(II) ammines Stanbury, David M.; Haas, Otto; Taube, Henry Inorganic Chemistry, Vol. 19, Issue 2 https://doi.org/10.1021/ic50204a048	journal	February 1980
Reactivity of HO ₂ /O ⁻ ₂ Radicals in Aqueous Solution Bielski, Benon H. J.; Cabelli, Diane E.; Arudi, Ravindra L. Journal of Physical and Chemical Reference Data, Vol. 14, Issue 4 https://doi.org/10.1063/1.555739	journal	October 1985
A convenient route to superoxide ion in aqueous solution McDowell, M. Steven; Bakac, Andreja; Espenson, James H. Inorganic Chemistry, Vol. 22, Issue 5 https://doi.org/10.1021/ic00147a033	journal	March 1983
Superoxide reactions with (isonicotinamide)pentaammineruthenium(II) and -(III) Stanbury, David M.; Mulac, William A.; Sullivan, James C. Inorganic Chemistry, Vol. 19, Issue 12 https://doi.org/10.1021/ic50214a032	journal	December 1980
Kinetics of aqueous outer-sphere electron-transfer reactions of superoxide ion. Implications concerning the dioxygen/superoxide (O2/O2-) self-exchange rate constant McDowell, M. Steven; Espenson, James H.; Bakac, Andreja Inorganic Chemistry, Vol. 23, Issue 15 https://doi.org/10.1021/ic00183a007	journal	July 1984
Reactions of polypyridylchromium(II) ions with oxygen: determination of the self-exchange rate constant of oxygen O2/O2- Zahir, Khurram.; Espenson, James H.; Bakac, Andreja. Journal of the American Chemical Society, Vol. 110, Issue 15 https://doi.org/10.1021/ja00223a025	journal	July 1988
Determination of the rate constant of self-exchange of the oxygen O2/O2- couple in water by 18O/16O isotope marking Lind, J.; Shen, X.; Merenyi, Gabar Journal of the American Chemical Society, Vol. 111, Issue 19 https://doi.org/10.1021/ja00201a078	journal	September 1989
Oxygen Isotope Effects on Electron Transfer to O ₂ Probed Using Chemically Modified Flavins Bound to Glucose Oxidase Roth, Justine P.; Wincek, Roseanne; Nodet, Gabrielle Journal of the American Chemical Society, Vol. 126, Issue 46 https://doi.org/10.1021/ja047050e	journal	November 2004
Oxygen Isotope Effects as Probes of Electron Transfer Mechanisms and Structures of Activated O ₂ Roth, Justine P. Accounts of Chemical Research, Vol. 42, Issue 3 https://doi.org/10.1021/ar800169z	journal	February 2009
Outer-Sphere Oxidation of the Superoxide Radical Anion Weinstock, Ira A. Inorganic Chemistry, Vol. 47, Issue 2 https://doi.org/10.1021/ic701885q	journal	December 2007
Autoxidation of binuclear ruthenium(II) ammines Stanbury, David M.; Gaswick, Dennis; Brown, Gilbert M. Inorganic Chemistry, Vol. 22, Issue 14 https://doi.org/10.1021/ic00156a009	journal	July 1983
Reversible Reduction of Oxygen to Peroxide Facilitated by Molecular Recognition Lopez, N.; Graham, D. J.; McGuire, R. Science, Vol. 335, Issue 6067 https://doi.org/10.1126/science.1212678	journal	January 2012
Electron-Transfer Studies of a Peroxide Dianion Ullman, Andrew M.; Sun, Xianru; Graham, Daniel J. Inorganic Chemistry, Vol. 53, Issue 10 https://doi.org/10.1021/ic500759g	journal	April 2014
Ultrafast Photoinduced Electron Transfer from Peroxide Dianion Anderson, Bryce L.; Maher, Andrew G.; Nava, Matthew The Journal of Physical Chemistry B, Vol. 119, Issue 24 https://doi.org/10.1021/jp5110505	journal	December 2014
Hydrogen atom abstraction from amine complexes of iron(II), cobalt(II), and ruthenium(II) by superoxide: influence of driving force on rate Bernhard, Paul; Anson, Fred C. Inorganic Chemistry, Vol. 27, Issue 25 https://doi.org/10.1021/ic00298a014	journal	December 1988
Autoxidation of the (sarcophagine)ruthenium(2+) complex involving hydrogen atom transfer to superoxide Bernhard, Paul; Sargeson, Alan M.; Anson, Fred C. Inorganic Chemistry, Vol. 27, Issue 16 https://doi.org/10.1021/ic00289a003	journal	August 1988
Enabling direct H2O2 production through rational electrocatalyst design Siahrostami, Samira; Verdaguer-Casadevall, Arnau; Karamad, Mohammadreza Nature Materials, Vol. 12, Issue 12 https://doi.org/10.1038/nmat3795	journal	November 2013
Single Atom Hot-Spots at Au–Pd Nanoalloys for Electrocatalytic H ₂ O ₂ Production Jirkovský, Jakub S.; Panas, Itai; Ahlberg, Elisabet Journal of the American Chemical Society, Vol. 133, Issue 48 https://doi.org/10.1021/ja206477z	journal	December 2011
Mesoporous Nitrogen-Doped Carbon for the Electrocatalytic Synthesis of Hydrogen Peroxide Fellinger, Tim-Patrick; Hasché, Frédéric; Strasser, Peter Journal of the American Chemical Society, Vol. 134, Issue 9 https://doi.org/10.1021/ja300038p	journal	February 2012
Outer-sphere electron transfer kinetics of metal ion oxidation by molecular oxygen Rosso, Kevin M.; Morgan, James J. Geochimica et Cosmochimica Acta, Vol. 66, Issue 24 https://doi.org/10.1016/S0016-7037(02)01040-2	journal	December 2002
Mechanism of superoxide ion disproportionation in aprotic solvents Andrieux, Claude P.; Hapiot, Philippe; Saveant, Jean Michel Journal of the American Chemical Society, Vol. 109, Issue 12 https://doi.org/10.1021/ja00246a040	journal	June 1987
Electrolytic reduction of oxygen in aprotic solvents: The superoxide ion Peover, M. E.; White, B. S. Electrochimica Acta, Vol. 11, Issue 8 https://doi.org/10.1016/0013-4686(66)80043-9	journal	August 1966
Electrochemistry of oxygen and superoxide ion in dimethylsulfoxide at platinum, gold and mercury electrodes Sawyer, Donald T.; Roberts, Julian L. Journal of Electroanalytical Chemistry (1959), Vol. 12, Issue 2 https://doi.org/10.1016/0022-0728(66)80021-9	journal	August 1966
Acceleration of the Homogeneous and Electrochemical Reductions of Dioxygen in Aprotic Media by Ammonium Ions. Is the Driving Force a Function of NH ₄ ⁺ Concentration? What Is the Mechanism of the Reaction? Costentin, Cyrille; Robert, Marc; Savéant, Jean-Michel The Journal of Physical Chemistry C, Vol. 111, Issue 35 https://doi.org/10.1021/jp0750654	journal	September 2007
Proton-induced disproportionation of superoxide ion in aprotic media Chin, Der Hang; Chiericato, Glaico; Nanni, Edward J. Journal of the American Chemical Society, Vol. 104, Issue 5 https://doi.org/10.1021/ja00369a025	journal	March 1982
Electrochemical reduction of dioxygen to perhydroxyl (HO2.cntdot.) in aprotic solvents that contain Broensted acids Cofre, Pablo.; Sawyer, Donald T. Analytical Chemistry, Vol. 58, Issue 6 https://doi.org/10.1021/ac00297a017	journal	May 1986
Activation of Electron-Transfer Reduction of Oxygen by Hydrogen Bond Formation of Superoxide Anion with Ammonium Ion Ohkubo, Kei; Kitaguchi, Hironori; Fukuzumi, Shunichi The Journal of Physical Chemistry A, Vol. 110, Issue 41 https://doi.org/10.1021/jp064115m	journal	September 2006
One-electron mechanism for the electrochemical reduction of molecular oxygen Sawyer, Donald T.; Seo, Eddie T. Inorganic Chemistry, Vol. 16, Issue 2 https://doi.org/10.1021/ic50168a059	journal	February 1977
Electrochemical reduction of superoxide ion and oxidation of hydroxide ion in dimethyl sulfoxide Goolsby, Alvin D.; Sawyer, Donald T. Analytical Chemistry, Vol. 40, Issue 1 https://doi.org/10.1021/ac60257a022	journal	January 1968
Electroreduction of oxygen in aprotic media Vasudevan, D.; Wendt, H. Journal of Electroanalytical Chemistry, Vol. 392, Issue 1-2 https://doi.org/10.1016/0022-0728(95)04044-O	journal	July 1995
Electrochemical Approach to Concerted Proton and Electron Transfers. Reduction of the Water−Superoxide Ion Complex Costentin, Cyrille; Evans, Dennis H.; Robert, Marc Journal of the American Chemical Society, Vol. 127, Issue 36 https://doi.org/10.1021/ja053911n	journal	September 2005
Study of the Electrochemical Reduction of Dioxygen in Acetonitrile in the Presence of Weak Acids Singh, Pradyumna S.; Evans, Dennis H. The Journal of Physical Chemistry B, Vol. 110, Issue 1 https://doi.org/10.1021/jp055296f	journal	January 2006
Electrochemical Concerted Proton and Electron Transfers. Further Insights in the Reduction Mechanism of Superoxide Ion in the Presence of Water and Other Weak Acids Savéant, Jean-Michel The Journal of Physical Chemistry C, Vol. 111, Issue 7 https://doi.org/10.1021/jp068322y	journal	February 2007
Direct and Cytochromec Mediated Electrochemistry of Bilirubin Oxidase on Gold Dronov, Roman; Kurth, Dirk G.; Scheller, Frieder W. Electroanalysis, Vol. 19, Issue 15 https://doi.org/10.1002/elan.200703900	journal	August 2007
Mediated Electrochemistry of Horseradish Peroxidase. Catalysis and Inhibition Dequaire, Murielle; Limoges, Benoît; Moiroux, Jacques Journal of the American Chemical Society, Vol. 124, Issue 2 https://doi.org/10.1021/ja0170706	journal	December 2001
Electron transfer coupling of diffusional pathways. Homogeneous redox catalysis of dioxygen reduction by the methylviologen cation radical in acidic dimethylsulfoxide Andrieux, C. P.; Hapiot, P.; Sa Véant, J. M. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 189, Issue 1 https://doi.org/10.1016/0368-1874(85)85630-6	journal	July 1985
Homogeneous redox catalysis of electrochemical reaction Savéant, J. M.; Su, K. B. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 171, Issue 1-2 https://doi.org/10.1016/0022-0728(84)80125-4	journal	August 1984
Molecular catalysis of electrochemical reactions Costentin, Cyrille; Robert, Marc; Savéant, Jean-Michel Current Opinion in Electrochemistry, Vol. 2, Issue 1 https://doi.org/10.1016/j.coelec.2017.02.006	journal	April 2017
Preparation and electrochemistry of several substituted 9-(4-R-phenyl)-N-methylacridinium salts. Audebert, P.; Hapiot, P. Journal of Electroanalytical Chemistry, Vol. 361, Issue 1-2 https://doi.org/10.1016/0022-0728(93)87052-W	journal	December 1993
Electroreduction of Oxygen in a Series of Room Temperature Ionic Liquids Composed of Group 15-Centered Cations and Anions Evans, Russell G.; Klymenko, Oleksiy V.; Saddoughi, Sahar A. The Journal of Physical Chemistry B, Vol. 108, Issue 23 https://doi.org/10.1021/jp031309i	journal	June 2004
Superoxide Protonation by Weak Acids in Imidazolium Based Ionic Liquids René, Alice; Hauchard, Didier; Lagrost, Corinne The Journal of Physical Chemistry B, Vol. 113, Issue 9 https://doi.org/10.1021/jp810249p	journal	March 2009
Oxygen Reduction Reaction in Ionic Liquids: The Addition of Protic Species Switzer, Elise E.; Zeller, Robert; Chen, Qing The Journal of Physical Chemistry C, Vol. 117, Issue 17 https://doi.org/10.1021/jp400845u	journal	April 2013
Electrochemical Reduction of Oxygen in Some Hydrophobic Room-Temperature Molten Salt Systems Katayama, Yasushi; Onodera, Hokuto; Yamagata, Masaki Journal of The Electrochemical Society, Vol. 151, Issue 1 https://doi.org/10.1149/1.1626669	journal	January 2004
Effect of Water and Dimethyl Sulfoxide on Oxygen Reduction Reaction in Bis(trifluoromethanesulfonyl)imide-based Ionic Liquids Yuan, Xiao-Zi; Alzate, Vanesa; Xie, Zhong Journal of The Electrochemical Society, Vol. 161, Issue 4 https://doi.org/10.1149/2.010404jes	journal	January 2014
The acceptor number ? A quantitative empirical parameter for the electrophilic properties of solvents Mayer, Ulrich; Gutmann, Viktor; Gerger, Wolfgang Monatshefte f�r Chemie, Vol. 106, Issue 6 https://doi.org/10.1007/BF00913599	journal	January 1975
Correlation of homogeneous self-exchange and electrochemical rate data. Anomalously low reorganizational barriers in electron transfer reactions of cobalt complexes Endicott, John F.; Schroeder, Ronald R.; Chidester, Dale H. The Journal of Physical Chemistry, Vol. 77, Issue 21 https://doi.org/10.1021/j100907a019	journal	October 1973
Electron spin resonance spectra of ferricenium salts Prins, R.; Kortbeek, A. G. T. G. Journal of Organometallic Chemistry, Vol. 33, Issue 2 https://doi.org/10.1016/S0022-328X(00)88390-4	journal	December 1971
Protonation of Metallocenes by Strong Acids. Structure of the Cation Curphey, T. J.; Santer, J. O.; Rosenblum, M. Journal of the American Chemical Society, Vol. 82, Issue 19 https://doi.org/10.1021/ja01504a062	journal	October 1960
Oxygen and proton reduction by decamethylferrocene in non-aqueous acidic media Su, Bin; Hatay, Imren; Ge, Pei Yu Chemical Communications, Vol. 46, Issue 17 https://doi.org/10.1039/b926963k	journal	January 2010
H2O2 Generation by Decamethylferrocene at a Liquid\|Liquid Interface Su, Bin; Nia, Raheleh Partovi; Li, Fei Angewandte Chemie International Edition, Vol. 47, Issue 25 https://doi.org/10.1002/anie.200801004	journal	June 2008
Oxygen and hydrogen peroxide reduction by 1,2-diferrocenylethane at a liquid/liquid interface Deng, Haiqiang; Peljo, Pekka; Cortés-Salazar, Fernando Journal of Electroanalytical Chemistry, Vol. 681 https://doi.org/10.1016/j.jelechem.2012.04.033	journal	August 2012
Oxygen reduction by decamethylferrocene at liquid/liquid interfaces catalyzed by dodecylaniline Su, Bin; Hatay, Imren; Li, Fei Journal of Electroanalytical Chemistry, Vol. 639, Issue 1-2 https://doi.org/10.1016/j.jelechem.2009.11.029	journal	February 2010
Mechanism of oxygen reduction by metallocenes near liquid\|liquid interfaces Jane Stockmann, T.; Deng, Haiqiang; Peljo, Pekka Journal of Electroanalytical Chemistry, Vol. 729 https://doi.org/10.1016/j.jelechem.2014.07.001	journal	September 2014
Hydrogen Peroxide Generation at Liquid\|Liquid Interface under Conditions Unfavorable for Proton Transfer from Aqueous to Organic Phase Jedraszko, Justyna; Nogala, Wojciech; Adamiak, Wojciech The Journal of Physical Chemistry C, Vol. 117, Issue 40 https://doi.org/10.1021/jp406422d	journal	September 2013
Detection of hydrogen peroxide produced at a liquid/liquid interface using scanning electrochemical microscopy Li, Fei; Su, Bin; Salazar, Fernando Cortes Electrochemistry Communications, Vol. 11, Issue 2 https://doi.org/10.1016/j.elecom.2008.12.020	journal	February 2009
Catalysis at the room temperature ionic liquid\|water interface: H ₂ O ₂ generation Jedraszko, Justyna; Nogala, Wojciech; Adamiak, Wojciech Chemical Communications, Vol. 51, Issue 31 https://doi.org/10.1039/C5CC01480H	journal	January 2015
Kinetic differentiation of bulk/interfacial oxygen reduction mechanisms at/near liquid/liquid interfaces using scanning electrochemical microscopy Deng, Haiqiang; Peljo, Pekka; Momotenko, Dmitry Journal of Electroanalytical Chemistry, Vol. 732 https://doi.org/10.1016/j.jelechem.2014.08.031	journal	October 2014
Electrochemical oxygen reduction at soft interfaces catalyzed by the transfer of hydrated lithium cations Deng, Haiqiang; Stockmann, T. Jane; Peljo, Pekka Journal of Electroanalytical Chemistry, Vol. 731 https://doi.org/10.1016/j.jelechem.2014.07.040	journal	October 2014
Hydrogen and Hydrogen Peroxide Formation in Trifluorotoluene–Water Biphasic Systems Adamiak, Wojciech; Jedraszko, Justyna; Krysiak, Olga The Journal of Physical Chemistry C, Vol. 118, Issue 40 https://doi.org/10.1021/jp507310d	journal	September 2014
Regioselective protonation of ferrocene in superacid and formation of a CHFe bond. An experimental and theoretical study of the structure and dynamics of the ferrocenonium ion Karlsson, Annika; Broo, Anders; Ahlberg, Per Canadian Journal of Chemistry, Vol. 77, Issue 5-6 https://doi.org/10.1139/v99-053	journal	June 1999
Enolization and oxidation: II. Oxidation of ferrocene by molecular oxygen and hydrogen peroxide in acidic media Lubach, J.; Drenth, W. Recueil des Travaux Chimiques des Pays-Bas, Vol. 92, Issue 6 https://doi.org/10.1002/recl.19730920602	journal	January 1973
Common relationships of ferrocene oxidation with oxygen and sulfur dioxide in acid solutions and of its direct oxidation with carboxylic acids Fomin, V. M. Russian Journal of General Chemistry, Vol. 77, Issue 5 https://doi.org/10.1134/S1070363207050246	journal	May 2007
Electrochemical evidence of catalysis of oxygen reduction at the polarized liquid–liquid interface by tetraphenylporphyrin monoacid and diacid Trojánek, Antonín; Langmaier, Jan; Su, Bin Electrochemistry Communications, Vol. 11, Issue 10 https://doi.org/10.1016/j.elecom.2009.08.022	journal	October 2009
Fine tuning of the catalytic effect of a metal-free porphyrin on the homogeneous oxygen reduction Trojánek, Antonín; Langmaier, Jan; Šebera, Jakub Chemical Communications, Vol. 47, Issue 19 https://doi.org/10.1039/c1cc11075f	journal	January 2011
Thermodynamic driving force effects in the oxygen reduction catalyzed by a metal-free porphyrin Trojánek, Antonín; Langmaier, Jan; Samec, Zdeněk Electrochimica Acta, Vol. 82 https://doi.org/10.1016/j.electacta.2012.03.129	journal	November 2012
Competitive inhibition of a metal-free porphyrin oxygen-reduction catalyst by water Trojánek, Antonín; Langmaier, Jan; Záliš, Stanislav Chemical Communications, Vol. 48, Issue 34 https://doi.org/10.1039/c2cc31082a	journal	January 2012
Metal-Free-Porphyrin-Catalyzed Oxygen Reduction at Liquid-Liquid Interfaces Wu, Suozhu; Su, Bin Chemistry - A European Journal, Vol. 18, Issue 11 https://doi.org/10.1002/chem.201103526	journal	February 2012
Catalytic two-electron reduction of dioxygen catalysed by metal-free [14]triphyrin(2.1.1) Mase, Kentaro; Ohkubo, Kei; Xue, Zhaoli Chemical Science, Vol. 6, Issue 11 https://doi.org/10.1039/C5SC02465J	journal	January 2015
Oxygen Reduction Catalyzed by a Fluorinated Tetraphenylporphyrin Free Base at Liquid/Liquid Interfaces Hatay, Imren; Su, Bin; Méndez, Manuel A. Journal of the American Chemical Society, Vol. 132, Issue 39 https://doi.org/10.1021/ja103460p	journal	October 2010
Lewis Acid Coupled Electron Transfer of Metal-Oxygen Intermediates Fukuzumi, Shunichi; Ohkubo, Kei; Lee, Yong-Min Chemistry - A European Journal, Vol. 21, Issue 49 https://doi.org/10.1002/chem.201502693	journal	September 2015
ESR Spectra of Superoxide Anion−Scandium Complexes Detectable in Fluid Solution Fukuzumi, Shunichi; Patz, Matthias; Suenobu, Tomoyoshi Journal of the American Chemical Society, Vol. 121, Issue 7 https://doi.org/10.1021/ja981289b	journal	February 1999
Quantitative Evaluation of Lewis Acidity of Metal Ions with Different Ligands and Counterions in Relation to the Promoting Effects of Lewis Acids on Electron Transfer Reduction of Oxygen Ohkubo, Kei; Menon, Saija C.; Orita, Akihiro The Journal of Organic Chemistry, Vol. 68, Issue 12 https://doi.org/10.1021/jo034258u	journal	June 2003
Metallophthalocyanines as catalysts in electrochemical reactions Zagal, José H. Coordination Chemistry Reviews, Vol. 119 https://doi.org/10.1016/0010-8545(92)80031-L	journal	October 1992
Models for the adsorption of dioxygen on metal chelates Elzing, A.; van der Putten, A.; Visscher, W. Recueil des Travaux Chimiques des Pays-Bas, Vol. 109, Issue 2 https://doi.org/10.1002/recl.19901090202	journal	January 1990
Dioxygen activation chemistry by synthetic mononuclear nonheme iron, copper and chromium complexes Hong, Seungwoo; Lee, Yong-Min; Ray, Kallol Coordination Chemistry Reviews, Vol. 334 https://doi.org/10.1016/j.ccr.2016.07.006	journal	March 2017
Activation of Dioxygen by Iron and Manganese Complexes: A Heme and Nonheme Perspective Sahu, Sumit; Goldberg, David P. Journal of the American Chemical Society, Vol. 138, Issue 36 https://doi.org/10.1021/jacs.6b05251	journal	August 2016
Role of the Secondary Coordination Sphere in Metal-Mediated Dioxygen Activation Shook, Ryan L.; Borovik, A. S. Inorganic Chemistry, Vol. 49, Issue 8 https://doi.org/10.1021/ic901550k	journal	April 2010
Role of Proton-Coupled Electron Transfer in O–O Bond Activation Rosenthal, Joel; Nocera, Daniel G. Accounts of Chemical Research, Vol. 40, Issue 7 https://doi.org/10.1021/ar7000638	journal	July 2007
Synthetic oxygen carriers related to biological systems Jones, Robert D.; Summerville, David A.; Basolo, Fred. Chemical Reviews, Vol. 79, Issue 2 https://doi.org/10.1021/cr60318a002	journal	April 1979
Synthetic Heme-Dioxygen Complexes Momenteau, Michel; Reed, Christopher A. Chemical Reviews, Vol. 94, Issue 3 https://doi.org/10.1021/cr00027a006	journal	May 1994
Structure and Spectroscopy of Copper−Dioxygen Complexes Mirica, Liviu M.; Ottenwaelder, Xavier; Stack, T. Daniel P. Chemical Reviews, Vol. 104, Issue 2 https://doi.org/10.1021/cr020632z	journal	February 2004
Reactivity of Dioxygen−Copper Systems Lewis, Elizabeth A.; Tolman, William B. Chemical Reviews, Vol. 104, Issue 2 https://doi.org/10.1021/cr020633r	journal	February 2004
Copper–Oxygen Complexes Revisited: Structures, Spectroscopy, and Reactivity Elwell, Courtney E.; Gagnon, Nicole L.; Neisen, Benjamin D. Chemical Reviews, Vol. 117, Issue 3 https://doi.org/10.1021/acs.chemrev.6b00636	journal	January 2017
Nature of the Iron–Oxygen Bond in Oxyhæmoglobin Pauling, Linus Nature, Vol. 203, Issue 4941 https://doi.org/10.1038/203182b0	journal	July 1964
N -Heterocyclic Carbene Complexes of Rh: Reaction with Dioxygen without Oxidation Praetorius, Jeremy M.; Allen, Daryl P.; Wang, Ruiyao Journal of the American Chemical Society, Vol. 130, Issue 12 https://doi.org/10.1021/ja7108213	journal	March 2008
Dioxygen adducts of rhodium N-heterocyclic carbene complexes Keske, Eric C.; Zenkina, Olena V.; Asadi, Ali Dalton Transactions, Vol. 42, Issue 20 https://doi.org/10.1039/c3dt32264e	journal	January 2013
Catalytic Reduction of Dioxygen to Water with a Monomeric Manganese Complex at Room Temperature Shook, Ryan L.; Peterson, Sonja M.; Greaves, John Journal of the American Chemical Society, Vol. 133, Issue 15 https://doi.org/10.1021/ja106564a	journal	April 2011
Molecular Catalysis in a Fuel Cell Matsumoto, Takahiro; Kim, Kyoungmok; Ogo, Seiji Angewandte Chemie International Edition, Vol. 50, Issue 47 https://doi.org/10.1002/anie.201104498	journal	September 2011
Simple Ligand Effects Switch a Hydrogenase Mimic between H ₂ and O ₂ Activation Kim, Kyoungmok; Matsumoto, Takahiro; Robertson, Andrew Chemistry - An Asian Journal, Vol. 7, Issue 6 https://doi.org/10.1002/asia.201101020	journal	March 2012
Hydrogenation of a Rhodium Peroxido Complex by Formate Derivatives: Mechanistic Studies and the Catalytic Formation of H ₂ O ₂ from O ₂ Meier, Gregor; Braun, Thomas Angewandte Chemie International Edition, Vol. 51, Issue 50 https://doi.org/10.1002/anie.201207073	journal	November 2012
Density Functional Theory Study of Transitional Metal Macrocyclic Complexes' Dioxygen-Binding Abilities and Their Catalytic Activities toward Oxygen Reduction Reaction Shi, Zheng; Zhang, Jiujun The Journal of Physical Chemistry C, Vol. 111, Issue 19 https://doi.org/10.1021/jp0671749	journal	May 2007
Homogeneous catalysis of the electrochemical reduction of dioxygen by a macrocyclic cobalt(III) complex Geiger, Thomas; Anson, Fred C. Journal of the American Chemical Society, Vol. 103, Issue 25 https://doi.org/10.1021/ja00415a016	journal	December 1981
Effects of Coordination to a Macrocyclic Cobalt Complex on the Electrochemistry of Dioxygen, Superoxide, and Hydroperoxide Kang, Chan; Anson, Fred C. Inorganic Chemistry, Vol. 34, Issue 10 https://doi.org/10.1021/ic00114a041	journal	May 1995
Analysis of Porphyrines as Catalysts for Electrochemical Reduction of O ₂ and Oxidation of H ₂ O Baran, Jakub D.; Grönbeck, Henrik; Hellman, Anders Journal of the American Chemical Society, Vol. 136, Issue 4 https://doi.org/10.1021/ja4060299	journal	January 2014
Probing structure-function relations in heme-containing oxygenases and peroxidases Dawson, J. Science, Vol. 240, Issue 4851 https://doi.org/10.1126/science.3358128	journal	April 1988
On the role of the axial ligand in heme-based catalysis of the peroxidase and P450 type Rietjens, I. M. C. M.; Osman, Ahmed M.; Veeger, Cees JBIC Journal of Biological Inorganic Chemistry, Vol. 1, Issue 4 https://doi.org/10.1007/s007750050068	journal	August 1996
The role of the proximal ligand in heme enzymes Poulos, Thomas L. JBIC Journal of Biological Inorganic Chemistry, Vol. 1, Issue 4 https://doi.org/10.1007/s007750050064	journal	August 1996
When an amide is more like histidine than imidazole: the role of axial ligands in heme catalysis Goodin, D. B. JBIC Journal of Biological Inorganic Chemistry, Vol. 1, Issue 4 https://doi.org/10.1007/s007750050065	journal	August 1996
Chemical properties of water-soluble porphyrins. 2. The reaction of iron(III) tetrakis(4-N-methylpyridyl)porphyrin with the superoxide radical dioxygen couple Solomon, D.; Peretz, P.; Faraggi, M. The Journal of Physical Chemistry, Vol. 86, Issue 10 https://doi.org/10.1021/j100207a021	journal	May 1982
Effects of Axial Coordination of the Metal Center on the Activity of Iron Tetraphenylporphyrin as a Nonprecious Catalyst for Oxygen Reduction Chlistunoff, Jerzy; Sansiñena, Jose-Maria The Journal of Physical Chemistry C, Vol. 118, Issue 33 https://doi.org/10.1021/jp5044249	journal	August 2014
Imidazole ligand effect on O2 interaction with metalloporphyrins Tsuda, Muneyuki; Kasai, Hideaki Surface Science, Vol. 601, Issue 22 https://doi.org/10.1016/j.susc.2007.04.229	journal	November 2007
The secondary coordination sphere and axial ligand effects on oxygen reduction reaction by iron porphyrins: a DFT computational study Ohta, Takehiro; Nagaraju, Perumandla; Liu, Jin-Gang JBIC Journal of Biological Inorganic Chemistry, Vol. 21, Issue 5-6 https://doi.org/10.1007/s00775-016-1380-9	journal	August 2016
Heme-Containing Oxygenases Sono, Masanori; Roach, Mark P.; Coulter, Eric D. Chemical Reviews, Vol. 96, Issue 7 https://doi.org/10.1021/cr9500500	journal	January 1996
Copper Active Sites in Biology Solomon, Edward I.; Heppner, David E.; Johnston, Esther M. Chemical Reviews, Vol. 114, Issue 7 https://doi.org/10.1021/cr400327t	journal	January 2014
Catalytic mechanism of cytochrome P-450: evidence for a distal charge relay Gerber, Nancy C.; Sligar, Stephen G. Journal of the American Chemical Society, Vol. 114, Issue 22 https://doi.org/10.1021/ja00048a081	journal	October 1992
Control of the catalytic activity of prosthetic heme by the structure of hemoproteins Ortiz de Montellano, Paul R. Accounts of Chemical Research, Vol. 20, Issue 8 https://doi.org/10.1021/ar00140a004	journal	August 1987
Mechanism of Oxidation Reactions Catalyzed by Cytochrome P450 Enzymes Meunier, Bernard; de Visser, Samuël P.; Shaik, Sason Chemical Reviews, Vol. 104, Issue 9 https://doi.org/10.1021/cr020443g	journal	September 2004
Insights into metalloenzyme microenvironments: biomimetic metal complexes with a functional second coordination sphere Zhao, Meng; Wang, Hai-Bo; Ji, Liang-Nian Chemical Society Reviews, Vol. 42, Issue 21 https://doi.org/10.1039/c3cs60162e	journal	January 2013
Synthetic Models for Heme−Copper Oxidases Kim, Eunsuk; Chufán, Eduardo E.; Kamaraj, Kaliappan Chemical Reviews, Vol. 104, Issue 2 https://doi.org/10.1021/cr0206162	journal	February 2004
Bioinspired Hydrogen Bond Motifs in Ligand Design: The Role of Noncovalent Interactions in Metal Ion Mediated Activation of Dioxygen Borovik, A. S. Accounts of Chemical Research, Vol. 38, Issue 1 https://doi.org/10.1021/ar030160q	journal	January 2005
Stereoelectronic factors in CO, NO and O2 binding to heme from vibrational spectroscopy and DFT analysis Spiro, T. Coordination Chemistry Reviews, Vol. 219-221 https://doi.org/10.1016/S0010-8545(01)00384-8	journal	October 2001
On the significance of hydrogen bonds for the discrimination between CO and O2 by myoglobin Sigfridsson, Emma; Ryde, U. JBIC Journal of Biological Inorganic Chemistry, Vol. 4, Issue 1 https://doi.org/10.1007/s007750050293	journal	February 1999
“Hangman” Porphyrins for the Assembly of a Model Heme Water Channel Yeh, Chen-Yu; Chang, Christopher J.; Nocera, Daniel G. Journal of the American Chemical Society, Vol. 123, Issue 7 https://doi.org/10.1021/ja003245k	journal	February 2001
Proton-Directed Redox Control of O−O Bond Activation by Heme Hydroperoxidase Models Soper, Jake D.; Kryatov, Sergey V.; Rybak-Akimova, Elena V. Journal of the American Chemical Society, Vol. 129, Issue 16 https://doi.org/10.1021/ja0683032	journal	April 2007
Hangman Corroles: Efficient Synthesis and Oxygen Reaction Chemistry Dogutan, Dilek K.; Stoian, Sebastian A.; McGuire, Robert Journal of the American Chemical Society, Vol. 133, Issue 1 https://doi.org/10.1021/ja108904s	journal	January 2011
Catalytic O−O Activation Chemistry Mediated by Iron Hangman Porphyrins with a Wide Range of Proton-Donating Abilities Chng, Leng Leng; Chang, Christopher J.; Nocera, Daniel G. Organic Letters, Vol. 5, Issue 14 https://doi.org/10.1021/ol034581j	journal	July 2003
Synthesis of sterically hindered xanthene-modified iron corroles with catalase-like activity Zyska, Björn; Schwalbe, Matthias Chemical Communications, Vol. 49, Issue 36 https://doi.org/10.1039/c3cc40625c	journal	January 2013
Electocatalytic Water Oxidation by Cobalt(III) Hangman β-Octafluoro Corroles Dogutan, Dilek K.; McGuire, Robert; Nocera, Daniel G. Journal of the American Chemical Society, Vol. 133, Issue 24 https://doi.org/10.1021/ja202138m	journal	June 2011
O–O bond splitting mechanism in cytochrome oxidase Blomberg, M. Journal of Inorganic Biochemistry, Vol. 80, Issue 3-4 https://doi.org/10.1016/S0162-0134(00)00080-5	journal	July 2000
Modeling Cytochrome Oxidase: A Quantum Chemical Study of the O−O Bond Cleavage Mechanism Blomberg, Margareta R. A.; Siegbahn, Per E. M.; Babcock, Gerald T. Journal of the American Chemical Society, Vol. 122, Issue 51 https://doi.org/10.1021/ja002745a	journal	December 2000
Phenol-Induced O–O Bond Cleavage in a Low-Spin Heme–Peroxo–Copper Complex: Implications for O ₂ Reduction in Heme–Copper Oxidases Schaefer, Andrew W.; Kieber-Emmons, Matthew T.; Adam, Suzanne M. Journal of the American Chemical Society, Vol. 139, Issue 23 https://doi.org/10.1021/jacs.7b03292	journal	June 2017
Concerted heavy-atom bond cleavage and proton and electron transfers illustrated by proton-assisted reductive cleavage of an O-O bond Costentin, C.; Hajj, V.; Robert, M. Proceedings of the National Academy of Sciences, Vol. 108, Issue 21 https://doi.org/10.1073/pnas.1104952108	journal	May 2011
Oxygen reduction reactivity of cobalt(ii) hangman porphyrins McGuire Jr., Robert; Dogutan, Dilek K.; Teets, Thomas S. Chemical Science, Vol. 1, Issue 3 https://doi.org/10.1039/c0sc00281j	journal	January 2010
The effects of hydrogen bonds on metal-mediated O2 activation and related processes Shook, Ryan L.; Borovik, A. S. Chemical Communications, Issue 46 https://doi.org/10.1039/b810957e	journal	January 2008
Synthesis and Reactivity of Tripodal Complexes Containing Pendant Bases Blacquiere, Johanna M.; Pegis, Michael L.; Raugei, Simone Inorganic Chemistry, Vol. 53, Issue 17 https://doi.org/10.1021/ic5013389	journal	August 2014
Synthetic Mononuclear Nonheme Iron–Oxygen Intermediates Nam, Wonwoo Accounts of Chemical Research, Vol. 48, Issue 8 https://doi.org/10.1021/acs.accounts.5b00218	journal	July 2015
Status of Reactive Non-Heme Metal–Oxygen Intermediates in Chemical and Enzymatic Reactions Ray, Kallol; Pfaff, Florian Felix; Wang, Bin Journal of the American Chemical Society, Vol. 136, Issue 40 https://doi.org/10.1021/ja507807v	journal	August 2014
Electron-transfer properties of high-valent metal-oxo complexes Fukuzumi, Shunichi Coordination Chemistry Reviews, Vol. 257, Issue 9-10 https://doi.org/10.1016/j.ccr.2012.07.021	journal	May 2013
Spectroscopic Capture and Reactivity of a Low-Spin Cobalt(IV)-Oxo Complex Stabilized by Binding Redox-Inactive Metal Ions Hong, Seungwoo; Pfaff, Florian F.; Kwon, Eunji Angewandte Chemie International Edition, Vol. 53, Issue 39 https://doi.org/10.1002/anie.201405874	journal	July 2014
An Oxocobalt(IV) Complex Stabilized by Lewis Acid Interactions with Scandium(III) Ions Pfaff, Florian Felix; Kundu, Subrata; Risch, Marcel Angewandte Chemie International Edition, Vol. 50, Issue 7 https://doi.org/10.1002/anie.201005869	journal	December 2010
Autocatalytic Formation of an Iron(IV)–Oxo Complex via Scandium Ion-Promoted Radical Chain Autoxidation of an Iron(II) Complex with Dioxygen and Tetraphenylborate Nishida, Yusuke; Lee, Yong-Min; Nam, Wonwoo Journal of the American Chemical Society, Vol. 136, Issue 22 https://doi.org/10.1021/ja502732p	journal	May 2014
Sc ³⁺ -Triggered Oxoiron(IV) Formation from O ₂ and its Non-Heme Iron(II) Precursor via a Sc ³⁺ –Peroxo–Fe ³⁺ Intermediate Li, Feifei; Van Heuvelen, Katherine M.; Meier, Katlyn K. Journal of the American Chemical Society, Vol. 135, Issue 28 https://doi.org/10.1021/ja402645y	journal	May 2013
A Mononuclear Non-Heme Manganese(IV)–Oxo Complex Binding Redox-Inactive Metal Ions Chen, Junying; Lee, Yong-Min; Davis, Katherine M. Journal of the American Chemical Society, Vol. 135, Issue 17 https://doi.org/10.1021/ja312113p	journal	January 2013
Metal Ion-Coupled Electron Transfer of a Nonheme Oxoiron(IV) Complex: Remarkable Enhancement of Electron-Transfer Rates by Sc ³⁺ Morimoto, Yuma; Kotani, Hiroaki; Park, Jiyun Journal of the American Chemical Society, Vol. 133, Issue 3 https://doi.org/10.1021/ja109056x	journal	January 2011
A Manganese(V)–Oxo Complex: Synthesis by Dioxygen Activation and Enhancement of Its Oxidizing Power by Binding Scandium Ion Hong, Seungwoo; Lee, Yong-Min; Sankaralingam, Muniyandi Journal of the American Chemical Society, Vol. 138, Issue 27 https://doi.org/10.1021/jacs.6b03874	journal	June 2016
Nonredox Metal-Ions-Enhanced Dioxygen Activation by Oxidovanadium(IV) Complexes toward Hydrogen Atom Abstraction Zhang, Jisheng; Yang, Hang; Sun, Tingting Inorganic Chemistry, Vol. 56, Issue 2 https://doi.org/10.1021/acs.inorgchem.6b02277	journal	December 2016
A mononuclear nonheme iron(iii)–peroxo complex binding redox-inactive metal ions Lee, Yong-Min; Bang, Suhee; Kim, Yun Mi Chemical Science, Vol. 4, Issue 10 https://doi.org/10.1039/c3sc51864g	journal	January 2013
Fine Control of the Redox Reactivity of a Nonheme Iron(III)-Peroxo Complex by Binding Redox-Inactive Metal Ions Bae, Seong Hee; Lee, Yong-Min; Fukuzumi, Shunichi Angewandte Chemie International Edition, Vol. 56, Issue 3 https://doi.org/10.1002/anie.201610828	journal	December 2016
Redox-inactive metal ions modulate the reactivity and oxygen release of mononuclear non-haem iron(III)–peroxo complexes Bang, Suhee; Lee, Yong-Min; Hong, Seungwoo Nature Chemistry, Vol. 6, Issue 10 https://doi.org/10.1038/nchem.2055	journal	September 2014
Iron(III) Complex of a Crown Ether−Porphyrin Conjugate and Reversible Binding of Superoxide to Its Iron(II) Form Dürr, Katharina; Macpherson, Brendan P.; Warratz, Ralf Journal of the American Chemical Society, Vol. 129, Issue 14 https://doi.org/10.1021/ja064984p	journal	April 2007
Volume Profile Analysis for the Reversible Binding of Superoxide to Form Iron(II)-Superoxo/Iron(III)-Peroxo Porphyrin Complexes Dürr, Katharina; Jux, Norbert; Zahl, Achim Inorganic Chemistry, Vol. 49, Issue 23 https://doi.org/10.1021/ic102092h	journal	December 2010
Solution behavior of iron( iii ) and iron( ii ) porphyrins in DMSO and reaction with superoxide. Effect of neighboring positive charge on thermodynamics, kinetics and nature of iron-(su)peroxo product Duerr, K.; Troeppner, O.; Olah, J. Dalton Trans., Vol. 41, Issue 2 https://doi.org/10.1039/C1DT11521A	journal	January 2012
A Heterobimetallic Superoxide Complex formed through O ₂ Activation between Chromium(II) and a Lithium Cation Schax, Fabian; Suhr, Simon; Bill, Eckhard Angewandte Chemie International Edition, Vol. 54, Issue 4 https://doi.org/10.1002/anie.201409294	journal	December 2014
Synthesis and Characterization of Cofacial Metallodiporphyrins Involving Cobalt and Lewis Acid Metals: New Dinuclear Multielectron Redox Catalysts of Dioxygen Reduction Guilard, Roger; Brandes, Stephane; Tardieux, Catherine Journal of the American Chemical Society, Vol. 117, Issue 47 https://doi.org/10.1021/ja00152a013	journal	November 1995
Catalytic Cycle of a Divanadium Complex with Salen Ligands in O ₂ Reduction: Two-Electron Redox Process of the Dinuclear Center (salen = N,N‘ -Ethylenebis(salicylideneamine)) Yamamoto, Kimihisa; Oyaizu, Kenichi; Tsuchida, Eishun Journal of the American Chemical Society, Vol. 118, Issue 50 https://doi.org/10.1021/ja9617799	journal	January 1996
Catalysis of the Electroreduction of O ₂ to H ₂ O by Vanadium−salen Complexes in Acidified Dichloromethane Tsuchida, Eishun; Oyaizu, Kenichi; Dewi, Eniya Listiani Inorganic Chemistry, Vol. 38, Issue 16 https://doi.org/10.1021/ic990268v	journal	July 1999
Electrochemical Properties of Vanadium(III,IV,V)−Salen Complexes in Acetonitrile. Four-Electron Reduction of O ₂ by V(III)−Salen Liu, Zenghe; Anson, Fred C. Inorganic Chemistry, Vol. 39, Issue 2 https://doi.org/10.1021/ic990958z	journal	January 2000
Schiff Base Complexes of Vanadium(III, IV, V) as Catalysts for the Electroreduction of O ₂ to H ₂ O in Acetonitrile Liu, Zenghe; Anson, Fred C. Inorganic Chemistry, Vol. 40, Issue 6 https://doi.org/10.1021/ic0010407	journal	March 2001
High-Valent Chromium–Oxo Complex Acting as an Efficient Catalyst Precursor for Selective Two-Electron Reduction of Dioxygen by a Ferrocene Derivative Liu, Shuo; Mase, Kentaro; Bougher, Curt Inorganic Chemistry, Vol. 53, Issue 14 https://doi.org/10.1021/ic5013457	journal	June 2014
A Redox-Active Ligand as a Reservoir for Protons and Electrons: O2 Reduction at Zirconium(IV) Lu, Feng; Zarkesh, Ryan A.; Heyduk, Alan F. European Journal of Inorganic Chemistry, Vol. 2012, Issue 3 https://doi.org/10.1002/ejic.201100798	journal	October 2011
Combination of Redox-Active Ligand and Lewis Acid for Dioxygen Reduction with π-Bound Molybdenum−Quinonoid Complexes Henthorn, Justin T.; Lin, Sibo; Agapie, Theodor Journal of the American Chemical Society, Vol. 137, Issue 4 https://doi.org/10.1021/ja5100405	journal	January 2015
Electrocatalytic Reduction of Oxygen Using Water-Soluble Iron and Cobalt Phthalocyanines and Porphyrins Kobayashi, Nagao; Nevin, W. Andrew Applied Organometallic Chemistry, Vol. 10, Issue 8 https://doi.org/10.1002/(SICI)1099-0739(199610)10:8<579::AID-AOC523>3.0.CO;2-Q	journal	October 1996
Phthalocyanine Metal Complexes in Catalysis Sorokin, Alexander B. Chemical Reviews, Vol. 113, Issue 10 https://doi.org/10.1021/cr4000072	journal	June 2013
Electrochemistry of Corroles in Nonaqueous Media Fang, Yuanyuan; Ou, Zhongping; Kadish, Karl M. Chemical Reviews, Vol. 117, Issue 4 https://doi.org/10.1021/acs.chemrev.6b00546	journal	November 2016
Synthesis and Functionalization of Porphyrins through Organometallic Methodologies Hiroto, Satoru; Miyake, Yoshihiro; Shinokubo, Hiroshi Chemical Reviews, Vol. 117, Issue 4 https://doi.org/10.1021/acs.chemrev.6b00427	journal	October 2016
Catalytic electroreduction of molecular oxygen using water soluble iron porphyrin Kuwana, Theodore; Fujihira, Masamichi; Sunakawa, Kiyotaka Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 88, Issue 2 https://doi.org/10.1016/S0022-0728(78)80278-2	journal	April 1978
Rotating-ring-disk analysis of iron tetra(N-methylpyridyl)porphyrin in electrocatalysis of oxygen Bettelheim, Armand.; Kuwana, Theodore. Analytical Chemistry, Vol. 51, Issue 13 https://doi.org/10.1021/ac50049a046	journal	November 1979
Electrochemistry of oxygen reduction. 4. Oxygen to water conversion by iron(II)(tetrakis(N-methyl-4-pyridyl)porphyrin) via hydrogen peroxide Forshey, Paul A.; Kuwana, Theodore Inorganic Chemistry, Vol. 22, Issue 5 https://doi.org/10.1021/ic00147a001	journal	March 1983
Electrocatalysis of oxygen reduction by water-soluble iron porphyrins Oliver Su, Y.; Kuwana, Theodore; Chen, Shen-Ming Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 288, Issue 1-2 https://doi.org/10.1016/0022-0728(90)80034-4	journal	August 1990
Molecular Catalysis of O ₂ Reduction by Iron Porphyrins in Water: Heterogeneous versus Homogeneous Pathways Costentin, Cyrille; Dridi, Hachem; Savéant, Jean-Michel Journal of the American Chemical Society, Vol. 137, Issue 42 https://doi.org/10.1021/jacs.5b06834	journal	October 2015
Unraveling the Phase-Transfer Catalysis Mechanism of Oxygen Reduction Catalyzed by Iron(III) meso -tetra-(4- N -Methyl-pyridyl) Porphine at the Liquid/Liquid Interface Huang, Xiao; Xuan, Yaofang; Xie, Lisiqi ChemElectroChem, Vol. 3, Issue 11 https://doi.org/10.1002/celc.201600480	journal	September 2016
Catalytic electroreduction of molecular oxygen using iron or cobalt 4,4',4",4'"-tetracarboxyphthalocyanine Kobayashi, Nagao; Nishiyama, Yoshiyuki The Journal of Physical Chemistry, Vol. 89, Issue 7 https://doi.org/10.1021/j100253a023	journal	March 1985
Chemically Regenerative Redox Fuel Cells Using Iron Redox Couples as a Liquid Catalyst with Cocatalysts Han, Sang-Beom; Kwak, Da-Hee; Park, Hyun Suk ACS Catalysis, Vol. 6, Issue 8 https://doi.org/10.1021/acscatal.6b01388	journal	July 2016
Efficient reduction of dioxygen with ferrocene derivatives, catalyzed by metalloporphyrins in the presence of perchloric acid Fukuzumi, Shunichi; Mochizuki, Seiji; Tanaka, Toshio Inorganic Chemistry, Vol. 28, Issue 12 https://doi.org/10.1021/ic00311a042	journal	June 1989
Metalloporphyrin-Catalyzed Reduction of Dioxygen by Ferrocene Derivatives Fukuzumi, Shunichi; Mochizuki, Seiji; Tanaka, Toshio Chemistry Letters, Vol. 18, Issue 1 https://doi.org/10.1246/cl.1989.27	journal	January 1989
Second Sphere Control of Redox Catalysis: Selective Reduction of O ₂ to O ₂ ^– or H ₂ O by an Iron Porphyrin Catalyst Samanta, Subhra; Mittra, Kaustuv; Sengupta, Kushal Inorganic Chemistry, Vol. 52, Issue 3 https://doi.org/10.1021/ic3021782	journal	January 2013
Selective 4e ^– /4H ⁺ O ₂ Reduction by an Iron(tetraferrocenyl)Porphyrin Complex: From Proton Transfer Followed by Electron Transfer in Organic Solvent to Proton Coupled Electron Transfer in Aqueous Medium Mittra, Kaustuv; Chatterjee, Sudipta; Samanta, Subhra Inorganic Chemistry, Vol. 52, Issue 24 https://doi.org/10.1021/ic402297f	journal	December 2013
Novel Multinuclear Catalysts for the Electroreduction of Dioxygen Directly to Water Anson, Fred C.; Shi, Chunnian; Steiger, Beat Accounts of Chemical Research, Vol. 30, Issue 11 https://doi.org/10.1021/ar960264j	journal	November 1997
Factors Determining the Rate and Selectivity of 4e ^– /4H ⁺ Electrocatalytic Reduction of Dioxygen by Iron Porphyrin Complexes Chatterjee, Sudipta; Sengupta, Kushal; Mondal, Biswajit Accounts of Chemical Research, Vol. 50, Issue 7 https://doi.org/10.1021/acs.accounts.7b00192	journal	July 2017
Catalytic Reduction of O ₂ by Cytochrome c Using a Synthetic Model of Cytochrome c Oxidase Collman, James P.; Ghosh, Somdatta; Dey, Abhishek Journal of the American Chemical Society, Vol. 131, Issue 14 https://doi.org/10.1021/ja9001579	journal	April 2009
Homogeneous catalytic O2 reduction to water by a cytochrome c oxidase model with trapping of intermediates and mechanistic insights Halime, Z.; Kotani, H.; Li, Y. Proceedings of the National Academy of Sciences, Vol. 108, Issue 34 https://doi.org/10.1073/pnas.1104698108	journal	August 2011
An experimental and theoretical study of the synthesis and vibrational spectroscopy of triacetone triperoxide (TATP) Pacheco-Londono, Leonardo C.; Pena, Alvaro J.; Primera-Pedrozo, Oliva M. Defense and Security, SPIE Proceedings https://doi.org/10.1117/12.542851	conference	September 2004
Molecular Catalysts for Multielectron Redox Reactions of Small Molecules: The“Cofacial Metallodiporphyrin” Approach Collman, James P.; Wagenknecht, Paul S.; Hutchison, James E. Angewandte Chemie International Edition in English, Vol. 33, Issue 1516 https://doi.org/10.1002/anie.199415371	journal	September 1994
Electrocatalysis of oxygen reduction. 5. Oxygen to hydrogen peroxide conversion by cobalt(II) tetrakis(N-methyl-4-pyridyl)porphyrin Chan, Ray J. H.; Su, Y. Oliver; Kuwana, Theodore Inorganic Chemistry, Vol. 24, Issue 23 https://doi.org/10.1021/ic00217a017	journal	November 1985
The use of an electrogenerated cobalt(I) porphyrin for the homogeneous catalytic reduction of dioxygen in dimethylformamide. Reactions of [(TMpyP)CoII]4+ and [(TMpyP)CoI]3+ where TMpyP = meso-tetrakis(1-methylpyridinium-4-yl)porphyrin Sazou, D.; Araullo-McAdams, C.; Han, B. C. Journal of the American Chemical Society, Vol. 112, Issue 22 https://doi.org/10.1021/ja00178a005	journal	October 1990
Synthesis and studies on the electrocatalytic reduction of molecular oxygen by non-planar cobalt(II) tetrakis-(N-methyl pyridyl)-β-octabromoporphyrin D'Souza, Francis; Deviprasad, R. G.; Hsieh, Yi-Ying Journal of Electroanalytical Chemistry, Vol. 411, Issue 1-2 https://doi.org/10.1016/0022-0728(96)04599-8	journal	August 1996
Electrocatalytic reduction of molecular oxygen using non-planar cobalt tetrakis-(4-sulfonatophenyl)-β-octabromoporphyrin D'Souza, Francis; Hsieh, Yi-Ying; Deviprasad, G. R. Journal of Electroanalytical Chemistry, Vol. 426, Issue 1-2 https://doi.org/10.1016/S0022-0728(97)00040-5	journal	April 1997
Inhibitory Effect of Water on the Oxygen Reduction Catalyzed by Cobalt(II) Tetraphenylporphyrin Trojánek, Antonín; Langmaier, Jan; Kvapilová, Hana The Journal of Physical Chemistry A, Vol. 118, Issue 11 https://doi.org/10.1021/jp500057x	journal	March 2014
Water may inhibit oxygen binding in hemoprotein models Collman, J. P.; Decreau, R. A.; Dey, A. Proceedings of the National Academy of Sciences, Vol. 106, Issue 11 https://doi.org/10.1073/pnas.0900893106	journal	February 2009
Oxidation-reduction reactions of complexes with macrocyclic ligands. Oxygen uptake kinetics, equilibriums and intermediates in aqueous CoII(N4) systems Wong, Chung-Lai; Switzer, Jay A.; Balakrishnan, K. P. Journal of the American Chemical Society, Vol. 102, Issue 17 https://doi.org/10.1021/ja00537a016	journal	August 1980
Oxidation-reduction reactions of complexes with macrocyclic ligands. Role of intermediates in reactions of .mu.-peroxo-dicobalt complexes Wong, Chung-Lai; Endicott, John F. Inorganic Chemistry, Vol. 20, Issue 7 https://doi.org/10.1021/ic50221a059	journal	July 1981
Oxidation-reduction reactions of complexes with macrocyclic ligands. Electron-transfer reactivity of a 1:1 cobalt(II)-dioxygen adduct Kumar, Krishan; Endicott, John F. Inorganic Chemistry, Vol. 23, Issue 16 https://doi.org/10.1021/ic00184a018	journal	August 1984
Electrode catalysis of the four-electron reduction of oxygen to water by dicobalt face-to-face porphyrins Collman, James P.; Denisevich, Peter; Konai, Yutaka Journal of the American Chemical Society, Vol. 102, Issue 19 https://doi.org/10.1021/ja00539a009	journal	September 1980
Formation and homolysis of a mononuclear cobalt-oxygen adduct Bakac, Andreja; Espenson, James H. Journal of the American Chemical Society, Vol. 112, Issue 6 https://doi.org/10.1021/ja00162a030	journal	March 1990
Electrochemical and Spectroelectrochemical Studies on Metallophthalocyanine‐Oxygen Interactions in Nonaqueous Solutions Mho, Sun‐il; Ortiz, Bertha; Doddapaneni, Narayan Journal of The Electrochemical Society, Vol. 142, Issue 4 https://doi.org/10.1149/1.2044129	journal	April 1995
Clarification of the Oxidation State of Cobalt Corroles in Heterogeneous and Homogeneous Catalytic Reduction of Dioxygen Kadish, Karl M.; Shen, Jing; Frémond, Laurent Inorganic Chemistry, Vol. 47, Issue 15 https://doi.org/10.1021/ic800458s	journal	June 2008
Efficient Two-Electron Reduction of Dioxygen to Hydrogen Peroxide with One-Electron Reductants with a Small Overpotential Catalyzed by a Cobalt Chlorin Complex Mase, Kentaro; Ohkubo, Kei; Fukuzumi, Shunichi Journal of the American Chemical Society, Vol. 135, Issue 7 https://doi.org/10.1021/ja312199h	journal	February 2013
Much Enhanced Catalytic Reactivity of Cobalt Chlorin Derivatives on Two-Electron Reduction of Dioxygen to Produce Hydrogen Peroxide Mase, Kentaro; Ohkubo, Kei; Fukuzumi, Shunichi Inorganic Chemistry, Vol. 54, Issue 4 https://doi.org/10.1021/ic502678k	journal	January 2015
A Self-Assembled Cofacial Cobalt Porphyrin Prism for Oxygen Reduction Catalysis Oldacre, Amanda N.; Friedman, Alan E.; Cook, Timothy R. Journal of the American Chemical Society, Vol. 139, Issue 4 https://doi.org/10.1021/jacs.6b12404	journal	January 2017
Further studies of the dimeric .beta.-linked "face-to-face four" porphyrin: FTF4 Collman, James P.; Anson, Fred C.; Barnes, Craig E. Journal of the American Chemical Society, Vol. 105, Issue 9 https://doi.org/10.1021/ja00347a029	journal	May 1983
Electroreduction of oxygen by pillared cobalt(II) cofacial diporphyrin catalysts Chang, C. K.; Liu, H. Y.; Abdalmuhdi, I. Journal of the American Chemical Society, Vol. 106, Issue 9 https://doi.org/10.1021/ja00321a055	journal	May 1984
Symmetrical and unsymmetrical quadruply aza bridged closely interspaced cofacial bis(5,10,15,20-tetraphenylporphyrins). 3. Interplanar distances, proton NMR chemical shifts, and the catalysis of the electrochemical reduction of oxygen Karaman, Rafik; Jeon, Seungwon; Almarsson, Orn Journal of the American Chemical Society, Vol. 114, Issue 12 https://doi.org/10.1021/ja00038a066	journal	June 1992
Dehydrogenation versus Oxygenation in Two-Electron and Four-Electron Reduction of Dioxygen by 9-Alkyl-10-methyl-9,10-dihydroacridines Catalyzed by Monomeric Cobalt Porphyrins and Cofacial Dicobalt Porphyrins in the Presence of Perchloric Acid Fukuzumi, Shunichi; Okamoto, Ken; Tokuda, Yoshihiro Journal of the American Chemical Society, Vol. 126, Issue 51 https://doi.org/10.1021/ja046422g	journal	December 2004
Catalytic Activity of Biscobalt Porphyrin-Corrole Dyads Toward the Reduction of Dioxygen Kadish, Karl M.; Frémond, Laurent; Shen, Jing Inorganic Chemistry, Vol. 48, Issue 6 https://doi.org/10.1021/ic802092n	journal	March 2009
Remarkable oxygen affinity of a mixed valence dicobalt cofacial porphyrin CoIIICoIIFTF4 Le Mest, Yves.; L'Her, Maurice.; Collman, James P. Journal of the American Chemical Society, Vol. 108, Issue 3 https://doi.org/10.1021/ja00263a044	journal	February 1986
Reactivity toward Dioxygen of Dicobalt Face-to-Face Diporphyrins in Aprotic Media. Experimental and Theoretical Aspects. Possible Mechanistic Implication in the Reduction of Dioxygen Le Mest, Yves; Inisan, Claude; Laouénan, André Journal of the American Chemical Society, Vol. 119, Issue 26 https://doi.org/10.1021/ja9618659	journal	July 1997
Dioxygen Reduction at Dicobalt Complexes of a Schiff Base Calixpyrrole Ligand Givaja, Gonzalo; Volpe, Manuel; Edwards, Michael A. Angewandte Chemie International Edition, Vol. 46, Issue 4 https://doi.org/10.1002/anie.200603201	journal	January 2007
Binuclear Cobalt Complexes of Schiff-Base Calixpyrroles and Their Roles in the Catalytic Reduction of Dioxygen Volpe, Manuel; Hartnett, Heather; Leeland, James W. Inorganic Chemistry, Vol. 48, Issue 12 https://doi.org/10.1021/ic9001175	journal	June 2009
Tailoring dicobalt Pacman complexes of Schiff-base calixpyrroles towards dioxygenreduction catalysis Askarizadeh, Elham; Yaghoob, Sahar Bani; Boghaei, Davar M. Chem. Commun., Vol. 46, Issue 5 https://doi.org/10.1039/B923189G	journal	January 2010
Double-pillared cobalt Pacman complexes: synthesis, structures and oxygen reduction catalysis Devoille, Aline M. J.; Love, Jason B. Dalton Trans., Vol. 41, Issue 1 https://doi.org/10.1039/C1DT11424G	journal	January 2012
Catalysis of the electroreduction of O2 by cobalt 5,10,15,20-tetraphenylporphyrin dissolved in thin layers of benzonitrile on graphite electrodes Chung, Taek Dong; Anson, Fred C. Journal of Electroanalytical Chemistry, Vol. 508, Issue 1-2 https://doi.org/10.1016/S0022-0728(01)00524-1	journal	July 2001
Molecular electrocatalysis of the oxygen reduction at a polarised interface between two immiscible electrolyte solutions by Co(II) tetraphenylporphyrin Trojánek, Antonín; Mareček, Vladimír; Jänchenová, Hana Electrochemistry Communications, Vol. 9, Issue 9 https://doi.org/10.1016/j.elecom.2007.06.017	journal	September 2007
Proton Pump for O ₂ Reduction Catalyzed by 5,10,15,20-Tetraphenylporphyrinatocobalt(II) Partovi-Nia, Raheleh; Su, Bin; Li, Fei Chemistry - A European Journal, Vol. 15, Issue 10 https://doi.org/10.1002/chem.200801807	journal	February 2009
Oxygen reduction at a water-1,2-dichlorobenzene interface catalyzed by cobalt tetraphenyl porphyrine – A fuel cell approach Peljo, Pekka; Rauhala, Taina; Murtomäki, Lasse International Journal of Hydrogen Energy, Vol. 36, Issue 16 https://doi.org/10.1016/j.ijhydene.2011.05.042	journal	August 2011
Dioxygen Reduction by Cobalt(II) Octaethylporphyrin at Liquid\|Liquid Interfaces Partovi-Nia, Raheleh; Su, Bin; Méndez, Manuel A. ChemPhysChem, Vol. 11, Issue 13 https://doi.org/10.1002/cphc.201000200	journal	July 2010
Biomimetic Oxygen Reduction by Cofacial Porphyrins at a Liquid–Liquid Interface Peljo, Pekka; Murtomäki, Lasse; Kallio, Tanja Journal of the American Chemical Society, Vol. 134, Issue 13 https://doi.org/10.1021/ja3004914	journal	March 2012
Proton-Coupled O ₂ Reduction Reaction Catalysed by Cobalt Phthalocyanine at Liquid/Liquid Interfaces Li, Yan; Wu, Suozhu; Su, Bin Chemistry - A European Journal, Vol. 18, Issue 24 https://doi.org/10.1002/chem.201200191	journal	May 2012
Fluorinated-cobalt phthalocyanine catalyzed oxygen reduction at liquid/liquid interfaces Patir, Imren Hatay Electrochimica Acta, Vol. 87 https://doi.org/10.1016/j.electacta.2012.09.059	journal	January 2013
Catalytic Two-Electron Reduction of Dioxygen by Ferrocene Derivatives with Manganese(V) Corroles Jung, Jieun; Liu, Shuo; Ohkubo, Kei Inorganic Chemistry, Vol. 54, Issue 9 https://doi.org/10.1021/ic503012s	journal	April 2015
Catalytic Electroreduction of Molecular Oxygen Using [5,10,15,20-Tetrakis-(1-Methylpyridinium-4-Yl)Porphinato]Manganese Kobayashi, Nagao; Saiki, Hiroshi; Osa, Tetsuo Chemistry Letters, Vol. 14, Issue 12 https://doi.org/10.1246/cl.1985.1917	journal	December 1985
The production of hydrogen peroxide from dioxygen and hydroxylamine catalysed by manganese complexes Evans, Dennis F.; Sheriff, Tippu S. Journal of the Chemical Society, Chemical Communications, Issue 20 https://doi.org/10.1039/c39850001407	journal	January 1985
Production of hydrogen peroxide from dioxygen and hydroxylamine or hydrazine catalysed by manganese complexes Sheriff, Tippu S. Journal of the Chemical Society, Dalton Transactions, Issue 6 https://doi.org/10.1039/dt9920001051	journal	January 1992
Dioxygen Activation and Catalytic Reduction to Hydrogen Peroxide by a Thiolate-Bridged Dimanganese(II) Complex with a Pendant Thiol Gennari, Marcello; Brazzolotto, Deborah; Pécaut, Jacques Journal of the American Chemical Society, Vol. 137, Issue 26 https://doi.org/10.1021/jacs.5b04917	journal	June 2015
A Hydrogen-Bond Facilitated Cycle for Oxygen Reduction by an Acid- and Base-Compatible Iron Platform Soo, Han Sen; Komor, Alexis C.; Iavarone, Anthony T. Inorganic Chemistry, Vol. 48, Issue 21 https://doi.org/10.1021/ic9006668	journal	November 2009
Mononuclear Copper Complex-Catalyzed Four-Electron Reduction of Oxygen Fukuzumi, Shunichi; Kotani, Hiroaki; Lucas, Heather R. Journal of the American Chemical Society, Vol. 132, Issue 20 https://doi.org/10.1021/ja100538x	journal	May 2010
Enhanced Catalytic Four-Electron Dioxygen (O ₂ ) and Two-Electron Hydrogen Peroxide (H ₂ O ₂ ) Reduction with a Copper(II) Complex Possessing a Pendant Ligand Pivalamido Group Kakuda, Saya; Peterson, Ryan L.; Ohkubo, Kei Journal of the American Chemical Society, Vol. 135, Issue 17 https://doi.org/10.1021/ja3125977	journal	April 2013
Lewis Acid-Induced Change from Four- to Two-Electron Reduction of Dioxygen Catalyzed by Copper Complexes Using Scandium Triflate Kakuda, Saya; Rolle, Clarence J.; Ohkubo, Kei Journal of the American Chemical Society, Vol. 137, Issue 9 https://doi.org/10.1021/ja512584r	journal	February 2015
Electrochemical reduction of dioxygen by copper complexes with pyridylalkylamine ligands dissolved in aqueous buffer solution: the relationship between activity and redox potential Asahi, Masafumi; Yamazaki, Shin-ichi; Itoh, Shinobu Dalton Transactions, Vol. 43, Issue 28 https://doi.org/10.1039/c4dt00606b	journal	January 2014
Factors That Control Catalytic Two- versus Four-Electron Reduction of Dioxygen by Copper Complexes Fukuzumi, Shunichi; Tahsini, Laleh; Lee, Yong-Min Journal of the American Chemical Society, Vol. 134, Issue 16 https://doi.org/10.1021/ja211656g	journal	April 2012
Electron-Transfer Reduction of Dinuclear Copper Peroxo and Bis-μ-oxo Complexes Leading to the Catalytic Four-Electron Reduction of Dioxygen to Water Tahsini, Laleh; Kotani, Hiroaki; Lee, Yong-Min Chemistry - A European Journal, Vol. 18, Issue 4 https://doi.org/10.1002/chem.201103215	journal	January 2012
Cooperative Effects in Copper Polyamidoamine Dendrimer Complexes Catalyzing the Reduction of Molecular Oxygen: Cooperative Effects in Polyamidoamine Dendrimer Cu Complexes Tang, Yi-Hsuan; Lin, Yen Chung; Hsu, Sodio C. N. European Journal of Inorganic Chemistry, Vol. 2015, Issue 29 https://doi.org/10.1002/ejic.201500540	journal	September 2015
Catalytic Four-Electron Reduction of O ₂ via Rate-Determining Proton-Coupled Electron Transfer to a Dinuclear Cobalt-μ-1,2-peroxo Complex Fukuzumi, Shunichi; Mandal, Sukanta; Mase, Kentaro Journal of the American Chemical Society, Vol. 134, Issue 24 https://doi.org/10.1021/ja303674n	journal	June 2012
Four-electron reduction of dioxygen catalysed by dinuclear cobalt complexes bridged by bis(terpyridyl)anthracene Wada, Tohru; Maki, Hidetaka; Imamoto, Tomoyuki Chem. Commun., Vol. 49, Issue 39 https://doi.org/10.1039/C2CC36528F	journal	January 2013
Homogeneous Catalytic Reduction of Dioxygen Using Transfer Hydrogenation Catalysts Heiden, Zachariah M.; Rauchfuss, Thomas B. Journal of the American Chemical Society, Vol. 129, Issue 46 https://doi.org/10.1021/ja073774p	journal	November 2007
Highly Practical Copper(I)/TEMPO Catalyst System for Chemoselective Aerobic Oxidation of Primary Alcohols Hoover, Jessica M.; Stahl, Shannon S. Journal of the American Chemical Society, Vol. 133, Issue 42 https://doi.org/10.1021/ja206230h	journal	October 2011
Catalytic Oxidation of Organic Substrates by Molecular Oxygen and Hydrogen Peroxide by Multistep Electron Transfer—A Biomimetic Approach Piera, Julio; Bäckvall, Jan-E. Angewandte Chemie International Edition, Vol. 47, Issue 19 https://doi.org/10.1002/anie.200700604	journal	April 2008
Palladium Oxidase Catalysis: Selective Oxidation of Organic Chemicals by Direct Dioxygen-Coupled Turnover Stahl, Shannon S. Angewandte Chemie International Edition, Vol. 43, Issue 26 https://doi.org/10.1002/anie.200300630	journal	June 2004
CHEMISTRY: Palladium-Catalyzed Oxidation of Organic Chemicals with O2 Stahl, S. S. Science, Vol. 309, Issue 5742 https://doi.org/10.1126/science.1114666	journal	September 2005
Aerobic Copper-Catalyzed Organic Reactions Allen, Scott E.; Walvoord, Ryan R.; Padilla-Salinas, Rosaura Chemical Reviews, Vol. 113, Issue 8 https://doi.org/10.1021/cr300527g	journal	June 2013
Copper/TEMPO-Catalyzed Aerobic Alcohol Oxidation: Mechanistic Assessment of Different Catalyst Systems Hoover, Jessica M.; Ryland, Bradford L.; Stahl, Shannon S. ACS Catalysis, Vol. 3, Issue 11 https://doi.org/10.1021/cs400689a	journal	October 2013
Mechanism of Copper(I)/TEMPO-Catalyzed Aerobic Alcohol Oxidation Hoover, Jessica M.; Ryland, Bradford L.; Stahl, Shannon S. Journal of the American Chemical Society, Vol. 135, Issue 6 https://doi.org/10.1021/ja3117203	journal	January 2013
Room Temperature Aerobic Copper–Catalysed Selective Oxidation of Primary Alcohols to Aldehydes Gamez, Patrick; Arends, Isabel W. C. E.; Sheldon, Roger A. Advanced Synthesis & Catalysis, Vol. 346, Issue 7 https://doi.org/10.1002/adsc.200404063	journal	June 2004
Catalytic Activity Dependency on Catalyst Components in Aerobic Copper-TEMPO Oxidation Kumpulainen, Esa T. T.; Koskinen, Ari M. P. Chemistry - A European Journal, Vol. 15, Issue 41 https://doi.org/10.1002/chem.200901245	journal	September 2009
Oxidation of alcohols to aldehydes with oxygen and cupric ion, mediated by nitrosonium ion Semmelhack, M. F.; Schmid, Christopher R.; Cortes, David A. Journal of the American Chemical Society, Vol. 106, Issue 11 https://doi.org/10.1021/ja00323a064	journal	May 1984
Mechanism of Alcohol Oxidation Mediated by Copper(II) and Nitroxyl Radicals Ryland, Bradford L.; McCann, Scott D.; Brunold, Thomas C. Journal of the American Chemical Society, Vol. 136, Issue 34 https://doi.org/10.1021/ja5070137	journal	August 2014
Mechanism of the Copper/TEMPO-Catalyzed Aerobic Oxidation of Alcohols Iron, Mark A.; Szpilman, Alex M. Chemistry - A European Journal, Vol. 23, Issue 6 https://doi.org/10.1002/chem.201604402	journal	December 2016
Co(salophen)-Catalyzed Aerobic Oxidation of p -Hydroquinone: Mechanism and Implications for Aerobic Oxidation Catalysis Anson, Colin W.; Ghosh, Soumya; Hammes-Schiffer, Sharon Journal of the American Chemical Society, Vol. 138, Issue 12 https://doi.org/10.1021/jacs.6b00254	journal	March 2016
Development of a monolith-based process for H2O2 production: from idea to large-scale implementation Edvinsson Albers, R.; Nyström, M.; Siverström, M. Catalysis Today, Vol. 69, Issue 1-4 https://doi.org/10.1016/S0920-5861(01)00376-5	journal	September 2001
Homogeneous Molecular Catalysis of Electrochemical Reactions: Catalyst Benchmarking and Optimization Strategies Costentin, Cyrille; Savéant, Jean-Michel Journal of the American Chemical Society, Vol. 139, Issue 24 https://doi.org/10.1021/jacs.7b02879	journal	June 2017

Cited By (50)

Supramolecular Tuning Enables Selective Oxygen Reduction Catalyzed by Cobalt Porphyrins for Direct Electrosynthesis of Hydrogen Peroxide Smith, Peter T.; Kim, Younghoon; Benke, Bahiru Punja Angewandte Chemie International Edition, Vol. 59, Issue 12 https://doi.org/10.1002/anie.201916131	journal	January 2020
Efficient photocatalytic proton-coupled electron-transfer reduction of O ₂ using a saddle-distorted porphyrin as a photocatalyst Aoki, Emi; Suzuki, Wataru; Kotani, Hiroaki Chemical Communications, Vol. 55, Issue 34 https://doi.org/10.1039/c9cc01547g	journal	January 2019
Tuning the Activity of Heterogeneous Cofacial Cobalt Porphyrins for Oxygen Reduction Electrocatalysis through Self-Assembly Oldacre, Amanda N.; Crawley, Matthew R.; Friedman, Alan E. Chemistry - A European Journal, Vol. 24, Issue 43 https://doi.org/10.1002/chem.201802585	journal	July 2018
Impact of Intramolecular Hydrogen Bonding on the Reactivity of Cupric Superoxide Complexes with O−H and C−H Substrates Diaz, Daniel E.; Quist, David A.; Herzog, Austin E. Angewandte Chemie International Edition, Vol. 58, Issue 49 https://doi.org/10.1002/anie.201908471	journal	December 2019
Molecular Engineering of a 3D Self‐Supported Electrode for Oxygen Electrocatalysis in Neutral Media Xie, Lisi; Li, Xialiang; Wang, Bin Angewandte Chemie International Edition, Vol. 58, Issue 52 https://doi.org/10.1002/anie.201911441	journal	December 2019
Metallosupramolecular Polymer Precursor Design for Multi-Element Co-Doped Carbon Shells with Improved Oxygen Reduction Reaction Catalytic Activity Wu, Yuzhe; Li, Yuntong; Mao, Jie Catalysts, Vol. 9, Issue 1 https://doi.org/10.3390/catal9010102	journal	January 2019
Electronically varied manganese tris-arylacetamide tripodal complexes Cannella, Anthony F.; Surendhran, Roshaan; MacMillan, Samantha N. Taylor & Francis https://doi.org/10.6084/m9.figshare.7931276	text	January 2019
Trifluoromethylation for affecting the structural, electronic and redox properties of cobalt corroles Sudhakar, Kolanu; Mahammed, Atif; Fridman, Natalia Dalton Transactions, Vol. 48, Issue 15 https://doi.org/10.1039/c9dt00675c	journal	January 2019
Metal–Organic Frameworks Based Electrocatalysts for the Oxygen Reduction Reaction Lu, Xue Feng; Xia, Bao Yu; Zang, Shuang‐Quan Angewandte Chemie International Edition, Vol. 59, Issue 12 https://doi.org/10.1002/anie.201910309	journal	December 2019
Visible-light-promoted oxidative halogenation of alkynes Li, Yiming; Mou, Tao; Lu, Lingling Chemical Communications, Vol. 55, Issue 95 https://doi.org/10.1039/c9cc07655g	journal	January 2019
A mixed-ion strategy to construct CNT-decorated Co/N-doped hollow carbon for enhanced oxygen reduction Feng, Taotao; Zhang, Meining Chemical Communications, Vol. 54, Issue 82 https://doi.org/10.1039/c8cc05959d	journal	January 2018
Free‐Standing 3D Electrodes for Electrochemical Detection of Hydrogen Peroxide Peng, Ming; Zhao, Yang; Chen, Dechao ChemCatChem, Vol. 11, Issue 17 https://doi.org/10.1002/cctc.201900913	journal	July 2019
The oxygen reduction reaction catalyzed by Synechocystis sp. PCC 6803 flavodiiron proteins Brown, Katherine A.; Guo, Zhanjun; Tokmina-Lukaszewska, Monika Sustainable Energy & Fuels, Vol. 3, Issue 11 https://doi.org/10.1039/c9se00523d	journal	January 2019
Combining scaling relationships overcomes rate versus overpotential trade-offs in O ₂ molecular electrocatalysis Martin, Daniel J.; Mercado, Brandon Q.; Mayer, James M. Science Advances, Vol. 6, Issue 11 https://doi.org/10.1126/sciadv.aaz3318	journal	March 2020
Structure and reactivity of the first-row d-block metal-superoxo complexes Fukuzumi, Shunichi; Lee, Yong-Min; Nam, Wonwoo Dalton Transactions, Vol. 48, Issue 26 https://doi.org/10.1039/c9dt01402k	journal	January 2019
A General Method for Transition Metal Single Atoms Anchored on Honeycomb‐Like Nitrogen‐Doped Carbon Nanosheets Zhang, Xiaoyan; Zhang, Shan; Yang, Yong Advanced Materials, Vol. 32, Issue 10 https://doi.org/10.1002/adma.201906905	journal	January 2020
Liquefied Sunshine: Transforming Renewables into Fertilizers and Energy Carriers with Electromaterials MacFarlane, Douglas R.; Choi, Jaecheol; Suryanto, Bryan H. R. Advanced Materials, Vol. 32, Issue 18 https://doi.org/10.1002/adma.201904804	journal	November 2019
Carbon Nanotubes with Cobalt Corroles for Hydrogen and Oxygen Evolution in pH 0–14 Solutions Li, Xialiang; Lei, Haitao; Liu, Jieyu Angewandte Chemie, Vol. 130, Issue 46 https://doi.org/10.1002/ange.201807996	journal	October 2018
Programmable Exposure of Pt Active Facets for Efficient Oxygen Reduction Wang, Guanzhi; Yang, Zhenzhong; Du, Yingge Angewandte Chemie, Vol. 131, Issue 44 https://doi.org/10.1002/ange.201907322	journal	September 2019
A Phthalocyanine‐Based Layered Two‐Dimensional Conjugated Metal–Organic Framework as a Highly Efficient Electrocatalyst for the Oxygen Reduction Reaction Zhong, Haixia; Ly, Khoa Hoang; Wang, Mingchao Angewandte Chemie, Vol. 131, Issue 31 https://doi.org/10.1002/ange.201907002	journal	July 2019
Metal-free electrocatalysts for oxygen reduction reaction based on trioxotriangulene Murata, Tsuyoshi; Kotsuki, Kenji; Murayama, Hirotaka Communications Chemistry, Vol. 2, Issue 1 https://doi.org/10.1038/s42004-019-0149-9	journal	May 2019
Active Sites and Mechanism of Oxygen Reduction Reaction Electrocatalysis on Nitrogen-Doped Carbon Materials Singh, Santosh K.; Takeyasu, Kotaro; Nakamura, Junji Advanced Materials, Vol. 31, Issue 13 https://doi.org/10.1002/adma.201804297	journal	October 2018
Small-molecule activation with iron porphyrins using electrons, photons and protons: some recent advances and future strategies Anxolabéhère-Mallart, Elodie; Bonin, Julien; Fave, Claire Dalton Transactions, Vol. 48, Issue 18 https://doi.org/10.1039/c9dt00136k	journal	January 2019
A bi-functional cobalt-porphyrinoid electrocatalyst: balance between overpotential and selectivity Amanullah, Sk; Dey, Abhishek JBIC Journal of Biological Inorganic Chemistry, Vol. 24, Issue 4 https://doi.org/10.1007/s00775-019-01670-5	journal	May 2019
Carbon Nanotubes with Cobalt Corroles for Hydrogen and Oxygen Evolution in pH 0-14 Solutions Li, Xialiang; Lei, Haitao; Liu, Jieyu Angewandte Chemie International Edition, Vol. 57, Issue 46 https://doi.org/10.1002/anie.201807996	journal	October 2018
Triple hydrogen atom abstraction from Mn–NH 3 complexes results in cyclophosphazenium cations Cook, Brian J.; Johnson, Samantha I.; Chambers, Geoffrey M. Chemical Communications, Vol. 55, Issue 93 https://doi.org/10.1039/c9cc06915a	journal	January 2019
Programmable Exposure of Pt Active Facets for Efficient Oxygen Reduction Wang, Guanzhi; Yang, Zhenzhong; Du, Yingge Angewandte Chemie International Edition, Vol. 58, Issue 44 https://doi.org/10.1002/anie.201907322	journal	September 2019
A Phthalocyanine-Based Layered Two-Dimensional Conjugated Metal-Organic Framework as a Highly Efficient Electrocatalyst for the Oxygen Reduction Reaction Zhong, Haixia; Ly, Khoa Hoang; Wang, Mingchao Angewandte Chemie International Edition, Vol. 58, Issue 31 https://doi.org/10.1002/anie.201907002	journal	July 2019
Electrochemical Minisci-type trifluoromethylation of electron-deficient heterocycles mediated by bromide ions Dou, Gui-Yuan; Jiang, Yang-Ye; Xu, Kun Organic Chemistry Frontiers, Vol. 6, Issue 14 https://doi.org/10.1039/c9qo00552h	journal	January 2019
MOFs for Electrocatalysis: From Serendipity to Design Strategies Aiyappa, Harshitha Barike; Masa, Justus; Andronescu, Corina Small Methods, Vol. 3, Issue 8 https://doi.org/10.1002/smtd.201800415	journal	December 2018
Hierarchical N-Doped Porous Carbons for Zn–Air Batteries and Supercapacitors Guo, Beibei; Ma, Ruguang; Li, Zichuang Nano-Micro Letters, Vol. 12, Issue 1 https://doi.org/10.1007/s40820-019-0364-z	journal	January 2020
Controlled O ₂ reduction at a mixed-valent (II,I) Cu ₂ S core Mangue, Jordan; Gondre, Clément; Pécaut, Jacques Chemical Communications, Vol. 56, Issue 67 https://doi.org/10.1039/d0cc03987j	journal	January 2020
Metal–Organic Frameworks Based Electrocatalysts for the Oxygen Reduction Reaction Lu, Xue Feng; Xia, Bao Yu; Zang, Shuang‐Quan Angewandte Chemie, Vol. 132, Issue 12 https://doi.org/10.1002/ange.201910309	journal	December 2019
Lattice-strained metal–organic-framework arrays for bifunctional oxygen electrocatalysis Cheng, Weiren; Zhao, Xu; Su, Hui Nature Energy, Vol. 4, Issue 2 https://doi.org/10.1038/s41560-018-0308-8	journal	January 2019
Designing electrochemically reversible H2 oxidation and production catalysts Dutta, Arnab; Appel, Aaron M.; Shaw, Wendy J. Nature Reviews Chemistry, Vol. 2, Issue 9 https://doi.org/10.1038/s41570-018-0032-8	journal	August 2018
High-valence Cu II Cu III species in action: demonstration of aliphatic C–H bond activation at room temperature Isaac, James A.; Thibon-Pourret, Aurore; Durand, Amélie Chemical Communications, Vol. 55, Issue 84 https://doi.org/10.1039/c9cc04422a	journal	January 2019
Significantly improved electrocatalytic oxygen reduction by an asymmetrical Pacman dinuclear cobalt( ii ) porphyrin–porphyrin dyad Liu, Yanju; Zhou, Guojun; Zhang, Zongyao Chemical Science, Vol. 11, Issue 1 https://doi.org/10.1039/c9sc05041h	journal	January 2020
Synthetic access to new porphyrinoids from 2-nitro-5,10,15,20-tetraphenylporphyrin and an arylacetonitrile Amiri, Ouafa; Moura, Nuno M. M.; Faustino, Maria A. F. Monatshefte für Chemie - Chemical Monthly, Vol. 150, Issue 1 https://doi.org/10.1007/s00706-018-2283-y	journal	October 2018
Proton-coupled electron transfer oxidation of O–H bond by the N-radical cation of Wurster's blue salt (TMPDA˙ ⁺ ) Li, Han; Guo, Yu-Hua; Wu, Jun-Yan Chemical Communications, Vol. 55, Issue 24 https://doi.org/10.1039/c9cc00354a	journal	January 2019
Molecular Engineering of a 3D Self‐Supported Electrode for Oxygen Electrocatalysis in Neutral Media Xie, Lisi; Li, Xialiang; Wang, Bin Angewandte Chemie, Vol. 131, Issue 52 https://doi.org/10.1002/ange.201911441	journal	November 2019
Reactivity of rhodium and iridium peroxido complexes towards hydrogen in the presence of B(C ₆ F ₅ ) ₃ or [H(OEt ₂ ) ₂ ][B{3,5-(CF ₃ ) ₂ C ₆ H ₃ } ₄ ] Baumgarth, Hanna; Meier, Gregor; von Hahmann, Cortney N. Dalton Transactions, Vol. 47, Issue 45 https://doi.org/10.1039/c8dt03853h	journal	January 2018
Impact of Intramolecular Hydrogen Bonding on the Reactivity of Cupric Superoxide Complexes with O−H and C−H Substrates Diaz, Daniel E.; Quist, David A.; Herzog, Austin E. Angewandte Chemie, Vol. 131, Issue 49 https://doi.org/10.1002/ange.201908471	journal	October 2019
Polyaromatic hydrocarbon derivatized azo-oximes of cobalt( iii ) for the ligand-redox controlled electrocatalytic oxygen reduction reaction Dinda, Soumitra; Roy, Syamantak; Patra, Sarat Chandra New Journal of Chemistry, Vol. 44, Issue 9 https://doi.org/10.1039/c9nj05527d	journal	January 2020
Fast Oxygen Reduction Catalyzed by a Copper(II) Tris(2‐pyridylmethyl)amine Complex through a Stepwise Mechanism Langerman, Michiel; Hetterscheid, Dennis G. H. Angewandte Chemie, Vol. 131, Issue 37 https://doi.org/10.1002/ange.201904075	journal	June 2019
Directly immobilizing a Ru–tannic acid linkage coordination complex on carbon cloth: an efficient and ultrastable catalyst for the hydrogen evolution reaction Chen, Jiadong; Wang, Haiyan; Gong, Yutong Journal of Materials Chemistry A, Vol. 7, Issue 18 https://doi.org/10.1039/c9ta02680k	journal	January 2019
Applications of the Marcus cross relation to inner sphere reduction of O ₂ : implications in small-molecule activation Lacy, David C. Inorganic Chemistry Frontiers, Vol. 6, Issue 9 https://doi.org/10.1039/c9qi00828d	journal	January 2019
Supramolecular Tuning Enables Selective Oxygen Reduction Catalyzed by Cobalt Porphyrins for Direct Electrosynthesis of Hydrogen Peroxide Smith, Peter T.; Kim, Younghoon; Benke, Bahiru Punja Angewandte Chemie, Vol. 132, Issue 12 https://doi.org/10.1002/ange.201916131	journal	January 2020
Electronically varied manganese tris-arylacetamide tripodal complexes Cannella, Anthony F.; Surendhran, Roshaan; MacMillan, Samantha N. Journal of Coordination Chemistry, Vol. 72, Issue 8 https://doi.org/10.1080/00958972.2019.1601714	journal	March 2019
Fast Oxygen Reduction Catalyzed by a Copper(II) Tris(2-pyridylmethyl)amine Complex through a Stepwise Mechanism Langerman, Michiel; Hetterscheid, Dennis G. H. Angewandte Chemie International Edition, Vol. 58, Issue 37 https://doi.org/10.1002/anie.201904075	journal	July 2019
Postoperative pain in children: Comparison between ratings of children and nurses Rømsing, Janne; Møller-Sonnergaard, Jørn; Hertel, Steen Journal of Pain and Symptom Management, Vol. 11, Issue 1 https://doi.org/10.1016/0885-3924(95)00136-0	journal	January 1996

Similar Records

Oxygen Reduction by Homogeneous Molecular Catalysts and Electrocatalysts

Journal Article · Wed Mar 14 00:00:00 EDT 2018 · Chemical Reviews · OSTI ID:1470267

Pegis, Michael L.; Wise, Catherine F.; Martin, Daniel J.; +1 more

Design of Efficient Molecular Electrocatalysts for Water and Carbon Dioxide Reduction Using Predictive Models of Thermodynamic Properties

Technical Report · Tue May 11 00:00:00 EDT 2021 · OSTI ID:1470267

Yang, Jenny Y.

Nitride or Oxynitride? Elucidating the Composition–Activity Relationships in Molybdenum Nitride Electrocatalysts for the Oxygen Reduction Reaction

Journal Article · Wed Mar 25 00:00:00 EDT 2020 · Chemistry of Materials · OSTI ID:1470267

Kreider, Melissa E.; Stevens, Michaela Burke; Liu, Yunhzi; +12 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
catalysis (homogeneous)
catalysis (heterogeneous)
solar (fuels)
bio-inspired
energy storage (including batteries and capacitors)
hydrogen and fuel cells
charge transport
materials and chemistry by design
synthesis (novel materials)

Title: Oxygen Reduction by Homogeneous Molecular Catalysts and Electrocatalysts

Citation Formats

References (310)

Cited By (50)

Similar Records

Related Subjects