Electron Transfer from Photoexcited Naphthalene Diimide Radical Anion to Electrocatalytically Active Re(bpy)(CO)3 Cl in a Molecular Triad

Martinez, Jose F.; La Porte, Nathan T.; Wasielewski, Michael R.

doi:10.1021/acs.jpcc.7b11999

Title: Electron Transfer from Photoexcited Naphthalene Diimide Radical Anion to Electrocatalytically Active Re(bpy)(CO)₃ Cl in a Molecular Triad

Journal Article · Fri Jan 12 00:00:00 EST 2018 · Journal of Physical Chemistry. C

DOI:https://doi.org/10.1021/acs.jpcc.7b11999· OSTI ID:1470239

Martinez, Jose F. ^[1];

^[1];

^[1]

Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry and Argonne-Northwestern Solar Energy Research (ANSER) Center

Electron donor–acceptor photosensitizers having long charge separation lifetimes and high-reducing potentials that can be easily appended to thermodynamically difficult to reduce catalysts hold great promise for driving CO₂ reduction. We introduce a new molecular triad utilizing a naphthalene diimide radical anion (NDI^•–) donor chromophore appended to a 9,10-diphenylanthracene (DPA) acceptor, which is in turn linked to Re(bpy)(CO)3Cl. The NDI^•– chromophore is readily generated by mild chemical or electrochemical reduction, absorbs at wavelengths as long as 800 nm, and has an excited state oxidation potential (–2.1 V vs SCE), which rivals or exceeds those of metalorganic and organometallic chromophores. Photoexcitation of NDI^•– to *NDI^•– is followed by ultrafast reduction of DPA to DPA^•–, which then rapidly reduces the metal complex. The overall quantum yield for reduction of Re(bpy)(CO)₃Cl is approximately 90% using visible light. The general time constant for the forward electron transfer to reduce the metal complex is τ = 14.5 ps, while the time constant for back-electron transfer is τ = 24.5 ns. Under typical electrocatalytic conditions, the molecular triad demonstrates electrochemical reduction of CO₂.

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Research Organization:: Northwestern Univ., Evanston, IL (United States). Energy Frontier Research Center (EFRC) Argonne-Northwestern Solar Energy Research (ANSER) Center

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: SC0001059

OSTI ID:: 1470239

Journal Information:: Journal of Physical Chemistry. C, Vol. 122, Issue 5; Related Information: ANSER partners with Northwestern University (lead); Argonne National Laboratory; University of Chicago; University of Illinois, Urbana-Champaign; Yale University; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 22 works

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Title: Electron Transfer from Photoexcited Naphthalene Diimide Radical Anion to Electrocatalytically Active Re(bpy)(CO)₃ Cl in a Molecular Triad