Thermal anisotropy enhanced by phonon size effects in nanoporous materials

Journal Article · Mon Feb 27 00:00:00 EST 2017 · Applied Physics Letters

DOI:https://doi.org/10.1063/1.4976540· OSTI ID:1466007

Romano, Giuseppe ^[1]; Kolpak, Alexie M. ^[1]

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1. Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)

While thermal anisotropy is a desirable materials property for many applications, including transverse thermoelectrics and thermal management in electronic devices, it remains elusive in practical natural compounds. In this work, we show how nanoporous materials with anisotropic pore lattices can be used as a platform for inducing strong heat transport directionality in isotropic materials. Using density functional theory and the phonon Boltzmann transport equation, we calculate the phonon-size effects and thermal conductivity of nanoporous silicon with different anisotropic pore lattices. Here, our calculations predict a strong directionality in the thermal conductivity, dictated by the difference in the pore-pore distances, i.e., the phonon bottleneck, along the two Cartesian axes. Using Fourier’s law, we also compute the diffusive heat transport for the same geometries obtaining significantly smaller anisotropy, revealing the crucial role of phonon-size effects in tuning thermal transport directionality. Besides enhancing our understanding of nanoscale heat transport, our results demonstrate the promise of nanoporous materials for modulating anisotropy in thermal conductivity.

• Research Organization: Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
• Sponsoring Organization: USDOE Office of Science (SC), Basic Energy Sciences (BES)
• Grant/Contract Number: SC0001299; DESC0001
• OSTI ID: 1466007
• Alternate ID(s): OSTI ID: 1348268
• Journal Information: Applied Physics Letters, Vol. 110, Issue 9; ISSN 0003-6951
• Publisher: American Institute of Physics (AIP)
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE