All-solid-state interpenetrating network polymer electrolytes for long cycle life of lithium metal batteries

Tong, Yongfen; Lyu, Hailong; Xu, Yuzhong; Prasad Thapaliya, Bishnu; Li, Peipei; Sun, Xiao-Guang; Dai, Sheng

doi:10.1039/C8TA03062F

Title: All-solid-state interpenetrating network polymer electrolytes for long cycle life of lithium metal batteries

Journal Article · Mon Jul 02 00:00:00 EDT 2018 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/C8TA03062F· OSTI ID:1462867

Tong, Yongfen ^[1]; Lyu, Hailong ^[2]; Xu, Yuzhong ^[3]; Prasad Thapaliya, Bishnu ^[4]; Li, Peipei ^[2];

^[2];

^[4]

Nanchang Hangkong Univ., Nanchang (China). School of Environmental and Chemical Engineering; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Science Division
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Science Division
Nanchang Hangkong Univ., Nanchang (China). School of Environmental and Chemical Engineering
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Science Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry

A star-shape polymer of 3-armed poly(ethylene glycol) methyl ether methacrylate-co-glycidyl methacrylate copolymer (3PPEGM-co-GMA) was synthesized using an atom transfer radical polymerization (ATRP) technique. All-solid-state interpenetrating network polymer electrolytes (INSPEs) were fabricated by simultaneous reaction of 3PPEGM-co-GMA and bisphenol A diglycidyl ether (BPDE) with polyetherdiamine (ED2003) in the presence of lithium bis(trifluoromethane) sulfonamide (LiTFSI). The INSPEs exhibited ionic conductivities higher than 10^-5 S cm^-1 at room temperature, a high oxidation stability of 4.5 vs. Li/Li⁺ and remarkable stability towards lithium metal. Li metal batteries with LiFePO₄ as the cathode and INSPEs as the electrolyte cycled at a current rate of 0.1C at 60 °C showed a high initial discharge capacity of 156.2 mA h g^-1 and a stable cycling performance over 200 cycles with a high coulombic efficiency of 99%. In conclusion, the results demonstrate that the interpenetrating network polymer electrolytes are promising electrolytes for next generation lithium-based batteries with high ionic conductivity, improved safety, and stable electrochemical performance.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1462867

Alternate ID(s):: OSTI ID: 1460879

Journal Information:: Journal of Materials Chemistry. A, Vol. 6, Issue 30; ISSN 2050-7488

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 40 works

Citation information provided by
Web of Science

References (64)

Effect of Molecular Weight on the Mechanical and Electrical Properties of Block Copolymer Electrolytes Singh, Mohit; Odusanya, Omolola; Wilmes, Gregg M. Macromolecules, Vol. 40, Issue 13 https://doi.org/10.1021/ma0629541	journal	June 2007
Thermal/oxidative degradation and stabilization of polyethylene glycol Han, Seongok; Kim, Chongyoup; Kwon, Dongsook Polymer, Vol. 38, Issue 2 https://doi.org/10.1016/S0032-3861(97)88175-X	journal	January 1997
Recent Developments of the Lithium Metal Anode for Rechargeable Non-Aqueous Batteries Zhang, Kai; Lee, Gi-Hyeok; Park, Mihui Advanced Energy Materials, Vol. 6, Issue 20 https://doi.org/10.1002/aenm.201600811	journal	July 2016
Issues and challenges facing rechargeable lithium batteries Tarascon, J.-M.; Armand, M. Nature, Vol. 414, Issue 6861, p. 359-367 https://doi.org/10.1038/35104644	journal	November 2001
Thermal Stability of the Polymer Electrolyte (PEO)[sub 8]LiCF[sub 3]SO[sub 3] Shodai, Takahisa Journal of The Electrochemical Society, Vol. 141, Issue 11 https://doi.org/10.1149/1.2059268	journal	January 1994
Conductivity relaxation in the PEO–salt polymer electrolytes Choi, Byoung-Koo; Kim, Young-Wan Electrochimica Acta, Vol. 49, Issue 14 https://doi.org/10.1016/j.electacta.2004.01.011	journal	June 2004
Effect of polyacrylonitrile on triethylene glycol diacetate-2-propenoic acid butyl ester gel polymer electrolytes with interpenetrating crosslinked network for flexible lithium ion batteries Wang, Qiujun; Song, Wei-Li; Fan, Li-Zhen Journal of Power Sources, Vol. 295 https://doi.org/10.1016/j.jpowsour.2015.06.152	journal	November 2015
Single Lithium-Ion Conducting Polymer Electrolytes Based on a Super-Delocalized Polyanion Ma, Qiang; Zhang, Heng; Zhou, Chongwang Angewandte Chemie International Edition, Vol. 55, Issue 7 https://doi.org/10.1002/anie.201509299	journal	January 2016
Synthesis and Characterization of Network Single Ion Conductors Based on Comb-Branched Polyepoxide Ethers and Lithium Bis(allylmalonato)borate Sun, Xiao-Guang; Kerr, John B. Macromolecules, Vol. 39, Issue 1 https://doi.org/10.1021/ma0507701	journal	January 2006
A lithium superionic conductor Kamaya, Noriaki; Homma, Kenji; Yamakawa, Yuichiro Nature Materials, Vol. 10, Issue 9, p. 682-686 https://doi.org/10.1038/nmat3066	journal	July 2011
Microscopic investigation of ionic conductivity in alkali metal salts-poly(ethylene oxide) adducts Berthier, C.; Gorecki, W.; Minier, M. Solid State Ionics, Vol. 11, Issue 1 https://doi.org/10.1016/0167-2738(83)90068-1	journal	September 1983
Network Single Ion Conductors Based on Comb-Branched Polyepoxide Ethers and Lithium Bis(allylmalonato)borate Sun, Xiao-Guang; Kerr, John B.; Reeder, Craig L. Macromolecules, Vol. 37, Issue 14 https://doi.org/10.1021/ma049331c	journal	July 2004
Solid electrolyte membranes from semi-interpenetrating polymer networks of PEG-grafted polymethacrylates and poly(methyl methacrylate) Munchelmer, A.; Jannasch, P. Solid State Ionics, Vol. 177, Issue 5-6 https://doi.org/10.1016/j.ssi.2005.12.021	journal	February 2006
Correlating Electrode-Electrolyte Interface and Battery Performance in Hybrid Solid Polymer Electrolyte-Based Lithium Metal Batteries Pan, Qiwei; Barbash, Dmitri; Smith, Derrick M. Advanced Energy Materials, Vol. 7, Issue 22 https://doi.org/10.1002/aenm.201701231	journal	August 2017
Basic characteristics of uniaxial extension rheology: Comparing monodisperse and bidisperse polymer melts Wang, Yangyang; Cheng, Shiwang; Wang, Shi-Qing Journal of Rheology, Vol. 55, Issue 6 https://doi.org/10.1122/1.3626416	journal	November 2011
A highly-concentrated poly(ethylene carbonate)-based electrolyte for all-solid-state Li battery working at room temperature Kimura, Kento; Yajima, Mari; Tominaga, Yoichi Electrochemistry Communications, Vol. 66 https://doi.org/10.1016/j.elecom.2016.02.022	journal	May 2016
Single-ion BAB triblock copolymers as highly efficient electrolytes for lithium-metal batteries Bouchet, Renaud; Maria, Sébastien; Meziane, Rachid Nature Materials, Vol. 12, Issue 5 https://doi.org/10.1038/nmat3602	journal	March 2013
Fast Li-ion conduction in poly(ethylene carbonate)-based electrolytes and composites filled with TiO ₂ nanoparticles Tominaga, Yoichi; Yamazaki, Kenta Chem. Commun., Vol. 50, Issue 34 https://doi.org/10.1039/C3CC49588D	journal	January 2014
Block copolymer electrolytes for rechargeable lithium batteries Young, Wen-Shiue; Kuan, Wei-Fan; Epps, Thomas H. Journal of Polymer Science Part B: Polymer Physics, Vol. 52, Issue 1 https://doi.org/10.1002/polb.23404	journal	November 2013
Comb-shaped single ion conductors based on polyacrylate ethers and lithium alkyl sulfonate Sun, Xiao-Guang; Hou, Jun; Kerr, John B. Electrochimica Acta, Vol. 50, Issue 5 https://doi.org/10.1016/j.electacta.2004.08.011	journal	January 2005
Polymerized Ionic Liquids with Enhanced Static Dielectric Constants Choi, U. Hyeok; Mittal, Anuj; Price, Terry L. Macromolecules, Vol. 46, Issue 3 https://doi.org/10.1021/ma301833j	journal	January 2013
Segmental Dynamics and Dielectric Constant of Polysiloxane Polar Copolymers as Plasticizers for Polymer Electrolytes Choi, U. Hyeok; Liang, Siwei; Chen, Quan ACS Applied Materials & Interfaces, Vol. 8, Issue 5 https://doi.org/10.1021/acsami.5b10797	journal	January 2016
Influence of crystallization on dielectric properties of PEO:LiTFSI polymer electrolyte Marzantowicz, M.; Dygas, J. R.; Krok, F. Journal of Non-Crystalline Solids, Vol. 352, Issue 42-49 https://doi.org/10.1016/j.jnoncrysol.2006.02.161	journal	November 2006
The Impact of Elastic Deformation on Deposition Kinetics at Lithium/Polymer Interfaces Monroe, Charles; Newman, John Journal of The Electrochemical Society, Vol. 152, Issue 2 https://doi.org/10.1149/1.1850854	journal	January 2005
From Precision Synthesis of Block Copolymers to Properties and Applications of Nanoparticles Li, Xiao; Iocozzia, James; Chen, Yihuang Angewandte Chemie International Edition, Vol. 57, Issue 8 https://doi.org/10.1002/anie.201705019	journal	January 2018
Single lithium-ion conducting solid polymer electrolytes: advances and perspectives Zhang, Heng; Li, Chunmei; Piszcz, Michal Chemical Society Reviews, Vol. 46, Issue 3 https://doi.org/10.1039/C6CS00491A	journal	January 2017
Lithium metal anodes for rechargeable batteries Xu, Wu; Wang, Jiulin; Ding, Fei Energy Environ. Sci., Vol. 7, Issue 2 https://doi.org/10.1039/C3EE40795K	journal	January 2014
Effect of Molecular Weight and Salt Concentration on Conductivity of Block Copolymer Electrolytes Panday, Ashoutosh; Mullin, Scott; Gomez, Enrique D. Macromolecules, Vol. 42, Issue 13 https://doi.org/10.1021/ma900451e	journal	July 2009
Comparison of lithium-polymer cell performance with unity and nonunity transference numbers Thomas, Karen E.; Sloop, Steve E.; Kerr, John B. Journal of Power Sources, Vol. 89, Issue 2 https://doi.org/10.1016/S0378-7753(00)00420-1	journal	August 2000
Polymer electrolytes: Present, past and future Di Noto, Vito; Lavina, Sandra; Giffin, Guinevere A. Electrochimica Acta, Vol. 57 https://doi.org/10.1016/j.electacta.2011.08.048	journal	December 2011
Highly Conducting 3D-Hybrid Polymer Electrolytes for Lithium Batteries Based on Siloxane Networks and Cross-Linked Organic Polar Interphases Boaretto, Nicola; Bittner, Andreas; Brinkmann, Christine Chemistry of Materials, Vol. 26, Issue 22 https://doi.org/10.1021/cm5024647	journal	November 2014
Sequential effect and enhanced conductivity of star-shaped diblock liquid-crystalline copolymers for solid electrolytes Tong, Yongfen; Chen, Lie; He, Xiaohui Journal of Power Sources, Vol. 247 https://doi.org/10.1016/j.jpowsour.2013.08.139	journal	February 2014
The Role of Solvating 12-Crown-4 Plasticizer on Dielectric Constant and Ion Conduction of Poly(ethylene oxide) Single-Ion Conductors Choi, U. Hyeok; Colby, Ralph H. Macromolecules, Vol. 50, Issue 14 https://doi.org/10.1021/acs.macromol.7b00467	journal	July 2017
Functional dendrimers, hyperbranched and star polymers Inoue, K. Progress in Polymer Science, Vol. 25, Issue 4 https://doi.org/10.1016/S0079-6700(00)00011-3	journal	May 2000
Synthesis and Characterization of Network Type Single Ion Conductors Sun, Xiao-Guang; Reeder, Craig L.; Kerr, John B. Macromolecules, Vol. 37, Issue 6 https://doi.org/10.1021/ma035690g	journal	March 2004
Lithium-Sulfur Batteries: Electrochemistry, Materials, and Prospects Yin, Ya-Xia; Xin, Sen; Guo, Yu-Guo Angewandte Chemie International Edition, Vol. 52, Issue 50 https://doi.org/10.1002/anie.201304762	journal	November 2013
A Particle-Controlled, High-Performance, Gum-Like Electrolyte for Safe and Flexible Energy Storage Devices Wang, Yu; Zhong, Wei-Hong; Schiff, Tyler Advanced Energy Materials, Vol. 5, Issue 2 https://doi.org/10.1002/aenm.201400463	journal	August 2014
A novel all-solid electrolyte based on a co-polymer of poly-(methoxy/hexadecal-poly(ethylene glycol) methacrylate) for lithium-ion cell Zuo, Xiang; Liu, Xiao-Min; Cai, Feng Journal of Materials Chemistry, Vol. 22, Issue 41 https://doi.org/10.1039/c2jm34270g	journal	January 2012
Reshaping Lithium Plating/Stripping Behavior via Bifunctional Polymer Electrolyte for Room-Temperature Solid Li Metal Batteries Zeng, Xian-Xiang; Yin, Ya-Xia; Li, Nian-Wu Journal of the American Chemical Society, Vol. 138, Issue 49 https://doi.org/10.1021/jacs.6b10088	journal	December 2016
Synthesis and Lithium Ion Conduction of Polysiloxane Single-Ion Conductors Containing Novel Weak-Binding Borates Liang, Siwei; Choi, U. Hyeok; Liu, Wenjuan Chemistry of Materials, Vol. 24, Issue 12 https://doi.org/10.1021/cm3005387	journal	June 2012
On the origin of strain hardening in glassy polymers van Melick, H. G. H.; Govaert, L. E.; Meijer, H. E. H. Polymer, Vol. 44, Issue 8 https://doi.org/10.1016/S0032-3861(03)00112-5	journal	April 2003
Super Soft All-Ethylene Oxide Polymer Electrolyte for Safe All-Solid Lithium Batteries Porcarelli, Luca; Gerbaldi, Claudio; Bella, Federico Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep19892	journal	January 2016
Thermally cured semi-interpenetrating electrolyte networks (s-IPN) for safe and aging-resistant secondary lithium polymer batteries Nair, Jijeesh R.; Destro, Matteo; Bella, Federico Journal of Power Sources, Vol. 306 https://doi.org/10.1016/j.jpowsour.2015.12.001	journal	February 2016
The conformation of linear and star polymers in solution Allegra, Giuseppe; Ganazzoli, Fabio Progress in Polymer Science, Vol. 16, Issue 2-3 https://doi.org/10.1016/0079-6700(91)90026-H	journal	January 1991
Thermo‐mechanical Properties of PEO‐PU/PAN Semi‐Interpenetrating Polymer Networks and their LiClO ₄ Salt‐Complexes Basak, Pratyay; Manorama, Sunkara V. Journal of Macromolecular Science, Part A, Vol. 43, Issue 2 https://doi.org/10.1080/10601320500437292	journal	February 2006
Reviving the lithium metal anode for high-energy batteries Lin, Dingchang; Liu, Yayuan; Cui, Yi Nature Nanotechnology, Vol. 12, Issue 3 https://doi.org/10.1038/nnano.2017.16	journal	March 2017
High Performance of Transferring Lithium Ion for Polyacrylonitrile-Interpenetrating Crosslinked Polyoxyethylene Network as Gel Polymer Electrolyte Kuo, Ping-Lin; Wu, Ching-An; Lu, Chung-Yu ACS Applied Materials & Interfaces, Vol. 6, Issue 5 https://doi.org/10.1021/am404248b	journal	February 2014
Star-Shaped Polymer Electrolyte with Microphase Separation Structure for All-Solid-State Lithium Batteries Niitani, Takeshi; Amaike, Masato; Nakano, Hiroyuki Journal of The Electrochemical Society, Vol. 156, Issue 7 https://doi.org/10.1149/1.3129245	journal	January 2009
Synthesis and characterization of novel semi-interpenetrating polymer network electrolyte based on crosslinked P(GMA-co-AN)/PEO Luo, Dan; Li, Yang; Li, Weili Journal of Applied Polymer Science, Vol. 108, Issue 4 https://doi.org/10.1002/app.27713	journal	January 2008
Electrochemical measurement of transference numbers in polymer electrolytes Evans, James; Vincent, Colin A.; Bruce, Peter G. Polymer, Vol. 28, Issue 13 https://doi.org/10.1016/0032-3861(87)90394-6	journal	December 1987
Metallic anodes for next generation secondary batteries Kim, Hansu; Jeong, Goojin; Kim, Young-Ugk Chemical Society Reviews, Vol. 42, Issue 23 https://doi.org/10.1039/c3cs60177c	journal	January 2013
An interpenetrating network poly(diethylene glycol carbonate)-based polymer electrolyte for solid state lithium batteries Liu, Xiaochen; Ding, Guoliang; Zhou, Xinhong Journal of Materials Chemistry A, Vol. 5, Issue 22 https://doi.org/10.1039/C7TA02423A	journal	January 2017
UV-curable semi-interpenetrating polymer network-integrated, highly bendable plastic crystal composite electrolytes for shape-conformable all-solid-state lithium ion batteries Ha, Hyo-Jeong; Kil, Eun-Hye; Kwon, Yo Han Energy & Environmental Science, Vol. 5, Issue 4 https://doi.org/10.1039/c2ee03025j	journal	January 2012
Steady state current flow in solid binary electrolyte cells Bruce, Peter G.; Vincent, Colin A. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 225, Issue 1-2 https://doi.org/10.1016/0022-0728(87)80001-3	journal	June 1987
Estimation of Li+ transport number in polymer electrolytes by the combination of complex impedance and potentiostatic polarization measurements Watanabe, M. Solid State Ionics, Vol. 28-30 https://doi.org/10.1016/0167-2738(88)90303-7	journal	September 1988
Li–O₂ and Li–S batteries with high energy storage Bruce, Peter G.; Freunberger, Stefan A.; Hardwick, Laurence J. Nature Materials, Vol. 11, Issue 1, p. 19-29 https://doi.org/10.1038/nmat3191	journal	January 2012
Segmental Dynamics of Ethylene Oxide-Containing Polymers with Diverse Backbone Chemistries Bartels, Joshua; Wang, Jing-Han Helen; Chen, Quan Macromolecules, Vol. 49, Issue 5 https://doi.org/10.1021/acs.macromol.5b02423	journal	February 2016
Toward ambient temperature operation with all-solid-state lithium metal batteries with a sp boron-based solid single ion conducting polymer electrolyte Zhang, Yunfeng; Cai, Weiwei; Rohan, Rupesh Journal of Power Sources, Vol. 306 https://doi.org/10.1016/j.jpowsour.2015.12.010	journal	February 2016
Electrolytes for solid-state lithium rechargeable batteries: recent advances and perspectives Quartarone, Eliana; Mustarelli, Piercarlo Chemical Society Reviews, Vol. 40, Issue 5 https://doi.org/10.1039/c0cs00081g	journal	January 2011
A novel polymeric electrolyte based on a copolymer containing self-assembled stearylate moiety for lithium-ion batteries Yoshimoto, Nobuko; Shimamura, Osamu; Nishimura, Takuya Electrochemistry Communications, Vol. 11, Issue 2 https://doi.org/10.1016/j.elecom.2008.12.030	journal	February 2009
Polymer Elasticity-Driven Wrinkling and Coarsening in High Temperature Buckling of Metal-Capped Polymer Thin Films Yoo, Pil J.; Suh, Kahp Y.; Kang, Hyewon Physical Review Letters, Vol. 93, Issue 3 https://doi.org/10.1103/PhysRevLett.93.034301	journal	July 2004
Stable lithium electrodeposition in liquid and nanoporous solid electrolytes Lu, Yingying; Tu, Zhengyuan; Archer, Lynden A. Nature Materials, Vol. 13, Issue 10 https://doi.org/10.1038/nmat4041	journal	August 2014
Single Lithium-Ion Conducting Polymer Electrolytes Based on a Super-Delocalized Polyanion Ma, Qiang; Zhang, Heng; Zhou, Chongwang Angewandte Chemie, Vol. 128, Issue 7 https://doi.org/10.1002/ange.201509299	journal	January 2016
Stable Lithium Electrodeposition in Liquid and Nanoporous Solid Electrolytes Lu, Yingying; Tu, Zhengyuan; Archer, Lynden arXiv https://doi.org/10.48550/arxiv.1404.6177	text	January 2014

Cited By (6)

Simultaneously Boosting the Ionic Conductivity and Mechanical Strength of Polymer Gel Electrolyte Membranes by Confining Ionic Liquids into Hollow Silica Nanocavities Thapaliya, Bishnu P.; Do‐Thanh, Chi‐Linh; Jafta, Charl J. Batteries & Supercaps, Vol. 2, Issue 12 https://doi.org/10.1002/batt.201900095	journal	September 2019
CO ₂ -sourced polycarbonates as solid electrolytes for room temperature operating lithium batteries Ouhib, Farid; Meabe, Leire; Mahmoud, Abdelfattah Journal of Materials Chemistry A, Vol. 7, Issue 16 https://doi.org/10.1039/c9ta01564g	journal	January 2019
Development of the PEO Based Solid Polymer Electrolytes for All-Solid State Lithium Ion Batteries Jiang, Yu; Yan, Xuemin; Ma, Zhaofei Polymers, Vol. 10, Issue 11 https://doi.org/10.3390/polym10111237	journal	November 2018
All-Solid-State Lithium Battery Working without an Additional Separator in a Polymeric Electrolyte Cho, Seonggyu; Kim, Shinho; Kim, Wonho Polymers, Vol. 10, Issue 12 https://doi.org/10.3390/polym10121364	journal	December 2018
Preparation and Properties of a High-Performance EOEOEA-Based Gel-Polymer-Electrolyte Lithium Battery Ding, Wenwen; Wei, Chun; Wang, Shiqi Polymers, Vol. 11, Issue 8 https://doi.org/10.3390/polym11081296	journal	August 2019
Triple Layer Tungsten Trioxide, Graphene, and Polyaniline Composite Films for Combined Energy Storage and Electrochromic Applications Lyu, Hailong Polymers, Vol. 12, Issue 1 https://doi.org/10.3390/polym12010049	journal	December 2019

Similar Records

Constructing a multi-functional polymer network for ultra-stable and safe Li-metal batteries

Journal Article · Mon Nov 28 00:00:00 EST 2022 · Energy Storage Materials · OSTI ID:1462867

Gao, Shilun; Li, Zhenxi; Zhang, Zhen; +7 more

Single-Ion Conducting Polymer Nanoparticles as Functional Fillers for Solid Electrolytes in Lithium Metal Batteries

Journal Article · Wed Nov 03 00:00:00 EDT 2021 · ACS Applied Materials and Interfaces · OSTI ID:1462867

Porcarelli, Luca; Sutton, Preston; Bocharova, Vera; +7 more

Facile and scalable fabrication of polymer-ceramic composite electrolyte with high ceramic loadings

Journal Article · Tue Apr 24 00:00:00 EDT 2018 · Journal of Power Sources · OSTI ID:1462867

Pandian, Amaresh Samuthira; Chen, Xi Chelsea; Chen, Jihua; +7 more

Related Subjects

25 ENERGY STORAGE

Title: All-solid-state interpenetrating network polymer electrolytes for long cycle life of lithium metal batteries

Citation Formats

References (64)

Cited By (6)

Similar Records

Related Subjects