High order harmonic generation from SF6: Deconvolution of macroscopic effects
Journal Article
·
· Journal of Chemical Physics
- Louisiana State Univ., Baton Rouge, LA (United States). Dept. of Chemistry
- Kansas State Univ., Manhattan, KS (United States). J.R. Macdonald Lab.
- Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry; Indian Inst. of Technology Patna (IITP), Bihta (India). Dept. of Physics
- Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry
In this paper, we measure high order harmonics from the molecule SF6 over a large range of phase matching conditions and observe several features in the harmonics that are largely independent of such macroscopic conditions. The experimental data are then compared to the quantitative rescattering theory for the generation of harmonics from three orbitals. Finally, with this comparison, we are able to assign spectroscopic features in the harmonics to contributions from 1t1g (HOMO) and 5t1u (HOMO-1) orbitals.
- Research Organization:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); Robert A. Welch Foundation (United States)
- Grant/Contract Number:
- SC0012198; FG02-86ER13491; A-1020
- OSTI ID:
- 1461112
- Alternate ID(s):
- OSTI ID: 1335708
- Journal Information:
- Journal of Chemical Physics, Vol. 145, Issue 22; ISSN 0021-9606
- Publisher:
- American Institute of Physics (AIP)Copyright Statement
- Country of Publication:
- United States
- Language:
- English
Cited by: 4 works
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