Electrochemical and interfacial behavior of all solid state batteries using Li10SnP2S12 solid electrolyte

Vinado, Carolina; Wang, Shanyu; He, Yang; Xiao, Xingcheng; Li, Yun; Wang, Chongmin; Yang, Jihui

doi:10.1016/J.JPOWSOUR.2018.06.038

Title: Electrochemical and interfacial behavior of all solid state batteries using Li₁₀SnP₂S₁₂ solid electrolyte

Journal Article · Tue Jun 19 00:00:00 EDT 2018 · Journal of Power Sources

DOI:https://doi.org/10.1016/J.JPOWSOUR.2018.06.038· OSTI ID:1457752

Vinado, Carolina ^[1]; Wang, Shanyu ^[1]; He, Yang ^[2];

^[3]; Li, Yun ^[1]; Wang, Chongmin ^[2]; Yang, Jihui ^[1]

Univ. of Washington, Seattle, WA (United States). Materials Science and Engineering Department
Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Environmental Molecular Sciences Lab. (EMSL)
General Motors R&D Center, Warren, MI (United States). Chemical Sciences and Materials Systems Lab

Thio-Lithium Superionic Conductor (Thio-LISICON) Li₁₀GeP₂S₁₂ equivalent Li₁₀SnP₂S₁₂ (LSPS) is comparable in ionic conductivity yet with a lower cost as an electrolyte for all solid-state batteries (ASSBs). In this study, ASSBs with LSPS solid electrolyte (SE), lithium-indium alloy anode, and LiCoO₂ (LCO) cathode were successfully fabricated and their electrochemical performance at 60 °C was examined. Atomic layer deposition of Li₃NbO₄ on LCO was conducted to improve the interfacial stability. The Li₃NbO₄ coating effectively improves the cycle stability of the ASSB. Electrochemical impedance spectroscopy tests indicate a rapid growth of charge transfer resistance upon cycling for the cell with the uncoated LCO, primarily due to the surface instability and build-up of a space charge layer. However, the ASSBs with Li₃NbO₄ coated LCO show a more stable interface with a negligible impedance increase upon cycling, attributable to the buffering and passivating roles of the Li₃NbO₄ coating. Lastly, the interfacial microstructure was analyzed to elucidate at the underlying reasons for the impedance increase and the pivotal role of the Li₃NbO₄ coating.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE Office of Science (SC), Biological and Environmental Research (BER); USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC05-76RL01830; EE0007787; AC02-05CH11231; 18769; 6951379; AC05-76RLO1830

OSTI ID:: 1457752

Alternate ID(s):: OSTI ID: 1495302

Report Number(s):: PNNL-SA-132845; PII: S0378775318306347

Journal Information:: Journal of Power Sources, Vol. 396; ISSN 0378-7753

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 43 works

Citation information provided by
Web of Science

References (36)

Interfacial behaviours between lithium ion conductors and electrode materials in various battery systems Wu, Bingbin; Wang, Shanyu; Evans IV, Willie J. Journal of Materials Chemistry A, Vol. 4, Issue 40 https://doi.org/10.1039/C6TA05439K	journal	January 2016
Challenges for Rechargeable Li Batteries Goodenough, John B.; Kim, Youngsik Chemistry of Materials, Vol. 22, Issue 3, p. 587-603 https://doi.org/10.1021/cm901452z	journal	February 2010
All-solid-state lithium secondary batteries using LiCoO₂ particles with pulsed laser deposition coatings of Li₂S–P₂S₅ solid electrolytes Sakuda, Atsushi; Hayashi, Akitoshi; Ohtomo, Takamasa Journal of Power Sources, Vol. 196, Issue 16, p. 6735-6741 https://doi.org/10.1016/j.jpowsour.2010.10.103	journal	August 2011
A lithium superionic conductor Kamaya, Noriaki; Homma, Kenji; Yamakawa, Yuichiro Nature Materials, Vol. 10, Issue 9, p. 682-686 https://doi.org/10.1038/nmat3066	journal	July 2011
High-power all-solid-state batteries using sulfide superionic conductors Kato, Yuki; Hori, Satoshi; Saito, Toshiya Nature Energy, Vol. 1, Issue 4 https://doi.org/10.1038/nenergy.2016.30	journal	March 2016
Phase stability, electrochemical stability and ionic conductivity of the Li _10±1 MP ₂ X ₁₂ (M = Ge, Si, Sn, Al or P, and X = O, S or Se) family of superionic conductors Ong, Shyue Ping; Mo, Yifei; Richards, William Davidson Energy Environ. Sci., Vol. 6, Issue 1 https://doi.org/10.1039/C2EE23355J	journal	January 2013
Li ₁₀ SnP ₂ S ₁₂ : An Affordable Lithium Superionic Conductor Bron, Philipp; Johansson, Sebastian; Zick, Klaus Journal of the American Chemical Society, Vol. 135, Issue 42 https://doi.org/10.1021/ja407393y	journal	October 2013
Li10Si0.3Sn0.7P2S12 – A low-cost and low-grain-boundary-resistance lithium superionic conductor Bron, Philipp; Dehnen, Stefanie; Roling, Bernhard Journal of Power Sources, Vol. 329 https://doi.org/10.1016/j.jpowsour.2016.08.115	journal	October 2016
Enhancement of the High-Rate Capability of Solid-State Lithium Batteries by Nanoscale Interfacial Modification Ohta, N.; Takada, K.; Zhang, L. Advanced Materials, Vol. 18, Issue 17, p. 2226-2229 https://doi.org/10.1002/adma.200502604	journal	September 2006
Positive and Negative Aspects of Interfaces in Solid-State Batteries Takada, Kazunori; Ohno, Takahisa; Ohta, Narumi ACS Energy Letters, Vol. 3, Issue 1 https://doi.org/10.1021/acsenergylett.7b01105	journal	November 2017
All-solid-state lithium secondary batteries with oxide-coated LiCoO2 electrode and Li2S–P2S5 electrolyte Sakuda, Atsushi; Kitaura, Hirokazu; Hayashi, Akitoshi Journal of Power Sources, Vol. 189, Issue 1 https://doi.org/10.1016/j.jpowsour.2008.10.129	journal	April 2009
First principles study on electrochemical and chemical stability of solid electrolyte–electrode interfaces in all-solid-state Li-ion batteries Zhu, Yizhou; He, Xingfeng; Mo, Yifei Journal of Materials Chemistry A, Vol. 4, Issue 9 https://doi.org/10.1039/C5TA08574H	journal	January 2016
A Battery Made from a Single Material Han, Fudong; Gao, Tao; Zhu, Yujie Advanced Materials, Vol. 27, Issue 23 https://doi.org/10.1002/adma.201500180	journal	April 2015
Space–Charge Layer Effect at Interface between Oxide Cathode and Sulfide Electrolyte in All-Solid-State Lithium-Ion Battery Haruyama, Jun; Sodeyama, Keitaro; Han, Liyuan Chemistry of Materials, Vol. 26, Issue 14 https://doi.org/10.1021/cm5016959	journal	July 2014
Effects of surface modification by MgO on interfacial reactions of lithium cobalt oxide thin film electrode Iriyama, Yasutoshi; Kurita, Hiroyuki; Yamada, Izumi Journal of Power Sources, Vol. 137, Issue 1 https://doi.org/10.1016/j.jpowsour.2004.05.029	journal	October 2004
A modified ZrO2-coating process to improve electrochemical performance of Li(Ni1/3Co1/3Mn1/3)O2 Huang, Youyuan; Chen, Jitao; Ni, Jiangfeng Journal of Power Sources, Vol. 188, Issue 2 https://doi.org/10.1016/j.jpowsour.2008.12.037	journal	March 2009
A modified Al2O3 coating process to enhance the electrochemical performance of Li(Ni1/3Co1/3Mn1/3)O2 and its comparison with traditional Al2O3 coating process Huang, Youyuan; Chen, Jitao; Cheng, Fuquan Journal of Power Sources, Vol. 195, Issue 24 https://doi.org/10.1016/j.jpowsour.2010.07.021	journal	December 2010
Characterization of Spinel Li _x Co ₂ O ₄ -Coated LiCoO ₂ Prepared with Post-Thermal Treatment as a Cathode Material for Lithium Ion Batteries Shim, Jae-Hyun; Lee, Ki-Soo; Missyul, Alexander Chemistry of Materials, Vol. 27, Issue 9 https://doi.org/10.1021/acs.chemmater.5b00159	journal	April 2015
Role of surface coating on cathode materials for lithium-ion batteries Chen, Zonghai; Qin, Yan; Amine, Khalil Journal of Materials Chemistry, Vol. 20, Issue 36, p. 7606-7612 https://doi.org/10.1039/c0jm00154f	journal	January 2010
Improving the Cycling Performance and Thermal Stability of LiNi0.6Co0.2Mn0.2O2 Cathode Materials by Nb-doping and Surface Modification Kaneda, Haruki International Journal of Electrochemical Science https://doi.org/10.20964/2017.06.19	journal	June 2017
Interfacial modification for high-power solid-state lithium batteries Takada, Kazunori; Ohta, Narumi; Zhang, Lianqi Solid State Ionics, Vol. 179, Issue 27-32 https://doi.org/10.1016/j.ssi.2008.02.017	journal	September 2008
Electrode surface engineering by atomic layer deposition: A promising pathway toward better energy storage Ahmed, Bilal; Xia, Chuan; Alshareef, Husam N. Nano Today, Vol. 11, Issue 2 https://doi.org/10.1016/j.nantod.2016.04.004	journal	April 2016
Solid state lithium battery with oxysulfide glass Takada, K. Solid State Ionics, Vol. 86-88 https://doi.org/10.1016/0167-2738(96)00199-3	journal	July 1996
Uncovering the role of Nb modification in improving the structure stability and electrochemical performance of LiNi 0.6 Co 0.2 Mn 0.2 O 2 cathode charged at higher voltage of 4.5 V Liu, Siyang; Chen, Xiang; Zhao, Jiayue Journal of Power Sources, Vol. 374 https://doi.org/10.1016/j.jpowsour.2017.11.037	journal	January 2018
LiNbO3-coated LiCoO2 as cathode material for all solid-state lithium secondary batteries Ohta, Narumi; Takada, Kazunori; Sakaguchi, Isao Electrochemistry Communications, Vol. 9, Issue 7 https://doi.org/10.1016/j.elecom.2007.02.008	journal	July 2007
Commentary: The Materials Project: A materials genome approach to accelerating materials innovation Jain, Anubhav; Ong, Shyue Ping; Hautier, Geoffroy APL Materials, Vol. 1, Issue 1 https://doi.org/10.1063/1.4812323	journal	July 2013
A new ultrafast superionic Li-conductor: ion dynamics in Li ₁₁ Si ₂ PS ₁₂ and comparison with other tetragonal LGPS-type electrolytes Kuhn, Alexander; Gerbig, Oliver; Zhu, Changbao Phys. Chem. Chem. Phys., Vol. 16, Issue 28 https://doi.org/10.1039/C4CP02046D	journal	January 2014
Chemical stability enhancement of lithium conducting solid electrolyte plates using sputtered LiPON thin films West, W. C.; Whitacre, J. F.; Lim, J. R. Journal of Power Sources, Vol. 126, Issue 1-2, p. 134-138 https://doi.org/10.1016/j.jpowsour.2003.08.030	journal	February 2004
Electrochemical characterization of Li10SnP2S12: An electrolyte or a negative electrode for solid state Li-ion batteries? Tarhouchi, Ilyas; Viallet, Virginie; Vinatier, Philippe Solid State Ionics, Vol. 296 https://doi.org/10.1016/j.ssi.2016.08.016	journal	November 2016
Synthesis, structure, and ionic conductivity of solid solution, Li _10+δ M _1+δ P _2−δ S ₁₂ (M = Si, Sn) Hori, Satoshi; Suzuki, Kota; Hirayama, Masaaki Faraday Discuss., Vol. 176 https://doi.org/10.1039/C4FD00143E	journal	January 2014
Investigating the first-cycle irreversibility of lithium metal oxide cathodes for Li batteries Kang, Sun-Ho; Yoon, Won-Sub; Nam, Kyung-Wan Journal of Materials Science, Vol. 43, Issue 14 https://doi.org/10.1007/s10853-007-2355-6	journal	July 2008
All-solid-state lithium secondary batteries with metal-sulfide-coated LiCoO2 prepared by thermal decomposition of dithiocarbamato complexes Sakuda, Atsushi; Nakamoto, Naoyuki; Kitaura, Hirokazu Journal of Materials Chemistry, Vol. 22, Issue 30 https://doi.org/10.1039/c2jm32490c	journal	January 2012
A new composite solid electrolyte PEO/Li10GeP2S12/SN for all-solid-state lithium battery Chen, Bo; Huang, Zhen; Chen, Xiaotian Electrochimica Acta, Vol. 210 https://doi.org/10.1016/j.electacta.2016.06.025	journal	August 2016
Study of the Failure Mechanisms of LiNi _0.8 Mn _0.1 Co _0.1 O ₂ Cathode Material for Lithium Ion Batteries Li, Jing; Downie, Laura E.; Ma, Lin Journal of The Electrochemical Society, Vol. 162, Issue 7 https://doi.org/10.1149/2.1011507jes	journal	January 2015
Optical and Electrical Properties of Chemical Bath Deposited Cobalt Sulphide Thin Films Govindasamy, Geetha; Murugasen, Priya; Sagadevan, Suresh Materials Research, Vol. 20, Issue 1 https://doi.org/10.1590/1980-5373-mr-2016-0441	journal	November 2016
Optical and electrical properties of SnS semiconductor crystals grown by physical vapor deposition technique Hegde, S. S.; Kunjomana, A. G.; Chandrasekharan, K. A. Physica B: Condensed Matter, Vol. 406, Issue 5 https://doi.org/10.1016/j.physb.2010.12.068	journal	March 2011

Cited By (2)

Building Better Batteries in the Solid State: A Review Mauger, Alain; Julien, Christian M.; Paolella, Andrea Materials, Vol. 12, Issue 23, p. 3892 https://doi.org/10.3390/ma12233892	journal	November 2019
Crystal and Electronic Structure and Optical Properties of AE ₂ SiP ₄ ( AE = Sr, Eu, Ba) and Ba ₄ Si ₃ P ₈ : Crystal and Electronic Structure and Optical Properties of Mark, Justin; Dolyniuk, Juli-Anna; Tran, Nhon Zeitschrift für anorganische und allgemeine Chemie, Vol. 645, Issue 3 https://doi.org/10.1002/zaac.201800430	journal	November 2018

Figures / Tables (5)

Similar Records

Electrochemical and Interfacial Behavior of All Solid State Batteries Using Li10SnP2S12 Solid Electrolyte

Journal Article · Fri Aug 31 00:00:00 EDT 2018 · Journal of Power Sources · OSTI ID:1457752

Vinado, Carolina; Wang, Shanyu; He, Yang; +4 more

Interphase Stabilization of LiNi_0.5Mn_1.5O₄ Cathode for 5 V–Class All–Solid–State Batteries

Journal Article · Fri Sep 01 00:00:00 EDT 2023 · Small · OSTI ID:1457752

Lee, Dongsoo; Cui, Zehao; Goodenough, John B.; +1 more

Elucidating Reversible Electrochemical Redox of Li₆PS₅Cl Solid Electrolyte

Journal Article · Tue Aug 20 00:00:00 EDT 2019 · ACS Energy Letters · OSTI ID:1457752

Tan, Darren H. S.; Wu, Erik A.; Nguyen, Han; +7 more

Related Subjects

25 ENERGY STORAGE
36 MATERIALS SCIENCE
Li10SnP2S12
All-solid-state battery
Solid electrolyte
Atomic layer deposition
Interfacial stability

Title: Electrochemical and interfacial behavior of all solid state batteries using Li10SnP2S12 solid electrolyte

Citation Formats