Systematic Structure–Property Relationship Studies in Palladium-Catalyzed Methane Complete Combustion

Willis, Joshua J.; Gallo, Alessandro; Sokaras, Dimosthenis; Aljama, Hassan; Nowak, Stanislaw H.; Goodman, Emmett D.; Wu, Liheng; Tassone, Christopher J.; Jaramillo, Thomas F.; Abild-Pedersen, Frank; Cargnello, Matteo

doi:10.1021/acscatal.7b02414

Title: Systematic Structure–Property Relationship Studies in Palladium-Catalyzed Methane Complete Combustion

Journal Article · Mon Oct 09 00:00:00 EDT 2017 · ACS Catalysis

DOI:https://doi.org/10.1021/acscatal.7b02414· OSTI ID:1457139

Willis, Joshua J. ^[1]; Gallo, Alessandro ^[2]; Sokaras, Dimosthenis ^[3]; Aljama, Hassan ^[1]; Nowak, Stanislaw H. ^[3]; Goodman, Emmett D. ^[1]; Wu, Liheng ^[2]; Tassone, Christopher J. ^[3];

^[1];

^[1]

Stanford Univ., Stanford, CA (United States)
Stanford Univ., Stanford, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)
SLAC National Accelerator Lab., Menlo Park, CA (United States)

To limit further rising levels in methane emissions from stationary and mobile sources and to enable promising technologies based on methane, the development of efficient combustion catalysts that completely oxidize CH4 to CO2 and H2O at low temperatures in the presence of high steam concentrations is required. Palladium is widely considered as one of the most promising materials for this reaction, and a better understanding of the factors affecting its activity and stability is crucial to design even more improved catalysts that efficiently utilize this precious metal. Here we report a study of the effect of three important variables (particle size, support, and reaction conditions including water) on the activity of supported Pd catalysts. We use uniform palladium nanocrystals as catalyst precursors to prepare a library of well-defined catalysts to systematically describe structure–property relationships with help from theory and in situ X-ray absorption spectroscopy. With this approach, we confirm that PdO is the most active phase and that small differences in reaction rates as a function of size are likely due to variations in the surface crystal structure. We further demonstrate that the support exerts a limited influence on the PdO activity, with inert (SiO2), acidic (Al2O3), and redox-active (Ce0.8Zr0.2O2) supports providing similar rates, while basic (MgO) supports show remarkably lower activity. Finally, we show that the introduction of steam leads to a considerable decrease in rates that is due to coverage effects, rather than structural and/or phase changes. Altogether, the data suggest that to further increase the activity and stability of Pd-based catalysts for methane combustion, increasing the surface area of supported PdO phases while avoiding strong adsorption of water on the catalytic surfaces is required. This study clarifies contrasting reports in the literature about the active phase and stability of Pd-based materials for methane combustion.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: DGE-1656518; AC02-76SF00515

OSTI ID:: 1457139

Alternate ID(s):: OSTI ID: 1485426

Journal Information:: ACS Catalysis, Vol. 7, Issue 11; ISSN 2155-5435

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 114 works

Citation information provided by
Web of Science

References (80)

From shale gas to renewable energy based transportation solutions Mallapragada, Dharik S.; Duan, Gang; Agrawal, Rakesh Energy Policy, Vol. 67 https://doi.org/10.1016/j.enpol.2013.12.056	journal	April 2014
Durable and High-Performance Direct-Methane Fuel Cells with Coke-Tolerant Ceria-Coated Ni Catalysts at Reduced Temperatures Lee, Jin Goo; Jeon, Ok Sung; Hwang, Ho Jung Electrochimica Acta, Vol. 191 https://doi.org/10.1016/j.electacta.2016.01.091	journal	February 2016
Stable direct-methane solid oxide fuel cells with calcium-oxide-modified nickel-based anodes operating at reduced temperatures Qu, Jifa; Wang, Wei; Chen, Yubo Applied Energy, Vol. 164 https://doi.org/10.1016/j.apenergy.2015.12.014	journal	February 2016
Direct, Nonoxidative Conversion of Methane to Ethylene, Aromatics, and Hydrogen Guo, X.; Fang, G.; Li, G. Science, Vol. 344, Issue 6184 https://doi.org/10.1126/science.1253150	journal	May 2014
Methane Activation by Heterogeneous Catalysis Horn, Raimund; Schlögl, Robert Catalysis Letters, Vol. 145, Issue 1 https://doi.org/10.1007/s10562-014-1417-z	journal	November 2014
Influence of Methane Emissions and Vehicle Efficiency on the Climate Implications of Heavy-Duty Natural Gas Trucks Camuzeaux, Jonathan R.; Alvarez, Ramón A.; Brooks, Susanne A. Environmental Science & Technology, Vol. 49, Issue 11 https://doi.org/10.1021/acs.est.5b00412	journal	May 2015
Nanofaceted PdO Sites in PdCe Surface Superstructures: Enhanced Activity in Catalytic Combustion of Methane Colussi, Sara; Gayen, Arup; Farnesi Camellone, Matteo Angewandte Chemie International Edition, Vol. 48, Issue 45 https://doi.org/10.1002/anie.200903581	journal	October 2009
Conversion of Methane to Methanol with a Bent Mono(μ-oxo)dinickel Anchored on the Internal Surfaces of Micropores Shan, Junjun; Huang, Weixin; Nguyen, Luan Langmuir, Vol. 30, Issue 28 https://doi.org/10.1021/la501184b	journal	July 2014
An Introduction of CO ₂ Conversion by Dry Reforming with Methane and New Route of Low-Temperature Methanol Synthesis Shi, Lei; Yang, Guohui; Tao, Kai Accounts of Chemical Research, Vol. 46, Issue 8 https://doi.org/10.1021/ar300217j	journal	March 2013
Understanding complete oxidation of methane on spinel oxides at a molecular level Tao, Franklin Feng; Shan, Jun-jun; Nguyen, Luan Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8798	journal	August 2015
Methane combustion over supported cobalt catalysts Xiao, Tian-cun; Ji, Sheng-fu; Wang, Hai-tao Journal of Molecular Catalysis A: Chemical, Vol. 175, Issue 1-2 https://doi.org/10.1016/S1381-1169(01)00205-9	journal	October 2001
Structure and Reactivity of PdOx/ZrO2Catalysts for Methane Oxidation at Low Temperatures Fujimoto, Ken-ichiro; Ribeiro, Fabio H.; Avalos-Borja, Miguel Journal of Catalysis, Vol. 179, Issue 2 https://doi.org/10.1006/jcat.1998.2178	journal	October 1998
Kinetics of the Complete Oxidation of Methane over Supported Palladium Catalysts Ribeiro, F. H.; Chow, M.; Dallabetta, R. A. Journal of Catalysis, Vol. 146, Issue 2 https://doi.org/10.1006/jcat.1994.1092	journal	April 1994
The Turnover Rate for the Catalytic Combustion of Methane over Palladium Is Not Sensitive to the Structure of the Catalyst Zhu, Guanghui; Han, Jinyi; Zemlyanov, Dmitri Y. Journal of the American Chemical Society, Vol. 126, Issue 32 https://doi.org/10.1021/ja049406s	journal	August 2004
Temperature Dependence of the Kinetics for the Complete Oxidation of Methane on Palladium and Palladium Oxide ^† Zhu, Guanghui; Han, Jinyi; Zemlyanov, Dmitri Yu. The Journal of Physical Chemistry B, Vol. 109, Issue 6 https://doi.org/10.1021/jp0488665	journal	February 2005
Catalyst-controlled selectivity in the C-H borylation of methane and ethane Cook, A. K.; Schimler, S. D.; Matzger, A. J. Science, Vol. 351, Issue 6280 https://doi.org/10.1126/science.aad9289	journal	March 2016
Catalytic borylation of methane Smith, K. T.; Berritt, S.; Gonzalez-Moreiras, M. Science, Vol. 351, Issue 6280 https://doi.org/10.1126/science.aad9730	journal	March 2016
Catalytic Oxidation of Methane Anderson, R. B.; Stein, K. C.; Feenan, J. J. Industrial & Engineering Chemistry, Vol. 53, Issue 10 https://doi.org/10.1021/ie50622a024	journal	October 1961
Oxidation of methane over supported precious metal catalysts Cullis, C. Journal of Catalysis, Vol. 83, Issue 2 https://doi.org/10.1016/0021-9517(83)90054-4	journal	October 1983
Consequences of Metal–Oxide Interconversion for C–H Bond Activation during CH ₄ Reactions on Pd Catalysts Chin, Ya-Huei (Cathy); Buda, Corneliu; Neurock, Matthew Journal of the American Chemical Society, Vol. 135, Issue 41 https://doi.org/10.1021/ja405004m	journal	October 2013
Complete methane oxidation over Pd catalyst supported on α-alumina. Influence of temperature and oxygen pressure on the catalyst activity Lyubovsky, Maxim; Pfefferle, Lisa Catalysis Today, Vol. 47, Issue 1-4 https://doi.org/10.1016/S0920-5861(98)00281-8	journal	January 1999
Catalytic chemistry of supported palladium for combustion of methane Farrauto, R. J.; Hobson, M. C.; Kennelly, T. Applied Catalysis A: General, Vol. 81, Issue 2, p. 227-237 https://doi.org/10.1016/0926-860X(92)80095-T	journal	February 1992
Turnover Rate and Reaction Orders for the Complete Oxidation of Methane on a Palladium Foil in Excess Dioxygen Monteiro, R. S.; Zemlyanov, D.; Storey, J. M. Journal of Catalysis, Vol. 199, Issue 2 https://doi.org/10.1006/jcat.2001.3176	journal	April 2001
Kinetics of Heterogeneous Catalytic Reactions Boudart, Michel; Djega-Mariadassou, G. https://doi.org/10.1515/9781400853335	book	January 1984
Catalytic combustion of methane over supported palladium catalysts Baldwin, T. R.; Burch*, R. Applied Catalysis, Vol. 66, Issue 1 https://doi.org/10.1016/S0166-9834(00)81648-6	journal	November 1990
Structure sensitivity of methane oxidation over platinum and palladium Hicks, R. Journal of Catalysis, Vol. 122, Issue 2 https://doi.org/10.1016/0021-9517(90)90282-O	journal	April 1990
Intrinsic Ligand Effect Governing the Catalytic Activity of Pd Oxide Thin Films Martin, Natalia M.; Van den Bossche, Maxime; Hellman, Anders ACS Catalysis, Vol. 4, Issue 10 https://doi.org/10.1021/cs5010163	journal	August 2014
Molecular adsorption of small alkanes on a PdO(101) thin film: Evidence of σ-complex formation Weaver, Jason F.; Hakanoglu, Can; Hawkins, Jeffery M. The Journal of Chemical Physics, Vol. 132, Issue 2 https://doi.org/10.1063/1.3277672	journal	January 2010
Support effect on methane combustion over palladium catalysts Yoshida, Hisao; Nakajima, Tomoyuki; Yazawa, Yoshiteru Applied Catalysis B: Environmental, Vol. 71, Issue 1-2 https://doi.org/10.1016/j.apcatb.2006.08.010	journal	February 2007
Thermal decomposition and reformation of PdO catalysts; support effects Farrauto, Robert J.; Lampert, Jordan K.; Hobson, Melvin C. Applied Catalysis B: Environmental, Vol. 6, Issue 3 https://doi.org/10.1016/0926-3373(95)00015-1	journal	August 1995
Influence of co-metals on bimetallic palladium catalysts for methane combustion Persson, K.; Ersson, A.; Jansson, K. Journal of Catalysis, Vol. 231, Issue 1 https://doi.org/10.1016/j.jcat.2005.01.001	journal	April 2005
Catalytic combustion of propane and natural gas over Cu and Pd modified ZSM zeolite catalysts Neyestanaki, A. Kalantar; Kumar, N.; Lindfors, L. -E. Applied Catalysis B: Environmental, Vol. 7, Issue 1-2 https://doi.org/10.1016/0926-3373(95)00029-1	journal	December 1995
Support effect of zeolite on the methane combustion activity of palladium Okumura, Kazu; Matsumoto, Sachi; Nishiaki, Noriko Applied Catalysis B: Environmental, Vol. 40, Issue 2 https://doi.org/10.1016/S0926-3373(02)00149-2	journal	January 2003
The effect of CeO2 on the dynamics of Pd–PdO transformation over Pd/Al2O3 combustion catalysts Colussi, Sara; Trovarelli, Alessandro; Groppi, Gianpiero Catalysis Communications, Vol. 8, Issue 8 https://doi.org/10.1016/j.catcom.2006.11.020	journal	August 2007
Low-Temperature Oxidation of Methane over Pd Supported on SnO ₂ -Based Oxides Widjaja, Hardiyanto; Sekizawa, Koshi; Eguchi, Koichi Bulletin of the Chemical Society of Japan, Vol. 72, Issue 2 https://doi.org/10.1246/bcsj.72.313	journal	February 1999
Effect of ceria on palladium supported catalysts for high temperature combustion of CH4 under lean conditions Groppi, G.; Cristiani, C.; Lietti, L. Catalysis Today, Vol. 50, Issue 2 https://doi.org/10.1016/S0920-5861(98)00518-5	journal	April 1999
Contributions of Lattice Oxygen in Methane Combustion over PdO-Based Catalysts Ciuparu, Dragos; Altman, Eric; Pfefferle, Lisa Journal of Catalysis, Vol. 203, Issue 1 https://doi.org/10.1006/jcat.2001.3331	journal	October 2001
Oxygen Exchange between Palladium and Oxide Supports in Combustion Catalysts Ciuparu, Dragos; Bozon-Verduraz, Francois; Pfefferle, Lisa The Journal of Physical Chemistry B, Vol. 106, Issue 13 https://doi.org/10.1021/jp013577r	journal	April 2002
Combustion of Methane over Palladium-Based Catalysts: Support Interactions Schwartz, William R.; Pfefferle, Lisa D. The Journal of Physical Chemistry C, Vol. 116, Issue 15 https://doi.org/10.1021/jp2119668	journal	April 2012
Control of Metal Nanocrystal Size Reveals Metal-Support Interface Role for Ceria Catalysts Cargnello, M.; Doan-Nguyen, V. V. T.; Gordon, T. R. Science, Vol. 341, Issue 6147 https://doi.org/10.1126/science.1240148	journal	July 2013
Size and Support Effects for the Water–Gas Shift Catalysis over Gold Nanoparticles Supported on Model Al ₂ O ₃ and TiO ₂ Shekhar, Mayank; Wang, Jun; Lee, Wen-Sheng Journal of the American Chemical Society, Vol. 134, Issue 10 https://doi.org/10.1021/ja210083d	journal	February 2012
Metallic Corner Atoms in Gold Clusters Supported on Rutile Are the Dominant Active Site during Water−Gas Shift Catalysis Williams, W. Damion; Shekhar, Mayank; Lee, Wen-Sheng Journal of the American Chemical Society, Vol. 132, Issue 40 https://doi.org/10.1021/ja1064262	journal	October 2010
Methane Catalytic Combustion over Hierarchical Pd@CeO ₂ /Si-Al ₂ O ₃ : Effect of the Presence of Water Monai, Matteo; Montini, Tiziano; Chen, Chen ChemCatChem, Vol. 7, Issue 14 https://doi.org/10.1002/cctc.201402717	journal	October 2014
Complete oxidation of methane at low temperature over Pt and Pd catalysts for the abatement of lean-burn natural gas fuelled vehicles emissions: influence of water and sulphur containing compounds Gélin, Patrick; Urfels, Laetitia; Primet, Michel Catalysis Today, Vol. 83, Issue 1-4 https://doi.org/10.1016/S0920-5861(03)00215-3	journal	August 2003
Methane combustion over palladium catalysts: The effect of carbon dioxide and water on activity Burch, R.; Urbano, F.; Loader, P. Applied Catalysis A: General, Vol. 123, Issue 1 https://doi.org/10.1016/0926-860X(94)00251-7	journal	March 1995
Catalytic behaviour of Cl-free and Cl-containing Pd/Al2O3 catalysts in the total oxidation of methane at low temperature Roth, Delphine; Gélin, Patrick; Primet, Michel Applied Catalysis A: General, Vol. 203, Issue 1 https://doi.org/10.1016/S0926-860X(00)00465-8	journal	September 2000
Combustion of Methane over Palladium-Based Catalysts: Catalytic Deactivation and Role of the Support Schwartz, William R.; Ciuparu, Dragos; Pfefferle, Lisa D. The Journal of Physical Chemistry C, Vol. 116, Issue 15 https://doi.org/10.1021/jp212236e	journal	April 2012
Engineering uniform nanocrystals: Mechanism of formation and self-assembly into bimetallic nanocrystal superlattices Cargnello, Matteo; Doan-Nguyen, Vicky V. T.; Murray, Christopher B. AIChE Journal, Vol. 62, Issue 2 https://doi.org/10.1002/aic.15063	journal	October 2015
Synthesis of Monodisperse Palladium Nanoparticles Kim, Sang-Wook; Park, Jongnam; Jang, Youngjin Nano Letters, Vol. 3, Issue 9 https://doi.org/10.1021/nl0343405	journal	September 2003
Gas-Bubble Effects on the Formation of Colloidal Iron Oxide Nanocrystals Lynch, Jared; Zhuang, Jiaqi; Wang, Tie Journal of the American Chemical Society, Vol. 133, Issue 32 https://doi.org/10.1021/ja2032597	journal	August 2011
Novel embedded Pd@CeO ₂ catalysts: a way to active and stable catalysts Cargnello, Matteo; Montini, Tiziano; Polizzi, Stefano Dalton Trans., Vol. 39, Issue 8 https://doi.org/10.1039/B916035C	journal	January 2010
Simple method to synthesize high surface area magnesium oxide and its use as a heterogeneous base catalyst Bartley, Jonathan K.; Xu, Chunli; Lloyd, Rhys Applied Catalysis B: Environmental, Vol. 128 https://doi.org/10.1016/j.apcatb.2012.03.036	journal	November 2012
Efficient Removal of Organic Ligands from Supported Nanocrystals by Fast Thermal Annealing Enables Catalytic Studies on Well-Defined Active Phases Cargnello, Matteo; Chen, Chen; Diroll, Benjamin T. Journal of the American Chemical Society, Vol. 137, Issue 21 https://doi.org/10.1021/jacs.5b03333	journal	May 2015
Low temperature CO pulse adsorption for the determination of Pt particle size in a Pt/cerium-based oxide catalyst Tanabe, Toshitaka; Nagai, Yasutaka; Hirabayashi, Takeshi Applied Catalysis A: General, Vol. 370, Issue 1-2 https://doi.org/10.1016/j.apcata.2009.09.030	journal	November 2009
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials Giannozzi, Paolo; Baroni, Stefano; Bonini, Nicola Journal of Physics: Condensed Matter, Vol. 21, Issue 39, Article No. 395502 https://doi.org/10.1088/0953-8984/21/39/395502	journal	September 2009
Implementation of ultrasoft pseudopotentials in ab initio molecular dynamics Laasonen, Kari; Car, Roberto; Lee, Changyol Physical Review B, Vol. 43, Issue 8 https://doi.org/10.1103/PhysRevB.43.6796	journal	March 1991
An object-oriented scripting interface to a legacy electronic structure code Bahn, S. R.; Jacobsen, K. W. Computing in Science & Engineering, Vol. 4, Issue 3 https://doi.org/10.1109/5992.998641	journal	January 2002
A climbing image nudged elastic band method for finding saddle points and minimum energy paths Henkelman, Graeme; Uberuaga, Blas P.; Jónsson, Hannes The Journal of Chemical Physics, Vol. 113, Issue 22, p. 9901-9904 https://doi.org/10.1063/1.1329672	journal	December 2000
CatMAP: A Software Package for Descriptor-Based Microkinetic Mapping of Catalytic Trends Medford, Andrew J.; Shi, Chuan; Hoffmann, Max J. Catalysis Letters, Vol. 145, Issue 3 https://doi.org/10.1007/s10562-015-1495-6	journal	February 2015
A Method for Evaluating and Correlating Thermodynamic Da ta Shomate, C. Howard The Journal of Physical Chemistry, Vol. 58, Issue 4 https://doi.org/10.1021/j150514a018	journal	April 1954
The statistics of surface atoms and surface sites on metal crystals Van Hardeveld, R.; Hartog, F. Surface Science, Vol. 15, Issue 2 https://doi.org/10.1016/0039-6028(69)90148-4	journal	June 1969
100° Temperature Reduction of Wet Methane Combustion: Highly Active Pd–Ni/Al 2 O 3 Catalyst versus Pd/NiAl 2 O 4 Shen, Jing; Hayes, Robert E.; Wu, Xiaoxing ACS Catalysis, Vol. 5, Issue 5 https://doi.org/10.1021/acscatal.5b00060	journal	March 2015
Oxidation behaviour and catalytic properties of Pd/Al2O3 catalysts in the total oxidation of methane Roth, D.; Gélin, P.; Kaddouri, A. Catalysis Today, Vol. 112, Issue 1-4 https://doi.org/10.1016/j.cattod.2005.11.048	journal	March 2006
Dynamics and Thermodynamics of Pd–PdO Phase Transitions: Effects of Pd Cluster Size and Kinetic Implications for Catalytic Methane Combustion Chin, Ya-Huei (Cathy); García-Diéguez, Mónica; Iglesia, Enrique The Journal of Physical Chemistry C, Vol. 120, Issue 3 https://doi.org/10.1021/acs.jpcc.5b06677	journal	January 2016
How Strain Affects the Reactivity of Surface Metal Oxide Catalysts Amakawa, Kazuhiko; Sun, Lili; Guo, Chunsheng Angewandte Chemie International Edition, Vol. 52, Issue 51 https://doi.org/10.1002/anie.201306620	journal	November 2013
Direct and continuous strain control of catalysts with tunable battery electrode materials Wang, Haotian; Xu, Shicheng; Tsai, Charlie Science, Vol. 354, Issue 6315 https://doi.org/10.1126/science.aaf7680	journal	November 2016
Balance of Nanostructure and Bimetallic Interactions in Pt Model Fuel Cell Catalysts: In Situ XAS and DFT Study Friebel, Daniel; Viswanathan, Venkatasubramanian; Miller, Daniel J. Journal of the American Chemical Society, Vol. 134, Issue 23 https://doi.org/10.1021/ja3003765	journal	May 2012
The Active Phase of Palladium during Methane Oxidation Hellman, A.; Resta, A.; Martin, N. M. The Journal of Physical Chemistry Letters, Vol. 3, Issue 6 https://doi.org/10.1021/jz300069s	journal	February 2012
Surface Chemistry of Late Transition Metal Oxides Weaver, Jason F. Chemical Reviews, Vol. 113, Issue 6 https://doi.org/10.1021/cr300323w	journal	December 2012
Thermodynamic stability of PdO surfaces Rogal, Jutta; Reuter, Karsten; Scheffler, Matthias Physical Review B, Vol. 69, Issue 7 https://doi.org/10.1103/PhysRevB.69.075421	journal	February 2004
Methane Oxidation over PdO(101) Revealed by First-Principles Kinetic Modeling Bossche, Maxime Van den; Grönbeck, Henrik Journal of the American Chemical Society, Vol. 137, Issue 37 https://doi.org/10.1021/jacs.5b06069	journal	September 2015
A comparison of CO oxidation on ceria-supported Pt, Pd, and Rh Bunluesin, T.; Putna, E. S.; Gorte, R. J. Catalysis Letters, Vol. 41, Issue 1-2 https://doi.org/10.1007/BF00811703	journal	January 1996
The support effect on platinum catalyst under oxidizing atmosphere: improvement in the oxidation-resistance of platinum by the electrophilic property of support materials Yazawa, Yoshiteru; Yoshida, Hisao; Hattori, Tadashi Applied Catalysis A: General, Vol. 237, Issue 1-2 https://doi.org/10.1016/S0926-860X(02)00323-X	journal	November 2002
CO2 absorption and regeneration of alkali metal-based solid sorbents Lee, Soo Chool; Choi, Bo Yun; Lee, Tae Jin Catalysis Today, Vol. 111, Issue 3-4 https://doi.org/10.1016/j.cattod.2005.10.051	journal	February 2006
Synthesis of highly coke resistant Ni nanoparticles supported MgO/ZnO catalyst for reforming of methane with carbon dioxide Singha, Rajib Kumar; Yadav, Aditya; Agrawal, Ayush Applied Catalysis B: Environmental, Vol. 191 https://doi.org/10.1016/j.apcatb.2016.03.029	journal	August 2016
Selective Hydrogenation of Ethyne in Ethene‐Rich Streams on Palladium Catalysts, Part 2: Steady‐State Kinetics and Effects of Palladium Particle Size, Carbon Monoxide, and Promoters Borodziński, Andrzej; Bond, Geoffrey C. Catalysis Reviews, Vol. 50, Issue 3 https://doi.org/10.1080/01614940802142102	journal	August 2008
Role of Site Stability in Methane Activation on Pd _x Ce _{1 –x} O _δ Surfaces Senftle, Thomas P.; van Duin, Adri C. T.; Janik, Michael J. ACS Catalysis, Vol. 5, Issue 10 https://doi.org/10.1021/acscatal.5b00741	journal	September 2015
Methane Activation at the Pd/CeO ₂ Interface Senftle, Thomas P.; van Duin, Adri C. T.; Janik, Michael J. ACS Catalysis, Vol. 7, Issue 1 https://doi.org/10.1021/acscatal.6b02447	journal	December 2016
Exceptional Activity for Methane Combustion over Modular Pd@CeO2 Subunits on Functionalized Al2O3 Cargnello, M.; Jaen, J. J. D.; Garrido, J. C. H. Science, Vol. 337, Issue 6095 https://doi.org/10.1126/science.1222887	journal	August 2012

Cited By (15)

Understanding the Role of SnO ₂ Support in Water‐Tolerant Methane Combustion: In situ Observation of Pd(OH) ₂ and Comparison with Pd/Al ₂ O ₃ Barrett, William; Shen, Jing; Hu, Yongfeng ChemCatChem, Vol. 12, Issue 3 https://doi.org/10.1002/cctc.201901744	journal	December 2019
Accessing the C–C transition state energy on transition metals Aljama, Hassan; Abild-Pedersen, Frank Physical Chemistry Chemical Physics, Vol. 21, Issue 45 https://doi.org/10.1039/c9cp04897a	journal	January 2019
Palladium oxidation leads to methane combustion activity: Effects of particle size and alloying with platinum Goodman, Emmett D.; Ye, Angela A.; Aitbekova, Aisulu The Journal of Chemical Physics, Vol. 151, Issue 15 https://doi.org/10.1063/1.5126219	journal	October 2019
Catalytic Oxidation of Methane: Pd and Beyond: Catalytic Oxidation of Methane: Pd and Beyond Monai, Matteo; Montini, Tiziano; Gorte, Raymond J. European Journal of Inorganic Chemistry, Vol. 2018, Issue 25 https://doi.org/10.1002/ejic.201800326	journal	June 2018
Transition state and product diffusion control by polymer–nanocrystal hybrid catalysts Riscoe, Andrew R.; Wrasman, Cody J.; Herzing, Andrew A. Nature Catalysis, Vol. 2, Issue 10 https://doi.org/10.1038/s41929-019-0322-7	journal	August 2019
Catalyst deactivation via decomposition into single atoms and the role of metal loading Goodman, Emmett D.; Johnston-Peck, Aaron C.; Dietze, Elisabeth M. Nature Catalysis, Vol. 2, Issue 9 https://doi.org/10.1038/s41929-019-0328-1	journal	August 2019
Pentacoordinated Al ³⁺ ‐Stabilized Active Pd Structures on Al ₂ O ₃ ‐Coated Palladium Catalysts for Methane Combustion Duan, Huimei; You, Rui; Xu, Shutao Angewandte Chemie, Vol. 131, Issue 35 https://doi.org/10.1002/ange.201904883	journal	July 2019
Confined Ultrathin Pd-Ce Nanowires with Outstanding Moisture and SO ₂ Tolerance in Methane Combustion Peng, Honggen; Rao, Cheng; Zhang, Ning Angewandte Chemie International Edition, Vol. 57, Issue 29 https://doi.org/10.1002/anie.201803393	journal	June 2018
Pentacoordinated Al ³⁺ ‐Stabilized Active Pd Structures on Al ₂ O ₃ ‐Coated Palladium Catalysts for Methane Combustion Duan, Huimei; You, Rui; Xu, Shutao Angewandte Chemie International Edition, Vol. 58, Issue 35 https://doi.org/10.1002/anie.201904883	journal	August 2019
N-Doped Carbon–Silica Composite Confined Pd Nanoparticles for Abatement of Methane Emission From Automobiles Zhou, Chaoqun; Xu, Wenbin; Liu, Chunjiang Topics in Catalysis, Vol. 62, Issue 1-4 https://doi.org/10.1007/s11244-018-1099-7	journal	November 2018
In Situ X-ray Absorption Spectroscopy Studies of Nanoscale Electrocatalysts Wang, Maoyu; Árnadóttir, Líney; Xu, Zhichuan J. Nano-Micro Letters, Vol. 11, Issue 1 https://doi.org/10.1007/s40820-019-0277-x	journal	June 2019
Ultrafast X-ray Absorption Studies of the Structural Dynamics of Molecular and Biological Systems in Solution Milne, Christopher J.; Van der Veen, Renske M.; Pham, Van-Thai CHIMIA International Journal for Chemistry, Vol. 65, Issue 5 https://doi.org/10.2533/chimia.2011.303	journal	May 2011
Confined Ultrathin Pd-Ce Nanowires with Outstanding Moisture and SO ₂ Tolerance in Methane Combustion Peng, Honggen; Rao, Cheng; Zhang, Ning Angewandte Chemie, Vol. 130, Issue 29 https://doi.org/10.1002/ange.201803393	journal	June 2018
Synthesis of a Highly Stable Pd@CeO ₂ Catalyst for Methane Combustion with the Synergistic Effect of Urea and Citric Acid Cai, Guohui; Luo, Wei; Xiao, Yihong ACS Omega, Vol. 3, Issue 12 https://doi.org/10.1021/acsomega.8b02556	journal	December 2018
Cooperative Catalysis of Methane Oxidation through Modulating the Stabilization of PdO and Electronic Properties over Ti-Doped Alumina-Supported Palladium Catalysts Chen, Benxia; Lin, Jia; Chen, Xiaohua ACS Omega, Vol. 4, Issue 20 https://doi.org/10.1021/acsomega.9b02370	journal	November 2019

Figures / Tables (6)

Similar Records

Uniform Pt/Pd Bimetallic Nanocrystals Demonstrate Platinum Effect on Palladium Methane Combustion Activity and Stability

Journal Article · Thu May 18 00:00:00 EDT 2017 · ACS Catalysis · OSTI ID:1457139

Goodman, Emmett D.; Dai, Sheng; Yang, An-Chih; +8 more

Modular Pd/Zeolite Composites Demonstrating the Key Role of Support Hydrophobic/Hydrophilic Character in Methane Catalytic Combustion

Journal Article · Thu Apr 11 00:00:00 EDT 2019 · ACS Catalysis · OSTI ID:1457139

Losch, Pit; Huang, Weixin; Vozniuk, Olena; +3 more

Dispersion of palladium on alumina surfaces

Journal Article · Sat Oct 15 00:00:00 EDT 1994 · Scripta Metallurgica et Materialia; (United States) · OSTI ID:1457139

McCarty, J G; Chang, Y F

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
36 MATERIALS SCIENCE
in situ XAS
methane complete combustion
nanocrystals
palladium catalysts
structure−property relationships