Single-site trinuclear copper oxygen clusters in mordenite for selective conversion of methane to methanol

Grundner, Sebastian; Markovits, Monica A. C.; Li, Guanna; Tromp, Moniek; Pidko, Evgeny A.; Hensen, Emiel J. M.; Jentys, Andreas; Sanchez-Sanchez, Maricruz; Lercher, Johannes A.

doi:10.1038/ncomms8546

Title: Single-site trinuclear copper oxygen clusters in mordenite for selective conversion of methane to methanol

Journal Article · Thu Jun 25 00:00:00 EDT 2015 · Nature Communications

DOI:https://doi.org/10.1038/ncomms8546· OSTI ID:1454255

Grundner, Sebastian ^[1]; Markovits, Monica A. C. ^[1]; Li, Guanna ^[2]; Tromp, Moniek ^[3]; Pidko, Evgeny A. ^[2]; Hensen, Emiel J. M. ^[2]; Jentys, Andreas ^[1]; Sanchez-Sanchez, Maricruz ^[1]; Lercher, Johannes A. ^[4]

Technische Univ. Munchen, Garching (Germany)
Eindhoven Univ. of Technology, Eindhoven (The Netherlands)
Univ. of Amsterdam, Amsterdam (The Netherlands)
Technische Univ. Munchen, Garching (Germany); Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Copper-exchanged zeolites with mordenite structure mimic the nuclearity and reactivity of active sites in particulate methane monooxygenase, which are enzymes able to selectively oxidize methane to methanol. Here we show that the mordenite micropores provide a perfect confined environment for the highly selective stabilization of trinuclear copper-oxo clusters that exhibit a high reactivity towards activation of carbon–hydrogen bonds in methane and its subsequent transformation to methanol. In conclusion, the similarity with the enzymatic systems is also implied from the similarity of the reversible rearrangements of the trinuclear clusters occurring during the selective transformations of methane along the reaction path towards methanol, in both the enzyme system and copper-exchanged mordenite.

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Research Organization:: Univ. of Minnesota, Minneapolis, MN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012702

OSTI ID:: 1454255

Journal Information:: Nature Communications, Vol. 6, Issue 1; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 540 works

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