skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Ageless Aluminum-Cerium-Based Alloys in High-Volume Die Casting for Improved Energy Efficiency

Journal Article · · JOM. Journal of the Minerals, Metals & Materials Society

Strong chemical reactions between Al and Ce lead to the formation of intermetallics with exceptional thermal stability. The rapid formation of intermetallics directly from the liquid phase during solidification of Al-Ce alloys leads to an ultrafine microconstituent structure that effectively strengthens as-cast alloys without further microstructural optimization via thermal processing. Die casting is a high-volume manufacturing technology that accounts for greater than 40% of all cast Al products, whereas Ce is highly overproduced as a waste product of other rare earth element (REE) mining. Reducing heat treatments would stimulate significant improvements in manufacturing energy efficiency, exceeding (megatonnes/year) per large-scale heat-treatment line. In this study, multiple compositions were evaluated with wedge mold castings to test the sensitivity of alloys to the variable solidification rate inherent in high-pressure die casting. Once a suitable composition was determined, it was successfully demonstrated at 800 lbs/h in a 600-ton die caster, after which the as-die cast parts performed similarly to ubiquitous A380 in the same geometry without requiring heat treatment. Furthermore, this work demonstrates the compatibility of Al REE alloys with high-volume die-casting applications with minimal heat treatments.

Research Organization:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
Grant/Contract Number:
AC05-00OR22725
OSTI ID:
1439950
Journal Information:
JOM. Journal of the Minerals, Metals & Materials Society, Vol. 70, Issue 6; ISSN 1047-4838
Publisher:
SpringerCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 19 works
Citation information provided by
Web of Science

References (17)

High-Pressure Die-Casting: Contradictions and Challenges journal February 2015
Microstructural Evolution and Solidification Behavior of Al-Mg-Si Alloy in High-Pressure Die Casting journal February 2013
Analysis of solidification microstructures during wedge-casting journal August 2006
Influence of Magnesium Alloy Degradation on Undifferentiated Human Cells journal November 2015
Effects of solidification cooling rate on the corrosion resistance of Mg–Zn–Ca alloy journal October 2014
The influence of Cr content on the microstructure and mechanical properties of AlSi9Cu3(Fe) die-casting alloys journal November 2010
Aluminium die casting alloys: alloy composition, microstructure, and properties-performance relationships journal January 1995
Waste Tire Derived Carbon-Polymer Composite Paper as Pseudocapacitive Electrode with Long Cycle Life journal September 2015
Cerium-Based, Intermetallic-Strengthened Aluminum Casting Alloy: High-Volume Co-product Development journal May 2016
Monodispersed Li 4 Ti 5 O 12 with Controlled Morphology as High Power Lithium Ion Battery Anodes journal May 2016
Improving the strength and ductility of magnesium die-casting alloys via rare-earth addition journal November 2003
Highly Robust Lithium Ion Battery Anodes from Lignin: An Abundant, Renewable, and Low-Cost Material journal August 2013
Influence of Injection Parameters on the Porosity and Tensile Properties of High-Pressure Die Cast Al-Si Alloys: A Review journal January 2015
Cradle-to-Gate Impact Assessment of a High-Pressure Die-Casting Safety-Relevant Automotive Component journal August 2016
China’s Rare Earth Supply Chain: Illegal Production, and Response to new Cerium Demand journal March 2016
Thermodynamic modeling of Al–Ce–Mg phase equilibria coupled with key experiments journal May 2002
Evaluation of an Al-Ce alloy for laser additive manufacturing journal March 2017

Similar Records

Enhancements in Magnesium Die Casting Impact Properties
Technical Report · Fri Jun 30 00:00:00 EDT 2000 · OSTI ID:1439950

Effect of as-cast microstructure heterogeneity on aging behavior of a high-pressure die-cast A380 alloy
Journal Article · Mon Jan 15 00:00:00 EST 2018 · Materials Characterization · OSTI ID:1439950

Effect of tool design and pass strategy on defect elimination and uniform, enhanced tensile properties of friction stir processed high-pressure die-cast A380 alloy
Journal Article · Thu Nov 24 00:00:00 EST 2022 · Materials Science and Engineering. A, Structural Materials: Properties, Microstructure and Processing · OSTI ID:1439950

Related Subjects