Structural diversity in NiII cluster chemistry: Ni5, Ni6, and {NiNa2}n complexes bearing the Schiff-base ligand N-naphthalidene-2-amino-5-chlorobenzoic acid

Perlepe, Panagiota S.; Cunha-Silva, Luis; Bekiari, Vlasoula; Gagnon, Kevin J.; Teat, Simon J.; Escuer, A; Stamatatos, Theocharis C.

doi:10.1039/c6dt01162d

Title: Structural diversity in Ni^II cluster chemistry: Ni₅, Ni₆, and {NiNa₂}_n complexes bearing the Schiff-base ligand N-naphthalidene-2-amino-5-chlorobenzoic acid

Journal Article · Mon May 23 00:00:00 EDT 2016 · Dalton Transactions

DOI:https://doi.org/10.1039/c6dt01162d· OSTI ID:1439192

Perlepe, Panagiota S. ^[1]; Cunha-Silva, Luis ^[2]; Bekiari, Vlasoula ^[3]; Gagnon, Kevin J. ^[4]; Teat, Simon J. ^[4]; Escuer, A ^[5]; Stamatatos, Theocharis C. ^[1]

Brock Univ., St. Catharine's, ON (Canada). Dept. of Chemistry
Univ. of Porto (Portugal). REQUIMTE/LAQV, Dept. of Chemistry and Biochemistry and Faculty of Sciences
Technological Educational Inst. of Western Greece (TEIWEST), Messolonghi (Greece). Dept. of Aquaculture and Fisheries Management
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
Univ. of Barcelona (Spain). Dept. of Inorganic Chemistry and Inst. of Nanoscience and Nanotechnology (IN2UB)

The employment of the fluorescent bridging and chelating ligand N-naphthalidene-2-amino-5-chlorobenzoic acid (nacbH₂) in Ni^II cluster chemistry has led to a series of pentanuclear and hexanuclear compounds with different structural motifs, magnetic and optical properties, as well as an interesting 1-D coordination polymer. Synthetic parameters such as the inorganic anion present in the NiX₂ starting materials (X = ClO₄^- or Cl^-), the reaction solvent and the nature of the organic base employed for the deprotonation of nacbH₂ were also proved to be structure-directing components. Undoubtedly, the reported results demonstrate the rich coordination chemistry of nacbH₂ in the presence of Ni^II metal ions and the ability of this chelate to adopt a variety of different modes, thus fostering the formation of high-nuclearity molecules with many physical properties.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); Brock Univ., St. Catharine's, ON (Canada); Natural Sciences and Engineering Research Council of Canada (NSERC); European Research Area (ERA); Alexander S. Onassis Public Benefit Foundation; Foundation for Science and Technology (FCT) (Portugal); European Union (EU)

Grant/Contract Number:: AC02-05CH11231; UID/QUI/50006/2013; CTQ2015-63614-P

OSTI ID:: 1439192

Journal Information:: Dalton Transactions, Vol. 45, Issue 25; Related Information: © The Royal Society of Chemistry 2016.; ISSN 1477-9226

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 14 works

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Synthesis, structure, and spectroscopic properties of copper( II ) compounds containing nitrogen–sulphur donor ligands; the crystal and molecular structure of aqua[1,7-bis(N-methylbenzimidazol-2′-yl)-2,6-dithiaheptane]copper( II ) perchlorate Addison, Anthony W.; Rao, T. Nageswara; Reedijk, Jan J. Chem. Soc., Dalton Trans., Issue 7 https://doi.org/10.1039/DT9840001349	journal	January 1984
A semi-flexible aminotriazine-based bis-methylpyridine ligand for the design of nickel( ii ) spin clusters Tzeng, Yen-Wen; Lin, Chang-Jui; Nakano, Motohiro Dalton Trans., Vol. 43, Issue 8 https://doi.org/10.1039/C3DT52903G	journal	January 2014
Lanthanide-Based Luminescent Hybrid Materials Binnemans, Koen Chemical Reviews, Vol. 109, Issue 9 https://doi.org/10.1021/cr8003983	journal	September 2009
A short history of SHELX Sheldrick, George M. Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122 https://doi.org/10.1107/S0108767307043930	journal	December 2007
Syntheses, Characterization, and Magneto-Structural Analyses in μ _1,3 -Acetato-Bridged Tetracopper(II) and μ _1,3 - and μ _1,1,3 -Acetato-Bridged Pentanickel(II) Clusters : Acetato-Bridged Tetracopper(II) and Pentanickel(II) Clusters Das, Sudhanshu; Sorace, Lorenzo; Guha, Averi European Journal of Inorganic Chemistry, Vol. 2014, Issue 17 https://doi.org/10.1002/ejic.201301581	journal	May 2014
Triangular Nickel Complexes Derived from 2-Pyridylcyanoxime: An Approach to the Magnetic Properties of the [Ni3(μ3-OH){pyC(R)NO}3]2+ Core Esteban, Jordi; Ruiz, Eliseo; Font-Bardia, Mercé Chemistry - A European Journal, Vol. 18, Issue 12 https://doi.org/10.1002/chem.201102987	journal	February 2012
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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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CCDC 1448720: Experimental Crystal Structure Determination: ENOWEL : tetrakis(μ-5-chloro-2-(((2-oxido-1-naphthyl)methylene)amino)benzoato)-bis(μ-methoxo)-tris(methanol)-penta-nickel methanol hexane solvate Perlepe, Panagiota; Cunha-Silva, Luís; Bekiari, Vlasoula https://doi.org/10.5517/ccdc.csd.cc1kmhxl The current record is supplemented by this dataset	dataset	May 2016
CCDC 1448721: Experimental Crystal Structure Determination: ENOWAH : tetrakis(μ-5-chloro-2-(((2-oxido-1-naphthyl)methylene)amino)benzoato)-bis(μ-hydroxo)-tetrakis(N,N-dimethylformamide)-penta-nickel N,N-dimethylformamide solvate Space Group: P 1 (2), Cell: a 14.1417(10)Å b 14.1587(10)Å c 14.7117(11)Å, α 92.408(2)° β 99.389(2)° γ 116.998(2)° Perlepe, Panagiota S.; Cunha-Silva, Luis; Bekiari, Vlasoula https://doi.org/10.5517/ccdc.csd.cc1kmhym The current record is supplemented by this dataset	dataset	May 2016
CCDC 1448722: Experimental Crystal Structure Determination: ENOWIP : tetrakis(μ-5-chloro-2-(((2-oxido-1-naphthyl)methylene)amino)benzoato)-(μ-methoxo)-(μ-chloro)-tris(methanol)-(acetonitrile)-penta-nickel acetonitrile methanol diethyl ether solvate Perlepe, Panagiota; Cunha-Silva, Luís; Bekiari, Vlasoula https://doi.org/10.5517/ccdc.csd.cc1kmhzn The current record is supplemented by this dataset	dataset	May 2016
CCDC 1448723: Experimental Crystal Structure Determination: ENOWOV : bis(triethylammonium) tetrakis(μ-5-chloro-2-(((2-oxido-1-naphthyl)methylene)amino)benzoato)-bis(μ-hydroxo)-bis(5-chloro-2-(((2-oxido-1-naphthyl)methylene)amino)benzoato)-tetra-aqua-hexa-nickel dichloromethane solvate Space Group: P 21/n (14), Cell: a 14.7531(12)Å b 18.2554(16)Å c 26.332(2)Å, α 90° β 99.008(4)° γ 90° Perlepe, Panagiota S.; Cunha-Silva, Luis; Bekiari, Vlasoula https://doi.org/10.5517/ccdc.csd.cc1kmj0q The current record is supplemented by this dataset	dataset	May 2016
CCDC 1448725: Experimental Crystal Structure Determination: ENOYUD : hexakis(μ-5-chloro-2-(((2-oxy-1-naphthyl)methylene)amino)benzoato)-tris(μ-aqua)-hexakis(methanol)-hexa-nickel dichloromethane unknown solvate hydrate Perlepe, Panagiota; Cunha-Silva, Luís; Bekiari, Vlasoula https://doi.org/10.5517/ccdc.csd.cc1kmj2s The current record is supplemented by this dataset	dataset	January 2016
CCDC 1448724: Experimental Crystal Structure Determination: ENOYOX : catena-[((μ-5-chloro-2-(((2-oxy-1-naphthyl)methylene)amino)benzoato)-bis(methanol)-diaqua-di-sodium-nickel) ((μ-5-chloro-2-(((2-oxy-1-naphthyl)methylene)amino)benzoato)-bis(methanol)-di-sodium-nickel) dihydrate] Space Group: P 1 (2), Cell: a 7.5505(16)Å b 18.877(4)Å c 26.086(6)Å, α 79.415(11)° β 86.090(10)° γ 89.411(10)° Perlepe, Panagiota S.; Cunha-Silva, Luís; Bekiari, Vlasoula https://doi.org/10.5517/ccdc.csd.cc1kmj1r The current record is supplemented by this dataset	dataset	January 2016

Title: Structural diversity in NiII cluster chemistry: Ni5, Ni6, and {NiNa2}n complexes bearing the Schiff-base ligand N-naphthalidene-2-amino-5-chlorobenzoic acid

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