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Title: Synchrotron X-ray Analytical Techniques for Studying Materials Electrochemistry in Rechargeable Batteries

Journal Article · · Chemical Reviews
ORCiD logo [1]; ORCiD logo [2];  [3];  [4];  [5];  [5];  [6];  [7];  [4];  [8];  [9]; ORCiD logo [10];  [2];  [7];  [4]
  1. Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States). Dept. of Chemistry
  2. SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Synchrotron Radiation Lightsource (SSRL)
  3. Brookhaven National Lab. (BNL), Upton, NY (United States). Dept. of Chemistry; Chinese Academy of Sciences (CAS), Beijing (China). Inst. of Physics. Beijing National Lab. for Condensed Matter Physics (BNLCP-CAS)
  4. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Energy Storage and Distributed Resources Division
  5. Univ. of California, San Diego, CA (United States). Dept. of Physics
  6. Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)
  7. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
  8. Center for High Pressure Science & Technology Advanced Research, Shanghai (China)
  9. Brookhaven National Lab. (BNL), Upton, NY (United States). Dept. of Chemistry
  10. Univ. of California, San Diego, CA (United States). Dept. of NanoEngineering
+ Show Author Affiliations

Research Organization:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Brookhaven National Laboratory (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II); SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE Office of Science (SC), Basic Energy Sciences (BES); Chinese Academy of Sciences (CAS); USDOE Office of Energy Efficiency and Renewable Energy (EERE)
Grant/Contract Number:
AC02-05CH11231; SC0012704; SC0001805; AC02-76SF00515; 2016YFA0202500
OSTI ID:
1437973
Alternate ID(s):
OSTI ID: 1377367; OSTI ID: 1474323
Report Number(s):
BNL-114217-2017-JA; ark:/13030/qt6px3m7ks
Journal Information:
Chemical Reviews, Vol. 117, Issue 21; Related Information: © 2017 American Chemical Society.; ISSN 0009-2665
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 323 works
Citation information provided by
Web of Science

References (425)

Rapidly falling costs of battery packs for electric vehicles journal March 2015
EXAFS: A new tool for the study of battery and fuel cell materials journal March 1988
X-ray absorption studies on organo-disulfide redox cathodes journal January 1992
X-ray-absorption studies of organodisulfide redox polymeric electrodes journal March 1992
Xas Studies of Peo Based Polymer Electrolytes journal January 1994
Synchrotron x‐ray diffraction studies of the structural properties of electrode materials in operating battery cells journal July 1996
In situ synchrotron x-ray studies of battery and fuel cell materials journal May 1998
Structural Evolution of Li[sub x]Mn[sub 2]O[sub 4] in Lithium-Ion Battery Cells Measured In Situ Using Synchrotron X-Ray Diffraction Techniques journal January 1998
New findings on the phase transitions in Li1−xNiO2: in situ synchrotron X-ray diffraction studies journal June 1999
A review on the separators of liquid electrolyte Li-ion batteries journal January 2007
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries journal October 2004
A review on electrolyte additives for lithium-ion batteries journal November 2006
A General Discussion of Li Ion Battery Safety journal January 2012
Silicon/Graphite Composite Electrodes for High-Capacity Anodes: Influence of Binder Chemistry on Cycling Stability journal January 2008
Quantifying microstructural dynamics and electrochemical activity of graphite and silicon-graphite lithium ion battery anodes journal September 2016
LixCoO2 (0<x<-1): A new cathode material for batteries of high energy density journal June 1980
Future generations of cathode materials: an automotive industry perspective journal January 2015
Diffraction-limited storage rings – a window to the science of tomorrow journal August 2014
Alloy Design for Lithium-Ion Battery Anodes journal January 2007
Li-alloy based anode materials for Li secondary batteries journal January 2010
Alloy Negative Electrodes for Li-Ion Batteries journal October 2014
Si Electrodes for Li-Ion Batteries—A New Way to Look at an Old Problem journal January 2008
Nanostructured silicon for high capacity lithium battery anodes journal January 2011
Silicon-Based Nanomaterials for Lithium-Ion Batteries: A Review journal October 2013
Review—Nano-Silicon/Carbon Composite Anode Materials Towards Practical Application for Next Generation Li-Ion Batteries journal January 2015
Critical roles of binders and formulation at multiscales of silicon-based composite electrodes journal April 2015
Studies of tin–transition metal–carbon and tin–cobalt–transition metal–carbon negative electrode materials prepared by mechanical attrition journal December 2009
Materials Challenges Facing Electrical Energy Storage journal April 2008
Beyond Intercalation-Based Li-Ion Batteries: The State of the Art and Challenges of Electrode Materials Reacting Through Conversion Reactions journal August 2010
Review—Advances in Anode and Electrolyte Materials for the Progress of Lithium-Ion and beyond Lithium-Ion Batteries journal January 2015
Li-Storage via Heterogeneous Reaction in Selected Binary Metal Fluorides and Oxides journal January 2004
A review of Ni-based layered oxides for rechargeable Li-ion batteries journal January 2017
Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries journal March 2014
Nickel-Rich Layered Lithium Transition-Metal Oxide for High-Energy Lithium-Ion Batteries journal March 2015
Layered Cathode Materials Li[Ni[sub x]Li[sub (1/3−2x/3)]Mn[sub (2/3−x/3)]]O[sub 2] for Lithium-Ion Batteries journal January 2001
High-capacity lithium insertion materials of lithium nickel manganese oxides for advanced lithium-ion batteries: toward rechargeable capacity more than 300 mA h g−1 journal January 2011
Understanding the Rate Capability of High-Energy-Density Li-Rich Layered Li 1.2 Ni 0.15 Co 0.1 Mn 0.55 O 2 Cathode Materials journal December 2013
6Li MAS NMR and in situ X-ray studies of lithium nickel manganese oxides journal June 2003
Long-Range and Local Structure in the Layered Oxide Li 1.2 Co 0.4 Mn 0.4 O 2 journal April 2011
Unravelling structural ambiguities in lithium- and manganese-rich transition metal oxides journal October 2015
Review of the U.S. Department of Energy’s “Deep Dive” Effort to Understand Voltage Fade in Li- and Mn-Rich Cathodes journal October 2015
Anionic redox processes for electrochemical devices journal January 2016
Calibrating transition-metal energy levels and oxygen bands in first-principles calculations: Accurate prediction of redox potentials and charge transfer in lithium transition-metal oxides journal September 2015
Reversible anionic redox chemistry in high-capacity layered-oxide electrodes journal July 2013
Visualization of O-O peroxo-like dimers in high-capacity layered oxides for Li-ion batteries journal December 2015
High-capacity electrode materials for rechargeable lithium batteries: Li 3 NbO 4 -based system with cation-disordered rocksalt structure journal June 2015
The rechargeable revolution: A better battery journal March 2014
The energy-storage frontier: Lithium-ion batteries and beyond journal November 2015
Quantifying the promise of ‘beyond’ Li–ion batteries journal November 2015
Review—Practical Challenges Hindering the Development of Solid State Li Ion Batteries journal January 2017
Lithium-Sulfur Cells: The Gap between the State-of-the-Art and the Requirements for High Energy Battery Cells journal April 2015
Lithium−Air Battery: Promise and Challenges journal June 2010
A Critical Review of Li∕Air Batteries journal January 2012
Review on Li–air batteries—Opportunities, limitations and perspective journal February 2011
Quantifying the promise of lithium–air batteries for electric vehicles journal January 2014
Cycling Li-O2 batteries via LiOH formation and decomposition journal October 2015
A lithium–oxygen battery based on lithium superoxide journal January 2016
A rechargeable room-temperature sodium superoxide (NaO2) battery journal December 2012
A thin-film solid-state microbattery journal April 1993
Thin-film lithium and lithium-ion batteries journal November 2000
Inorganic solid Li ion conductors: An overview journal June 2009
Recent Advances in Inorganic Solid Electrolytes for Lithium Batteries journal June 2014
Highly Conductive and Thermally Stable Ion Gels with Tunable Anisotropy and Modulus journal January 2016
Sodium-Ion Batteries journal May 2012
Update on Na-based battery materials. A growing research path journal January 2013
Prototype systems for rechargeable magnesium batteries journal October 2000
Quest for Nonaqueous Multivalent Secondary Batteries: Magnesium and Beyond journal October 2014
Towards a calcium-based rechargeable battery journal October 2015
Rechargeable Ca-Ion Batteries: A New Energy Storage System journal December 2015
Capturing metastable structures during high-rate cycling of LiFePO4 nanoparticle electrodes journal June 2014
Topological defect dynamics in operando battery nanoparticles journal June 2015
Structural Dynamics of the Electrical Double Layer during Capacitive Charging/Discharging Processes journal September 2014
The effect of particle surface facets on the kinetic properties of LiMn 1.5 Ni 0.5 O 4 cathode materials journal January 2013
Intercalation compounds of graphite journal January 2002
The Formation Mechanism of Fluorescent Metal Complexes at the Li x Ni 0.5 Mn 1.5 O 4−δ /Carbonate Ester Electrolyte Interface journal March 2015
Infrared Chemical Nano-Imaging: Accessing Structure, Coupling, and Dynamics on Molecular Length Scales journal March 2015
Side-Chain Conducting and Phase-Separated Polymeric Binders for High-Performance Silicon Anodes in Lithium-Ion Batteries journal February 2015
Recent Progress on Synchrotron-Based In-Situ Soft X-ray Spectroscopy for Energy Materials journal May 2014
Phase Transformation and Lithiation Effect on Electronic Structure of Li x FePO 4 : An In-Depth Study by Soft X-ray and Simulations journal August 2012
A high resolution and large solid angle x-ray Raman spectroscopy end-station at the Stanford Synchrotron Radiation Lightsource journal April 2012
Hard X-rays in–soft X-rays out: An operando piggyback view deep into a charging lithium ion battery with X-ray Raman spectroscopy journal April 2015
Profiling the nanoscale gradient in stoichiometric layered cathode particles for lithium-ion batteries journal January 2014
Investigation of the Charge Compensation Mechanism on the Electrochemically Li-Ion Deintercalated Li 1 - x Co 1/3 Ni 1/3 Mn 1/3 O 2 Electrode System by Combination of Soft and Hard X-ray Absorption Spectroscopy journal December 2005
Phase evolution for conversion reaction electrodes in lithium-ion batteries journal February 2014
Rate-Dependent, Li-Ion Insertion/Deinsertion Behavior of LiFePO 4 Cathodes in Commercial 18650 LiFePO 4 Cells journal February 2014
High-energy X-ray powder diffraction and atomic-pair distribution-function studies of charged/discharged structures in carbon-hybridized Li2MnSiO4 nanoparticles as a cathode material for lithium-ion batteries journal October 2014
In situ high-energy X-ray diffraction to study overcharge abuse of 18650-size lithium-ion battery journal May 2013
Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques journal January 2013
New phases and phase transitions observed in Li1−xCoO2 during charge: in situ synchrotron X-ray diffraction studies journal February 2000
In Situ Investigation of Phase Transitions of Li[sub 1+y]Mn[sub 2]O[sub 4] Spinel during Li-Ion Extraction and Insertion journal January 2002
A Swagelok-type in situ cell for battery investigations using synchrotron radiation journal September 2005
Design and performance of an electrochemical in-situ cell for high resolution full-pattern X-ray powder diffraction journal May 2005
Study on dynamics of structural transformation during charge/discharge of LiFePO4 cathode journal February 2008
Overpotential-Dependent Phase Transformation Pathways in Lithium Iron Phosphate Battery Electrodes journal November 2010
Dynamic Structural Changes at LiMn 2 O 4 /Electrolyte Interface during Lithium Battery Reaction journal November 2010
An Electrochemical Cell for Operando Study of Lithium Batteries Using Synchrotron Radiation journal January 2010
Investigation of the structural changes in Li1−xFePO4 upon charging by synchrotron radiation techniques journal January 2011
Identifying surface structural changes in layered Li-excess nickel manganese oxides in high voltage lithium ion batteries: A joint experimental and theoretical study journal January 2011
Why Substitution Enhances the Reactivity of LiFePO 4 journal December 2012
Interplay between two-phase and solid solution reactions in high voltage spinel cathode material for lithium ion batteries journal November 2013
Layered Molybdenum (Oxy)Pyrophosphate as Cathode for Lithium-Ion Batteries journal August 2013
A long-life lithium-ion battery with a highly porous TiNb 2 O 7 anode for large-scale electrical energy storage journal January 2014
Direct Observation of Active Material Concentration Gradients and Crystallinity Breakdown in LiFePO 4 Electrodes During Charge/Discharge Cycling of Lithium Batteries journal March 2014
Understanding Inhomogeneous Reactions in Li-Ion Batteries: Operando Synchrotron X-Ray Diffraction on Two-Layer Electrodes journal May 2015
Direct view on the phase evolution in individual LiFePO4 nanoparticles during Li-ion battery cycling journal September 2015
Structural Underpinnings of the Enhanced Cycling Stability upon Al-Substitution in LiNi 0.45 Mn 0.45 Co 0.1– y Al y O 2 Positive Electrode Materials for Li-ion Batteries journal August 2012
In operando X-ray studies of the conversion reaction in Mn 3 O 4 lithium battery anodes journal January 2013
Comprehensive Study of the CuF 2 Conversion Reaction Mechanism in a Lithium Ion Battery journal July 2014
Study of the Conversion Reaction Mechanism for Copper Borate as Electrode Material in Lithium-Ion Batteries journal January 2011
CoSn5 Phase: Crystal Structure Resolving and Stable High Capacity as Anodes for Li Ion Batteries journal May 2012
In Situ X-ray Diffraction Studies of (De)lithiation Mechanism in Silicon Nanowire Anodes journal May 2012
Electrochemical Reaction of Lithium with Nanostructured Silicon Anodes: A Study by In-Situ Synchrotron X-Ray Diffraction and Electron Energy-Loss Spectroscopy journal August 2013
Better Cycling Performances of Bulk Sb in Na-Ion Batteries Compared to Li-Ion Systems: An Unexpected Electrochemical Mechanism journal December 2012
(De)Lithiation Mechanism of Li/SeS x ( x = 0–7) Batteries Determined by in Situ Synchrotron X-ray Diffraction and X-ray Absorption Spectroscopy journal May 2013
Phospho-olivines as Positive-Electrode Materials for Rechargeable Lithium Batteries journal April 1997
Lithium extraction/insertion in LiFePO4: an X-ray diffraction and Mössbauer spectroscopy study journal May 2000
Lithium deintercalation in LiFePO4 nanoparticles via a domino-cascade model journal July 2008
The thermodynamic origin of hysteresis in insertion batteries journal April 2010
Current-induced transition from particle-by-particle to concurrent intercalation in phase-separating battery electrodes journal September 2014
Confirmation of the Domino-Cascade Model by LiFePO 4 /FePO 4 Precession Electron Diffraction journal October 2011
Kinetics of non-equilibrium lithium incorporation in LiFePO4 journal July 2011
Direct Observation of a Metastable Crystal Phase of Li x FePO 4 under Electrochemical Phase Transition journal April 2013
Focusing of hard x-rays to 16 nanometers with a multilayer Laue lens journal June 2008
Single-nanometer focusing of hard x-rays by Kirkpatrick–Baez mirrors journal September 2011
New avenues in x-ray microbeam experiments journal February 2000
A hard x-ray scanning microprobe for fluorescence imaging and microdiffraction at the advanced photon source conference January 2000
Polychromatic X-ray microdiffraction studies of mesoscale structure and dynamics journal February 2005
A new white beam x-ray microdiffraction setup on the BM32 beamline at the European Synchrotron Radiation Facility journal March 2011
A superbend X-ray microdiffraction beamline at the advanced light source journal October 2009
Plastic deformation in Al (Cu) interconnects stressed by electromigration and studied by synchrotron polychromatic x-ray microdiffraction journal July 2008
Residual stress preserved in quartz from the San Andreas Fault Observatory at Depth journal February 2015
Role of joule heating effect and bulk-surface phases in voltage-driven metal-insulator transition in VO 2 crystal journal August 2013
Scanning X-ray Fluorescence Imaging Study of Lithium Insertion into Copper Based Oxysulfides for Li-Ion Batteries journal July 2012
Visualization of Charge Distribution in a Lithium Battery Electrode journal June 2010
Fast Lithium Ion Conduction in Garnet-Type Li7La3Zr2O12 journal October 2007
Novel Fast Lithium Ion Conduction in Garnet-Type Li 5 La 3 M 2 O 12 (M = Nb, Ta) journal March 2003
Li6ALa2Ta2O12 (A = Sr, Ba): Novel Garnet-Like Oxides for Fast Lithium Ion Conduction journal January 2005
Li6ALa2Nb2O12 (A=Ca, Sr, Ba): A New Class of Fast Lithium Ion Conductors with Garnet-Like Structure journal February 2005
Crystal Structure Revision and Identification of Li + -Ion Migration Pathways in the Garnet-like Li 5 La 3 M 2 O 12 (M = Nb, Ta) Oxides journal August 2004
Grain Boundaries in a Lithium Aluminum Titanium Phosphate-Type Fast Lithium Ion Conducting Glass Ceramic: Microstructure and Nonlinear Ion Transport Properties journal October 2012
Atomic-scale origin of the large grain-boundary resistance in perovskite Li-ion-conducting solid electrolytes journal January 2014
A dedicated superbend x-ray microdiffraction beamline for materials, geo-, and environmental sciences at the advanced light source journal March 2009
Effect of Surface Microstructure on Electrochemical Performance of Garnet Solid Electrolytes journal January 2015
Effects of crystallinity and impurities on the electrical conductivity of Li–La–Zr–O thin films journal February 2015
Energy dispersive X-ray diffraction of lithium–silver vanadium phosphorous oxide cells: in situ cathode depth profiling of an electrochemical reduction–displacement reaction journal January 2013
Electrochemical reduction of Ag 2 VP 2 O 8 composite electrodes visualized via in situ energy dispersive X-ray diffraction (EDXRD): unexpected conductive additive effects journal January 2015
In situ visualization of Li/Ag2VP2O8 batteries revealing rate-dependent discharge mechanism journal January 2015
Energy Dispersive X-ray Diffraction Profiling of Prototype LiMn 2 O 4 -Based Coin Cells journal January 2013
Tracking inhomogeneity in high-capacity lithium iron phosphate batteries journal February 2015
Spectroscopic X-ray Diffraction for Microfocus Inspection of Li-Ion Batteries journal August 2014
Factors determining the packing-limitation of active materials in the composite electrode of lithium-ion batteries journal January 2016
Quantitative Analysis of Transition-Metal Migration Induced Electrochemically in Lithium-Rich Layered Oxide Cathode and Its Contribution to Properties at High and Low Temperatures journal November 2016
A new in situ synchrotron X-ray diffraction technique to study the chemical delithiation of LiFePO4 journal January 2011
In Situ Studies of Solvothermal Synthesis of Energy Materials journal March 2014
In Situ Hydrothermal Synthesis of LiFePO 4 Studied by Synchrotron X-ray Diffraction journal July 2011
Solvothermal Synthesis of LiMn 1– x Fe x PO 4 Cathode Materials: A Study of Reaction Mechanisms by Time-Resolved in Situ Synchrotron X-ray Diffraction journal January 2015
Time-Resolved XRD Study on the Thermal Decomposition of Li[sub 1−x]Ni[sub 0.8]Co[sub 0.15]Al[sub 0.05]O[sub 2] Cathode Materials for Li-Ion Batteries journal January 2005
Thermal Stability of Lithium Nickel Oxide Derivatives. Part I: Li x Ni 1.02 O 2 and Li x Ni 0.89 Al 0.16 O 2 ( x = 0.50 and 0.30) journal November 2003
Thermal Stability of Lithium Nickel Oxide Derivatives. Part II:  Li x Ni 0.70 Co 0.15 Al 0.15 O 2 and Li x Ni 0.90 Mn 0.10 O 2 ( x = 0.50 and 0.30). Comparison with Li x Ni 1.02 O 2 and Li x Ni 0.89 Al 0.16 O 2 journal November 2003
Thermal Instability of Cycled Li x Ni 0.5 Mn 0.5 O 2 Electrodes: An in Situ Synchrotron X-ray Powder Diffraction Study journal August 2008
Multi-scale study of thermal stability of lithiated graphite journal January 2011
Mesoscale Phase Distribution in Single Particles of LiFePO 4 following Lithium Deintercalation journal April 2013
Probing Thermally Induced Decomposition of Delithiated Li 1.2– x Ni 0.15 Mn 0.55 Co 0.1 O 2 by in Situ High-Energy X-ray Diffraction journal July 2014
An in-situ, high-energy X-ray diffraction study of the thermal stability of delithiated LiVPO4F journal January 2015
Surface Modification of Li-Excess Mn-based Cathode Materials journal January 2010
Combining In Situ Synchrotron X-Ray Diffraction and Absorption Techniques with Transmission Electron Microscopy to Study the Origin of Thermal Instability in Overcharged Cathode Materials for Lithium-Ion Batteries journal June 2012
Structural Changes and Thermal Stability of Charged LiNi x Mn y Co z O 2 Cathode Materials Studied by Combined In Situ Time-Resolved XRD and Mass Spectroscopy journal December 2014
Oxygen-Release-Related Thermal Stability and Decomposition Pathways of Li x Ni 0.5 Mn 1.5 O 4 Cathode Materials journal December 2013
Correlating Structural Changes and Gas Evolution during the Thermal Decomposition of Charged Li x Ni 0.8 Co 0.15 Al 0.05 O 2 Cathode Materials journal January 2013
Comparison of the structural and electrochemical properties of layered Li[NixCoyMnz]O2 (x = 1/3, 0.5, 0.6, 0.7, 0.8 and 0.85) cathode material for lithium-ion batteries journal July 2013
Experimental visualization of lithium conduction pathways in garnet-type Li7La3Zr2O12 journal January 2012
Structural and Electrochemical Consequences of Al and Ga Cosubstitution in Li 7 La 3 Zr 2 O 12 Solid Electrolytes journal March 2016
In-situ neutron diffraction study of the xLi2MnO3·(1 − x)LiMO2 (x = 0, 0.5; M = Ni, Mn, Co) layered oxide compounds during electrochemical cycling journal October 2013
Real-time observations of lithium battery reactions—operando neutron diffraction analysis during practical operation journal June 2016
New in-situ neutron diffraction cell for electrode materials journal February 2014
“In-operando” neutron scattering studies on Li-ion batteries journal April 2012
Structural changes in a commercial lithium-ion battery during electrochemical cycling: An in situ neutron diffraction study journal December 2010
In Situ Neutron Diffraction Monitoring of Li 7 La 3 Zr 2 O 12 Formation: Toward a Rational Synthesis of Garnet Solid Electrolytes. journal April 2015
X-ray scattering characterisation of nanoparticles journal June 2015
Methods and Protocols for Electrochemical Energy Storage Materials Research journal November 2016
Quantitative nanostructure characterization using atomic pair distribution functions obtained from laboratory electron microscopes journal May 2012
One hundred years of diffuse scattering journal July 2015
Structure of V 2 O 5 · n H 2 O Xerogel Solved by the Atomic Pair Distribution Function Technique journal August 2002
Short- and Long-Range Order in the Positive Electrode Material, Li(NiMn) 0.5 O 2 :  A Joint X-ray and Neutron Diffraction, Pair Distribution Function Analysis and NMR Study journal May 2005
Origin of additional capacities in metal oxide lithium-ion battery electrodes journal November 2013
Emerging operando and x-ray pair distribution function methods for energy materials development journal March 2016
Comprehensive Insights into the Structural and Chemical Changes in Mixed-Anion FeOF Electrodes by Using Operando PDF and NMR Spectroscopy
  • Wiaderek, Kamila M.; Borkiewicz, Olaf J.; Castillo-Martínez, Elizabeth
  • Journal of the American Chemical Society, Vol. 135, Issue 10 https://doi.org/10.1021/ja400229v
journal March 2013
Structure of nanocrystalline materials using atomic pair distribution function analysis: Study of LiMoS 2 journal February 2002
Investigating Sodium Storage Mechanisms in Tin Anodes: A Combined Pair Distribution Function Analysis, Density Functional Theory, and Solid-State NMR Approach journal May 2017
Accommodating High Transformation Strains in Battery Electrodes via the Formation of Nanoscale Intermediate Phases: Operando Investigation of Olivine NaFePO 4 journal February 2017
Introduction to XAFS book January 2010
Extended x-ray absorption fine structure—its strengths and limitations as a structural tool journal October 1981
Theoretical approaches to x-ray absorption fine structure journal July 2000
A Review on the Structural Studies of Batteries and Host Materials by X-Ray Absorption Spectroscopy journal January 2013
In situ methods for Li-ion battery research: A review of recent developments journal August 2015
The 1s x-ray absorption pre-edge structures in transition metal oxides journal February 2009
EXAFS spectroelectrochemistry journal July 1990
In situ chemical mapping of a lithium-ion battery using full-field hard X-ray spectroscopic imaging journal January 2013
Direct Observation of the Redistribution of Sulfur and Polysufides in Li-S Batteries During the First Cycle by In Situ X-Ray Fluorescence Microscopy journal March 2015
Probing Reversible Multielectron Transfer and Structure Evolution of Li 1.2 Cr 0.4 Mn 0.4 O 2 Cathode Material for Li-Ion Batteries in a Voltage Range of 1.0–4.8 V journal July 2015
In situ x-ray absorption spectroscopic study of the Li[Ni1∕3Co1∕3Mn1∕3]O2 cathode material journal June 2005
In-Situ X-ray Absorption Spectroscopic Study on Variation of Electronic Transitions and Local Structure of LiNi 1/3 Co 1/3 Mn 1/3 O 2 Cathode Material during Electrochemical Cycling journal June 2005
In situ X-ray absorption spectroscopic study of Li-rich layered cathode material Li[Ni0.17Li0.2Co0.07Mn0.56]O2 journal August 2011
Mechanistic studies on lithium intercalation in a lithium-rich layered material using Li 2 RuO 3 epitaxial film electrodes and in situ surface X-ray analysis journal January 2014
Structural and Electrochemical Investigation of Li(Ni[sub 0.4]Co[sub 0.15]Al[sub 0.05]Mn[sub 0.4])O[sub 2] Cathode Material journal January 2010
Valence change by in situ XAS in surface modified LiMn2O4 for Li-ion battery journal November 2006
Phase transition kinetics of LiNi0.5Mn1.5O4 electrodes studied by in situ X-ray absorption near-edge structure and X-ray diffraction analysis journal January 2013
Utilizing Environmental Friendly Iron as a Substitution Element in Spinel Structured Cathode Materials for Safer High Energy Lithium-Ion Batteries journal December 2015
Synchrotron X-Ray Absorption Study of LiFePO[sub 4] Electrodes journal January 2005
Characterization of Sol−Gel-Synthesized LiFePO 4 by Multiple Scattering XAFS journal March 2006
Understanding the High Capacity of Li 2 FeSiO 4 : In Situ XRD/XANES Study Combined with First-Principles Calculations journal May 2013
High rate delithiation behaviour of LiFePO4 studied by quick X-ray absorption spectroscopy journal January 2012
Investigation on porous MnO microsphere anode for lithium ion batteries journal August 2011
Reaction Mechanism of Tin Phosphide Anode by Mechanochemical Method for Lithium Secondary Batteries journal January 2004
An understanding of anomalous capacity of nano-sized CoO anode materials for advanced Li-ion battery journal March 2010
Remarkably Improved Electrode Performance of Bulk MnS by Forming a Solid Solution with FeS - Understanding the Li Storage Mechanism journal July 2014
What Happens Structurally and Electronically during the Li Conversion Reaction of CoFe 2 O 4 Nanoparticles: An Operando XAS and XRD Investigation journal January 2016
At the Heart of a Conversion Reaction: An Operando X-ray Absorption Spectroscopy Investigation of NiSb 2 , a Negative Electrode Material for Li-Ion Batteries journal November 2014
Electrochemical properties of nano-sized Li4Ti5O12 powders synthesized by a sol–gel process and characterized by X-ray absorption spectroscopy journal August 2005
New Insights on the Reversible Lithiation Mechanism of TiO 2 (B) by Operando X-ray Absorption Spectroscopy and X-ray Diffraction Assisted by First-Principles Calculations journal November 2014
Conversion Reaction Mechanisms in Lithium Ion Batteries: Study of the Binary Metal Fluoride Electrodes journal November 2011
Electronic Structure of the Electrochemically Delithiated Li[sub 1−x]FePO[sub 4] Electrodes Investigated by P K-edge X-Ray Absorption Spectroscopy journal January 2006
In Situ X-ray Absorption Spectroscopic Study on LiNi 0.5 Mn 0.5 O 2 Cathode Material during Electrochemical Cycling journal August 2003
Oxygen and transition metal involvement in the charge compensation mechanism of LiNi1/3Mn1/3Co1/3O2 cathodes journal January 2012
New Technique for Investigating Noncrystalline Structures: Fourier Analysis of the Extended X-Ray—Absorption Fine Structure journal November 1971
Kinetics of Phase Change. I General Theory journal December 1939
Li Conductivity in Li[sub x]MPO[sub 4] (M = Mn, Fe, Co, Ni) Olivine Materials journal January 2004
Atomic-Scale Investigation of Defects, Dopants, and Lithium Transport in the LiFePO 4 Olivine-Type Battery Material journal October 2005
Electron Microscopy Study of the LiFePO[sub 4] to FePO[sub 4] Phase Transition journal January 2006
Phase Transition Analysis between LiFePO 4 and FePO 4 by In-Situ Time-Resolved X-ray Absorption and X-ray Diffraction journal January 2013
First In Situ Observation of the LiCoO 2 Electrode/Electrolyte Interface by Total-Reflection X-ray Absorption Spectroscopy journal October 2012
Improved Cyclic Performance of Lithium-Ion Batteries: An Investigation of Cathode/Electrolyte Interface via In Situ Total-Reflection Fluorescence X-ray Absorption Spectroscopy journal April 2014
Core Level Spectroscopy of Solids book January 2008
Key electronic states in lithium battery materials probed by soft X-ray spectroscopy journal October 2013
Distinct Solid-Electrolyte-Interphases on Sn (100) and (001) Electrodes Studied by Soft X-Ray Spectroscopy journal February 2014
Soft x-ray spectroscopy for probing electronic and chemical states of battery materials journal January 2016
Determination of absorption coefficients for concentrated samples by fluorescence detection journal June 1993
Determination of total x-ray absorption coefficient using non-resonant x-ray emission journal December 2011
Modular soft x-ray spectrometer for applications in energy sciences and quantum materials journal January 2017
High-efficiency in situ resonant inelastic x-ray scattering (iRIXS) endstation at the Advanced Light Source journal March 2017
Resonant inelastic x-ray scattering studies of elementary excitations journal June 2011
Polymers with Tailored Electronic Structure for High Capacity Lithium Battery Electrodes journal September 2011
Toward an Ideal Polymer Binder Design for High-Capacity Battery Anodes journal July 2013
Multiplet effects in X-ray spectroscopy journal January 2005
Dichotomy in the Lithiation Pathway of Ellipsoidal and Platelet LiFePO 4 Particles Revealed through Nanoscale Operando State-of-Charge Imaging journal May 2015
Mg deposition observed by in situ electrochemical Mg K-edge X-ray absorption spectroscopy journal October 2012
Experiments and Theory of In situ and Operando Soft X-ray Spectroscopy for Energy Storage journal September 2014
Revealing and suppressing surface Mn(II) formation of Na0.44MnO2 electrodes for Na-ion batteries journal September 2015
Direct evidence of gradient Mn(II) evolution at charged states in LiNi0.5Mn1.5O4 electrodes with capacity fading journal January 2015
Spectroscopic fingerprints of valence and spin states in manganese oxides and fluorides journal May 2013
Ab Initio Study of the Sodium Intercalation and Intermediate Phases in Na 0.44 MnO 2 for Sodium-Ion Battery journal March 2012
Coupled Commensurate Cation and Charge Modulation in the Tunneled Structure, Na 0.40(2) MnO 2 journal September 2011
Distinct charge dynamics in battery electrodes revealed by in situ and operando soft X-ray spectroscopy journal October 2013
Direct Experimental Probe of the Ni(II)/Ni(III)/Ni(IV) Redox Evolution in LiNi 0.5 Mn 1.5 O 4 Electrodes journal November 2015
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