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Title: Cathodic Corrosion at the Bismuth-Ionic Liquid Electrolyte Interface under Conditions for CO2 Reduction

Journal Article · · Chemistry of Materials
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  1. Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
  2. Pennsylvania State Univ., University Park, PA (United States). Dept of Mechanical and Nuclear Engineering
  3. Univ. of Minnesota, Minneapolis, MN (United States). Dept. of Chemical Engineering and Materials Science
  4. Univ. of Delaware, Newark, DE (United States). Dept. of Chemistry and Biochemistry
+ Show Author Affiliations

Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States); Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC02-06CH11357; AC02-05CH11231; AC05-00OR22725
OSTI ID:
1434934
Alternate ID(s):
OSTI ID: 1435201
Journal Information:
Chemistry of Materials, Vol. 30; ISSN 0897-4756
Publisher:
American Chemical Society (ACS)Copyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 25 works
Citation information provided by
Web of Science

References (35)

Efficient Conversion of CO 2 to CO Using Tin and Other Inexpensive and Easily Prepared Post-Transition Metal Catalysts journal April 2015
Efficient Reduction of CO 2 to CO with High Current Density Using in Situ or ex Situ Prepared Bi-Based Materials journal May 2014
Rational Design of Bi Nanoparticles for Efficient Electrochemical CO 2 Reduction: The Elucidation of Size and Surface Condition Effects journal August 2016
Selective Conversion of CO 2 to CO with High Efficiency Using an Inexpensive Bismuth-Based Electrocatalyst journal June 2013
Structural Dynamics and Evolution of Bismuth Electrodes during Electrochemical Reduction of CO 2 in Imidazolium-Based Ionic Liquid Solutions journal September 2017
Dimensionally Controlled Lithiation of Chromium Oxide journal December 2015
Co-refinement of multiple-contrast neutron/X-ray reflectivity data using MOTOFIT journal March 2006
Interfacial ionic ‘liquids’: connecting static and dynamic structures journal December 2014
Structural Origins of Potential Dependent Hysteresis at the Electrified Graphene/Ionic Liquid Interface journal December 2013
Heteroepitaxial growth of cadmium carbonate at dolomite and calcite surfaces: Mechanisms and rates journal May 2017
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Projector augmented-wave method journal December 1994
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Semiempirical GGA-type density functional constructed with a long-range dispersion correction journal January 2006
Low-Temperature Growth of Bismuth Thin Films with (111) Facet on Highly Oriented Pyrolytic Graphite journal April 2015
Special points for Brillouin-zone integrations journal June 1976
Elucidation of the Electrochemical Activation of Water over Pd by First Principles journal January 2006
Publisher's Note: First principles reaction modeling of the electrochemical interface: Consideration and calculation of a tunable surface potential from atomic and electronic structure [Phys. Rev. B 73 , 165402 (2006)] journal April 2006
Ab initio effective core potentials for molecular calculations. Potentials for main group elements Na to Bi journal January 1985
Quaternary ammonium amalgams journal January 1968
On the cathodic behaviour of tetraalkylammonium cations at a platinum electrode journal July 1998
Reactivity of Platinum Metal with Organic Radical Anions from Metal to Negative Oxidation States journal April 2007
Spectroscopic Evidence of Platinum Negative Oxidation States at Electrochemically Reduced Surfaces journal April 2007
Cathodic Corrosion as a Facile and Effective Method To Prepare Clean Metal Alloy Nanoparticles journal November 2011
Cathodic Corrosion: A Quick, Clean, and Versatile Method for the Synthesis of Metallic Nanoparticles journal May 2011
Reaction of solid cathodes with tetraalkylammonium electrolytes journal May 1990
Dimethylpyrrolidinium amalgam formation and catalysis of organic electroreductions journal June 1984
Dimethylpyrrolidinium, a catalyst for organic electroreductions journal May 1985
Hydrated Cation Speciation at the Muscovite (001)−Water Interface journal November 2010
Tuning Selectivity of CO 2 Hydrogenation Reactions at the Metal/Oxide Interface journal July 2017
Reversible amorphization and the catalytically active state of crystalline Co3O4 during oxygen evolution journal October 2015
Partially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel journal January 2016
Directing the Outcome of CO 2 Reduction at Bismuth Cathodes Using Varied Ionic Liquid Promoters journal March 2018

Cited By (2)

Few‐Layer Bismuthene with Anisotropic Expansion for High‐Areal‐Capacity Sodium‐Ion Batteries journal January 2019
Reaction mechanisms at the homogeneous–heterogeneous frontier: insights from first-principles studies on ligand-decorated metal nanoparticles journal January 2019

Figures / Tables (7)

Figure 1(p. 8)figure Figure 1
Figure 2(p. 10)figure Figure 2
Figure 3(p. 13)figure Figure 3
Figure 4(p. 15)figure Figure 4
Figure 5(p. 17)figure Figure 5
Table 1(p. 20)table Table 1
Figure 6(p. 22)figure Figure 6

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Related Subjects

36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Bismuth electrodes
cathodic corrosion
CO2 reduction
imidazolium ionic liquids