Reactions of water and C1 molecules on carbide and metal-modified carbide surfaces
Abstract
The formation of carbides can significantly modify the physical and chemical properties of the parent metals. In the current review, we summarize the general trends in the reactions of water and C1 molecules over transition metal carbide (TMC) and metal-modified TMC surfaces and thin films. Although the primary focus of the current review is on the theoretical and experimental studies of reactions of C1 molecules (CO, CO2, CH3OH, etc.), the reactions of water will also be reviewed because water plays an important role in many of the C1 transformation reactions. This review is organized by discussing separately thermal reactions and electrochemical reactions, which provides insights into the application of TMCs in heterogeneous catalysis and electrocatalysis, respectively. In thermal reactions, we discuss the thermal decomposition of water and methanol, as well as the reactions of CO and CO2 over TMC surfaces. In electrochemical reactions, we summarize recent studies in the hydrogen evolution reaction, electrooxidation of methanol and CO, and electroreduction of CO2. Lastly, future research opportunities and challenges associated with using TMCs as catalysts and electrocatalysts are also discussed.
- Authors:
-
- Columbia Univ., New York, NY (United States)
- Columbia Univ., New York, NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States). Biological, Environmental & Climate Sciences Dept.
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1434771
- Report Number(s):
- BNL-203549-2018-JAAM
Journal ID: ISSN 0306-0012; CSRVBR
- Grant/Contract Number:
- SC0012704
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Chemical Society Reviews
- Additional Journal Information:
- Journal Volume: 46; Journal Issue: 7; Journal ID: ISSN 0306-0012
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
Citation Formats
Wan, Weiming, Tackett, Brian M., and Chen, Jingguang G. Reactions of water and C1 molecules on carbide and metal-modified carbide surfaces. United States: N. p., 2017.
Web. doi:10.1039/C6CS00862C.
Wan, Weiming, Tackett, Brian M., & Chen, Jingguang G. Reactions of water and C1 molecules on carbide and metal-modified carbide surfaces. United States. https://doi.org/10.1039/C6CS00862C
Wan, Weiming, Tackett, Brian M., and Chen, Jingguang G. 2017.
"Reactions of water and C1 molecules on carbide and metal-modified carbide surfaces". United States. https://doi.org/10.1039/C6CS00862C. https://www.osti.gov/servlets/purl/1434771.
@article{osti_1434771,
title = {Reactions of water and C1 molecules on carbide and metal-modified carbide surfaces},
author = {Wan, Weiming and Tackett, Brian M. and Chen, Jingguang G.},
abstractNote = {The formation of carbides can significantly modify the physical and chemical properties of the parent metals. In the current review, we summarize the general trends in the reactions of water and C1 molecules over transition metal carbide (TMC) and metal-modified TMC surfaces and thin films. Although the primary focus of the current review is on the theoretical and experimental studies of reactions of C1 molecules (CO, CO2, CH3OH, etc.), the reactions of water will also be reviewed because water plays an important role in many of the C1 transformation reactions. This review is organized by discussing separately thermal reactions and electrochemical reactions, which provides insights into the application of TMCs in heterogeneous catalysis and electrocatalysis, respectively. In thermal reactions, we discuss the thermal decomposition of water and methanol, as well as the reactions of CO and CO2 over TMC surfaces. In electrochemical reactions, we summarize recent studies in the hydrogen evolution reaction, electrooxidation of methanol and CO, and electroreduction of CO2. Lastly, future research opportunities and challenges associated with using TMCs as catalysts and electrocatalysts are also discussed.},
doi = {10.1039/C6CS00862C},
url = {https://www.osti.gov/biblio/1434771},
journal = {Chemical Society Reviews},
issn = {0306-0012},
number = 7,
volume = 46,
place = {United States},
year = {Thu Feb 23 00:00:00 EST 2017},
month = {Thu Feb 23 00:00:00 EST 2017}
}
Web of Science
Works referenced in this record:
Low-temperature water–gas shift reaction over cobalt–molybdenum carbide catalyst
journal, March 2006
- Nagai, M.; Matsuda, K.
- Journal of Catalysis, Vol. 238, Issue 2
Adsorption of Water on TiC(100): Evidence for Complex Reaction and Desorption Pathways
journal, September 1998
- Merrill, Philip B.; Perry, Scott S.; Frantz, Peter
- The Journal of Physical Chemistry B, Vol. 102, Issue 39
Reaction of Ethylene with Clean and Carbide-Modified Mo(110): Converting Surface Reactivities of Molybdenum to Pt-Group Metals
journal, January 1996
- Frühberger, B.; Chen, J. G.
- Journal of the American Chemical Society, Vol. 118, Issue 46
Chemisorption of CO on NbC(111) at 80 K: Angle‐resolved photoemission study
journal, January 1992
- Edamoto, Kazuyuki; Shiobara, Eishi; Anazawa, Toshihisa
- The Journal of Chemical Physics, Vol. 96, Issue 1
The adsorption and decomposition of formaldehyde and formic acid on the clean and modified Fe (100) surface
journal, February 1996
- Hung, Wei-Hsiu; Bernasek, Steven L.
- Surface Science, Vol. 346, Issue 1-3
Molecular adsorption of oxygen on transition-metal carbide
journal, June 1996
- Aizawa, Takashi; Hayami, Wataru; Souda, Ryutaro
- Surface Science, Vol. 357-358
In situ gas-phase catalytic properties of TiC-supported size-selected gold nanoparticles synthesized by diblock copolymer encapsulation
journal, December 2006
- Ono, L. K.; Sudfeld, D.; Roldan Cuenya, B.
- Surface Science, Vol. 600, Issue 23
Transition metal carbides (WC, Mo2C, TaC, NbC) as potential electrocatalysts for the hydrogen evolution reaction (HER) at medium temperatures
journal, February 2015
- Meyer, Simon; Nikiforov, Aleksey V.; Petrushina, Irina M.
- International Journal of Hydrogen Energy, Vol. 40, Issue 7
Small Cluster Models of the Surface Electronic Structure and Bonding Properties of Titanium Carbide, Vanadium Carbide, and Titanium Nitride
journal, December 2003
- Didziulis, Stephen V.; Butcher, Kristine D.; Perry, Scott S.
- Inorganic Chemistry, Vol. 42, Issue 24
Substrate-Dependent Reactivity of Water on Metal Carbide Surfaces
journal, December 1999
- Didziulis, Stephen V.; Frantz, Peter; Perry, Scott S.
- The Journal of Physical Chemistry B, Vol. 103, Issue 50
Effects of Potassium on the Chemisorption of CO on the Mo 2 C/Mo(100) Surface
journal, May 2001
- Bugyi, L.; Solymosi, F.
- The Journal of Physical Chemistry B, Vol. 105, Issue 19
Effect of cobalt (nickel) content on the catalytic performance of molybdenum carbides in dry-methane reforming
journal, February 2010
- Cheng, Jinmin; Huang, Wei
- Fuel Processing Technology, Vol. 91, Issue 2, p. 185-193
High Activity Carbide Supported Catalysts for Water Gas Shift
journal, March 2011
- Schweitzer, Neil M.; Schaidle, Joshua A.; Ezekoye, Obiefune K.
- Journal of the American Chemical Society, Vol. 133, Issue 8
Theoretical study of methane reforming on molybdenum carbide
journal, August 2007
- Tominaga, Hiroyuki; Nagai, Masatoshi
- Applied Catalysis A: General, Vol. 328, Issue 1
Identifying Different Types of Catalysts for CO 2 Reduction by Ethane through Dry Reforming and Oxidative Dehydrogenation
journal, November 2015
- Porosoff, Marc D.; Myint, Myat Noe Zin; Kattel, Shyam
- Angewandte Chemie International Edition, Vol. 54, Issue 51
Effects of sulfur on Mo2C and Pt/Mo2C catalysts: Water gas shift reaction
journal, June 2010
- Schaidle, Joshua A.; Lausche, Adam C.; Thompson, Levi T.
- Journal of Catalysis, Vol. 272, Issue 2
Hydrogenation of CO 2 to Methanol: Importance of Metal–Oxide and Metal–Carbide Interfaces in the Activation of CO 2
journal, October 2015
- Rodriguez, José A.; Liu, Ping; Stacchiola, Dario J.
- ACS Catalysis, Vol. 5, Issue 11
Monolayer bimetallic surfaces: Experimental and theoretical studies of trends in electronic and chemical properties
journal, May 2008
- Chen, Jingguang G.; Menning, Carl A.; Zellner, Michael B.
- Surface Science Reports, Vol. 63, Issue 5
Enhancing CO Tolerance of Electrocatalysts: Electro-oxidation of CO on WC and Pt-Modified WC
journal, January 2008
- Mellinger, Zachary J.; Weigert, Erich C.; Stottlemyer, Alan L.
- Electrochemical and Solid-State Letters, Vol. 11, Issue 5
Comparison of bond scission sequence of methanol on tungsten monocarbide and Pt-modified tungsten monocarbide
journal, September 2010
- Stottlemyer, Alan Lee; Liu, Ping; Chen, Jingguang G.
- The Journal of Chemical Physics, Vol. 133, Issue 10
Preparation of a Nickel Molybdenum Carbide Catalyst and Its Activity in the Dry Reforming of Methane
journal, May 2011
- Hirose, Taro; Ozawa, Yasushi; Nagai, Masatoshi
- Chinese Journal of Catalysis, Vol. 32, Issue 5
Trends in the Exchange Current for Hydrogen Evolution
journal, January 2005
- Nørskov, J. K.; Bligaard, T.; Logadottir, A.
- Journal of The Electrochemical Society, Vol. 152, Issue 3
In-situ synthesis of nickel modified molybdenum carbide catalyst for dry reforming of methane
journal, April 2011
- Zhang, Anjie; Zhu, Aimin; Chen, Bingbing
- Catalysis Communications, Vol. 12, Issue 9
Chemistry of SO 2 , H 2 S, and CH 3 SH on Carbide-Modified Mo(110) and Mo 2 C Powders: Photoemission and XANES Studies
journal, December 2000
- Rodriguez, José A.; Dvorak, Joseph; Jirsak, Tomas
- The Journal of Physical Chemistry B, Vol. 104, Issue 48
Correlating NEXAFS characterization of Co–W and Ni–W bimetallic carbide catalysts with reactivity for dry reforming of methane
journal, March 2009
- Shao, Huifang; Kugler, Edwin L.; Dadyburjor, Dady B.
- Applied Catalysis A: General, Vol. 356, Issue 1
Adsorption of O2, Co and CH3OH on NbC (100) and (111) single crystal surfaces by ultraviolet photoelectron spectroscopy
journal, September 1985
- Kojima, Isao; Orita, Masahiro; Miyazaki, Eizo
- Surface Science, Vol. 160, Issue 1
Hydrogen adsorption on model tungsten carbide surfaces
journal, August 2009
- Gaston, Nicola; Hendy, Shaun
- Catalysis Today, Vol. 146, Issue 1-2
Water-Gas-Shift Reaction on Molybdenum Carbide Surfaces: Essential Role of the Oxycarbide
journal, October 2006
- Liu, Ping; Rodriguez, José A.
- The Journal of Physical Chemistry B, Vol. 110, Issue 39
Selective Hydrodeoxygenation of Biomass-Derived Oxygenates to Unsaturated Hydrocarbons using Molybdenum Carbide Catalysts
journal, April 2013
- Ren, Hui; Yu, Weiting; Salciccioli, Michael
- ChemSusChem, Vol. 6, Issue 5
The interaction of water with oxygen-modified ZrC(100) surfaces
journal, March 2001
- Kitaoka, H.; Ozawa, K.; Edamoto, K.
- Solid State Communications, Vol. 118, Issue 1
Correlating the hydrogen evolution reaction activity in alkaline electrolytes with the hydrogen binding energy on monometallic surfaces
journal, January 2013
- Sheng, Wenchao; Myint, MyatNoeZin; Chen, Jingguang G.
- Energy & Environmental Science, Vol. 6, Issue 5
Dry reforming kinetics over a bulk molybdenum carbide catalyst
journal, July 2005
- LaMont, David C.; Thomson, William J.
- Chemical Engineering Science, Vol. 60, Issue 13
Production of CO-Free H2 by Formic Acid Decomposition over Mo2C/Carbon Catalysts
journal, June 2010
- Koós, Ákos; Solymosi, Frigyes
- Catalysis Letters, Vol. 138, Issue 1-2
Interaction of water and methanol with oxygen-modified ZrC() surfaces
journal, October 2002
- Kitaoka, H.; Ozawa, K.; Edamoto, K.
- Surface Science, Vol. 518, Issue 3
Activity and coke formation of nickel and nickel carbide in dry reforming: A deactivation scheme from density functional theory
journal, March 2014
- Wang, Ziyun; Cao, X. -M.; Zhu, Jinghao
- Journal of Catalysis, Vol. 311
Hydrogen evolution reaction (HER) at thin film and bulk TiC electrodes
journal, December 2007
- Ferri, T.; Gozzi, D.; Latini, A.
- International Journal of Hydrogen Energy, Vol. 32, Issue 18
Hydrogen evolution activity and electrochemical stability of selected transition metal carbides in concentrated phosphoric acid
journal, August 2014
- Tomás-García, Antonio Luis; Jensen, Jens Oluf; Bjerrum, Niels J.
- Electrochimica Acta, Vol. 137
Theoretical prediction and experimental verification of low loading of platinum on titanium carbide as low-cost and stable electrocatalysts
journal, April 2014
- Kimmel, Yannick C.; Yang, Leerang; Kelly, Thomas G.
- Journal of Catalysis, Vol. 312
Trends in the chemical properties of early transition metal carbide surfaces: A density functional study
journal, July 2005
- Kitchin, John R.; Nørskov, Jens K.; Barteau, Mark A.
- Catalysis Today, Vol. 105, Issue 1
Theoretical Study of the Interaction of CO on TiC(001) and Au Nanoparticles Supported on TiC(001): Probing the Nature of the Au/TiC Interface
journal, October 2011
- Asara, Gian Giacomo; Feria, Leticia; Florez, Elizabeth
- The Journal of Physical Chemistry C, Vol. 115, Issue 45
The Carburization of Transition Metal Molybdates (MxMoO4, M = Cu, Ni or Co) and the Generation of Highly Active Metal/Carbide Catalysts for CO2 Hydrogenation
journal, May 2015
- Xu, Wenqian; Ramírez, Pedro J.; Stacchiola, Dario
- Catalysis Letters, Vol. 145, Issue 7
CO and O2 adsorption on α-Mo2C (0001)
journal, November 2000
- St. Clair, Todd P.; Oyama, S. Ted; Cox, David F.
- Surface Science, Vol. 468, Issue 1-3
Metal-modified niobium carbides as low-cost and impurity-resistant electrocatalysts for hydrogen evolution in acidic and alkaline electrolytes
journal, April 2016
- Tackett, Brian M.; Kimmel, Yannick C.; Chen, Jingguang G.
- International Journal of Hydrogen Energy, Vol. 41, Issue 14
Reactions of methanol and water over carbide-modified Mo()
journal, June 2003
- Hwu, Henry H.; Chen, Jingguang G.
- Surface Science, Vol. 536, Issue 1-3
Carbide and Nitride Overlayers on Early Transition Metal Surfaces: Preparation, Characterization, and Reactivities
journal, January 1996
- Chen, Jingguang G.
- Chemical Reviews, Vol. 96, Issue 4
The chemical and electronic properties of oxygen-modified C/Mo(110): a model system for molybdenum oxycarbides
journal, January 2005
- Hwu, H.; Zellner, M.; Chen, J.
- Journal of Catalysis, Vol. 229, Issue 1
Frictional properties of titanium carbide, titanium nitride, and vanadium carbide: Measurement of a compositional dependence with atomic force microscopy
journal, January 2000
- Lee, Seunghwan; El-bjeirami, Oussama; Perry, Scott S.
- Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 18, Issue 1
Effect of surface carbon on the hydrogen evolution reactivity of tungsten carbide (WC) and Pt-modified WC electrocatalysts
journal, February 2012
- Kimmel, Yannick C.; Esposito, Daniel V.; Birkmire, Robert W.
- International Journal of Hydrogen Energy, Vol. 37, Issue 4
Glycolaldehyde as a Probe Molecule for Biomass Derivatives: Reaction of C—OH and C═O Functional Groups on Monolayer Ni Surfaces
journal, December 2011
- Yu, Weiting; Barteau, Mark A.; Chen, Jingguang G.
- Journal of the American Chemical Society, Vol. 133, Issue 50
The decomposition of formic acid on W(100) and W(100)?(5 $times; 1) C surfaces
journal, June 1979
- Benziger, J.
- Journal of Catalysis, Vol. 58, Issue 1
Surface Chemistry of Transition Metal Carbides
journal, January 2005
- Hwu, Henry H.; Chen, Jingguang G.
- Chemical Reviews, Vol. 105, Issue 1
Engineering Transition-Metal-Coated Tungsten Carbides for Efficient and Selective Electrochemical Reduction of CO 2 to Methane
journal, July 2015
- Wannakao, Sippakorn; Artrith, Nongnuch; Limtrakul, Jumras
- ChemSusChem, Vol. 8, Issue 16
Self-assembly of noble metal monolayers on transition metal carbide nanoparticle catalysts
journal, May 2016
- Hunt, S. T.; Milina, M.; Alba-Rubio, A. C.
- Science, Vol. 352, Issue 6288
Electrochemical Stability of Tungsten and Tungsten Monocarbide (WC) Over Wide pH and Potential Ranges
journal, January 2010
- Weidman, Mark C.; Esposito, Daniel V.; Hsu, Irene J.
- Journal of The Electrochemical Society, Vol. 157, Issue 12
Effect of Temperature on Structure and Performance of In-House Cobalt−Tungsten Carbide Catalyst for Dry Reforming of Methane
journal, July 2005
- Shao, Huifang; Kugler, Edwin L.; Ma, Wenping
- Industrial & Engineering Chemistry Research, Vol. 44, Issue 14
Surface chemistry of transition metal carbides: a theoretical analysis
journal, January 1988
- Jansen, Susan A.; Hoffmann, Roald
- Surface Science, Vol. 197, Issue 3
A Combined Surface Science and Electrochemical Study of Tungsten Carbides as Anode Electrocatalysts
journal, November 2007
- Weigert, Erich C.; Zellner, Michael B.; Stottlemyer, Alan L.
- Topics in Catalysis, Vol. 46, Issue 3-4
Electrocatalytic activity of some carburised nickel, tungsten and molybdenum compounds
journal, January 1997
- Barnett, C. J.; Burstein, G. T.; Kucernak, A. R. J.
- Electrochimica Acta, Vol. 42, Issue 15
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
journal, January 2012
- Kuhl, Kendra P.; Cave, Etosha R.; Abram, David N.
- Energy & Environmental Science, Vol. 5, Issue 5
Rotating disk electrode measurements of activity and stability of monolayer Pt on tungsten carbide disks for oxygen reduction reaction
journal, February 2012
- Hsu, Irene J.; Kimmel, Yannick C.; Dai, Yu
- Journal of Power Sources, Vol. 199
Potential Application of Tungsten Carbides as Electrocatalysts: 4. Reactions of Methanol, Water, and Carbon Monoxide over Carbide-Modified W(110)
journal, March 2003
- Hwu, Henry H.; Chen, Jingguang G.
- The Journal of Physical Chemistry B, Vol. 107, Issue 9
Spectroscopic characterization of thin vanadium carbide films on a vanadium (110) surface: Formation, stability, and reactivities
journal, May 1995
- Chen, J. G.; DeVries, B. D.; Frühberger, B.
- Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 13, Issue 3
Core-shell structured tungsten–tungsten carbide as a Pt catalyst support and its activity for methanol electrooxidation
journal, July 2012
- Obradović, M. D.; Babić, B. M.; Radmilović, V. R.
- International Journal of Hydrogen Energy, Vol. 37, Issue 14
Electron spectroscopic study of the interaction of WC(0001) with different adsorbates (C6H6, CO and NO)
journal, March 1998
- Brillo, J.; Sur, R.; Kuhlenbeck, H.
- Journal of Electron Spectroscopy and Related Phenomena, Vol. 88-91
Effect of carbon modification on a vanadium(110) surface: observation of surface reactivities characteristics of platinum-group metals
journal, September 1993
- Chen, J. G.; Weisel, M. D.; Liu, Z. M.
- Journal of the American Chemical Society, Vol. 115, Issue 19
Reactions of methanol on W(100) and W(100)-(5 $times; 1)C surfaces
journal, April 1980
- Ko, E.
- Journal of Catalysis, Vol. 62, Issue 2
Interaction of O2 with WC(0001)
journal, July 1998
- Brillo, J.; Kuhlenbeck, H.; Freund, H. -J
- Surface Science, Vol. 409, Issue 2
Evidence for nitrile hydrogenation on tungsten(100)-(5 .times. 1)-carbon: spectroscopic studies of surface intermediates derived from hydrogen cyanide
journal, November 1988
- Serafin, J. G.; Friend, C. M.
- The Journal of Physical Chemistry, Vol. 92, Issue 23
New Catalysts for the Conversion of Methane to Synthesis Gas: Molybdenum and Tungsten Carbide
journal, November 1998
- Claridge, John B.; York, Andrew P. E.; Brungs, Attila J.
- Journal of Catalysis, Vol. 180, Issue 1
Trends in Hydrogen Evolution Activity of Metal-Modified Molybdenum Carbides in Alkaline and Acid Electrolytes
journal, May 2016
- Zhang, Qian; Tackett, Brian M.; Wu, Qiyuan
- ChemElectroChem, Vol. 3, Issue 10
Fundamentals of Methanol Synthesis on Metal Carbide Based Catalysts: Activation of CO2 and H2
journal, December 2014
- Posada-Pérez, Sergio; Viñes, Francesc; Rodriguez, José A.
- Topics in Catalysis, Vol. 58, Issue 2-3
Identifying trends and descriptors for selective CO 2 conversion to CO over transition metal carbides
journal, January 2015
- Porosoff, Marc D.; Kattel, Shyam; Li, Wenhui
- Chemical Communications, Vol. 51, Issue 32
Electrochemical reduction of carbon dioxides to carbon monoxide at a gold electrode in aqueous potassium hydrogen carbonate
journal, January 1987
- Hori, Yoshio; Murata, Akira; Kikuchi, Katsuhei
- Journal of the Chemical Society, Chemical Communications, Issue 10
Molybdenum Carbide as Alternative Catalysts to Precious Metals for Highly Selective Reduction of CO 2 to CO
journal, May 2014
- Porosoff, Marc D.; Yang, Xiaofang; Boscoboinik, J. Anibal
- Angewandte Chemie International Edition, Vol. 53, Issue 26
SECM characterization of Pt–Ru–WC and Pt–Ru–Co ternary thin film combinatorial libraries as anode electrocatalysts for PEMFC
journal, October 2006
- Lu, Guojin; Cooper, James S.; McGinn, Paul J.
- Journal of Power Sources, Vol. 161, Issue 1
Surface science and electrochemical studies of WC and W2C PVD films as potential electrocatalysts
journal, January 2005
- Zellner, Michael B.; Chen, Jingguang G.
- Catalysis Today, Vol. 99, Issue 3-4
Mechanistic study on the methane activation over various supported molybdenum carbide catalysts with isotopic tracer methods
journal, August 2005
- Naito, Shuichi; Takada, Akiko; Tokizawa, Satoshi
- Applied Catalysis A: General, Vol. 289, Issue 1
Selective decomposition of formic acid on molybdenum carbide: A new reaction pathway
journal, January 2010
- Flaherty, David W.; Berglund, Sean P.; Mullins, C. Buddie
- Journal of Catalysis, Vol. 269, Issue 1
Exploring the activity of a novel Au/TiC(001) model catalyst towards CO and CO2 hydrogenation
journal, October 2015
- Asara, Gian Giacomo; Ricart, Josep M.; Rodriguez, Jose A.
- Surface Science, Vol. 640
Low-Cost Hydrogen-Evolution Catalysts Based on Monolayer Platinum on Tungsten Monocarbide Substrates
journal, September 2010
- Esposito, Daniel V.; Hunt, Sean T.; Stottlemyer, Alan L.
- Angewandte Chemie International Edition, Vol. 49, Issue 51
Synthesis, characterization and surface reactivity of tungsten carbide (WC) PVD films
journal, October 2004
- Zellner, Michael B.; Chen, Jingguang G.
- Surface Science, Vol. 569, Issue 1-3
Understanding the Low-Overpotential Production of CH 4 from CO 2 on Mo 2 C Catalysts
journal, February 2016
- Kim, Seok Ki; Zhang, Yin-Jia; Bergstrom, Helen
- ACS Catalysis, Vol. 6, Issue 3
Monolayer platinum supported on tungsten carbides as low-cost electrocatalysts: opportunities and limitations
journal, January 2011
- Esposito, Daniel V.; Chen, Jingguang G.
- Energy & Environmental Science, Vol. 4, Issue 10
Comparison of electrochemical stability of transition metal carbides (WC, W2C, Mo2C) over a wide pH range
journal, March 2012
- Weidman, Mark C.; Esposito, Daniel V.; Hsu, Yeh-Chun
- Journal of Power Sources, Vol. 202
Methanol Oxidation Reaction on α-Tungsten Carbide Versus Platinum (1 1 1) Surfaces: A DFT Electrochemical Study
journal, September 2015
- Di Valentin, Cristiana; Fittipaldi, Diego; Pacchioni, Gianfranco
- ChemCatChem, Vol. 7, Issue 21
Molybdenum carbide catalysed hydrogen production from formic acid – A density functional theory study
journal, January 2014
- Luo, Qiquan; Wang, Tao; Walther, Guido
- Journal of Power Sources, Vol. 246
The bending machine: CO 2 activation and hydrogenation on δ-MoC(001) and β-Mo 2 C(001) surfaces
journal, January 2014
- Posada-Pérez, Sergio; Viñes, Francesc; Ramirez, Pedro J.
- Phys. Chem. Chem. Phys., Vol. 16, Issue 28
A New Class of Electrocatalysts for Hydrogen Production from Water Electrolysis: Metal Monolayers Supported on Low-Cost Transition Metal Carbides
journal, February 2012
- Esposito, Daniel V.; Hunt, Sean T.; Kimmel, Yannick C.
- Journal of the American Chemical Society, Vol. 134, Issue 6
Spectroscopic study on the formation of CO−2 on K-promoted Mo2C/Mo(100) surface
journal, August 2000
- Bugyi, László; Oszkó, Albert; Solymosi, Frigyes
- Surface Science, Vol. 461, Issue 1-3
Extended X-ray Absorption Fine Structure and X-ray Diffraction Examination of Sputtered Nickel Carbon Binary Thin Films for Fuel Cell Applications
journal, March 2012
- Ingham, Bridget; Gaston, Nicola; Fahy, Kieran
- The Journal of Physical Chemistry C, Vol. 116, Issue 10
Interaction of CO and NO with WC(0001)
journal, February 1998
- Brillo, J.; Sur, R.; Kuhlenbeck, H.
- Surface Science, Vol. 397, Issue 1-3
High activity PtPd-WC/C electrocatalyst for hydrogen evolution reaction
journal, April 2007
- Wu, Mei; Shen, Pei Kang; Wei, Zidong
- Journal of Power Sources, Vol. 166, Issue 2, p. 310-316
Metal overlayer on metal carbide substrate: unique bimetallic properties for catalysis and electrocatalysis
journal, January 2012
- Kelly, Thomas G.; Chen, Jingguang G.
- Chemical Society Reviews, Vol. 41, Issue 24
Potential application of tungsten carbides as electrocatalysts III. Reactions of methanol, water, and hydrogen on Pt-modified C/W(111) surfaces
journal, April 2003
- Liu, N.
- Journal of Catalysis, Vol. 215, Issue 2
RAIRS and TPD study of CO and NO on β-Mo2C
journal, March 1997
- Wang, J.; Castonguay, M.; Deng, J.
- Surface Science, Vol. 374, Issue 1-3
Methanol electro-oxidation on platinum modified tungsten carbides in direct methanol fuel cells: a DFT study
journal, January 2015
- Sheng, Tian; Lin, Xiao; Chen, Zhao-Yang
- Physical Chemistry Chemical Physics, Vol. 17, Issue 38
Pt-modified molybdenum carbide for the hydrogen evolution reaction: From model surfaces to powder electrocatalysts
journal, December 2014
- Kelly, Thomas G.; Lee, Kevin X.; Chen, Jingguang G.
- Journal of Power Sources, Vol. 271
Comparative studies of methanol decomposition on carbide-modified V(110) and Ti(0001)
journal, December 2005
- Zellner, Michael B.; Hwu, Henry H.; Chen, Jingguang G.
- Surface Science, Vol. 598, Issue 1-3
Effects of adsorbed carbon and oxygen on the chemisorption of H2 and Co on Mo(100)
journal, August 1981
- Ko, E. I.; Madix, R. J.
- Surface Science, Vol. 109, Issue 1
Potential Application of Tungsten Carbides as Electrocatalysts. 1. Decomposition of Methanol over Carbide-Modified W(111)
journal, October 2001
- Hwu, Henry H.; Chen, Jingguang G.; Kourtakis, Kostantinos
- The Journal of Physical Chemistry B, Vol. 105, Issue 41
Trends in Electrochemical Stability of Transition Metal Carbides and Their Potential Use As Supports for Low-Cost Electrocatalysts
journal, April 2014
- Kimmel, Yannick C.; Xu, Xiaoge; Yu, Weiting
- ACS Catalysis, Vol. 4, Issue 5
Cyclic voltammetry and X-ray photoelectron spectroscopy studies of electrochemical stability of clean and Pt-modified tungsten and molybdenum carbide (WC and Mo2C) electrocatalysts
journal, September 2009
- Weigert, Erich C.; Esposito, Daniel V.; Chen, Jingguang G.
- Journal of Power Sources, Vol. 193, Issue 2
Adsorption of methanol on ZrC(100) and (111) surfaces
journal, August 1999
- Nakane, T.; Noda, T.; Ozawa, K.
- Surface Science, Vol. 433-435
Low loadings of platinum on transition metal carbides for hydrogen oxidation and evolution reactions in alkaline electrolytes
journal, January 2016
- Wang, Lu; Mahoney, Elizabeth G.; Zhao, Shen
- Chemical Communications, Vol. 52, Issue 18
Pd-Modified Tungsten Carbide for Methanol Electro-oxidation: From Surface Science Studies to Electrochemical Evaluation
journal, April 2012
- Mellinger, Zachary J.; Kelly, Thomas G.; Chen, Jingguang G.
- ACS Catalysis, Vol. 2, Issue 5
Decomposition of formic acid on Ni(100)-p(2 × 2)C
journal, September 1979
- Ko, E. I.; Madix, R. J.
- Applications of Surface Science, Vol. 3, Issue 2
Density Functional Theory of Water−Gas Shift Reaction on Molybdenum Carbide
journal, November 2005
- Tominaga, Hiroyuki; Nagai, Masatoshi
- The Journal of Physical Chemistry B, Vol. 109, Issue 43
Theoretical Model for CO Adsorption and Dissociation on Clean and K-Doped β-Mo 2 C Surfaces
journal, November 2012
- Pistonesi, Carolina; Pronsato, María Estela; Bugyi, László
- The Journal of Physical Chemistry C, Vol. 116, Issue 46
Potential Application of Tungsten Carbides as Electrocatalysts. 2. Coadsorption of CO and H 2 O on Carbide-Modified W(111)
journal, October 2001
- Hwu, Henry H.; Polizzotti, Brian D.; Chen, Jingguang G.
- The Journal of Physical Chemistry B, Vol. 105, Issue 41
Monolayer palladium supported on molybdenum and tungsten carbide substrates as low-cost hydrogen evolution reaction (HER) electrocatalysts
journal, May 2013
- Kelly, Thomas G.; Hunt, Sean T.; Esposito, Daniel V.
- International Journal of Hydrogen Energy, Vol. 38, Issue 14
Understanding Trends in the Electrocatalytic Activity of Metals and Enzymes for CO 2 Reduction to CO
journal, January 2013
- Hansen, Heine A.; Varley, Joel B.; Peterson, Andrew A.
- The Journal of Physical Chemistry Letters, Vol. 4, Issue 3
CO2 hydrogenation on Au/TiC, Cu/TiC, and Ni/TiC catalysts: Production of CO, methanol, and methane
journal, November 2013
- Rodriguez, José A.; Evans, Jaime; Feria, Leticia
- Journal of Catalysis, Vol. 307
The Mechanism of the Cathodic Hydrogen Evolution Reaction
journal, January 1952
- Bockris, J. O'M.; Potter, E. C.
- Journal of The Electrochemical Society, Vol. 99, Issue 4
CO 2 Activation and Methanol Synthesis on Novel Au/TiC and Cu/TiC Catalysts
journal, August 2012
- Vidal, Alba B.; Feria, Leticia; Evans, Jaime
- The Journal of Physical Chemistry Letters, Vol. 3, Issue 16
Pt/WC as an anode catalyst for PEMFC: Activity and CO tolerance
journal, March 2008
- Ham, Dong Jin; Kim, Young Kwon; Han, Seung Hyun
- Catalysis Today, Vol. 132, Issue 1-4
Potential application of tungsten carbides as electrocatalysts
journal, July 2003
- Hwu, Henry H.; Chen, Jiangguang G.
- Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 21, Issue 4
Potential Application of Tungsten Carbides as Electrocatalysts: Synergistic Effect by Supporting Pt on C∕W(110) for the Reactions of Methanol, Water, and CO
journal, January 2005
- Zellner, Michael B.; Chen, Jingguang G.
- Journal of The Electrochemical Society, Vol. 152, Issue 8
Comparison of O−H, C−H, and C−O Bond Scission Sequence of Methanol on Tungsten Carbide Surfaces Modified by Ni, Rh, and Au
journal, March 2011
- Kelly, Thomas G.; Stottlemyer, Alan L.; Ren, Hui
- The Journal of Physical Chemistry C, Vol. 115, Issue 14
Tungsten carbide microsphere as an electrode for cathodic hydrogen evolution from water
journal, December 2008
- Ham, D.; Ganesan, R.; Lee, J.
- International Journal of Hydrogen Energy, Vol. 33, Issue 23
Modification of the surface reactivity of Mo(110) upon carbide formation
journal, November 1995
- Frühberger, B.; Chen, J. G.
- Surface Science, Vol. 342, Issue 1-3
Bonding and adsorption structure of CO on W(100)‐(5×1)–C
journal, August 1987
- Friend, C. M.; Serafin, J. G.; Baldwin, E. K.
- The Journal of Chemical Physics, Vol. 87, Issue 3
Reaction of Methanol with TiC and VC (100) Surfaces
journal, June 2002
- Frantz, Peter; Didziulis, Stephen V.; Fernandez-Torres, Luis C.
- The Journal of Physical Chemistry B, Vol. 106, Issue 25
Reactions of oxygen-containing molecules on transition metal carbides: Surface science insight into potential applications in catalysis and electrocatalysis
journal, September 2012
- Stottlemyer, Alan L.; Kelly, Thomas G.; Meng, Qinghe
- Surface Science Reports, Vol. 67, Issue 9-10
Reactions of formaldehyde on W(100) and W(100)-(5 $times; 1)C
journal, July 1980
- Benziger, J.
- Journal of Catalysis, Vol. 64, Issue 1
Departures from the Adsorption Energy Scaling Relations for Metal Carbide Catalysts
journal, June 2014
- Michalsky, Ronald; Zhang, Yin-Jia; Medford, Andrew J.
- The Journal of Physical Chemistry C, Vol. 118, Issue 24
Effects of potassium on the adsorption and dissociation pathways of methanol and ethanol on Mo2C/Mo(100)
journal, April 2008
- Farkas, A. P.; Solymosi, F.
- Surface Science, Vol. 602, Issue 7
Alteration in surface reaction selectivity of nitriles. 1. Hydrogen cyanide on tungsten(100) and tungsten(100)-(5.times.1)-carbon
journal, August 1986
- Pearlstine, K. A.; Friend, C. M.
- The Journal of Physical Chemistry, Vol. 90, Issue 18
Platinum-Like Behavior of Tungsten Carbide in Surface Catalysis
journal, August 1973
- Levy, R. B.; Boudart, M.
- Science, Vol. 181, Issue 4099
Generation and Reactions of CH2 and C2H5 Species on Mo2C/Mo(111) Surface
journal, July 1999
- Solymosi, F.; Bugyi, L.; Oszkó, A.
- Journal of Catalysis, Vol. 185, Issue 1
Is platinum necessary for efficient hydrogen evolution? – DFT study of metal monolayers on tungsten carbide
journal, December 2013
- Vasić Anićijević, Dragana D.; Nikolić, Vladimir M.; Marčeta-Kaninski, Milica P.
- International Journal of Hydrogen Energy, Vol. 38, Issue 36
Review of Pt-Based Bimetallic Catalysis: From Model Surfaces to Supported Catalysts
journal, August 2012
- Yu, Weiting; Porosoff, Marc D.; Chen, Jingguang G.
- Chemical Reviews, Vol. 112, Issue 11, p. 5780-5817
Adsorption of methanol on TiC(100) and (111) surfaces
journal, March 1998
- Edamoto, K.; Nakane, T.; Noda, T.
- Journal of Electron Spectroscopy and Related Phenomena, Vol. 88-91
Tungsten Monocarbide as Potential Replacement of Platinum for Methanol Electrooxidation
journal, October 2007
- Weigert, Erich C.; Stottlemyer, Alan L.; Zellner, Michael B.
- The Journal of Physical Chemistry C, Vol. 111, Issue 40
Preparation and catalytic properties of transition metal carbides and nitrides
journal, June 1992
- Oyama, S. T.
- Catalysis Today, Vol. 15, Issue 2
Stability of supported and promoted-molybdenum carbide catalysts in dry-methane reforming
journal, December 2005
- Darujati, Anna R. S.; Thomson, William J.
- Applied Catalysis A: General, Vol. 296, Issue 2
Coordination Chemistry of Transition Metal Carbide Surfaces: Detailed Spectroscopic and Theoretical Investigations of CO Adsorption on TiC and VC (100) Surfaces
journal, June 2001
- Didziulis, Stephen V.; Frantz, Peter; Fernandez-Torres, Luis C.
- The Journal of Physical Chemistry B, Vol. 105, Issue 22
Works referencing / citing this record:
Enhancing Activity and Reducing Cost for Electrochemical Reduction of CO 2 by Supporting Palladium on Metal Carbides
journal, February 2019
- Wang, Jiajun; Kattel, Shyam; Hawxhurst, Christopher J.
- Angewandte Chemie, Vol. 131, Issue 19
Kopplung von Solarenergie und Wärmeenergie zur Kohlendioxidreduktion: Aktueller Stand und Perspektiven
journal, February 2020
- Wang, Zhou‐jun; Song, Hui; Liu, Huimin
- Angewandte Chemie, Vol. 132, Issue 21
Enhancing Activity and Reducing Cost for Electrochemical Reduction of CO 2 by Supporting Palladium on Metal Carbides
journal, April 2019
- Wang, Jiajun; Kattel, Shyam; Hawxhurst, Christopher J.
- Angewandte Chemie International Edition, Vol. 58, Issue 19
Coupling of Solar Energy and Thermal Energy for Carbon Dioxide Reduction: Status and Prospects
journal, February 2020
- Wang, Zhou-jun; Song, Hui; Liu, Huimin
- Angewandte Chemie International Edition
Vibrational Spectroscopic Characterization of Glycerol Reaction Pathways over Metal‐Modified Molybdenum Carbide Surfaces
journal, October 2019
- Wan, Weiming; Lin, Zhexi; Chen, Jingguang G.
- ChemCatChem, Vol. 12, Issue 1
Highly Active Bifunctional Electrocatalysts for Oxygen Evolution and Reduction in Zn–Air Batteries
journal, November 2018
- Kim, Sung‐Wook; Son, Yoonkook; Choi, Keunsu
- ChemSusChem, Vol. 11, Issue 24
CO 2 electroreduction performance of a single transition metal atom supported on porphyrin-like graphene: a computational study
journal, January 2017
- Wang, Zhongxu; Zhao, Jingxiang; Cai, Qinghai
- Physical Chemistry Chemical Physics, Vol. 19, Issue 34
Atomic layer deposition of nickel carbide for supercapacitors and electrocatalytic hydrogen evolution
journal, January 2018
- Xiong, Wei; Guo, Qun; Guo, Zheng
- Journal of Materials Chemistry A, Vol. 6, Issue 10
Highly selective and efficient reduction of CO 2 to CO on cadmium electrodes derived from cadmium hydroxide
journal, January 2018
- Shi, Jinbiao; Shao, Dan; Zhang, Jianling
- Chemical Communications, Vol. 54, Issue 43
Recent progress in Pt and Pd-based hybrid nanocatalysts for methanol electrooxidation
journal, January 2019
- Shang, Changshuai; Wang, Erkang
- Physical Chemistry Chemical Physics, Vol. 21, Issue 38
Insights into interface engineering in steam reforming reactions for hydrogen production
journal, January 2019
- Chen, Sai; Pei, Chunlei; Gong, Jinlong
- Energy & Environmental Science, Vol. 12, Issue 12