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Title: L-edge sum rule analysis on 3d transition metal sites: from d10 to d0 and towards application to extremely dilute metallo-enzymes

Journal Article · · Physical Chemistry Chemical Physics. PCCP (Print)
DOI:https://doi.org/10.1039/c7cp06624d· OSTI ID:1434331
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [4]; ORCiD logo [5]; ORCiD logo [6]; ORCiD logo [7]
  1. Univ. of California, Davis, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
  2. Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
  3. Univ. of Hyogo, Tatsuno (Japan)
  4. Univ. of California, Davis, CA (United States)
  5. Univ. of Illinois, Urbana, IL (United States)
  6. Argonne National Lab. (ANL), Argonne, IL (United States)
  7. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
+ Show Author Affiliations

According to L-edge sum rules, the number of 3d vacancies at a transition metal site is directly proportional to the integrated intensity of the L-edge X-ray absorption spectrum (XAS) for the corresponding metal complex.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States); Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Biological and Environmental Research (BER)
Grant/Contract Number:
AC02-06CH11357; AC52-07NA27344
OSTI ID:
1434331
Alternate ID(s):
OSTI ID: 1465312
Report Number(s):
LLNL-JRNL-746682; PPCPFQ; 142189; TRN: US1802684
Journal Information:
Physical Chemistry Chemical Physics. PCCP (Print), Vol. 20, Issue 12; ISSN 1463-9076
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 13 works
Citation information provided by
Web of Science

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Figures / Tables (7)

Table 1.(p. 17)table Table 1.
Figure 1(p. 18)figure Figure 1
Figure 2.(p. 19)figure Figure 2.
Figure 3.(p. 20)figure Figure 3.
Figure 4.(p. 21)figure Figure 4.
Figure 5.(p. 22)figure Figure 5.
Figure 6.(p. 23)figure Figure 6.

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY