skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: The impact of physicochemical property interactions of iso -octane/ethanol blends on ignition timescales

Journal Article · · Fuel
 [1];  [2];  [2];  [1]
  1. Univ. of Michigan, Ann Arbor, MI (United States)
  2. National Renewable Energy Lab. (NREL), Golden, CO (United States)

This work presents new measurements of liquid fuel ignition delay times of iso-octane and ethanol fuel blends obtained from an ignition quality tester at the National Renewable Energy Laboratory (NREL IQT), which are compared to previous ignition delay data from the University of Michigan rapid compression facility (UM RCF), at the same experimental conditions. Pressure-time histories were used to determine liquid fuel ignition delays at global stoichiometric non-premixed conditions for iso-octane, ethanol and iso-octane/ethanol blends of 25, 50, 75% by volume in mixtures of 10% oxygen diluted in nitrogen. Temperatures ranging from 880 to 970 K were studied at a pressure of 10 atm. By comparing total ignition delay times from the NREL IQT with chemical ignition delay times from the UM RCF, the contributions of physical phenomena were quantified as representative time scales for spray injection, breakup and evaporation processes, and for gas-phase turbulent mixing. Regression analyses were developed for ignition time scales as function of blend level and charge temperature. Non-dimensional analyses were also carried out to determine the relative effects of physical time scales with respect to chemical ignition delay times.

Research Organization:
National Renewable Energy Lab. (NREL), Golden, CO (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Bioenergy Technologies Office; USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC36-08GO28308; SC0002645; DE347AC36-99GO10337
OSTI ID:
1431423
Alternate ID(s):
OSTI ID: 1548554
Report Number(s):
NREL/JA-5400-71009; MainId:21373; UUID:bcd14d2d-2518-e811-9c12-2c44fd93e385; MainAdminID:9849
Journal Information:
Fuel, Vol. 224, Issue C; ISSN 0016-2361
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 12 works
Citation information provided by
Web of Science

References (25)

Effects of Fuel Octane Rating and Ethanol Content on Knock, Fuel Economy, and CO2 for a Turbocharged DI Engine journal April 2014
The effect of ethanol blending on mixture formation, combustion and soot emission studied in an optical DISI engine journal October 2015
In-Cylinder Particulate Matter and Spray Imaging of Ethanol/Gasoline Blends in a Direct Injection Spark Ignition Engine journal April 2013
Combustion chemistry of iso-octane/ethanol blends: Effects on ignition and reaction pathways journal February 2018
Alcohol combustion chemistry journal October 2014
Combustion Chemistry of Ethanol: Ignition and Speciation Studies in a Rapid Compression Facility journal September 2016
Investigation of Physical and Chemical Delay Periods of Different Fuels in the Ignition Quality Tester journal May 2013
Evaluating the Potential of a Direct-Injection Constant-Volume Combustion Chamber as a Tool to Validate Chemical-Kinetic Models for Liquid Fuels journal November 2016
Effects of iso-octane/ethanol blend ratios on the observance of negative temperature coefficient behavior within the Ignition Quality Tester journal December 2016
Ignition Quality Tester (IQT) Investigation of the Negative Temperature Coefficient Region of Alkane Autoignition journal March 2013
Experiments and Computational Fluid Dynamics Modeling Analysis of Large n -Alkane Ignition Kinetics in the Ignition Quality Tester journal May 2014
Effect of Temperature, Pressure and Equivalence Ratio on Ignition Delay in Ignition Quality Tester (IQT): Diesel, n-Heptane, and iso-Octane Fuels under Low Temperature Conditions journal April 2015
Investigation of Iso-octane Ignition and Validation of a Multizone Modeling Method in an Ignition Quality Tester journal September 2016
Experimental Investigation of the Autoignition Behavior of Surrogate Gasoline Fuels in a Constant-Volume Combustion Bomb Apparatus and Its Relevance to HCCI Combustion journal September 2012
The octane numbers of ethanol blended with gasoline and its surrogates journal January 2014
Relating the octane numbers of fuels to ignition delay times measured in an ignition quality tester (IQT) journal January 2017
Numerical and Experimental Investigation of n -Heptane Autoignition in the Ignition Quality Tester (IQT) journal December 2011
Two-stage Lagrangian modeling of ignition processes in ignition quality tester and constant volume combustion chambers journal December 2016
Relative Reactivities of the Isomeric Butanols and Ethanol in an Ignition Quality Tester journal September 2011
Autoignition Studies of trans - and cis -Decalin in an Ignition Quality Tester (IQT) and the Development of a High Thermal Stability Unifuel/Single Battlefield Fuel journal December 2009
The Relative Importance of Fuel Oxidation Chemistry and Physical Properties to Spray Ignition journal March 2017
Expanding the Experimental Capabilities of the Ignition Quality Tester for Autoigniting Fuels journal April 2010
Demonstration of a free-piston rapid compression facility for the study of high temperature combustion phenomena journal May 2004
Kinetic modeling of gasoline surrogate components and mixtures under engine conditions journal January 2011
Effects of fuel physical properties on direct injection spray and ignition behavior journal September 2016