Grand Challenges and Future Opportunities for Metal–Organic Frameworks

Hendon, Christopher H.; Rieth, Adam J.; Korzyński, Maciej D.; Dincă, Mircea

doi:10.1021/acscentsci.7b00197

Title: Grand Challenges and Future Opportunities for Metal–Organic Frameworks

Journal Article · Tue Jun 06 00:00:00 EDT 2017 · ACS Central Science

DOI:https://doi.org/10.1021/acscentsci.7b00197· OSTI ID:1426158

^[1]; Rieth, Adam J. ^[1]; Korzyński, Maciej D. ^[1];

^[1]

Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Department of Chemistry

Metal–organic frameworks (MOFs) allow compositional and structural diversity beyond conventional solid-state materials. Continued interest in the field is justified by potential applications of exceptional breadth, ranging from gas storage and separation, which takes advantage of the inherent pores and their volume, to electronic applications, which requires precise control of electronic structure. In this Outlook we present some of the pertinent challenges that MOFs face in their conventional implementations, as well as opportunities in less traditional areas. Here the aim is to discuss select design concepts and future research goals that emphasize nuances relevant to this class of materials as a whole. Particular emphasis is placed on synthetic aspects, as they influence the potential for MOFs in gas separation, electrical conductivity, and catalytic applications.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Excitonics (CE); Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0001088; SC0001299

OSTI ID:: 1426158

Journal Information:: ACS Central Science, Vol. 3, Issue 6; ISSN 2374-7943

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 265 works

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