Stabilizing CuPd Nanoparticles via CuPd Coupling to WO2.72 Nanorods in Electrochemical Oxidation of Formic Acid

Xi, Zheng; Li, Junrui; Su, Dong; Muzzio, Michelle; Yu, Chao; Li, Qing; Sun, Shouheng

doi:10.1021/jacs.7b08643

Title: Stabilizing CuPd Nanoparticles via CuPd Coupling to WO_2.72 Nanorods in Electrochemical Oxidation of Formic Acid

Journal Article · Thu Oct 05 00:00:00 EDT 2017 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.7b08643· OSTI ID:1425019

^[1]; Li, Junrui ^[1];

^[2]; Muzzio, Michelle ^[1];

^[1];

^[3];

^[1]

Brown Univ., Providence, RI (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Huazhong Univ. of Science and Technology, Wuhan (China)

Stabilizing a 3d-transition metal component M from an MPd alloy structure in an acidic environment is key to the enhancement of MPd catalysis for various reactions. Here we show a strategy to stabilize Cu in 5 nm CuPd nanoparticles (NPs) by coupling the CuPd NPs with perovskite-type WO_2.72 nanorods (NRs). The CuPd NPs are prepared by controlled diffusion of Cu into Pd NPs and the coupled CuPd/WO_2.72 are synthesized by growing WO_2.72 NRs in the presence of CuPd NPs. The CuPd/WO_2.72 can stabilize Cu in 0.1 M HClO4 solution and, as a result, they show Cu, Pd composition dependent activity for the electrochemical oxidation of formic acid in 0.1 M HClO₄ + 0.1 M HCOOH. Among three different CuPd/WO_2.72 studied, the Cu₄₈Pd₅₂/WO_2.72 is the most efficient catalyst with its mass activity reaching 2086 mA/mgPd in a broad potential range of 0.40 to 0.80 V (vs. RHE) and staying at this value after the 12 h chronoamperometry test at 0.40 V. The synthesis can be extended to obtain other MPd/WO_2.72 (M = Fe, Co, Ni), making it possible to study MPd-WO_2.72 interactions and MPd stabilization on enhancing MPd catalysis for various chemical reactions.

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Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704

OSTI ID:: 1425019

Report Number(s):: BNL-114858-2017-JAAM; TRN: US1802002

Journal Information:: Journal of the American Chemical Society, Vol. 139, Issue 42; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 94 works

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References (35)

Recent advances in direct formic acid fuel cells (DFAFC) Yu, Xingwen; Pickup, Peter G. Journal of Power Sources, Vol. 182, Issue 1, p. 124-132 https://doi.org/10.1016/j.jpowsour.2008.03.075	journal	July 2008
Direct liquid-feed fuel cells: Thermodynamic and environmental concerns Demirci, Umit B. Journal of Power Sources, Vol. 169, Issue 2 https://doi.org/10.1016/j.jpowsour.2007.03.050	journal	June 2007
Architecture for portable direct liquid fuel cells Qian, Weimin; Wilkinson, David P.; Shen, Jun Journal of Power Sources, Vol. 154, Issue 1 https://doi.org/10.1016/j.jpowsour.2005.12.019	journal	March 2006
Nanocrystalline intermetallics on mesoporous carbon for direct formic acid fuel cell anodes Ji, Xiulei; Lee, Kyu Tae; Holden, Reanne Nature Chemistry, Vol. 2, Issue 4, p. 286-293 https://doi.org/10.1038/nchem.553	journal	February 2010
Structure-Induced Enhancement in Electrooxidation of Trimetallic FePtAu Nanoparticles Zhang, Sen; Guo, Shaojun; Zhu, Huiyuan Journal of the American Chemical Society, Vol. 134, Issue 11 https://doi.org/10.1021/ja300708j	journal	March 2012
Highly Active Pt ₃ Pb and Core–Shell Pt ₃ Pb–Pt Electrocatalysts for Formic Acid Oxidation Kang, Yijin; Qi, Liang; Li, Meng ACS Nano, Vol. 6, Issue 3 https://doi.org/10.1021/nn3003373	journal	February 2012
Atomic scale deposition of Pt around Au nanoparticles to achieve much enhanced electrocatalysis of Pt Xi, Zheng; Lv, Haifeng; Erdosy, Daniel P. Nanoscale, Vol. 9, Issue 23 https://doi.org/10.1039/C7NR02711G	journal	January 2017
A first principles comparison of the mechanism and site requirements for the electrocatalytic oxidation of methanol and formic acid over Pt Neurock, Matthew; Janik, Michael; Wieckowski, Andrzej Faraday Discuss., Vol. 140 https://doi.org/10.1039/B804591G	journal	January 2009
Insights into the Preference of CO ₂ Formation from HCOOH Decomposition on Pd Surface: A Theoretical Study Zhang, Riguang; Liu, Hongyan; Wang, Baojun The Journal of Physical Chemistry C, Vol. 116, Issue 42 https://doi.org/10.1021/jp211900z	journal	October 2012
Pd Nanoparticles Coupled to WO _2.72 Nanorods for Enhanced Electrochemical Oxidation of Formic Acid Xi, Zheng; Erdosy, Daniel P.; Mendoza-Garcia, Adriana Nano Letters, Vol. 17, Issue 4 https://doi.org/10.1021/acs.nanolett.7b00870	journal	March 2017
Freestanding palladium nanosheets with plasmonic and catalytic properties Huang, Xiaoqing; Tang, Shaoheng; Mu, Xiaoliang Nature Nanotechnology, Vol. 6, Issue 1 https://doi.org/10.1038/nnano.2010.235	journal	December 2010
A Comprehensive Study of Formic Acid Oxidation on Palladium Nanocrystals with Different Types of Facets and Twin Defects Choi, Sang-Il; Herron, Jeffrey A.; Scaranto, Jessica ChemCatChem, Vol. 7, Issue 14 https://doi.org/10.1002/cctc.201500094	journal	April 2015
An Effective Pd-Ni ₂ P/C Anode Catalyst for Direct Formic Acid Fuel Cells Chang, Jinfa; Feng, Ligang; Liu, Changpeng Angewandte Chemie International Edition, Vol. 53, Issue 1 https://doi.org/10.1002/anie.201308620	journal	November 2013
Electrocatalysis of formic acid on palladium and platinum surfaces: from fundamental mechanisms to fuel cell applications Jiang, Kun; Zhang, Han-Xuan; Zou, Shouzhong Phys. Chem. Chem. Phys., Vol. 16, Issue 38 https://doi.org/10.1039/C4CP03151B	journal	January 2014
A Facile Synthesis of MPd (M = Co, Cu) Nanoparticles and Their Catalysis for Formic Acid Oxidation Mazumder, Vismadeb; Chi, Miaofang; Mankin, Max N. Nano Letters, Vol. 12, Issue 2 https://doi.org/10.1021/nl2045588	journal	January 2012
A facile route to monodisperse MPd (M = Co or Cu) alloy nanoparticles and their catalysis for electrooxidation of formic acid Ho, Sally Fae; Mendoza-Garcia, Adriana; Guo, Shaojun Nanoscale, Vol. 6, Issue 12 https://doi.org/10.1039/C4NR01107D	journal	January 2014
Tuning Selectivity of CO ₂ Hydrogenation Reactions at the Metal/Oxide Interface Kattel, Shyam; Liu, Ping; Chen, Jingguang G. Journal of the American Chemical Society, Vol. 139, Issue 29 https://doi.org/10.1021/jacs.7b05362	journal	July 2017
A Pd/C-CeO ₂ Anode Catalyst for High-Performance Platinum-Free Anion Exchange Membrane Fuel Cells Miller, Hamish A.; Lavacchi, Alessandro; Vizza, Francesco Angewandte Chemie International Edition, Vol. 55, Issue 20 https://doi.org/10.1002/anie.201600647	journal	April 2016
Photochemical route for synthesizing atomically dispersed palladium catalysts Liu, P.; Zhao, Y.; Qin, R. Science, Vol. 352, Issue 6287 https://doi.org/10.1126/science.aaf5251	journal	May 2016
Palladium-tin catalysts for the direct synthesis of H2O2 with high selectivity Freakley, S. J.; He, Q.; Harrhy, J. H. Science, Vol. 351, Issue 6276 https://doi.org/10.1126/science.aad5705	journal	February 2016
Poisoning effect diminished on a novel PdHoOx/C catalyst for the electrooxidation of formic acid Feng, Ligang; Sun, Xiujuan; Liu, Changpeng Chem. Commun., Vol. 48, Issue 3 https://doi.org/10.1039/C1CC16522D	journal	January 2012
Efficient electrooxidation of methanol and ethanol using MoOx-decorated Pd catalysts in alkaline media Lim, Eun Ja; Kim, Hyung Ju; Kim, Won Bae Catalysis Communications, Vol. 25 https://doi.org/10.1016/j.catcom.2012.04.011	journal	August 2012
Ultrathin W18O49 Nanowires with Diameters below 1 nm: Synthesis, Near-Infrared Absorption, Photoluminescence, and Photochemical Reduction of Carbon Dioxide Xi, Guangcheng; Ouyang, Shuxin; Li, Peng Angewandte Chemie International Edition, Vol. 51, Issue 10 https://doi.org/10.1002/anie.201107681	journal	January 2012
Size-Dependent Disorder–Order Transformation in the Synthesis of Monodisperse Intermetallic PdCu Nanocatalysts Wang, Chenyu; Chen, Dennis P.; Sang, Xiahan ACS Nano, Vol. 10, Issue 6 https://doi.org/10.1021/acsnano.6b02669	journal	May 2016
Surfactant-Induced Postsynthetic Modulation of Pd Nanoparticle Crystallinity Liu, Yi; Wang, Chao; Wei, Yujie Nano Letters, Vol. 11, Issue 4 https://doi.org/10.1021/nl104548g	journal	April 2011
Ordered PdCu-Based Nanoparticles as Bifunctional Oxygen-Reduction and Ethanol-Oxidation Electrocatalysts Jiang, Kezhu; Wang, Pengtang; Guo, Shaojun Angewandte Chemie International Edition, Vol. 55, Issue 31 https://doi.org/10.1002/anie.201603022	journal	June 2016
AgPd Nanoparticles Deposited on WO _2.72 Nanorods as an Efficient Catalyst for One-Pot Conversion of Nitrophenol/Nitroacetophenone into Benzoxazole/Quinazoline Yu, Chao; Guo, Xuefeng; Xi, Zheng Journal of the American Chemical Society, Vol. 139, Issue 16 https://doi.org/10.1021/jacs.7b01983	journal	April 2017
NixWO2.72 nanorods as an efficient electrocatalyst for oxygen evolution reaction Xi, Zheng; Mendoza-Garcia, Adriana; Zhu, Huiyuan Green Energy & Environment, Vol. 2, Issue 2 https://doi.org/10.1016/j.gee.2017.01.001	journal	April 2017
Strongly Coupled Pd Nanotetrahedron/Tungsten Oxide Nanosheet Hybrids with Enhanced Catalytic Activity and Stability as Oxygen Reduction Electrocatalysts Lu, Yizhong; Jiang, Yuanyuan; Gao, Xiaohui Journal of the American Chemical Society, Vol. 136, Issue 33 https://doi.org/10.1021/ja5041094	journal	August 2014
Tuning Sn-Catalysis for Electrochemical Reduction of CO ₂ to CO via the Core/Shell Cu/SnO ₂ Structure Li, Qing; Fu, Jiaju; Zhu, Wenlei Journal of the American Chemical Society, Vol. 139, Issue 12 https://doi.org/10.1021/jacs.7b00261	journal	March 2017
Interfacial electronic effects control the reaction selectivity of platinum catalysts Chen, Guangxu; Xu, Chaofa; Huang, Xiaoqing Nature Materials, Vol. 15, Issue 5 https://doi.org/10.1038/nmat4555	journal	January 2016
Engineering Interface and Surface of Noble Metal Nanoparticle Nanotubes toward Enhanced Catalytic Activity for Fuel Cell Applications Cui, Chun-Hua; Yu, Shu-Hong Accounts of Chemical Research, Vol. 46, Issue 7 https://doi.org/10.1021/ar300254b	journal	February 2013
Core/Shell Face-Centered Tetragonal FePd/Pd Nanoparticles as an Efficient Non-Pt Catalyst for the Oxygen Reduction Reaction Jiang, Guangming; Zhu, Huiyuan; Zhang, Xu ACS Nano, Vol. 9, Issue 11 https://doi.org/10.1021/acsnano.5b04361	journal	October 2015
Highly crystalline PtCu nanotubes with three dimensional molecular accessible and restructured surface for efficient catalysis Li, Hui-Hui; Fu, Qi-Qi; Xu, Liang Energy & Environmental Science, Vol. 10, Issue 8 https://doi.org/10.1039/C7EE00573C	journal	January 2017
Synthesis of Low Pt-Based Quaternary PtPdRuTe Nanotubes with Optimized Incorporation of Pd for Enhanced Electrocatalytic Activity Ma, Si-Yue; Li, Hui-Hui; Hu, Bi-Cheng Journal of the American Chemical Society, Vol. 139, Issue 16 https://doi.org/10.1021/jacs.7b01482	journal	April 2017

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Hyperbranched PdRu nanospine assemblies: an efficient electrocatalyst for formic acid oxidation Wang, Hongjing; Li, Yinghao; Li, Chunjie Journal of Materials Chemistry A, Vol. 6, Issue 36 https://doi.org/10.1039/c8ta06908e	journal	January 2018
Role of Ultrathin Carbon Shell in Enhancing the Performance of PtZn Intermetallic Nanoparticles as an Anode Electrocatalyst for Direct Formic Acid Fuel Cells Xu, Min; Zhao, Yufei; Chen, Hong ChemElectroChem, Vol. 6, Issue 8 https://doi.org/10.1002/celc.201900332	journal	April 2019
Recent Advances on Controlled Synthesis and Engineering of Hollow Alloyed Nanotubes for Electrocatalysis Li, Hui‐Hui; Yu, Shu‐Hong Advanced Materials, Vol. 31, Issue 38 https://doi.org/10.1002/adma.201803503	journal	July 2018
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Synergistic Activation of Palladium Nanoparticles by Polyoxometalate-Attached Melem for Boosting Formic Acid Dehydrogenation Efficiency Leng, Yan; Zhang, Chenjun; Liu, Bing ChemSusChem, Vol. 11, Issue 19 https://doi.org/10.1002/cssc.201801521	journal	September 2018
Ultrathin‐Carbon‐Layer‐Protected PtCu Nanoparticles Encapsulated in Carbon Capsules: A Structure Engineering of the Anode Electrocatalyst for Direct Formic Acid Fuel Cells Xu, Min; Chen, Hong; Zhao, Yufei Particle & Particle Systems Characterization, Vol. 36, Issue 7 https://doi.org/10.1002/ppsc.201900100	journal	May 2019
From monometallic Au nanowires to trimetallic AuPtRh nanowires: interface control for the formic acid electrooxidation Li, Fumin; Ding, Yu; Xiao, Xue Journal of Materials Chemistry A, Vol. 6, Issue 35 https://doi.org/10.1039/c8ta05710a	journal	January 2018
Treelike two-level Pd _x Ag _y nanocrystals tailored for bifunctional fuel cell electrocatalysis Jiang, Xian; Xiong, Yuexin; Wang, Yufei Journal of Materials Chemistry A, Vol. 7, Issue 10 https://doi.org/10.1039/c8ta11538a	journal	January 2019
Broadband photocatalysis using a Z-scheme heterojunction of Au/NaYF ₄ :Yb,Er/WO ₃ ·0.33H ₂ O-W ₁₈ O ₄₉ via a synergetic strategy of upconversion function and plasmonic effect Li, Xiaoxiao; Yang, Kai; Yu, Changlin Inorganic Chemistry Frontiers, Vol. 6, Issue 11 https://doi.org/10.1039/c9qi00823c	journal	January 2019
A radical capture mechanism for immediate Csp 2 –H bond hydroxylation via a heterogeneous Cu–graphene catalyst Sun, Wei; Gao, Lingfeng; Zheng, Gengxiu Chemical Communications, Vol. 55, Issue 61 https://doi.org/10.1039/c9cc02906k	journal	January 2019
Mesoporous Decoration of Freestanding Palladium Nanotube Arrays Boosts the Electrocatalysis Capabilities toward Formic Acid and Formate Oxidation Ding, Jia; Liu, Zhi; Liu, Xiaorui Advanced Energy Materials, Vol. 9, Issue 25 https://doi.org/10.1002/aenm.201900955	journal	May 2019
Core–shell CuPd@Pd tetrahedra with concave structures and Pd-enriched surface boost formic acid oxidation Chen, Yifan; Yang, Yifan; Fu, Gengtao Journal of Materials Chemistry A, Vol. 6, Issue 23 https://doi.org/10.1039/c8ta03322f	journal	January 2018
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Title: Stabilizing CuPd Nanoparticles via CuPd Coupling to WO_2.72 Nanorods in Electrochemical Oxidation of Formic Acid