Application of the 226Ra–230Th–234U and 227Ac–231Pa–235U radiochronometers to uranium certified reference materials

Rolison, John M.; Treinen, Kerri C.; McHugh, Kelly C.; Gaffney, Amy M.; Williams, Ross W.

doi:10.1007/s10967-017-5619-x

Title: Application of the ²²⁶Ra–²³⁰Th–²³⁴U and ²²⁷Ac–²³¹Pa–²³⁵U radiochronometers to uranium certified reference materials

Abstract

Uranium certified reference materials (CRM) issued by New Brunswick Laboratory were subjected to dating using four independent uranium-series radiochronometers. In all cases, there was acceptable agreement between the model ages calculated using the ²³¹Pa–²³⁵U, ²³⁰Th–²³⁴U, ²²⁷Ac–²³⁵U or ²²⁶Ra–²³⁴U radiochronometers and either the certified ²³⁰Th–²³⁴U model date (CRM 125-A and CRM U630), or the known purification date (CRM U050 and CRM U100). Finally, the agreement between the four independent radiochronometers establishes these uranium certified reference materials as ideal informal standards for validating dating techniques utilized in nuclear forensic investigations in the absence of standards with certified model ages for multiple radiochronometers.

Authors:

^[1]; Treinen, Kerri C. ^[1]; McHugh, Kelly C. ^[1]; Gaffney, Amy M. ^[1]; Williams, Ross W. ^[1]

Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States). Nuclear and Chemical Sciences Division. Physical and Life Sciences Directorate

Publication Date:: Mon Nov 06 00:00:00 EST 2017

Research Org.:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Org.:: USDOE; Dept. of Homeland Security (DHS) (United States)

OSTI Identifier:: 1424080

Report Number(s):: LLNL-JRNL-737009
Journal ID: ISSN 0236-5731; TRN: US1801901

Grant/Contract Number:: AC52-07NA27344

Resource Type:: Journal Article: Accepted Manuscript

Journal Name:: Journal of Radioanalytical and Nuclear Chemistry

Additional Journal Information:: Journal Volume: 314; Journal Issue: 3; Journal ID: ISSN 0236-5731

Publisher:: Springer

Country of Publication:: United States

Language:: English

Subject:: 38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; U-series radiochronometry; nuclear forensics; age-dating; 226Ra; 227Ac

Citation Formats


                    Rolison, John M., Treinen, Kerri C., McHugh, Kelly C., Gaffney, Amy M., and Williams, Ross W. Application of the 226Ra–230Th–234U and 227Ac–231Pa–235U radiochronometers to uranium certified reference materials.  United States: N. p., 2017. 
        Web.  doi:10.1007/s10967-017-5619-x.

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                    Rolison, John M., Treinen, Kerri C., McHugh, Kelly C., Gaffney, Amy M., & Williams, Ross W. Application of the 226Ra–230Th–234U and 227Ac–231Pa–235U radiochronometers to uranium certified reference materials.  United States.  https://doi.org/10.1007/s10967-017-5619-x

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                    Rolison, John M., Treinen, Kerri C., McHugh, Kelly C., Gaffney, Amy M., and Williams, Ross W. 2017.  
        "Application of the 226Ra–230Th–234U and 227Ac–231Pa–235U radiochronometers to uranium certified reference materials".  United States.  https://doi.org/10.1007/s10967-017-5619-x.  https://www.osti.gov/servlets/purl/1424080.

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@article{osti_1424080,

  title        = {Application of the 226Ra–230Th–234U and 227Ac–231Pa–235U radiochronometers to uranium certified reference materials},

  author       = {Rolison, John M. and Treinen, Kerri C. and McHugh, Kelly C. and Gaffney, Amy M. and Williams, Ross W.},

  abstractNote = {Uranium certified reference materials (CRM) issued by New Brunswick Laboratory were subjected to dating using four independent uranium-series radiochronometers. In all cases, there was acceptable agreement between the model ages calculated using the 231Pa–235U, 230Th–234U, 227Ac–235U or 226Ra–234U radiochronometers and either the certified 230Th–234U model date (CRM 125-A and CRM U630), or the known purification date (CRM U050 and CRM U100). Finally, the agreement between the four independent radiochronometers establishes these uranium certified reference materials as ideal informal standards for validating dating techniques utilized in nuclear forensic investigations in the absence of standards with certified model ages for multiple radiochronometers.},

  doi          = {10.1007/s10967-017-5619-x},

  url          = {https://www.osti.gov/biblio/1424080},
  journal      = {Journal of Radioanalytical and Nuclear Chemistry},

  issn         = {0236-5731},

  number       = 3,

  volume       = 314,

  place        = {United States},

  year         = {Mon Nov 06 00:00:00 EST 2017},

  month        = {Mon Nov 06 00:00:00 EST 2017}

}

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Works referenced in this record:

Precision Measurement of Half-Lives and Specific Activities of ${}^{235}U$ and ${}^{238}U$
journal, November 1971

Jaffey, A. H.; Flynn, K. F.; Glendenin, L. E.
Physical Review C, Vol. 4, Issue 5
https://doi.org/10.1103/PhysRevC.4.1889

235U–231Pa age dating of uranium materials for nuclear forensic investigations
journal, January 2013

Eppich, Gary R.; Williams, Ross W.; Gaffney, Amy M.
Journal of Analytical Atomic Spectrometry, Vol. 28, Issue 5
https://doi.org/10.1039/c3ja50041a

Round-robin 230Th–234U age dating of bulk uranium for nuclear forensics
journal, July 2015

Gaffney, Amy M.; Hubert, Amélie; Kinman, William S.
Journal of Radioanalytical and Nuclear Chemistry, Vol. 307, Issue 3
https://doi.org/10.1007/s10967-015-4334-8

Evaluation of chronometers in plutonium age determination for nuclear forensics: What if the ‘Pu/U clocks’ do not match?
journal, July 2014

Sturm, M.; Richter, S.; Aregbe, Y.
Journal of Radioanalytical and Nuclear Chemistry, Vol. 302, Issue 1
https://doi.org/10.1007/s10967-014-3294-8

Nuclear Forensic Analysis
book, February 2005

Moody, Kenton J.; Grant, Patrick M.; Hutcheon, Ian D.
https://doi.org/10.1201/9780203507803

Developing 226Ra and 227Ac age-dating techniques for nuclear forensics to gain insight from concordant and non-concordant radiochronometers
journal, September 2015

Kayzar, Theresa M.; Williams, Ross W.
Journal of Radioanalytical and Nuclear Chemistry, Vol. 307, Issue 3
https://doi.org/10.1007/s10967-015-4435-4

Age Determination of Highly Enriched Uranium: Separation and Analysis of ²³¹ Pa
journal, November 2002

Morgenstern, A.; Apostolidis, C.; Mayer, K.
Analytical Chemistry, Vol. 74, Issue 21
https://doi.org/10.1021/ac0203948

The half-lives of uranium-234 and thorium-230
journal, August 2000

Cheng, H.; Edwards, R. L.; Hoff, J.
Chemical Geology, Vol. 169, Issue 1-2
https://doi.org/10.1016/S0009-2541(99)00157-6

Works referencing / citing this record:

Application of the 226Ra–230Th–234U and 227Ac–231Pa–235U radiochronometers to UF6 cylinders
journal, June 2018

Rolison, John M.; Williams, Ross W.
Journal of Radioanalytical and Nuclear Chemistry, Vol. 317, Issue 2
https://doi.org/10.1007/s10967-018-5955-5

Production and standardization of an on-demand protactinium-233 tracer
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Naperstkow, Zoya; Moore, Kimberly; Szames, Daniel
Journal of Radioanalytical and Nuclear Chemistry, Vol. 318, Issue 1
https://doi.org/10.1007/s10967-018-6068-x

A case study in plutonium radiochronometry using multiple isotope systems
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Gaffney, Amy M.; Wimpenny, Josh B. N.; Parsons-Davis, Tashi
Journal of Radioanalytical and Nuclear Chemistry, Vol. 318, Issue 1
https://doi.org/10.1007/s10967-018-6131-7

Improved protactinium spike calibration method applied to 231Pa–235U age-dating of certified reference materials for nuclear forensics
journal, August 2018

Treinen, Kerri C.; Gaffney, Amy M.; Rolison, John M.
Journal of Radioanalytical and Nuclear Chemistry, Vol. 318, Issue 1
https://doi.org/10.1007/s10967-018-6149-x

Evaluating uranium radiochronometry by single-collector mass spectrometry for nuclear forensics: a multi-instrument investigation
journal, October 2019

Treinen, Kerri C.; Samperton, Kyle M.; Lindvall, Rachel E.
Journal of Radioanalytical and Nuclear Chemistry, Vol. 322, Issue 3
https://doi.org/10.1007/s10967-019-06832-y

An interlaboratory collaboration to determine consensus 231Pa/235U model ages of a uranium certified reference material for nuclear forensics
journal, February 2020

Kayzar-Boggs, Theresa M.; Treinen, Kerri C.; Okubo, Ayako
Journal of Radioanalytical and Nuclear Chemistry, Vol. 323, Issue 3
https://doi.org/10.1007/s10967-020-07030-x

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Similar Records

Title: Application of the 226Ra–230Th–234U and 227Ac–231Pa–235U radiochronometers to uranium certified reference materials

Abstract

Citation Formats

Precision Measurement of Half-Lives and Specific Activities of U 235 and U 238 journal, November 1971

235U–231Pa age dating of uranium materials for nuclear forensic investigations journal, January 2013

Round-robin 230Th–234U age dating of bulk uranium for nuclear forensics journal, July 2015

Evaluation of chronometers in plutonium age determination for nuclear forensics: What if the ‘Pu/U clocks’ do not match? journal, July 2014

Nuclear Forensic Analysis book, February 2005

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Age Determination of Highly Enriched Uranium: Separation and Analysis of 231 Pa journal, November 2002

The half-lives of uranium-234 and thorium-230 journal, August 2000

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Production and standardization of an on-demand protactinium-233 tracer journal, August 2018

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Title: Application of the ²²⁶Ra–²³⁰Th–²³⁴U and ²²⁷Ac–²³¹Pa–²³⁵U radiochronometers to uranium certified reference materials

Precision Measurement of Half-Lives and Specific Activities of ${}^{235}U$ and ${}^{238}U$
journal, November 1971

235U–231Pa age dating of uranium materials for nuclear forensic investigations
journal, January 2013

Round-robin 230Th–234U age dating of bulk uranium for nuclear forensics
journal, July 2015

Evaluation of chronometers in plutonium age determination for nuclear forensics: What if the ‘Pu/U clocks’ do not match?
journal, July 2014

Nuclear Forensic Analysis
book, February 2005

Developing 226Ra and 227Ac age-dating techniques for nuclear forensics to gain insight from concordant and non-concordant radiochronometers
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Age Determination of Highly Enriched Uranium: Separation and Analysis of ²³¹ Pa
journal, November 2002

The half-lives of uranium-234 and thorium-230
journal, August 2000

Application of the 226Ra–230Th–234U and 227Ac–231Pa–235U radiochronometers to UF6 cylinders
journal, June 2018

Production and standardization of an on-demand protactinium-233 tracer
journal, August 2018

A case study in plutonium radiochronometry using multiple isotope systems
journal, August 2018

Improved protactinium spike calibration method applied to 231Pa–235U age-dating of certified reference materials for nuclear forensics
journal, August 2018

Evaluating uranium radiochronometry by single-collector mass spectrometry for nuclear forensics: a multi-instrument investigation
journal, October 2019

An interlaboratory collaboration to determine consensus 231Pa/235U model ages of a uranium certified reference material for nuclear forensics
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