Effects of redox-active interlayer anions on the oxygen evolution reactivity of NiFe-layered double hydroxide nanosheets

Zhou, Daojin; Cai, Zhao; Bi, Yongmin; Tian, Weiliang; Luo, Ma; Zhang, Qian; Zhang, Qian; Xie, Qixian; Wang, Jindi; Li, Yaping; Kuang, Yun; Duan, Xue; Bajdich, Michal; Siahrostami, Samira; Sun, Xiaoming

doi:10.1007/s12274-017-1750-9

Title: Effects of redox-active interlayer anions on the oxygen evolution reactivity of NiFe-layered double hydroxide nanosheets

Journal Article · Fri Feb 02 00:00:00 EST 2018 · Nano Research

DOI:https://doi.org/10.1007/s12274-017-1750-9· OSTI ID:1423519

Zhou, Daojin ^[1]; Cai, Zhao ^[1]; Bi, Yongmin ^[1]; Tian, Weiliang ^[2]; Luo, Ma ^[1]; Zhang, Qian ^[1]; Zhang, Qian ^[1]; Xie, Qixian ^[1]; Wang, Jindi ^[1]; Li, Yaping ^[1]; Kuang, Yun ^[1]; Duan, Xue ^[1]; Bajdich, Michal ^[3]; Siahrostami, Samira ^[4]; Sun, Xiaoming ^[1]

Beijing Univ. of Chemical Technology, Beijing (China). State Key Lab. of Chemical Resource Engineering, College of Energy, Beijing Advanced Innovation Center for Soft Matter Science and Engineering
Beijing Univ. of Chemical Technology, Beijing (China). State Key Lab. of Chemical Resource Engineering, College of Energy, Beijing Advanced Innovation Center for Soft Matter Science and Engineering; Tarim Univ., Alar (China). Key Lab. of Chemical Engineering in South Xinjiang, College of Life Science
SLAC National Accelerator Lab., Menlo Park, CA (United States). SUNCAT Center for Interface Science and Catalysis
Stanford Univ., CA (United States). SUNCAT Center for Interface Science and Catalysis, Dept. of Chemical Engineering

Nickel-iron layered double hydroxide (NiFe-LDH) nanosheets have shown optimal oxygen evolution reaction (OER) performance; however, the role of the intercalated ions in the OER activity remains unclear. In this work, we show that the activity of the NiFe-LDHs can be tailored by the intercalated anions with different redox potentials. The intercalation of anions with low redox potential (high reducing ability), such as hypophosphites, leads to NiFe-LDHs with low OER overpotential of 240 mV and a small Tafel slope of 36.9 mV/dec, whereas NiFe-LDHs intercalated with anions of high redox potential (low reducing ability), such as fluorion, show a high overpotential of 370 mV and a Tafel slope of 80.8 mV/dec. The OER activity shows a surprising linear correlation with the standard redox potential. Density functional theory calculations and X-ray photoelectron spectroscopy analysis indicate that the intercalated anions alter the electronic structure of metal atoms which exposed at the surface. Anions with low standard redox potential and strong reducing ability transfer more electrons to the hydroxide layers. Finally, this increases the electron density of the surface metal sites and stabilizes their high-valence states, whose formation is known as the critical step prior to the OER process.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: SLAC National Accelerator Lab., Menlo Park, CA (United States)

Sponsoring Organization:: USDOE; National Natural Science Foundation of China (NSFC)

Grant/Contract Number:: AC02-76SF00515

OSTI ID:: 1423519

Journal Information:: Nano Research, Vol. 11, Issue 3; ISSN 1998-0124

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 110 works

Citation information provided by
Web of Science

References (63)

Ultrathin Cobalt–Manganese Layered Double Hydroxide Is an Efficient Oxygen Evolution Catalyst Song, Fang; Hu, Xile Journal of the American Chemical Society, Vol. 136, Issue 47 https://doi.org/10.1021/ja5096733	journal	November 2014
Benchmarking Hydrogen Evolving Reaction and Oxygen Evolving Reaction Electrocatalysts for Solar Water Splitting Devices McCrory, Charles C. L.; Jung, Suho; Ferrer, Ivonne M. Journal of the American Chemical Society, Vol. 137, Issue 13 https://doi.org/10.1021/ja510442p	journal	March 2015
The Stability Challenges of Oxygen Evolving Catalysts: Towards a Common Fundamental Understanding and Mitigation of Catalyst Degradation Spöri, Camillo; Kwan, Jason Tai Hong; Bonakdarpour, Arman Angewandte Chemie International Edition, Vol. 56, Issue 22 https://doi.org/10.1002/anie.201608601	journal	May 2017
Revised Oxygen Evolution Reaction Activity Trends for First-Row Transition-Metal (Oxy)hydroxides in Alkaline Media Burke, Michaela S.; Zou, Shihui; Enman, Lisa J. The Journal of Physical Chemistry Letters, Vol. 6, Issue 18 https://doi.org/10.1021/acs.jpclett.5b01650	journal	August 2015
Three-Dimensional N-Doped Graphene Hydrogel/NiCo Double Hydroxide Electrocatalysts for Highly Efficient Oxygen Evolution Chen, Sheng; Duan, Jingjing; Jaroniec, Mietek Angewandte Chemie International Edition, Vol. 52, Issue 51 https://doi.org/10.1002/anie.201306166	journal	November 2013
A mini review of NiFe-based materials as highly active oxygen evolution reaction electrocatalysts Gong, Ming; Dai, Hongjie Nano Research, Vol. 8, Issue 1 https://doi.org/10.1007/s12274-014-0591-z	journal	November 2014
Optimizing Perovskites for the Water-Splitting Reaction Vojvodic, A.; Norskov, J. K. Science, Vol. 334, Issue 6061 https://doi.org/10.1126/science.1215081	journal	December 2011
Inverse spinel NiFeAlO4 as a highly active oxygen evolution electrocatalyst: promotion of activity by a redox-inert metal ion Chen, Jamie Y. C.; Miller, Jeffrey T.; Gerken, James B. Energy & Environmental Science, Vol. 7, Issue 4 https://doi.org/10.1039/c3ee43811b	journal	January 2014
Comparing Electrochemical and Biological Water Splitting Rossmeisl, J.; Dimitrievski, K.; Siegbahn, P. The Journal of Physical Chemistry C, Vol. 111, Issue 51 https://doi.org/10.1021/jp077210j	journal	December 2007
Layered assembly of graphene oxide and Co–Al layered double hydroxide nanosheets as electrode materials for supercapacitors Wang, Lei; Wang, Dong; Dong, Xin Yi Chemical Communications, Vol. 47, Issue 12 https://doi.org/10.1039/c0cc05420h	journal	January 2011
Double perovskites as a family of highly active catalysts for oxygen evolution in alkaline solution Grimaud, Alexis; May, Kevin J.; Carlton, Christopher E. Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3439	journal	September 2013
Infrared Absorption Spectra of Minerals and Other Inorganic Compounds Hunt, J. M.; Wisherd, M. P.; Bonham, L. C. Analytical Chemistry, Vol. 22, Issue 12 https://doi.org/10.1021/ac60048a006	journal	December 1950
Ultrathin nickel–iron layered double hydroxide nanosheets intercalated with molybdate anions for electrocatalytic water oxidation Han, Na; Zhao, Feipeng; Li, Yanguang Journal of Materials Chemistry A, Vol. 3, Issue 31 https://doi.org/10.1039/C5TA03394B	journal	January 2015
Phosphorus oxoanion-intercalated layered double hydroxides for high-performance oxygen evolution Luo, Ma; Cai, Zhao; Wang, Cheng Nano Research, Vol. 10, Issue 5 https://doi.org/10.1007/s12274-017-1437-2	journal	February 2017
Rapid room-temperature synthesis of nanocrystalline spinels as oxygen reduction and evolution electrocatalysts Cheng, Fangyi; Shen, Jian; Peng, Bo Nature Chemistry, Vol. 3, Issue 1 https://doi.org/10.1038/nchem.931	journal	December 2010
Biotemplated Hierarchical Nanostructure of Layered Double Hydroxides with Improved Photocatalysis Performance Zhao, Yufei; Wei, Min; Lu, Jun ACS Nano, Vol. 3, Issue 12 https://doi.org/10.1021/nn901055d	journal	November 2009
Hierarchical Nanocomposites Derived from Nanocarbons and Layered Double Hydroxides - Properties, Synthesis, and Applications Zhao, Meng-Qiang; Zhang, Qiang; Huang, Jia-Qi Advanced Functional Materials, Vol. 22, Issue 4 https://doi.org/10.1002/adfm.201102222	journal	January 2012
Guidelines for the Rational Design of Ni-Based Double Hydroxide Electrocatalysts for the Oxygen Evolution Reaction Diaz-Morales, Oscar; Ledezma-Yanez, Isis; Koper, Marc T. M. ACS Catalysis, Vol. 5, Issue 9 https://doi.org/10.1021/acscatal.5b01638	journal	August 2015
An Advanced Ni–Fe Layered Double Hydroxide Electrocatalyst for Water Oxidation Gong, Ming; Li, Yanguang; Wang, Hailiang Journal of the American Chemical Society, Vol. 135, Issue 23 https://doi.org/10.1021/ja4027715	journal	May 2013
A Graphene Oxide and Copper-Centered Metal Organic Framework Composite as a Tri-Functional Catalyst for HER, OER, and ORR Jahan, Maryam; Liu, Zhaolin; Loh, Kian Ping Advanced Functional Materials, Vol. 23, Issue 43 https://doi.org/10.1002/adfm.201300510	journal	May 2013
Preparation of Ni ²⁺ −Fe ³⁺ Layered Double Hydroxide Material with High Crystallinity and Well-Defined Hexagonal Shapes Han, Yinfeng; Liu, Zong-Huai; Yang, Zupei Chemistry of Materials, Vol. 20, Issue 2 https://doi.org/10.1021/cm7023789	journal	January 2008
Spatially Confined Hybridization of Nanometer-Sized NiFe Hydroxides into Nitrogen-Doped Graphene Frameworks Leading to Superior Oxygen Evolution Reactivity Tang, Cheng; Wang, Han-Sen; Wang, Hao-Fan Advanced Materials, Vol. 27, Issue 30 https://doi.org/10.1002/adma.201501901	journal	June 2015
Infrared Spectra and Characteristic Frequencies of Inorganic Ions Miller, F. A.; Wilkins, C. H. Analytical Chemistry, Vol. 24, Issue 8 https://doi.org/10.1021/ac60068a007	journal	August 1952
An Approach to Understanding the Electrocatalytic Activity Enhancement by Superexchange Interaction toward OER in Alkaline Media of Ni–Fe LDH Oliver-Tolentino, Miguel A.; Vázquez-Samperio, Juvencio; Manzo-Robledo, Arturo The Journal of Physical Chemistry C, Vol. 118, Issue 39 https://doi.org/10.1021/jp506946b	journal	September 2014
Ni ₂ P as a Janus catalyst for water splitting: the oxygen evolution activity of Ni ₂ P nanoparticles Stern, Lucas-Alexandre; Feng, Ligang; Song, Fang Energy & Environmental Science, Vol. 8, Issue 8 https://doi.org/10.1039/C5EE01155H	journal	January 2015
A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital Principles Suntivich, J.; May, K. J.; Gasteiger, H. A. Science, Vol. 334, Issue 6061 https://doi.org/10.1126/science.1212858	journal	October 2011
Artificial Nacre-like Bionanocomposite Films from the Self-Assembly of Chitosan-Montmorillonite Hybrid Building Blocks Yao, Hong-Bin; Tan, Zhi-Hua; Fang, Hai-Yu Angewandte Chemie International Edition, Vol. 49, Issue 52 https://doi.org/10.1002/anie.201004748	journal	November 2010
Enhanced Activity of Gold-Supported Cobalt Oxide for the Electrochemical Evolution of Oxygen Yeo, Boon Siang; Bell, Alexis T. Journal of the American Chemical Society, Vol. 133, Issue 14 https://doi.org/10.1021/ja200559j	journal	April 2011
A Superlattice of Alternately Stacked Ni–Fe Hydroxide Nanosheets and Graphene for Efficient Splitting of Water Ma, Wei; Ma, Renzhi; Wang, Chengxiang ACS Nano, Vol. 9, Issue 2 https://doi.org/10.1021/nn5069836	journal	January 2015
Towards superior oxygen evolution through graphene barriers between metal substrates and hydroxide catalysts Wang, Hao-Fan; Tang, Cheng; Zhang, Qiang Journal of Materials Chemistry A, Vol. 3, Issue 31 https://doi.org/10.1039/C5TA03422A	journal	January 2015
Water Oxidation on Pure and Doped Hematite (0001) Surfaces: Prediction of Co and Ni as Effective Dopants for Electrocatalysis Liao, Peilin; Keith, John A.; Carter, Emily A. Journal of the American Chemical Society, Vol. 134, Issue 32 https://doi.org/10.1021/ja301567f	journal	August 2012
Effect of interlayer anions on [NiFe]-LDH nanosheet water oxidation activity Hunter, B. M.; Hieringer, W.; Winkler, J. R. Energy & Environmental Science, Vol. 9, Issue 5 https://doi.org/10.1039/C6EE00377J	journal	January 2016
Synthesis and Activities of Rutile IrO ₂ and RuO ₂ Nanoparticles for Oxygen Evolution in Acid and Alkaline Solutions Lee, Youngmin; Suntivich, Jin; May, Kevin J. The Journal of Physical Chemistry Letters, Vol. 3, Issue 3 https://doi.org/10.1021/jz2016507	journal	January 2012
Hierarchical NiMn Layered Double Hydroxide/Carbon Nanotubes Architecture with Superb Energy Density for Flexible Supercapacitors Zhao, Jingwen; Chen, Jiale; Xu, Simin Advanced Functional Materials, Vol. 24, Issue 20 https://doi.org/10.1002/adfm.201303638	journal	January 2014
Graphene Hybrids: Nitrogen-Doped Graphene/Carbon Nanotube Hybrids: In Situ Formation on Bifunctional Catalysts and Their Superior Electrocatalytic Activity for Oxygen Evolution/Reduction Reaction (Small 11/2014) Tian, Gui-Li; Zhao, Meng-Qiang; Yu, Dingshan Small, Vol. 10, Issue 11 https://doi.org/10.1002/smll.201470063	journal	June 2014
A Strongly Coupled Graphene and FeNi Double Hydroxide Hybrid as an Excellent Electrocatalyst for the Oxygen Evolution Reaction Long, Xia; Li, Jinkai; Xiao, Shuang Angewandte Chemie International Edition, Vol. 53, Issue 29 https://doi.org/10.1002/anie.201402822	journal	June 2014
Ternary NiFeMn layered double hydroxides as highly-efficient oxygen evolution catalysts Lu, Zhiyi; Qian, Li; Tian, Yang Chemical Communications, Vol. 52, Issue 5 https://doi.org/10.1039/C5CC08845C	journal	January 2016
An Investigation of Thin-Film Ni–Fe Oxide Catalysts for the Electrochemical Evolution of Oxygen Louie, Mary W.; Bell, Alexis T. Journal of the American Chemical Society, Vol. 135, Issue 33 https://doi.org/10.1021/ja405351s	journal	August 2013
Recent Advances in the Synthesis and Application of Layered Double Hydroxide (LDH) Nanosheets Wang, Qiang; O’Hare, Dermot Chemical Reviews, Vol. 112, Issue 7 https://doi.org/10.1021/cr200434v	journal	March 2012
Electrocatalytic Oxygen Evolution Reaction (OER) on Ru, Ir, and Pt Catalysts: A Comparative Study of Nanoparticles and Bulk Materials Reier, Tobias; Oezaslan, Mehtap; Strasser, Peter ACS Catalysis, Vol. 2, Issue 8 https://doi.org/10.1021/cs3003098	journal	July 2012
Electrodeposition of hierarchically structured three-dimensional nickel–iron electrodes for efficient oxygen evolution at high current densities Lu, Xunyu; Zhao, Chuan Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7616	journal	March 2015
Transition metal based layered double hydroxides tailored for energy conversion and storage Long, Xia; Wang, Zilong; Xiao, Shuang Materials Today, Vol. 19, Issue 4 https://doi.org/10.1016/j.mattod.2015.10.006	journal	May 2016
Ruthenium dioxide: a new electrode material. I. Behaviour in acid solutions of inert electrolytes Galizzioli, Dario; Tantardini, Franco; Trasatti, Sergio Journal of Applied Electrochemistry, Vol. 4, Issue 1 https://doi.org/10.1007/BF00615906	journal	February 1974
Ordered Mesoporous Cobalt Oxide as Highly Efficient Oxygen Evolution Catalyst Rosen, Jonathan; Hutchings, Gregory S.; Jiao, Feng Journal of the American Chemical Society, Vol. 135, Issue 11 https://doi.org/10.1021/ja400555q	journal	March 2013
Measurement Techniques for the Study of Thin Film Heterogeneous Water Oxidation Electrocatalysts Stevens, Michaela Burke; Enman, Lisa J.; Batchellor, Adam S. Chemistry of Materials, Vol. 29, Issue 1 https://doi.org/10.1021/acs.chemmater.6b02796	journal	October 2016
Changes in the crystal and electronic structure of LiCoO2 and LiNiO2 upon Li intercalation and de-intercalation Laubach, Sonja; Laubach, Stefan; Schmidt, Peter C. Physical Chemistry Chemical Physics, Vol. 11, Issue 17 https://doi.org/10.1039/b901200a	journal	January 2009
Theoretical study of the structure and vibrational spectra of chromyl perchlorate, CrO2(ClO4)2 Brandán, S. A. Journal of Molecular Structure: THEOCHEM, Vol. 908, Issue 1-3 https://doi.org/10.1016/j.theochem.2009.04.042	journal	August 2009
Pulse-Electrodeposited Ni–Fe (Oxy)hydroxide Oxygen Evolution Electrocatalysts with High Geometric and Intrinsic Activities at Large Mass Loadings Batchellor, Adam S.; Boettcher, Shannon W. ACS Catalysis, Vol. 5, Issue 11 https://doi.org/10.1021/acscatal.5b01551	journal	October 2015
Oxidation and Photo-Oxidation of Water on TiO ₂ Surface Valdés, Á.; Qu, Z. -W.; Kroes, G. -J. The Journal of Physical Chemistry C, Vol. 112, Issue 26 https://doi.org/10.1021/jp711929d	journal	June 2008
Amorphous FeOOH Oxygen Evolution Reaction Catalyst for Photoelectrochemical Water Splitting Chemelewski, William D.; Lee, Heung-Chan; Lin, Jung-Fu Journal of the American Chemical Society, Vol. 136, Issue 7 https://doi.org/10.1021/ja411835a	journal	February 2014
NiFe-Based (Oxy)hydroxide Catalysts for Oxygen Evolution Reaction in Non-Acidic Electrolytes Dionigi, Fabio; Strasser, Peter Advanced Energy Materials, Vol. 6, Issue 23 https://doi.org/10.1002/aenm.201600621	journal	July 2016
Oxygen Evolution Reaction Electrocatalysis on Transition Metal Oxides and (Oxy)hydroxides: Activity Trends and Design Principles Burke, Michaela S.; Enman, Lisa J.; Batchellor, Adam S. Chemistry of Materials, Vol. 27, Issue 22 https://doi.org/10.1021/acs.chemmater.5b03148	journal	October 2015
Identification of Highly Active Fe Sites in (Ni,Fe)OOH for Electrocatalytic Water Splitting Friebel, Daniel; Louie, Mary W.; Bajdich, Michal Journal of the American Chemical Society, Vol. 137, Issue 3 https://doi.org/10.1021/ja511559d	journal	January 2015
Layered Perovskite Oxide: A Reversible Air Electrode for Oxygen Evolution/Reduction in Rechargeable Metal-Air Batteries Takeguchi, Tatsuya; Yamanaka, Toshiro; Takahashi, Hiroki Journal of the American Chemical Society, Vol. 135, Issue 30 https://doi.org/10.1021/ja403476v	journal	July 2013
Electrocatalytic Oxygen Evolution Reaction in Acidic Environments - Reaction Mechanisms and Catalysts Reier, Tobias; Nong, Hong Nhan; Teschner, Detre Advanced Energy Materials, Vol. 7, Issue 1 https://doi.org/10.1002/aenm.201601275	journal	October 2016
Iridium-based double perovskites for efficient water oxidation in acid media Diaz-Morales, Oscar; Raaijman, Stefan; Kortlever, Ruud Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms12363	journal	August 2016
Nickel–Iron Oxyhydroxide Oxygen-Evolution Electrocatalysts: The Role of Intentional and Incidental Iron Incorporation Trotochaud, Lena; Young, Samantha L.; Ranney, James K. Journal of the American Chemical Society, Vol. 136, Issue 18 https://doi.org/10.1021/ja502379c	journal	April 2014
Advances in electrocatalysts for oxygen evolution reaction of water electrolysis-from metal oxides to carbon nanotubes Cheng, Yi; Jiang, San Ping Progress in Natural Science: Materials International, Vol. 25, Issue 6 https://doi.org/10.1016/j.pnsc.2015.11.008	journal	December 2015
Exfoliation of layered double hydroxides for enhanced oxygen evolution catalysis Song, Fang; Hu, Xile Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5477	journal	July 2014
Electrochemical tuning of layered lithium transition metal oxides for improvement of oxygen evolution reaction Lu, Zhiyi; Wang, Haotian; Kong, Desheng Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5345	journal	July 2014
Artificial Nacre-like Bionanocomposite Films from the Self-Assembly of Chitosan-Montmorillonite Hybrid Building Blocks Yao, Hong-Bin; Tan, Zhi-Hua; Fang, Hai-Yu Angewandte Chemie, Vol. 122, Issue 52 https://doi.org/10.1002/ange.201004748	journal	November 2010
A Strongly Coupled Graphene and FeNi Double Hydroxide Hybrid as an Excellent Electrocatalyst for the Oxygen Evolution Reaction Long, Xia; Li, Jinkai; Xiao, Shuang Angewandte Chemie, Vol. 126, Issue 29 https://doi.org/10.1002/ange.201402822	journal	June 2014
Three-Dimensional N-Doped Graphene Hydrogel/NiCo Double Hydroxide Electrocatalysts for Highly Efficient Oxygen Evolution Chen, Sheng; Duan, Jingjing; Jaroniec, Mietek Angewandte Chemie, Vol. 125, Issue 51 https://doi.org/10.1002/ange.201306166	journal	November 2013

Cited By (16)

2D Layered Double Hydroxides for Oxygen Evolution Reaction: From Fundamental Design to Application Lv, Lin; Yang, Zhaoxi; Chen, Kun Advanced Energy Materials, Vol. 9, Issue 17 https://doi.org/10.1002/aenm.201803358	journal	March 2019
Recent Development of Ni/Fe‐Based Micro/Nanostructures toward Photo/Electrochemical Water Oxidation Gao, Rui; Yan, Dongpeng Advanced Energy Materials https://doi.org/10.1002/aenm.201900954	journal	May 2019
Layered Metal Hydroxides and Their Derivatives: Controllable Synthesis, Chemical Exfoliation, and Electrocatalytic Applications Chen, Gen; Wan, Hao; Ma, Wei Advanced Energy Materials, Vol. 10, Issue 11 https://doi.org/10.1002/aenm.201902535	journal	November 2019
Advanced Bifunctional Oxygen Reduction and Evolution Electrocatalyst Derived from Surface‐Mounted Metal–Organic Frameworks Li, Weijin; Xue, Song; Watzele, Sebastian Angewandte Chemie, Vol. 132, Issue 14 https://doi.org/10.1002/ange.201916507	journal	January 2020
Advanced Bifunctional Oxygen Reduction and Evolution Electrocatalyst Derived from Surface‐Mounted Metal–Organic Frameworks Li, Weijin; Xue, Song; Watzele, Sebastian Angewandte Chemie International Edition, Vol. 59, Issue 14 https://doi.org/10.1002/anie.201916507	journal	January 2020
Interface Electronic Coupling in Hierarchical FeLDH(FeCo)/Co(OH) ₂ Arrays for Efficient Electrocatalytic Oxygen Evolution Kong, Fanhao; Zhang, Wenwen; Sun, Liping ChemSusChem, Vol. 12, Issue 15 https://doi.org/10.1002/cssc.201900943	journal	July 2019
One‐Step Synthesis of NiFe Layered Double Hydroxide Nanosheet Array/N‐Doped Graphite Foam Electrodes for Oxygen Evolution Reactions Li, Rui; Xu, Jingsong; Pan, Qifa ChemistryOpen, Vol. 8, Issue 7 https://doi.org/10.1002/open.201900190	journal	July 2019
Environmentally‐Friendly Exfoliate and Active Site Self‐Assembly: Thin 2D/2D Heterostructure Amorphous Nickel–Iron Alloy on 2D Materials for Efficient Oxygen Evolution Reaction Wang, Yuanzhe; Zhou, Yanyan; Han, Minze Small, Vol. 15, Issue 16 https://doi.org/10.1002/smll.201805435	journal	March 2019
Flame-Engraved Nickel-Iron Layered Double Hydroxide Nanosheets for Boosting Oxygen Evolution Reactivity Zhou, Daojin; Xiong, Xuya; Cai, Zhao Small Methods, Vol. 2, Issue 7 https://doi.org/10.1002/smtd.201800083	journal	May 2018
Intercalation Effect in NiAl-layered Double Hydroxide Nanosheets for CO2 Reduction Under Visible Light Kipkorir, Peter; Tan, Ling; Ren, Jing Chemical Research in Chinese Universities, Vol. 36, Issue 1 https://doi.org/10.1007/s40242-020-9096-3	journal	January 2020
Activating basal plane in NiFe layered double hydroxide by Mn ²⁺ doping for efficient and durable oxygen evolution reaction Zhou, Daojin; Cai, Zhao; Jia, Yin Nanoscale Horizons, Vol. 3, Issue 5 https://doi.org/10.1039/c8nh00121a	journal	January 2018
Construction of a hierarchical NiFe layered double hydroxide with a 3D mesoporous structure as an advanced electrocatalyst for water oxidation Yu, Jiahao; Yang, Fulin; Cheng, Gongzhen Inorganic Chemistry Frontiers, Vol. 5, Issue 8 https://doi.org/10.1039/c8qi00314a	journal	January 2018
Recent advances in layered double hydroxide electrocatalysts for the oxygen evolution reaction Cai, Zhengyang; Bu, Xiuming; Wang, Ping Journal of Materials Chemistry A, Vol. 7, Issue 10 https://doi.org/10.1039/c8ta11273h	journal	January 2019
Modulated transition metal–oxygen covalency in the octahedral sites of CoFe layered double hydroxides with vanadium doping leading to highly efficient electrocatalysts Yang, Yibin; Ou, Yingqing; Yang, Yang Nanoscale, Vol. 11, Issue 48 https://doi.org/10.1039/c9nr08795h	journal	January 2019
Solar-driven, highly sustained splitting of seawater into hydrogen and oxygen fuels Kuang, Yun; Kenney, Michael J.; Meng, Yongtao Proceedings of the National Academy of Sciences, Vol. 116, Issue 14 https://doi.org/10.1073/pnas.1900556116	journal	March 2019
Highly active oxygen evolution integrated with efficient CO ₂ to CO electroreduction Meng, Yongtao; Zhang, Xiao; Hung, Wei-Hsuan Proceedings of the National Academy of Sciences, Vol. 116, Issue 48 https://doi.org/10.1073/pnas.1915319116	journal	November 2019

Figures / Tables (8)

Similar Records

Revealing the effect of interfacial electron transfer in heterostructured Co₉S₈@NiFe LDH for enhanced electrocatalytic oxygen evolution

Journal Article · Thu Apr 29 00:00:00 EDT 2021 · Journal of Materials Chemistry. A · OSTI ID:1423519

Feng, Xueting; Jiao, Qingze; Dai, Zheng; +7 more

Cobalt Intercalated Layered NiFe Double Hydroxides for the Oxygen Evolution Reaction

Journal Article · Thu Sep 07 00:00:00 EDT 2017 · Journal of Physical Chemistry. B, Condensed Matter, Materials, Surfaces, Interfaces and Biophysical Chemistry · OSTI ID:1423519

Thenuwara, Akila C.; Attanayake, Nuwan H.; Yu, Jie; +4 more

Structure-property relationship of graphene coupled metal (Ni, Co, Fe) (oxy)hydroxides for efficient electrochemical evolution of oxygen

Journal Article · Fri Aug 23 00:00:00 EDT 2019 · Journal of Catalysis · OSTI ID:1423519

He, Junkai; Wu, Tianli; Chen, Sheng-Yu; +6 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
36 MATERIALS SCIENCE
oxygen evolution reaction
layered double hydroxide
intercalated anions
electronic structure