Colloidal Cobalt Phosphide Nanocrystals as Trifunctional Electrocatalysts for Overall Water Splitting Powered by a Zinc–Air Battery

Li, Hui; Li, Qi; Wen, Peng; Williams, Trey B.; Adhikari, Shiba; Dun, Chaochao; Lu, Chang; Itanze, Dominique; Jiang, Lin; Carroll, David L.; Donati, George L.; Lundin, Pamela M.; Qiu, Yejun; Geyer, Scott M.

doi:10.1002/adma.201705796

Title: Colloidal Cobalt Phosphide Nanocrystals as Trifunctional Electrocatalysts for Overall Water Splitting Powered by a Zinc–Air Battery

Journal Article · Mon Jan 15 00:00:00 EST 2018 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201705796· OSTI ID:1422608

Li, Hui ^[1]; Li, Qi ^[2]; Wen, Peng ^[3]; Williams, Trey B. ^[1];

^[4]; Dun, Chaochao ^[5]; Lu, Chang ^[1]; Itanze, Dominique ^[1]; Jiang, Lin ^[6]; Carroll, David L. ^[5]; Donati, George L. ^[1]; Lundin, Pamela M. ^[7]; Qiu, Yejun ^[3];

^[1]

Wake Forest Univ., Winston-Salem, NC (United States). Dept. of Chemistry
IBM TJ Watson Research Center, Yorktown Heights, NY (United States). Physical Science Division
Harbin Inst. of Technology, Shenzhen (China). Shenzhen Graduate School. Dept. of Materials Science and Engineering. Shenzhen Engineering Lab. of Flexible Transparent Conductive Films
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Material Science and Technology Division
Wake Forest Univ., Winston-Salem, NC (United States). Dept. of Physics. Center for Nanotechnology and Molecular Materials
Soochow Univ., Suzhou (China). Inst. of Functional Nano and Soft Materials
High Point Univ., NC (United States). Dept. of Chemistry

Highly efficient and stable electrocatalysts, particularly those that are capable of multifunctionality in the same electrolyte, are in high demand for the hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and oxygen reduction reaction (ORR). In this paper, highly monodisperse CoP and Co₂P nanocrystals (NCs) are synthesized using a robust solution-phase method. The highly exposed (211) crystal plane and abundant surface phosphide atoms make the CoP NCs efficient catalysts toward ORR and HER, while metal-rich Co₂P NCs show higher OER performance owing to easier formation of plentiful Co₂P@COOH heterojunctions. Density functional theory calculation results indicate that the desorption of OH* from cobalt sites is the rate-limiting step for both CoP and Co₂P in ORR and that the high content of phosphide can lower the reaction barrier. A water electrolyzer constructed with a CoP NC cathode and a Co₂P NC anode can achieve a current density of 10 mA cm^-2 at 1.56 V, comparable even to the noble metal-based Pt/C and RuO₂/C pair. Finally and furthermore, the CoP NCs are employed as an air cathode in a primary zinc–air battery, exhibiting a high power density of 62 mW cm^-2 and good stability.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE; Wake Forest Univ. (United States); National Science Foundation (NSF)

Grant/Contract Number:: AC05-00OR22725; CHE-1531698

OSTI ID:: 1422608

Journal Information:: Advanced Materials, Vol. 30, Issue 9; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 230 works

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Electronic structure modulation of bifunctional oxygen catalysts for rechargeable Zn–air batteries Yang, Jian; Chang, Le; Guo, Heng Journal of Materials Chemistry A, Vol. 8, Issue 3 https://doi.org/10.1039/c9ta11654k	journal	January 2020
Tunable Synthesis of CoP and CoP ₂ Decorated 3D Carbon Nanohybrids and the Application of CoP ₂ Decorated One in Electrochemical Detection of Chloramphenicol in Milk and Honey Wu, Xingxing; Lao, Chunfeng; Li, Yingchun Journal of The Electrochemical Society, Vol. 165, Issue 16 https://doi.org/10.1149/2.1011816jes	journal	January 2018

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
36 MATERIALS SCIENCE
cobalt phosphide
density functional theory
overall water splitting
trifunctional electrocatalysts
zinc-air batteries

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