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Title: Cosolvent electrolytes for electrochemical devices

Patent ·
OSTI ID:1420768

A system and method for stabilizing electrodes against dissolution and/or hydrolysis including use of cosolvents in liquid electrolyte batteries for three purposes: the extension of the calendar and cycle life time of electrodes that are partially soluble in liquid electrolytes, the purpose of limiting the rate of electrolysis of water into hydrogen and oxygen as a side reaction during battery operation, and for the purpose of cost reduction.

Research Organization:
Natron Energy, Inc., Santa Clara, CA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AR000300
Assignee:
Natron Energy, Inc. (Santa Clara, CA)
Patent Number(s):
9,893,382
Application Number:
15/062,184
OSTI ID:
1420768
Resource Relation:
Patent File Date: 2016 Mar 06
Country of Publication:
United States
Language:
English

References (65)

Nickel Hexacyanoferrate Nanoparticle Electrodes For Aqueous Sodium and Potassium Ion Batteries journal December 2011
The thermodynamics of the insertion electrochemistry of solid metal hexacyanometallates journal March 2002
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides journal September 1976
A simple and an efficient strategy to synthesize multi-component nanocomposites for biosensor applications journal January 2012
Fabrication of a Cyanide-Bridged Coordination Polymer Electrode for Enhanced Electrochemical Ion Storage Ability journal April 2012
Photogalvanic behaviour of K3Mn(CN)6 in CN aqueous solutions journal February 1990
Fast disproportionation of hexacyanomanganate(III) in acidic solution. Formation of hexacyanomanganate(IV) and kinetics of its decomposition journal December 1986
Some Performance Characteristics of a Prussian Blue Battery journal January 1985
Electrochemical behavior of iron-hexacyanoruthenate(II) thin films in aqueous electrolytes: potential analytical and catalytic applications journal June 2001
LI/AIR NON-AQUEOUS BATTERIES patent-application May 2007
High Affinity of Thallium Ions to Copper Hexacyanoferrate Films journal January 2001
Long life lithium batteries with stabilized electrodes patent-application January 2005
Method for Manufacturing Secondary Battery patent-application August 2010
Core-Multishell Magnetic Coordination Nanoparticles: Toward Multifunctionality on the Nanoscale journal November 2008
Method for producing electrolyte and method for producing secondary battery patent August 2001
Stabilized electrochemical cell patent February 1999
The crystal structure of Prussian Blue: Fe4[Fe(CN)6]3.xH2O journal November 1977
Stabilization of battery electrodes using prussian blue analogue coatings patent September 2015
A secondary cell based on thin layers of zeolite-like nickel hexacyanometallates journal August 1989
Prussian Blue Containing Nafion Composite Film as Rechargeable Battery journal January 1987
Systems, Methods of Manufacture and Use Involving Lithium and/or Hydrogen for Energy-Storage Applications patent-application September 2010
Charge–discharge characteristics of a solid-state Prussian blue secondary cell journal April 2000
The Color and Electronic Configurations of Prussian Blue journal May 1962
Tunable Reaction Potentials in Open Framework Nanoparticle Battery Electrodes for Grid-Scale Energy Storage journal January 2012
Method for High Volume Manufacturing of Thin Film Batteries patent-application August 2012
Beiträge zur Komplexchemie des Technetiums. II. Darstellung und Eigenschaften von Kalium-cyanotechnetat(I) journal December 1962
Anomalous Non-Prussian Blue Structures and Magnetic Ordering of K2MnII[MnII(CN)6] and Rb2MnII[MnII(CN)6] journal February 2010
Negative-Limited Lithium-Ion Battery patent-application February 2009
Fabrication of all-solid-state thin-film secondary cells using hexacyanometallate-based electrode materials journal May 2004
Nonflammable non-aqueous electrolyte and non-aqueous electrolyte cells comprising the same patent August 2005
Copper hexacyanoferrate battery electrodes with long cycle life and high power journal November 2011
Electrochemistry of polynuclear transition metal cyanides: Prussian blue and its analogues journal June 1986
Electrochemical properties and lithium ion solvation behavior of sulfone–ester mixed electrolytes for high-voltage rechargeable lithium cells journal May 2008
Novel Separators For Electrochemical Systems patent-application August 2013
In Situ Investigation of the Electrochemical Reduction of Carbonate Electrolyte Solutions at Graphite Electrodes journal January 1998
Über Hexacyanomanganate(I) und Hexacyanorhenat(I) journal December 1958
Lithium Battery Using an Aqueous Electrolyte patent-application April 2009
IUPAC-NIST Solubility Data Series. 83. Acetonitrile: Ternary and Quaternary Systems journal September 2007
Controlled growth of core@shell heterostructures based on Prussian blue analogues journal January 2011
Cyanide complexes of the early transition metals (groups IVa-VIIa) journal November 1975
Non-aqueous electrolyte and lithium secondary battery using the same patent August 2002
Cosolvent electrolytes for electrochemical devices patent March 2016
Switching Redox-Active Sites by Valence Tautomerism in Prussian Blue Analogues AxMny[Fe(CN)6]·nH2O (A: K, Rb): Robust Frameworks for Reversible Li Storage journal June 2010
Multilayer Material Based on Active Lithium, Method of Preparation and Applications in Electrochemical Generators patent-application November 2009
Electrochemical studies of the factors influencing the cycle stability of Prussian Blue films journal April 1992
The Effect of Insertion Species on Nanostructured Open Framework Hexacyanoferrate Battery Electrodes journal January 2012
The Formal Potentials of Solid Metal Hexacyanometalates journal January 1996
One-step synthesis and self-organization of polypyrrole ultrathin films inlayed with Prussian blue nanoparticles induced by a drop of toluene solution on water surface journal January 2012
Hexacyanoferrate layers as electrodes for secondary cells journal May 1987
High Rate, Long Cycle Life Battery Electrode Materials With An Open Framework Structure patent-application December 2012
Formation of copper(II), zinc(II), silver(I) and lead(II) ferrocyanides journal November 1970
Highly Sensitive Molecularly Imprinted Electrochemical Sensor Based on the Double Amplification by an Inorganic Prussian Blue Catalytic Polymer and the Enzymatic Effect of Glucose Oxidase journal January 2012
Materials for battery electrolytes and methods for use patent November 2012
A high-rate and long cycle life aqueous electrolyte battery for grid-scale energy storage journal January 2012
Electrochemical Analysis of Conductive Polymer-Coated LiFePO4 Nanocrystalline Cathodes with Controlled Morphology journal July 2011
Alkali and Alkaline-Earth Ion Batteries with Hexacyanometallate Cathode and Non-Metal Anode patent-application October 2013
High Rate, Long Cycle Life Electrochemical Energy Storage Devices patent-application February 2013
Sulfone-Based Electrolyte Solutions for Rechargeable Magnesium Batteries Using 2,5-Dimethoxy-1,4-benzoquinone Positive Electrode journal January 2014
Performance characteristics of zinc hexacyanoferrate/Prussian blue and copper hexacyanoferrate/Prussian blue solid state secondary cells journal December 2000
Mécanisme de la réduction électrochimique en milieu non aqueux de materiaux cathodiques utilises dans les piles au lithium. V. Utilisation des hexacyanoferrates de fer (II et III) comme materiaux cathodiques reversibles journal September 1980
Solubilities of some chloride and perchlorate salts in sulfolane journal February 1972
Mecanismes de la reduction electrochimique en milieu non aqueux de materiaux cathodiques utilises dans les piles au lithium: I. Reduction d'electrodes membranaires de chromate d'argent dans le 1,2-dim�thoxy�thane et les m�langes 1,2-dim�thoxy�thane-carbonate de propyl�ne journal March 1978
Photoelectric Converter and Semiconductor Electrode patent-application January 2009
Stabilization of battery electrodes patent September 2015
A secondary battery composed of multilayer Prussian Blue and its reaction characteristics journal November 1988