Achieving One-Electron Oxidation of a Mononuclear Nonheme Iron(V)-Imido Complex
Journal Article
·
· Journal of the American Chemical Society
- Ewha Womans Univ., Seoul (Korea); Sookmyung Women's Univ., Seoul (Korea)
- Ewha Womans Univ., Seoul (Korea)
- Univ. of Hyogo, Hyogo (Japan)
- Univ. Grenoble Alpes, Grenoble (France)
- SLAC National Accelerator Lab., Menlo Park, CA (United States)
- Ewha Womans Univ., Seoul (Korea); Chinese Academy of Sciences, Lanzhou (China)
Here, a mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [FeV(NTs)(TAML)]– (1), was oxidized by one-electron oxidants, affording formation of an iron(V)-imido TAML cation radical species, [FeV(NTs)(TAML+•)] (2); 2 is a diamagnetic (S = 0) complex, resulting from the antiferromagnetic coupling of the low-spin iron(V) ion (S = 1/2) with the one-electron oxidized ligand (TAML+•). 2 is a competent oxidant in C–H bond functionalization and nitrene transfer reaction, showing that the reactivity of 2 is greater than that of 1.
- Research Organization:
- SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
- Sponsoring Organization:
- USDOE
- Grant/Contract Number:
- AC02-76SF00515; ANR-11-LABX-003; NRF-2010-00353; NRF-2012R1A3A2048842; NRF-2017R1C1B2002037; 15H00960; P41GM103393
- OSTI ID:
- 1419655
- Journal Information:
- Journal of the American Chemical Society, Vol. 139, Issue 41; ISSN 0002-7863
- Publisher:
- American Chemical Society (ACS)Copyright Statement
- Country of Publication:
- United States
- Language:
- English
Cited by: 40 works
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