A spongy nickel-organic CO2 reduction photocatalyst for nearly 100% selective CO production

Niu, Kaiyang; Xu, You; Wang, Haicheng; Ye, Rong; Xin, Huolin L.; Lin, Feng; Tian, Chixia; Lum, Yanwei; Bustillo, Karen C.; Doeff, Marca M.; Koper, Marc T. M.; Ager, Joel; Xu, Rong; Zheng, Haimei

doi:10.1126/sciadv.1700921

Title: A spongy nickel-organic CO₂ reduction photocatalyst for nearly 100% selective CO production

Journal Article · Fri Jul 28 00:00:00 EDT 2017 · Science Advances

DOI:https://doi.org/10.1126/sciadv.1700921· OSTI ID:1419436

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Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Nanyang Technological Univ. (Singapore); SinBeRISE (Singapore-Berkeley Research Initiative for Sustainable Energy) CREATE (Singapore)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of Science and Technology Beijing, Beijing (People's Republic of China)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Leiden Univ., Leiden (Netherlands)

Solar-driven photocatalytic conversion of CO₂ into fuels has attracted a lot of interest; however, developing active catalysts that can selectively convert CO₂ to fuels with desirable reaction products remains a grand challenge. For instance, complete suppression of the competing H₂ evolution during photocatalytic CO₂-to-CO conversion has not been achieved before. We design and synthesize a spongy nickel-organic heterogeneous photocatalyst via a photochemical route. The catalyst has a crystalline network architecture with a high concentration of defects. It is highly active in converting CO₂ to CO, with a production rate of ~1.6 × 10⁴ μmol hour^–1 g^–1. No measurable H₂ is generated during the reaction, leading to nearly 100% selective CO production over H₂ evolution. When the spongy Ni-organic catalyst is enriched with Rh or Ag nanocrystals, the controlled photocatalytic CO₂ reduction reactions generate formic acid and acetic acid. As a result, achieving such a spongy nickel-organic photocatalyst is a critical step toward practical production of high-value multicarbon fuels using solar energy.

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Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231; SC0012704

OSTI ID:: 1419436

Alternate ID(s):: OSTI ID: 1409644

Report Number(s):: BNL-114699-2017-JA; ark:/13030/qt84194890

Journal Information:: Science Advances, Vol. 3, Issue 7; ISSN 2375-2548

Publisher:: AAASCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 131 works

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Title: A spongy nickel-organic CO2 reduction photocatalyst for nearly 100% selective CO production

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Title: A spongy nickel-organic CO₂ reduction photocatalyst for nearly 100% selective CO production