p-Type CuRhO2 as a Self-Healing Photoelectrode for Water Reduction under Visible Light
Abstract
Polycrystalline CuRhO2 is investigated as a photocathode for the splitting of water under visible irradiation. The band edge positions of this material straddle the water oxidation and reduction redox potentials. Thus, photogenerated conduction band electrons are sufficiently energetic to reduce water, while the associated valence band holes are energetically able to oxidize water to O2. Under visible illumination, H2 production is observed with ~0.2 V underpotential in an air-saturated solution. In contrast, H2 production in an Ar-saturated solution was found to be unstable. This instability is associated with the reduction of the semiconductor forming Cu(s). However, in the presence of air or O2, bulk Cu(s) was not detected, implying that CuRhO2 is self-healing when air is present. Here, this property allows for the stable formation of H2 with ca. 80% Faradaic efficiency.
- Authors:
-
- Princeton Univ., Princeton, NJ (United States)
- Publication Date:
- Research Org.:
- Princeton Univ., NJ (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Contributing Org.:
- Princeton University
- OSTI Identifier:
- 1418445
- Grant/Contract Number:
- SC0002133
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Journal of the American Chemical Society
- Additional Journal Information:
- Journal Volume: 136; Journal Issue: 3; Journal ID: ISSN 0002-7863
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 08 HYDROGEN; 14 SOLAR ENERGY; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; photoelectrochemistry; water splitting; solar fuels; new photocathode materials; CuRhO2
Citation Formats
Gu, Jing, Krizan, Jason W., Gibson, Quinn D., Detweiler, Zachary M., Cava, Robert J., Bocarsly, Andrew B., and Yang, Yong. p-Type CuRhO2 as a Self-Healing Photoelectrode for Water Reduction under Visible Light. United States: N. p., 2013.
Web. doi:10.1021/ja408876k.
Gu, Jing, Krizan, Jason W., Gibson, Quinn D., Detweiler, Zachary M., Cava, Robert J., Bocarsly, Andrew B., & Yang, Yong. p-Type CuRhO2 as a Self-Healing Photoelectrode for Water Reduction under Visible Light. United States. https://doi.org/10.1021/ja408876k
Gu, Jing, Krizan, Jason W., Gibson, Quinn D., Detweiler, Zachary M., Cava, Robert J., Bocarsly, Andrew B., and Yang, Yong. 2013.
"p-Type CuRhO2 as a Self-Healing Photoelectrode for Water Reduction under Visible Light". United States. https://doi.org/10.1021/ja408876k. https://www.osti.gov/servlets/purl/1418445.
@article{osti_1418445,
title = {p-Type CuRhO2 as a Self-Healing Photoelectrode for Water Reduction under Visible Light},
author = {Gu, Jing and Krizan, Jason W. and Gibson, Quinn D. and Detweiler, Zachary M. and Cava, Robert J. and Bocarsly, Andrew B. and Yang, Yong},
abstractNote = {Polycrystalline CuRhO2 is investigated as a photocathode for the splitting of water under visible irradiation. The band edge positions of this material straddle the water oxidation and reduction redox potentials. Thus, photogenerated conduction band electrons are sufficiently energetic to reduce water, while the associated valence band holes are energetically able to oxidize water to O2. Under visible illumination, H2 production is observed with ~0.2 V underpotential in an air-saturated solution. In contrast, H2 production in an Ar-saturated solution was found to be unstable. This instability is associated with the reduction of the semiconductor forming Cu(s). However, in the presence of air or O2, bulk Cu(s) was not detected, implying that CuRhO2 is self-healing when air is present. Here, this property allows for the stable formation of H2 with ca. 80% Faradaic efficiency.},
doi = {10.1021/ja408876k},
url = {https://www.osti.gov/biblio/1418445},
journal = {Journal of the American Chemical Society},
issn = {0002-7863},
number = 3,
volume = 136,
place = {United States},
year = {Mon Dec 30 00:00:00 EST 2013},
month = {Mon Dec 30 00:00:00 EST 2013}
}
Web of Science
Works referenced in this record:
Hydrogen futures: toward a sustainable energy system
journal, March 2002
- Dunn, S.
- International Journal of Hydrogen Energy, Vol. 27, Issue 3
Solar Water Splitting Cells
journal, November 2010
- Walter, Michael G.; Warren, Emily L.; McKone, James R.
- Chemical Reviews, Vol. 110, Issue 11, p. 6446-6473
Forming Heterojunctions at the Nanoscale for Improved Photoelectrochemical Water Splitting by Semiconductor Materials: Case Studies on Hematite
journal, February 2013
- Mayer, Matthew T.; Lin, Yongjing; Yuan, Guangbi
- Accounts of Chemical Research, Vol. 46, Issue 7
Photocatalyst releasing hydrogen from water
journal, March 2006
- Maeda, Kazuhiko; Teramura, Kentaro; Lu, Daling
- Nature, Vol. 440, Issue 7082
New Non-Oxide Photocatalysts Designed for Overall Water Splitting under Visible Light
journal, June 2007
- Maeda, Kazuhiko; Domen, Kazunari
- The Journal of Physical Chemistry C, Vol. 111, Issue 22
Artificial photosynthesis for solar water-splitting
journal, July 2012
- Tachibana, Yasuhiro; Vayssieres, Lionel; Durrant, James R.
- Nature Photonics, Vol. 6, Issue 8
Composite photoanodes for photoelectrochemical solar water splitting
journal, January 2010
- Sun, Jianwei; Zhong, Diane K.; Gamelin, Daniel R.
- Energy & Environmental Science, Vol. 3, Issue 9
Modified TiO2 nanotube arrays (TNTAs): progressive strategies towards visible light responsive photoanode, a review
journal, January 2011
- El Ruby Mohamed, Ahmed; Rohani, Sohrab
- Energy & Environmental Science, Vol. 4, Issue 4
Photocatalysis on TiO2 Surfaces: Principles, Mechanisms, and Selected Results
journal, May 1995
- Linsebigler, Amy L.; Lu, Guangquan.; Yates, John T.
- Chemical Reviews, Vol. 95, Issue 3
Preparation and Photoelectrochemical Properties of p-type Cu 5 Ta 11 O 30 and Cu 3 Ta 7 O 19 Semiconducting Polycrystalline Films
journal, May 2012
- Fuoco, Lindsay; Joshi, Upendra A.; Maggard, Paul A.
- The Journal of Physical Chemistry C, Vol. 116, Issue 19
Semiconducting Oxides to Facilitate the Conversion of Solar Energy to Chemical Fuels
journal, September 2010
- Joshi, Upendra A.; Palasyuk, Andriy; Arney, David
- The Journal of Physical Chemistry Letters, Vol. 1, Issue 18
Combinatorial Discovery and Optimization of a Complex Oxide with Water Photoelectrolysis Activity
journal, April 2008
- Woodhouse, Michael; Parkinson, B. A.
- Chemistry of Materials, Vol. 20, Issue 7
Preparation of p-Type CaFe 2 O 4 Photocathodes for Producing Hydrogen from Water
journal, December 2010
- Ida, Shintaro; Yamada, Keisuke; Matsunaga, Takuya
- Journal of the American Chemical Society, Vol. 132, Issue 49
Rh-Doped SrTiO 3 Photocatalyst Electrode Showing Cathodic Photocurrent for Water Splitting under Visible-Light Irradiation
journal, August 2011
- Iwashina, Katsuya; Kudo, Akihiko
- Journal of the American Chemical Society, Vol. 133, Issue 34
Photoelectrochemical and solid‐state properties of LuRhO 3
journal, July 1980
- Jarrett, H. S.; Sleight, A. W.; Kung, H. H.
- Journal of Applied Physics, Vol. 51, Issue 7
Photoelectrochemical properties of LuRhO3
journal, December 1980
- Jarrett, H. S.; Sleight, A. W.; Kung, H. H.
- Surface Science, Vol. 101, Issue 1-3
Crystal Face Dependence of p-Cu[sub 2]O Stability as Photocathode
journal, January 2009
- Sowers, Kelly L.; Fillinger, Akiko
- Journal of The Electrochemical Society, Vol. 156, Issue 5
Photoelectrochemistry of Porous p-Cu[sub 2]O Films
journal, January 2008
- Engel, Clifford J.; Polson, Thomas A.; Spado, Jacy R.
- Journal of The Electrochemical Society, Vol. 155, Issue 3
Highly active oxide photocathode for photoelectrochemical water reduction
journal, May 2011
- Paracchino, Adriana; Laporte, Vincent; Sivula, Kevin
- Nature Materials, Vol. 10, Issue 6
Crystal chemistry and electrical properties of the delafossite structure
journal, February 2006
- Marquardt, Meagen A.; Ashmore, Nathan A.; Cann, David P.
- Thin Solid Films, Vol. 496, Issue 1
Chemistry of noble metal oxides. III. Electrical transport properties and crystal chemistry of ABO2 compounds with the delafossite structure
journal, April 1971
- Shannon, Robert D.; Rogers, Donald Burl; Prewitt, Charles T.
- Inorganic Chemistry, Vol. 10, Issue 4
p-Type conductivity in the delafossite structure
journal, June 2001
- Nagarajan, R.; Duan, N.; Jayaraj, M. K.
- International Journal of Inorganic Materials, Vol. 3, Issue 3
Origins of the -type nature and cation deficiency in and related materials
journal, July 2007
- Raebiger, Hannes; Lany, Stephan; Zunger, Alex
- Physical Review B, Vol. 76, Issue 4
Electrochemical Synthesis of p-Type CuFeO 2 Electrodes for Use in a Photoelectrochemical Cell
journal, July 2012
- Read, Carrie G.; Park, Yiseul; Choi, Kyoung-Shin
- The Journal of Physical Chemistry Letters, Vol. 3, Issue 14
Mg-Doped CuFeO 2 Photocathodes for Photoelectrochemical Reduction of Carbon Dioxide
journal, June 2013
- Gu, Jing; Wuttig, Anna; Krizan, Jason W.
- The Journal of Physical Chemistry C, Vol. 117, Issue 24
Electrochemistry of Aqueous Pyridinium: Exploration of a Key Aspect of Electrocatalytic Reduction of CO 2 to Methanol
journal, September 2013
- Yan, Yong; Zeitler, Elizabeth L.; Gu, Jing
- Journal of the American Chemical Society, Vol. 135, Issue 38
Partitioning of ruthenium, rhodium, and palladium between spinel and silicate melt and implications for platinum group element fractionation trends
journal, March 1990
- Capobianco, Christopher J.; Drake, Michael J.
- Geochimica et Cosmochimica Acta, Vol. 54, Issue 3
Photooxidation of Organic Chemicals Catalyzed by Nanoscale MoS2
journal, January 1999
- Thurston, T. R.; Wilcoxon, J. P.
- The Journal of Physical Chemistry B, Vol. 103, Issue 1, p. 11-17
Cu2O: a catalyst for the photochemical decomposition of water?
journal, January 1999
- de Jongh, Petra E.; Vanmaekelbergh, Daniel; Kelly, John J.
- Chemical Communications, Issue 12
Works referencing / citing this record:
Multiple exciton generation for photoelectrochemical hydrogen evolution reactions with quantum yields exceeding 100%
journal, April 2017
- Yan, Yong; Crisp, Ryan W.; Gu, Jing
- Nature Energy, Vol. 2, Issue 5
Electronic transitions of the transparent delafossite-type CuGa 1−x Cr x O 2 system: first-principles calculations and temperature-dependent spectral experiments
journal, January 2017
- Wang, Junyong; Zhang, Peng; Deng, Qinglin
- Journal of Materials Chemistry C, Vol. 5, Issue 1
Unconventional aspects of electronic transport in delafossite oxides
journal, November 2017
- Daou, Ramzy; Frésard, Raymond; Eyert, Volker
- Science and Technology of Advanced Materials, Vol. 18, Issue 1
Interaction of SrO-terminated SrTiO 3 surface with oxygen, carbon dioxide, and water
journal, January 2018
- Staykov, Aleksandar; Fukumori, Shun; Yoshizawa, Kazunari
- Journal of Materials Chemistry A, Vol. 6, Issue 45
Bifunctional CdS@Co 9 S 8 /Ni 3 S 2 catalyst for efficient electrocatalytic and photo-assisted electrocatalytic overall water splitting
journal, January 2020
- Si, Fangyuan; Tang, Chengyang; Gao, Qiongzhi
- Journal of Materials Chemistry A, Vol. 8, Issue 6
Predicting the stable rhodium based chalcopyrites with remarkable optical properties
journal, December 2019
- Joshi, Nikunj; Upadhyay, Deepak; Pandya, Ankur
- Journal of Applied Physics, Vol. 126, Issue 23
Review—Copper Oxide-Based Ternary and Quaternary Oxides: Where Solid-State Chemistry Meets Photoelectrochemistry
journal, January 2018
- Rajeshwar, Krishnan; Hossain, Mohammad Kabir; Macaluso, Robin T.
- Journal of The Electrochemical Society, Vol. 165, Issue 4
Photoelectrochemical Water Splitting with p‐Type Metal Oxide Semiconductor Photocathodes
journal, November 2018
- Jang, Youn Jeong; Lee, Jae Sung
- ChemSusChem, Vol. 12, Issue 9
Directly Photoexcited Oxides for Photoelectrochemical Water Splitting
journal, September 2019
- Pan, Linfeng; Vlachopoulos, Nick; Hagfeldt, Anders
- ChemSusChem, Vol. 12, Issue 19
Enhancing the Performance of a Robust Sol-Gel-Processed p-Type Delafossite CuFeO 2 Photocathode for Solar Water Reduction
journal, January 2015
- Prévot, Mathieu S.; Guijarro, Néstor; Sivula, Kevin
- ChemSusChem, Vol. 8, Issue 8
Microwave-assisted deep eutectic-solvothermal preparation of iron oxide nanoparticles for photoelectrochemical solar water splitting
journal, January 2017
- Hammond, Oliver S.; Eslava, Salvador; Smith, Andrew J.
- J. Mater. Chem. A, Vol. 5, Issue 31
Highly Efficient and Visible Light Responsive Heterojunction Composites as Dual Photoelectrodes for Photocatalytic Fuel Cell
journal, January 2018
- Pan, Honghui; Liao, Wenjuan; Sun, Na
- Catalysts, Vol. 8, Issue 1
Semiconducting materials for photoelectrochemical energy conversion
journal, January 2016
- Sivula, Kevin; van de Krol, Roel
- Nature Reviews Materials, Vol. 1, Issue 2
Green and low-cost synthesis of PANI–TiO 2 nanocomposite mesoporous films for photoelectrochemical water splitting
journal, January 2015
- Hidalgo, D.; Bocchini, S.; Fontana, M.
- RSC Advances, Vol. 5, Issue 61
Delafossite CuGaO 2 as promising visible-light-driven photocatalyst: synthesize, properties, and performances
journal, January 2020
- Zhao, Qing-Meng; Zhao, Zong-Yan; Liu, Qing-Lu
- Journal of Physics D: Applied Physics, Vol. 53, Issue 13
Aerobic Conditions Enhance the Photocatalytic Stability of CdS/CdO x Quantum Dots
journal, June 2018
- Wakerley, David W.; Ly, Khoa H.; Kornienko, Nikolay
- Chemistry – A European Journal, Vol. 24, Issue 69
Recent Advances in Earth‐Abundant Photocathodes for Photoelectrochemical Water Splitting
journal, August 2018
- Yang, Wooseok; Moon, Jooho
- ChemSusChem, Vol. 12, Issue 9
Trilaminar graphene/tremella-like CuInS2/graphene oxide nanofilms and the enhanced activity for photoelectrochemical water splitting
journal, July 2015
- Bo, Wang; Liu, Zhifeng; Hong, Tiantian
- Journal of Nanoparticle Research, Vol. 17, Issue 7
Improving charge collection with delafossite photocathodes: a host–guest CuAlO 2 /CuFeO 2 approach
journal, January 2016
- Prévot, Mathieu S.; Li, Yang; Guijarro, Néstor
- Journal of Materials Chemistry A, Vol. 4, Issue 8
Water splitting catalyzed by titanium dioxide decorated with plasmonic nanoparticles
journal, November 2017
- Gellé, Alexandra; Moores, Audrey
- Pure and Applied Chemistry, Vol. 89, Issue 12
Alcoholic Compounds as an Efficient Energy Carrier
book, August 2018
- Fukushima, Takashi; Kitano, Sho; Sadakiyo, Masaaki
- Nanocarbons for Energy Conversion: Supramolecular Approaches
Efficient and Stable MoS 2 /CdSe/NiO Photocathode for Photoelectrochemical Hydrogen Generation from Water
journal, June 2015
- Dong, Yuming; Chen, Yanmei; Jiang, Pingping
- Chemistry - An Asian Journal, Vol. 10, Issue 8
Water reduction by a p-GaInP2 photoelectrode stabilized by an amorphous TiO2 coating and a molecular cobalt catalyst
journal, December 2015
- Gu, Jing; Yan, Yong; Young, James L.
- Nature Materials, Vol. 15, Issue 4
Rational strain engineering in delafossite oxides for highly efficient hydrogen evolution catalysis in acidic media
journal, December 2019
- Podjaski, Filip; Weber, Daniel; Zhang, Siyuan
- Nature Catalysis, Vol. 3, Issue 1
Photoelectrode for water splitting: Materials, fabrication and characterization
journal, April 2018
- Wang, Zhiliang; Wang, Lianzhou
- Science China Materials, Vol. 61, Issue 6
AgCuO 2 as a novel bifunctional electrocatalyst for overall water splitting in alkaline media
journal, January 2019
- Kamali Moghaddam, Saeideh; Seyed Ahmadian, Seyed Masoud; Haghighi, Behzad
- New Journal of Chemistry, Vol. 43, Issue 11
Aerobic conditions enhance the photocatalytic stability of CdS/CdOx quantum dots
text, January 2018
- Reisner, Erwin; Wakerley, David; Ly, Khoa
- Apollo - University of Cambridge Repository
Aerobic Conditions Enhance the Photocatalytic Stability of CdS/CdO x Quantum Dots
journal, June 2018
- Wakerley, David W.; Ly, Khoa H.; Kornienko, Nikolay
- Chemistry – A European Journal, Vol. 24, Issue 69
Reverse Electrodialysis-Assisted Solar Water Splitting
journal, September 2017
- Lee, Jihye; Yun, Jeongse; Kwon, Seung-Ryong
- Scientific Reports, Vol. 7, Issue 1
High production of CH4 and H2 by reducing PET waste water using a non-diaphragm-based electrochemical method
journal, February 2016
- Kim, Nam-Gyu; Yim, Kwang-Jin; Kim, Chan-Soo
- Scientific Reports, Vol. 6, Issue 1
Unconventional aspects of electronic transport in delafossite oxides
text, January 2017
- Daou, Ramzy; Frésard, Raymond; Eyert, Volker
- arXiv