Alkylamine functionalized metal-organic frameworks for composite gas separations
Abstract
Functionalized metal-organic framework adsorbents with ligands containing basic nitrogen groups such as alkylamines and alkyldiamines appended to the metal centers and method of isolating carbon dioxide from a stream of combined gases and carbon dioxide partial pressures below approximately 1 and 1000 mbar. The adsorption material has an isosteric heat of carbon dioxide adsorption of greater than -60 kJ/mol at zero coverage using a dual-site Langmuir model.
- Inventors:
- Publication Date:
- Research Org.:
- Univ. of California, Oakland, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1416741
- Patent Number(s):
- 9,861,953
- Application Number:
- 15/373,426
- Assignee:
- THE REGENTS OF THE UNIVERSITY OF CALIFORNIA (Oakland, CA)
- DOE Contract Number:
- SC0001015
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2016 Dec 08
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Long, Jeffrey R., McDonald, Thomas M., and D'Alessandro, Deanna M. Alkylamine functionalized metal-organic frameworks for composite gas separations. United States: N. p., 2018.
Web.
Long, Jeffrey R., McDonald, Thomas M., & D'Alessandro, Deanna M. Alkylamine functionalized metal-organic frameworks for composite gas separations. United States.
Long, Jeffrey R., McDonald, Thomas M., and D'Alessandro, Deanna M. 2018.
"Alkylamine functionalized metal-organic frameworks for composite gas separations". United States. https://www.osti.gov/servlets/purl/1416741.
@article{osti_1416741,
title = {Alkylamine functionalized metal-organic frameworks for composite gas separations},
author = {Long, Jeffrey R. and McDonald, Thomas M. and D'Alessandro, Deanna M.},
abstractNote = {Functionalized metal-organic framework adsorbents with ligands containing basic nitrogen groups such as alkylamines and alkyldiamines appended to the metal centers and method of isolating carbon dioxide from a stream of combined gases and carbon dioxide partial pressures below approximately 1 and 1000 mbar. The adsorption material has an isosteric heat of carbon dioxide adsorption of greater than -60 kJ/mol at zero coverage using a dual-site Langmuir model.},
doi = {},
url = {https://www.osti.gov/biblio/1416741},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jan 09 00:00:00 EST 2018},
month = {Tue Jan 09 00:00:00 EST 2018}
}
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Amine enriched solid sorbents for carbon dioxide capture
patent, April 2003
- Gray, McMahan L.; Soong, Yee; Champagne, Kenneth J.
- US Patent Document 6,547,854
High capacity immobilized amine sorbents
patent, October 2007
- Gray, McMahan L.; Champagne, Kenneth J.; Soong, Yee
- US Patent Document 7,288,136
Method for the separation of carbon dioxide using a porous metal-organic framework material
patent-application, May 2008
- Schubert, Markus; Muller, Ulrich; Kierner, Christoph
- US Patent Application 11/563101: 20080121105
Aluminum aminocarobxylates as porous metal organic frameworks
patent-application, June 2010
- Schubert, Markus; Mueller, Ulrich; Kiener, Christoph
- US Patent Application 12/601022; 20100154635
Porous Biomolecule-Containing Metal-Organic Frameworks
patent-application, May 2011
- Louis, Nathaniel; An, Jihyun
- US Patent Application 12/915178: 20110104213
Cooperative chemical adsorption of acid gases in functionalized metal-organic frameworks
patent-application, March 2017
- Long, Jeffrey R.; McDonald, Thomas M.
- US Patent Application 15/297114; 20170087531
Strong CO2 Binding in a Water-Stable, Triazolate-Bridged Metal−Organic Framework Functionalized with Ethylenediamine
journal, July 2009
- Demessence, Aude; D’Alessandro, Deanna M.; Foo, Maw Lin
- Journal of the American Chemical Society, Vol. 131, Issue 25, p. 8784-8786
Amine Grafting on Coordinatively Unsaturated Metal Centers of MOFs: Consequences for Catalysis and Metal Encapsulation
journal, May 2008
- Hwang, Young Kyu; Hong, Do-Young; Chang, Jong-San
- Angewandte Chemie International Edition, Vol. 47, Issue 22, p. 4144-4148
Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal–Organic Framework mmen-Mg2(dobpdc)
journal, April 2012
- McDonald, Thomas M.; Lee, Woo Ram; Mason, Jarad A.
- Journal of the American Chemical Society, Vol. 134, Issue 16, p. 7056-7065