Self-supporting activated carbon/carbon nanotube/reduced graphene oxide flexible electrode for high performance supercapacitor

Li, Xing; Tang, Yao; Song, Junhua; Yang, Wei; Wang, Mingshan; Zhu, Chengzhou; Zhao, Wengao; Zheng, Jianming; Lin, Yuehe

doi:10.1016/J.CARBON.2017.11.099

Title: Self-supporting activated carbon/carbon nanotube/reduced graphene oxide flexible electrode for high performance supercapacitor

Journal Article · Wed Dec 06 00:00:00 EST 2017 · Carbon

DOI:https://doi.org/10.1016/J.CARBON.2017.11.099· OSTI ID:1413463

Li, Xing ^[1]; Tang, Yao ^[1]; Song, Junhua ^[2]; Yang, Wei ^[1]; Wang, Mingshan ^[1]; Zhu, Chengzhou ^[3]; Zhao, Wengao ^[4]; Zheng, Jianming ^[4]; Lin, Yuehe ^[3]

Southwest Petroleum Univ., Chengdu (China). The Center of New Energy Materials and Technology
Washington State Univ., Pullman, WA (United States). School of Mechanical and Materials Engineering; Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Washington State Univ., Pullman, WA (United States). School of Mechanical and Materials Engineering
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

A self-supporting and flexible activated carbon/carbon nanotube/reduced graphene oxide (AC/CNT/RGO) film has been rationally designed for constructing high-performance supercapacitor. We prepared the AC/CNT/RGO film by anchoring the AC particles with a 3D and porous framework built by hierarchically weaving the 1 D CNT and 2D RGO using their intrinsic van der Waals force. The CNT network is beneficial for improving the electronic conductivity of the electrode, while the AC particles could effectively suppress the aggregation of RGO and CNT due to their blocking effect. The synergistic effects among the AC, CNT and RGO validate the AC/CNT/RGO as a promising electrode for supercapacitor, exhibiting greatly enhanced electrochemical performances in comparison with the pure RGO film, pure CNT film and AC electrode. Furthermore, the AC/CNT/RGO electrode delivers a high specific capacitance of 101 F g^-1 at the current density of 0.2 A g^-1 offering a maximum energy density of 30.0 W h kg^-1 in organic electrolyte at the cut-off voltage range of 0.001–3.0 V. The findings of this work open a new avenue for the design of self-supporting electrodes for the development of flexible and light weight energy storage supercapacitor.

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Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: 51474196; 51502250; 2016RZ0071; 2017JQ0044; AC05-76RL01830

OSTI ID:: 1413463

Report Number(s):: PNNL-SA-130448; PII: S0008622317312277

Journal Information:: Carbon, Vol. 129; ISSN 0008-6223

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 187 works

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References (36)

Three dimensional graphene based materials: Synthesis and applications from energy storage and conversion to electrochemical sensor and environmental remediation Wang, Hou; Yuan, Xingzhong; Zeng, Guangming Advances in Colloid and Interface Science, Vol. 221 https://doi.org/10.1016/j.cis.2015.04.005	journal	July 2015
MATERIALS SCIENCE: Electrochemical Capacitors for Energy Management Miller, J. R.; Simon, P. Science, Vol. 321, Issue 5889 https://doi.org/10.1126/science.1158736	journal	August 2008
On the molecular origin of supercapacitance in nanoporous carbon electrodes Merlet, Céline; Rotenberg, Benjamin; Madden, Paul A. Nature Materials, Vol. 11, Issue 4 https://doi.org/10.1038/nmat3260	journal	March 2012
Ultrathin Planar Graphene Supercapacitors Yoo, Jung Joon; Balakrishnan, Kaushik; Huang, Jingsong Nano Letters, Vol. 11, Issue 4 https://doi.org/10.1021/nl200225j	journal	April 2011
Flexible energy storage devices based on nanocomposite paper Pushparaj, Victor L.; Shaijumon, Manikoth M.; Kumar, Ashavani Proceedings of the National Academy of Sciences, Vol. 104, Issue 34, p. 13574-13577 https://doi.org/10.1073/pnas.0706508104	journal	August 2007
Graphene-Based Supercapacitor with an Ultrahigh Energy Density Liu, Chenguang; Yu, Zhenning; Neff, David Nano Letters, Vol. 10, Issue 12 https://doi.org/10.1021/nl102661q	journal	December 2010
Mn₃O₄−Graphene Hybrid as a High-Capacity Anode Material for Lithium Ion Batteries Wang, Hailiang; Cui, Li-Feng; Yang, Yuan Journal of the American Chemical Society, Vol. 132, Issue 40, p. 13978-13980 https://doi.org/10.1021/ja105296a	journal	October 2010
Graphene-Based Ultracapacitors Stoller, Meryl D.; Park, Sungjin; Zhu, Yanwu Nano Letters, Vol. 8, Issue 10 https://doi.org/10.1021/nl802558y	journal	October 2008
Materials for electrochemical capacitors Simon, Patrice; Gogotsi, Yury Nature Materials, Vol. 7, Issue 11 https://doi.org/10.1038/nmat2297	journal	November 2008
Fiber Supercapacitors Utilizing Pen Ink for Flexible/Wearable Energy Storage Fu, Yongping; Cai, Xin; Wu, Hongwei Advanced Materials, Vol. 24, Issue 42 https://doi.org/10.1002/adma.201202930	journal	August 2012
Controlled thin graphitic petal growth on oxidized silicon Xiong, Guoping; Hembram, K. P. S. S.; Zakharov, Dmitri N. Diamond and Related Materials, Vol. 27-28 https://doi.org/10.1016/j.diamond.2012.05.002	journal	July 2012
Fabrication of a Class of Nanostructured Materials Using Carbon Nanowalls as the Templates Wu, Y. H.; Yang, B. J.; Han, G. C. Advanced Functional Materials, Vol. 12, Issue 8 https://doi.org/10.1002/1616-3028(20020805)12:8<489::AID-ADFM489>3.0.CO;2-X	journal	August 2002
Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition Chen, Zongping; Ren, Wencai; Gao, Libo Nature Materials, Vol. 10, Issue 6, p. 424-428 https://doi.org/10.1038/nmat3001	journal	April 2011
3D graphene-based hybrid materials: synthesis and applications in energy storage and conversion Shi, Qiurong; Cha, Younghwan; Song, Yang Nanoscale, Vol. 8, Issue 34 https://doi.org/10.1039/C6NR04770J	journal	January 2016
Functionalized graphene sheets for polymer nanocomposites Ramanathan, T.; Abdala, A. A.; Stankovich, S. Nature Nanotechnology, Vol. 3, Issue 6, p. 327-331 https://doi.org/10.1038/nnano.2008.96	journal	May 2008
Charging graphene for energy Liu, Jun Nature Nanotechnology, Vol. 9, Issue 10 https://doi.org/10.1038/nnano.2014.233	journal	October 2014
Supercapacitors Based on Flexible Graphene/Polyaniline Nanofiber Composite Films Wu, Qiong; Xu, Yuxi; Yao, Zhiyi ACS Nano, Vol. 4, Issue 4, p. 1963-1970 https://doi.org/10.1021/nn1000035	journal	March 2010
Flexible Pillared Graphene-Paper Electrodes for High-Performance Electrochemical Supercapacitors Wang, Gongkai; Sun, Xiang; Lu, Fengyuan Small, Vol. 8, Issue 3 https://doi.org/10.1002/smll.201101719	journal	December 2011
Dispersing Carbon Nanotubes with Graphene Oxide in Water and Synergistic Effects between Graphene Derivatives Qiu, Ling; Yang, Xiaowei; Gou, Xinglong Chemistry - A European Journal, Vol. 16, Issue 35 https://doi.org/10.1002/chem.201001771	journal	August 2010
Intercalation of mesoporous carbon spheres between reduced graphene oxide sheets for preparing high-rate supercapacitor electrodes Lei, Zhibin; Christov, Nikolay; Zhao, X. S. Energy & Environmental Science, Vol. 4, Issue 5 https://doi.org/10.1039/c1ee01094h	journal	January 2011
Assembly of Graphene Sheets into Hierarchical Structures for High-Performance Energy Storage Yin, Shengyan; Zhang, Yanyan; Kong, Junhua ACS Nano, Vol. 5, Issue 5 https://doi.org/10.1021/nn2001728	journal	April 2011
Synthesis and electrochemical performance of Li2FeSiO4/carbon/carbon nano-tubes for lithium ion battery Huang, Xiaobing; Li, Xing; Wang, Haiyan Electrochimica Acta, Vol. 55, Issue 24 https://doi.org/10.1016/j.electacta.2010.07.036	journal	October 2010
Asymmetric supercapacitors based on nano-architectured nickel oxide/graphene foam and hierarchical porous nitrogen-doped carbon nanotubes with ultrahigh-rate performance Wang, Huanwen; Yi, Huan; Chen, Xiao J. Mater. Chem. A, Vol. 2, Issue 9 https://doi.org/10.1039/C3TA15046A	journal	January 2014
Mechanically Strong, Electrically Conductive, and Biocompatible Graphene Paper Chen, Haiqun; Müller, Marc B.; Gilmore, Kerry J. Advanced Materials, Vol. 20, Issue 18, p. 3557-3561 https://doi.org/10.1002/adma.200800757	journal	July 2008
Controlled growth of nanostructured MnO2 on carbon nanotubes for high-performance electrochemical capacitors Huang, Huajie; Zhang, Wenyao; Fu, Yongsheng Electrochimica Acta, Vol. 152 https://doi.org/10.1016/j.electacta.2014.11.162	journal	January 2015
Enhanced Capacitance of Thermally Reduced Hexagonal Graphene Oxide for High Performance Supercapacitor Fouda, A. N.; Assy, M. K. Abu; El Enany, Gaber Fullerenes, Nanotubes and Carbon Nanostructures, Vol. 23, Issue 7 https://doi.org/10.1080/1536383X.2014.943889	journal	September 2014
Rapid thermal decomposition of confined graphene oxide films in air Chen, Xianjue; Meng, Dongli; Wang, Bin Carbon, Vol. 101 https://doi.org/10.1016/j.carbon.2016.01.075	journal	May 2016
Graphene Oxide-Assisted Dispersion of Pristine Multiwalled Carbon Nanotubes in Aqueous Media Zhang, Chao; Ren, Lulu; Wang, Xiaoyan The Journal of Physical Chemistry C, Vol. 114, Issue 26 https://doi.org/10.1021/jp103745g	journal	June 2010
A flexible graphene/multiwalled carbon nanotube film as a high performance electrode material for supercapacitors Lu, Xiangjun; Dou, Hui; Gao, Bo Electrochimica Acta, Vol. 56, Issue 14 https://doi.org/10.1016/j.electacta.2011.03.066	journal	May 2011
Nanocomposites of Graphene Nanosheets/Multiwalled Carbon Nanotubes as Electrodes for In-plane Supercapacitors Trigueiro, João Paulo C.; Lavall, Rodrigo L.; Silva, Glaura G. Electrochimica Acta, Vol. 187 https://doi.org/10.1016/j.electacta.2015.11.053	journal	January 2016
Atomic Force and Scanning Tunneling Microscopy Imaging of Graphene Nanosheets Derived from Graphite Oxide Paredes, J. I.; Villar-Rodil, S.; Solís-Fernández, P. Langmuir, Vol. 25, Issue 10 https://doi.org/10.1021/la804216z	journal	May 2009
Electrical conductivity in graphene with point defects Skrypnyk, Yuriy V.; Loktev, Vadim M. Physical Review B, Vol. 82, Issue 8 https://doi.org/10.1103/PhysRevB.82.085436	journal	August 2010
Reduced graphene oxide-carbon nanotube grown on carbon fiber as binder-free electrode for flexible high-performance fiber supercapacitors Xiong, Chuanyin; Li, Tiehu; Zhao, Tingkai Composites Part B: Engineering, Vol. 116 https://doi.org/10.1016/j.compositesb.2017.02.028	journal	May 2017
Electrochemical Kinetics and Performance of Layered Composite Cathode Material Li[Li _0.2 Ni _0.2 Mn _0.6 ]O ₂ Zheng, Jianming; Shi, Wei; Gu, Meng Journal of The Electrochemical Society, Vol. 160, Issue 11 https://doi.org/10.1149/2.090311jes	journal	January 2013
Improved rate capability of a LiNi _1/3 Co _1/3 Mn _1/3 O ₂ /CNT/graphene hybrid material for Li-ion batteries Li, Xing; Zhao, Xing; Wang, Ming-Shan RSC Advances, Vol. 7, Issue 39 https://doi.org/10.1039/C7RA03438E	journal	January 2017
Freestanding Aligned Multi-walled Carbon Nanotubes for Supercapacitor Devices Moreira, João Vitor Silva; Corat, Evaldo José; May, Paul William Journal of Electronic Materials, Vol. 45, Issue 11 https://doi.org/10.1007/s11664-016-4817-6	journal	August 2016

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