Controlling Magnetism via Transition Metal Exchange in the Series of Intermetallics Eu(T1,T2)5In (T = Cu, Ag, Au)

Mudring, Anja -Verena; Smetana, Volodymyr; Pecharsky, Vitalij K.; Mudryk, Yaroslav

doi:10.1039/C7TC04964A

Title: Controlling Magnetism via Transition Metal Exchange in the Series of Intermetallics Eu(T1,T2)5In (T = Cu, Ag, Au)

Journal Article · Fri Nov 24 00:00:00 EST 2017 · Journal of Materials Chemistry C

DOI:https://doi.org/10.1039/C7TC04964A· OSTI ID:1410343

Mudring, Anja -Verena ^[1]; Smetana, Volodymyr ^[1]; Pecharsky, Vitalij K. ^[2]; Mudryk, Yaroslav ^[2]

Stockholm Univ., Stockholm (Sweden)
Ames Lab. and Iowa State Univ., Ames, IA (United States)

Three series of intermetallic compounds Eu(T1,T2)₅In (T = Cu, Ag, Au) have been investigated in full compositional ranges. Single crystals of all compounds have been obtained by self-flux and were analyzed by single X-ray diffraction revealing the representatives to fall into two structure types: CeCu₆ (oP28, Pnma, a = 8.832(3)–9.121(2) Å, b = 5.306(2)–5.645(1) Å, c = 11.059(4)–11.437(3) Å, V = 518.3(3)–588.9(2) Å³) and YbMo2Al4 (tI14, I4/mmm, a = 5.417(3)–5.508(1) Å, c = 7.139(2)– 7.199(2) Å, V = 276.1(2)–285.8(1) Å³). The structural preference was found to depend on the cation/anion size ratio, while the positional preference within the CeCu₆ type structure shows an apparent correlation with the anion size. Chemical compression, hence, a change in cell volume, which occurs upon anion substitution appears to be the main driving force for the change of magnetic ordering. While EuAg₅In shows antiferromagnetic behavior at low temperatures, mixing Cu and Au within the same type of structure results in considerable changes in the magnetism. The Eu(Cu,Au)₅In alloys with CeCu₆ structure show complex magnetic behaviors and strong magnetic field-induced spin-reorientation transition with the critical field of the transition being dependent on Cu/Au ratio. The alloys adopting the YbMo₂Al₄ type structure are ferromagnets exhibiting unusually high magnetic moments. The heat capacity of EuAu_2.66Cu_2.34In reveals a double-peak structure evolving with the magnetic field. Furthermore, low-temperature X-ray powder diffraction does not show a structural transition.

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Research Organization:: Ames Lab., Ames, IA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1410343

Report Number(s):: IS-J-9502; JMCCCX

Journal Information:: Journal of Materials Chemistry C, Vol. 6; ISSN 2050-7526

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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References (38)

A Transition from Localized to Strongly Correlated Electron Behavior and Mixed Valence Driven by Physical or Chemical Pressure in ACo ₂ As ₂ (A = Eu and Ca) Tan, Xiaoyan; Fabbris, Gilberto; Haskel, Daniel Journal of the American Chemical Society, Vol. 138, Issue 8 https://doi.org/10.1021/jacs.5b12659	journal	February 2016
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Cation-Poor Complex Metallic Alloys in Ba(Eu)–Au–Al(Ga) Systems: Identifying the Keys that Control Structural Arrangements and Atom Distributions at the Atomic Level Smetana, Volodymyr; Steinberg, Simon; Mudryk, Yaroslav Inorganic Chemistry, Vol. 54, Issue 21 https://doi.org/10.1021/acs.inorgchem.5b01633	journal	October 2015
An empirical correction for absorption anisotropy Blessing, R. H. Acta Crystallographica Section A Foundations of Crystallography, Vol. 51, Issue 1 https://doi.org/10.1107/S0108767394005726	journal	January 1995
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
The crystal structure of CeCu ₆ Cromer, D. T.; Larson, A. C.; Roof, R. B. Acta Crystallographica, Vol. 13, Issue 11 https://doi.org/10.1107/S0365110X60002235	journal	November 1960
Crystal structure of the ternary R.E.Mo2Al4 phases (R.E. = Gd, Er, Yb) Fornasini, M. L.; Palenzona, A. Journal of the Less Common Metals, Vol. 45, Issue 1 https://doi.org/10.1016/0022-5088(76)90205-8	journal	February 1976
SrAu4.76In1.24 with YbMo2Al4-type Structure Muts, I.; Matar, S. F.; Rodewald, U. Ch. Zeitschrift für Naturforschung B, Vol. 66 https://doi.org/10.5560/ZNB.2011.66b0993	journal	January 2011
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set Kresse, G.; Furthmüller, J. Computational Materials Science, Vol. 6, Issue 1, p. 15-50 https://doi.org/10.1016/0927-0256(96)00008-0	journal	July 1996
Long-range antiferromagnetic order in CeCu5.5Au0.5 Chattopadhyay, T.; v. Löhneysen, H.; Trappmann, T. Zeitschrift für Physik B Condensed Matter, Vol. 80, Issue 2 https://doi.org/10.1007/BF01357496	journal	June 1990
Tunable magnetic regenerator alloys with a giant magnetocaloric effect for magnetic refrigeration from ∼20 to ∼290 K Pecharsky, V. K.; Gschneidner, K. A. Applied Physics Letters, Vol. 70, Issue 24 https://doi.org/10.1063/1.119206	journal	June 1997
Controlling Magnetic Ordering in Ca _{1– x} Eu _x Co ₂ As ₂ by Chemical Compression Tan, Xiaoyan; Yaroslavtsev, Alexander A.; Cao, Huibo Chemistry of Materials, Vol. 28, Issue 20 https://doi.org/10.1021/acs.chemmater.6b03184	journal	October 2016
Linear infinite cadmium chains in CaAu4Cd2 and other intermetallics with YbMo2Al4-type structure Tappe, Frank; Matar, Samir F.; Schwickert, Christian Monatshefte für Chemie - Chemical Monthly, Vol. 144, Issue 6 https://doi.org/10.1007/s00706-013-0932-8	journal	February 2013
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
Na8Au9.8(4)Ga7.2 and Na17Au5.87(2)Ga46.63: The diversity of pseudo 5-fold symmetries in the Na–Au–Ga system Smetana, Volodymyr; Corbett, John D.; Miller, Gordon J. Journal of Solid State Chemistry, Vol. 207 https://doi.org/10.1016/j.jssc.2013.08.017	journal	November 2013
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Magnetic ordering in CeCu6−x Au x single crystals: Thermodynamic and transport properties Schlager, H. G.; Schröder, A.; Welsch, M. Journal of Low Temperature Physics, Vol. 90, Issue 3-4 https://doi.org/10.1007/BF00681999	journal	February 1993
Infinite Linear Zinc Chains in A Au ₄ Zn ₂ ( A = Ca, Ce, Pr, Nd) with YbAl ₄ Mo ₂ Type Structure : Linear Zinc Chains in Gerke, Birgit; Niehaus, Oliver; Hoffmann, Rolf-Dieter Zeitschrift für anorganische und allgemeine Chemie, Vol. 639, Issue 14 https://doi.org/10.1002/zaac.201300260	journal	July 2013
Crystal structure refinement with SHELXL Sheldrick, George M. Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue 1, p. 3-8 https://doi.org/10.1107/S2053229614024218	journal	January 2015
Anomalous susceptibility in single crystals of EuCo ₂ Si ₂ with trivalent Eu: Influence of excited J multiplets Seiro, Silvia; Kummer, Kurt; Vyalikh, Denis physica status solidi (b), Vol. 250, Issue 3 https://doi.org/10.1002/pssb.201200892	journal	February 2013
Gd5(SixGe1-x)4: An Extremum Material Pecharsky, V. K.; Gschneidner Jr., K. A. Advanced Materials, Vol. 13, Issue 9 https://doi.org/10.1002/1521-4095(200105)13:9<683::AID-ADMA683>3.0.CO;2-O	journal	May 2001
Long-range magnetic order in Ce(Cu 1-x Ag x ) 6 Gangopadhyay, A. K.; Lettau, K.; Lettau, C. Journal of Magnetism and Magnetic Materials, Vol. 103, Issue 3 https://doi.org/10.1016/0304-8853(92)90199-X	journal	January 1992
Gold Polar Intermetallics: Structural Versatility through Exclusive Bonding Motifs Smetana, Volodymyr; Rhodehouse, Melissa; Meyer, Gerd Accounts of Chemical Research, Vol. 50, Issue 11 https://doi.org/10.1021/acs.accounts.7b00316	journal	October 2017
Ab initiomolecular dynamics for liquid metals Kresse, G.; Hafner, J. Physical Review B, Vol. 47, Issue 1, p. 558-561 https://doi.org/10.1103/PhysRevB.47.558	journal	January 1993
EuNi ₅ InH _1.5−x (x = 0–1.5): hydrogen induced structural and magnetic transitions Bigun, Inna; Smetana, Volodymyr; Mudryk, Yaroslav Journal of Materials Chemistry C, Vol. 5, Issue 12 https://doi.org/10.1039/C7TC00121E	journal	January 2017
Synthesis, Crystal Structure, and Magnetic Properties of UFe5Sn Gonçalves, A. P.; Godinho, M.; Noël, H. Journal of Solid State Chemistry, Vol. 154, Issue 2 https://doi.org/10.1006/jssc.2000.8878	journal	November 2000
Magnetocaloric Behavior in Ternary Europium Indides EuT ₅ In: Probing the Design Capability of First-Principles-Based Methods on the Multifaceted Magnetic Materials Bigun, Inna; Steinberg, Simon; Smetana, Volodymyr Chemistry of Materials, Vol. 29, Issue 6 https://doi.org/10.1021/acs.chemmater.6b04782	journal	November 2016
Pronounced matrix effect in YbMo2Al4-type Ca(AuxZn2−x)Au4 (x=0.09–0.89) Mishra, Trinath; Lin, Qisheng; Corbett, John D. Journal of Solid State Chemistry, Vol. 218 https://doi.org/10.1016/j.jssc.2014.06.019	journal	October 2014
LuNi5Sn: A first representative of RNi5Sn stannides with CeCu5Au structure Romaka, V. V.; Marciniak, B.; Romaka, L. Journal of Alloys and Compounds, Vol. 493, Issue 1-2 https://doi.org/10.1016/j.jallcom.2009.12.073	journal	March 2010
SHELXT – Integrated space-group and crystal-structure determination Sheldrick, George M. Acta Crystallographica Section A Foundations and Advances, Vol. 71, Issue 1, p. 3-8 https://doi.org/10.1107/S2053273314026370	journal	January 2015
Structure and electrical resistivity of the heavy fermion compound CeCu ₅ Au Ruck, M.; Portisch, G.; Schlager, H. G. Acta Crystallographica Section B Structural Science, Vol. 49, Issue 6 https://doi.org/10.1107/S0108768193005233	journal	December 1993
Exploratory Syntheses and Structures of SrAu _4.3 In _1.7 and CaAg _3.5 In _1.9 : Electron-Poor Intermetallics with Diversified Polyanionic Frameworks That Are Derived from the CaAu ₄ In ₂ Approximant Lin, Qisheng; Corbett, John D. Inorganic Chemistry, Vol. 50, Issue 21 https://doi.org/10.1021/ic2016275	journal	November 2011
X-ray powder diffractometer for in situ structural studies in magnetic fields from 0 to 35 kOe between 2.2 and 315 K Holm, Aaron Patrick; Pecharsky, Vitalij K.; Gschneidner, Karl A. Review of Scientific Instruments, Vol. 75, Issue 4 https://doi.org/10.1063/1.1667253	journal	April 2004
Covalent radii revisited Cordero, Beatriz; Gómez, Verónica; Platero-Prats, Ana E. Dalton Transactions, Issue 21 https://doi.org/10.1039/b801115j	journal	January 2008
Reducing Dzyaloshinskii-Moriya interaction and field-free spin-orbit torque switching in synthetic antiferromagnets Chen, Ruyi; Cui, Qirui; Liao, Liyang Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-23414-3	journal	May 2021
High-resolution X-ray luminescence extension imaging Ou, Xiangyu; Qin, Xian; Huang, Bolong Nature, Vol. 590, Issue 7846 https://doi.org/10.1038/s41586-021-03251-6	journal	February 2021
Electronic structure of AlFeN films exhibiting crystallographic orientation change from c- to a-axis with Fe concentrations and annealing effect Tatemizo, Nobuyuki; Imada, Saki; Okahara, Kizuna Scientific Reports, Vol. 10, Issue 1 https://doi.org/10.1038/s41598-020-58835-5	journal	February 2020
SrAu _4.76 In _1.24 with YbMo ₂ Al ₄ -type Structure Muts, Ihor; Matar, Samir F.; Rodewald, Ute Ch. Zeitschrift für Naturforschung B, Vol. 66, Issue 10 https://doi.org/10.1515/znb-2011-1003	journal	October 2011

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Title: Controlling Magnetism via Transition Metal Exchange in the Series of Intermetallics Eu(T1,T2)5In (T = Cu, Ag, Au)

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