Field-assisted sintering and phase transition of ZnS-CaLa2S4 composite ceramics

Li, Yiyu; Zhang, Lihua; Kisslinger, Kim; Wu, Yiquan

doi:10.1016/j.jeurceramsoc.2017.07.009

Title: Field-assisted sintering and phase transition of ZnS-CaLa₂S₄ composite ceramics

Journal Article · Mon Jul 17 00:00:00 EDT 2017 · Journal of the European Ceramic Society

DOI:https://doi.org/10.1016/j.jeurceramsoc.2017.07.009· OSTI ID:1409645

Li, Yiyu ^[1]; Zhang, Lihua ^[2]; Kisslinger, Kim ^[2]; Wu, Yiquan ^[1]

Alfred Univ., Alfred, NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)

In the present study, zinc sulfide (ZnS) and calcium lanthanum sulfide (CaLa₂S₄, CLS) composite ceramics were consolidated via field-assisted sintering of 0.5ZnS-0.5CLS (volume ratio) composite powders at 800–1050 °C. Through sintering curve analyses and microstructural observations, it was determined that between 800 and 1000 °C, grain boundary diffusion was the main mechanism controlling grain growth for both the ZnS and CLS phases within the composite ceramics. The consolidated composite ceramics were determined to be composed of sphalerite ZnS, wurtzite ZnS and thorium phosphate CLS. The sphalerite-wurtzite phase transition of ZnS was further demonstrated to be accompanied by the formation of stacking faults and twins in the ceramics. Furthermore, it was also found that the addition of the CLS phase improved the indentation hardness of the ceramics relative to pure ZnS by homogeneous dispersion of ZnS and CLS small grains.

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Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704

OSTI ID:: 1409645

Alternate ID(s):: OSTI ID: 1549595

Report Number(s):: BNL-114702-2017-JA; R&D Project: 16060; 16060; KC0403020

Journal Information:: Journal of the European Ceramic Society, Vol. 37, Issue 15; ISSN 0955-2219

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 4 works

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