Synthesis, structure, and excited state kinetics of heteroleptic Cu(i) complexes with a new sterically demanding phenanthroline ligand

Kohler, Lars; Hadt, Ryan G.; Hayes, Dugan; Chen, Lin X.; Mulfort, Karen L.

doi:10.1039/C7DT02476B

Title: Synthesis, structure, and excited state kinetics of heteroleptic Cu(i) complexes with a new sterically demanding phenanthroline ligand

Journal Article · Mon Sep 25 00:00:00 EDT 2017 · Dalton Transactions

DOI:https://doi.org/10.1039/C7DT02476B· OSTI ID:1402055

Kohler, Lars ^[1]; Hadt, Ryan G. ^[1]; Hayes, Dugan ^[1]; Chen, Lin X. ^[1]; Mulfort, Karen L. ^[1]

Argonne National Lab. (ANL), Argonne, IL (United States)

In this report we describe the synthesis of a new phenanthroline ligand, 2,9-di(2,4,6-tri-isopropyl-phenyl)-1,10-phenanthroline (bL2) and its use as the blocking ligand in the preparation of two new heteroleptic Cu(i)diimine complexes.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1402055

Alternate ID(s):: OSTI ID: 1402497

Journal Information:: Dalton Transactions, Vol. 46, Issue 38; ISSN 1477-9226

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 38 works

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

CCDC 1515480: Experimental Crystal Structure Determination: DEBWAL : (2,9-bis(2,4,6-triisopropylphenyl)-1,10-phenanthroline)-(2,9-dimethyl-1,10-phenanthroline)-copper(i) hexafluorophosphate diethyl ether solvate Kohler, Lars; Hadt, Ryan; Hayes, Dugan https://doi.org/10.5517/ccdc.csd.cc1mvzgx The current record is supplemented by this dataset	dataset	August 2017
CCDC 1515481: Experimental Crystal Structure Determination: DEBVUE : (2,9-bis(2,4,6-triisopropylphenyl)-1,10-phenanthroline)-(1,10-phenanthroline)-copper(i) hexafluorophosphate dichloromethane solvate Kohler, Lars; Hadt, Ryan G.; Hayes, Dugan https://doi.org/10.5517/ccdc.csd.cc1mvzhy The current record is supplemented by this dataset	dataset	August 2017