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Title: Improved fracture toughness for copper oxide superconductors

Patent Application ·
OSTI ID:140148

An oxide-based strengthening and toughening agent, such as tetragonal Zro{sub 2} particles, has been added to copper oxide superconductors, such as superconducting YBa{sub 2}Cu{sub 3}O{sub x} (123) to improve it fracture toughness (K{sub IC}). A sol-gel coating which is non-reactive with the superconductor, such as Y{sub 2}BaCuO{sub 5} (211) on the ZrO{sub 2} particles minimized the deleterious reactions between the superconductor and the toughening agent dispersed therethrough. Addition of 20 mole percent ZrO{sub 2} coated with 211 yielded a 123 composite with a K{sub IC} of 4.5 MPa(m){sup 0.5}.

Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
W-31109-ENG-38
Assignee:
Dept. of Energy
Patent Number(s):
PATENTS-US-A7761551
Application Number:
ON: DE94003058; PAN: 7-761,551
OSTI ID:
140148
Resource Relation:
Other Information: PBD: 1991
Country of Publication:
United States
Language:
English