Functionalizing the Surface of Lithium-Metal Anodes

Buonaiuto, Megan; Neuhold, Susanna; Schroeder, David J.; Lopez, Carmen M.; Vaughey, John T.

doi:10.1002/cplu.201402084

Title: Functionalizing the Surface of Lithium-Metal Anodes

Journal Article · Wed Sep 03 00:00:00 EDT 2014 · ChemPlusChem

DOI:https://doi.org/10.1002/cplu.201402084· OSTI ID:1392338

Buonaiuto, Megan ^[1]; Neuhold, Susanna ^[1]; Schroeder, David J. ^[2]; Lopez, Carmen M. ^[1]; Vaughey, John T. ^[1]

Argonne National Lab. (ANL), Argonne, IL (United States)
Northern Illinois Univ., DeKalb, IL (United States)

Metal-air batteries are an important aspect of many beyond lithium ion research efforts. However, as our understanding of how molecular oxygen can act as a rechargeable cathode has progressed; the problems associated with how these materials at various states of charge interact with the lithium metal anode are only beginning to come to the surface. In this study we have devised a method to coat the surface a lithium with a functional group to act as either an anchor for further derivation studies or be polymerized to create a nanometer thick polymer coating attached to the surface by silane groups. These stable films, formed by polymerization of vinyl substituents, lower cell impedance at the electrode and over the first 50 cycles, increase cycling efficiency and demonstrate lower capacity fade.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1392338

Journal Information:: ChemPlusChem, Vol. 80, Issue 2; ISSN 2192-6506

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 9 works

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References (19)

Impact of ethyl tris-2-methoxyethoxy silane on the passivation of graphite electrode in Li-ion cells with PC-based electrolyte Schroeder, G.; Gierczyk, B.; Waszak, D. Electrochemistry Communications, Vol. 8, Issue 10, p. 1583-1587 https://doi.org/10.1016/j.elecom.2006.07.030	journal	October 2006
Pretreatment of Li metal anode with electrolyte additive for enhancing Li cycleability Ishikawa, Masashi; Kawasaki, Hiromi; Yoshimoto, Nobuko Journal of Power Sources, Vol. 146, Issue 1-2 https://doi.org/10.1016/j.jpowsour.2005.03.007	journal	August 2005
Effect of surface preparation and R-group size on the stabilization of lithium metal anodes with silanes Neuhold, Susanna; Schroeder, David J.; Vaughey, John T. Journal of Power Sources, Vol. 206 https://doi.org/10.1016/j.jpowsour.2012.01.129	journal	May 2012
Advances in Li–S batteries Ji, Xiulei; Nazar, Linda F. Journal of Materials Chemistry, Vol. 20, Issue 44, p. 9821-9826 https://doi.org/10.1039/b925751a	journal	January 2010
Stabilization of lithium metal anodes using silane-based coatings Thompson, Rebecca S.; Schroeder, David J.; López, Carmen M. Electrochemistry Communications, Vol. 13, Issue 12 https://doi.org/10.1016/j.elecom.2011.08.012	journal	December 2011
Protection of Lithium Metal Surfaces Using Chlorosilanes Marchioni, Filippo; Star, Kurt; Menke, Erik Langmuir, Vol. 23, Issue 23 https://doi.org/10.1021/la701662r	journal	November 2007
Insights into the Role of Interphasial Morphology on the Electrochemical Performance of Lithium Electrodes López, Carmen M.; Vaughey, John T.; Dees, Dennis W. Journal of The Electrochemical Society, Vol. 159, Issue 6 https://doi.org/10.1149/2.100206jes	journal	January 2012
Morphological Transitions on Lithium Metal Anodes López, Carmen M.; Vaughey, John T.; Dees, Dennis W. Journal of The Electrochemical Society, Vol. 156, Issue 9 https://doi.org/10.1149/1.3158548	journal	January 2009
Effect of Electrode Dimensionality and Morphology on the Performance of Cu2Sb Thin Film Electrodes for Lithium-Ion Batteries Trahey, Lynn; Kung, Harold H.; Thackeray, Michael M. European Journal of Inorganic Chemistry, Vol. 2011, Issue 26 https://doi.org/10.1002/ejic.201100329	journal	August 2011
In-situ FTIR investigations on the reduction of vinylene electrolyte additives suitable for use in lithium-ion batteries Santner, H. J.; Korepp, C.; Winter, M. Analytical and Bioanalytical Chemistry, Vol. 379, Issue 2 https://doi.org/10.1007/s00216-004-2522-4	journal	May 2004
Limited Stability of Ether-Based Solvents in Lithium–Oxygen Batteries Ryan, Kate R.; Trahey, Lynn; Ingram, Brian J. The Journal of Physical Chemistry C, Vol. 116, Issue 37 https://doi.org/10.1021/jp306797s	journal	September 2012
Electrochemical control of a Li metal anode interface: improvement of Li cyclability by inorganic additives compatible with electrolytes Ishikawa, Masashi; Machino, Shin-ichi; Morita, Masayuki Journal of Electroanalytical Chemistry, Vol. 473, Issue 1-2 https://doi.org/10.1016/S0022-0728(99)00170-9	journal	September 1999
History, Evolution, and Future Status of Energy Storage Whittingham, M. S. Proceedings of the IEEE, Vol. 100, Issue Special Centennial Issue https://doi.org/10.1109/JPROC.2012.2190170	journal	May 2012
X-Ray Photoelectron Spectroscopic Analysis and Scanning Electron Microscopic Observation of the Lithium Surface Immersed in Nonaqueous Solvents Kanamura, Kiyoshi Journal of The Electrochemical Society, Vol. 141, Issue 9 https://doi.org/10.1149/1.2055129	journal	January 1994
Importance of ‘unimportant’ experimental parameters in Li–S battery development Urbonaite, Sigita; Novák, Petr Journal of Power Sources, Vol. 249 https://doi.org/10.1016/j.jpowsour.2013.10.095	journal	March 2014
Rechargeable Li ₂ O ₂ Electrode for Lithium Batteries Ogasawara, Takeshi; Débart, Aurélie; Holzapfel, Michael Journal of the American Chemical Society, Vol. 128, Issue 4 https://doi.org/10.1021/ja056811q	journal	February 2006
Thin-Film Cu[sub 6]Sn[sub 5] Electrodes: Synthesis, Properties, and Current Collector Interactions Kim, Il-Seok; Vaughey, J. T.; Auciello, O. Journal of The Electrochemical Society, Vol. 155, Issue 6 https://doi.org/10.1149/1.2904525	journal	January 2008
Analysis of Vinylene Carbonate Derived SEI Layers on Graphite Anode Ota, Hitoshi; Sakata, Yuuichi; Inoue, Atsuyoshi Journal of The Electrochemical Society, Vol. 151, Issue 10 https://doi.org/10.1149/1.1785795	journal	January 2004
Investigation of Lithium Electrodeposits Formed in Practical Rechargeable Li-Li[sub x]MnO[sub 2] Batteries Based on LiAsF[sub 6]/1,3-Dioxolane Solutions Zinigrad, E.; Levi, E.; Teller, H. Journal of The Electrochemical Society, Vol. 151, Issue 1 https://doi.org/10.1149/1.1630591	journal	January 2004

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A Review of Solid Electrolyte Interphases on Lithium Metal Anode Cheng, Xin-Bing; Zhang, Rui; Zhao, Chen-Zi Advanced Science, Vol. 3, Issue 3 https://doi.org/10.1002/advs.201500213	journal	November 2015
Review on Li-Sulfur Battery Systems: an Integral Perspective Rosenman, Ariel; Markevich, Elena; Salitra, Gregory Advanced Energy Materials, Vol. 5, Issue 16 https://doi.org/10.1002/aenm.201500212	journal	May 2015
Fluorinated reduced graphene oxide as a protective layer on the metallic lithium for application in the high energy batteries Bobnar, Jernej; Lozinšek, Matic; Kapun, Gregor Scientific Reports, Vol. 8, Issue 1 https://doi.org/10.1038/s41598-018-23991-2	journal	April 2018
A chemistry and material perspective on lithium redox flow batteries towards high-density electrical energy storage Zhao, Yu; Ding, Yu; Li, Yutao Chemical Society Reviews, Vol. 44, Issue 22 https://doi.org/10.1039/c5cs00289c	journal	January 2015
Halosilane triggers anodic silanization and cathodic redox for stable and efficient lithium–O ₂ batteries Zhao, Xiaohui; Sun, Zhuang; Yao, Zhenguo Journal of Materials Chemistry A, Vol. 7, Issue 31 https://doi.org/10.1039/c9ta04268g	journal	January 2019
Pre-treatments of Lithium Foil Surface for Improving the Cycling Life of Li Metal Batteries Delaporte, Nicolas; Wang, Yuesheng; Zaghib, Karim Frontiers in Materials, Vol. 6 https://doi.org/10.3389/fmats.2019.00267	journal	November 2019

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25 ENERGY STORAGE
lithium
polymers
silanes
batteries
coating
electrochemistry
lithium metal
lithium metal
coating
batteries
surface chemistry

Title: Functionalizing the Surface of Lithium-Metal Anodes

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