Ultrahigh–current density anodes with interconnected Li metal reservoir through overlithiation of mesoporous AlF3 framework

Wang, Hansen; Lin, Dingchang; Liu, Yayuan; Li, Yuzhang; Cui, Yi

doi:10.1126/sciadv.1701301

Title: Ultrahigh–current density anodes with interconnected Li metal reservoir through overlithiation of mesoporous AlF₃ framework

Journal Article · Fri Sep 08 00:00:00 EDT 2017 · Science Advances

DOI:https://doi.org/10.1126/sciadv.1701301· OSTI ID:1389865

^[1];

^[2]

Stanford Univ., Stanford, CA (United States)
Stanford Univ., Stanford, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)

Lithium (Li) metal is the ultimate solution for next-generation high–energy density batteries but is plagued from commercialization by infinite relative volume change, low Coulombic efficiency due to side reactions, and safety issues caused by dendrite growth. These hazardous issues are further aggravated under high current densities needed by the increasing demand for fast charging/discharging. We report a one-step fabricated Li/Al₄Li₉-LiF nanocomposite (LAFN) through an “overlithiation” process of a mesoporous AlF₃ framework, which can simultaneously mitigate the abovementioned problems. Reaction-produced Al₄Li₉-LiF nanoparticles serve as the ideal skeleton for Li metal infusion, helping to achieve a near-zero volume change during stripping/plating and suppressed dendrite growth. As a result, the LAFN electrode is capable of working properly under an ultrahigh current density of 20 mA cm^–2 in symmetric cells and manifests highly improved rate capability with increased Coulombic efficiency in full cells. Here, the simple fabrication process and its remarkable electrochemical performances enable LAFN to be a promising anode candidate for next-generation lithium metal batteries.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-76SF00515; award343944; BMR program and Battery 500 Consortium

OSTI ID:: 1389865

Journal Information:: Science Advances, Vol. 3, Issue 9; ISSN 2375-2548

Publisher:: AAASCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 175 works

Citation information provided by
Web of Science

References (45)

First-principles calculation of the pressure dependence of phase equilibria in the Al-Li system Sluiter, Marcel H. F.; Watanabe, Y.; Fontaine, D. de Physical Review B, Vol. 53, Issue 10 https://doi.org/10.1103/PhysRevB.53.6137	journal	March 1996
Extending the Life of Lithium-Based Rechargeable Batteries by Reaction of Lithium Dendrites with a Novel Silica Nanoparticle Sandwiched Separator Liu, Kai; Zhuo, Denys; Lee, Hyun-Wook Advanced Materials, Vol. 29, Issue 4 https://doi.org/10.1002/adma.201603987	journal	November 2016
All-Integrated Bifunctional Separator for Li Dendrite Detection via Novel Solution Synthesis of a Thermostable Polyimide Separator Lin, Dingchang; Zhuo, Denys; Liu, Yayuan Journal of the American Chemical Society, Vol. 138, Issue 34 https://doi.org/10.1021/jacs.6b06324	journal	August 2016
The synergetic effect of lithium polysulfide and lithium nitrate to prevent lithium dendrite growth Li, Weiyang; Yao, Hongbin; Yan, Kai Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8436	journal	June 2015
Ultrathin Two-Dimensional Atomic Crystals as Stable Interfacial Layer for Improvement of Lithium Metal Anode Yan, Kai; Lee, Hyun-Wook; Gao, Teng Nano Letters, Vol. 14, Issue 10 https://doi.org/10.1021/nl503125u	journal	September 2014
The Correlation Between Surface Chemistry, Surface Morphology, and Cycling Efficiency of Lithium Electrodes in a Few Polar Aprotic Systems Aurbach, Doron Journal of The Electrochemical Society, Vol. 136, Issue 11 https://doi.org/10.1149/1.2096425	journal	January 1989
Excellent Cycle Life of Lithium-Metal Anodes in Lithium-Ion Batteries with Mussel-Inspired Polydopamine-Coated Separators Ryou, Myung-Hyun; Lee, Dong Jin; Lee, Je-Nam Advanced Energy Materials, Vol. 2, Issue 6 https://doi.org/10.1002/aenm.201100687	journal	April 2012
Surface Condition Changes in Lithium Metal Deposited in Nonaqueous Electrolyte Containing HF by Dissolution-Deposition Cycles Shiraishi, Soshi Journal of The Electrochemical Society, Vol. 146, Issue 5 https://doi.org/10.1149/1.1391818	journal	January 1999
Three-dimensional stable lithium metal anode with nanoscale lithium islands embedded in ionically conductive solid matrix Lin, Dingchang; Zhao, Jie; Sun, Jie Proceedings of the National Academy of Sciences, Vol. 114, Issue 18 https://doi.org/10.1073/pnas.1619489114	journal	April 2017
Lithium-coated polymeric matrix as a minimum volume-change and dendrite-free lithium metal anode Liu, Yayuan; Lin, Dingchang; Liang, Zheng Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms10992	journal	March 2016
A reversible dendrite-free high-areal-capacity lithium metal electrode Wang, Hui; Matsui, Masaki; Kuwata, Hiroko Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15106	journal	April 2017
Lithium/sulfur batteries with high specific energy: old challenges and new opportunities Song, Min-Kyu; Cairns, Elton J.; Zhang, Yuegang Nanoscale, Vol. 5, Issue 6 https://doi.org/10.1039/c2nr33044j	journal	January 2013
Reviving the lithium metal anode for high-energy batteries Lin, Dingchang; Liu, Yayuan; Cui, Yi Nature Nanotechnology, Vol. 12, Issue 3 https://doi.org/10.1038/nnano.2017.16	journal	March 2017
Composite lithium metal anode by melt infusion of lithium into a 3D conducting scaffold with lithiophilic coating Liang, Zheng; Lin, Dingchang; Zhao, Jie Proceedings of the National Academy of Sciences, Vol. 113, Issue 11 https://doi.org/10.1073/pnas.1518188113	journal	February 2016
Next-Generation Lithium Metal Anode Engineering via Atomic Layer Deposition Kozen, Alexander C.; Lin, Chuan-Fu; Pearse, Alexander J. ACS Nano, Vol. 9, Issue 6 https://doi.org/10.1021/acsnano.5b02166	journal	May 2015
Lithium Fluoride Additives for Stable Cycling of Lithium Batteries at High Current Densities Choudhury, Snehashis; Archer, Lynden A. Advanced Electronic Materials, Vol. 2, Issue 2 https://doi.org/10.1002/aelm.201500246	journal	January 2016
Artificial Protection Film on Lithium Metal Anode toward Long-Cycle-Life Lithium-Oxygen Batteries Liu, Qing-Chao; Xu, Ji-Jing; Yuan, Shuang Advanced Materials, Vol. 27, Issue 35 https://doi.org/10.1002/adma.201501490	journal	August 2015
Dendrite-Free Nanostructured Anode: Entrapment of Lithium in a 3D Fibrous Matrix for Ultra-Stable Lithium-Sulfur Batteries Cheng, Xin-Bing; Peng, Hong-Jie; Huang, Jia-Qi Small https://doi.org/10.1002/smll.201401837	journal	July 2014
Accommodating lithium into 3D current collectors with a submicron skeleton towards long-life lithium metal anodes Yang, Chun-Peng; Yin, Ya-Xia; Zhang, Shuai-Feng Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9058	journal	August 2015
Conformal Lithium Fluoride Protection Layer on Three-Dimensional Lithium by Nonhazardous Gaseous Reagent Freon Lin, Dingchang; Liu, Yayuan; Chen, Wei Nano Letters, Vol. 17, Issue 6 https://doi.org/10.1021/acs.nanolett.7b01020	journal	May 2017
The path towards sustainable energy Chu, Steven; Cui, Yi; Liu, Nian Nature Materials, Vol. 16, Issue 1 https://doi.org/10.1038/nmat4834	journal	December 2016
Spatially heterogeneous carbon-fiber papers as surface dendrite-free current collectors for lithium deposition Ji, Xiulei; Liu, De-Yu; Prendiville, Daniel G. Nano Today, Vol. 7, Issue 1 https://doi.org/10.1016/j.nantod.2011.11.002	journal	February 2012
Advances in Li–S batteries Ji, Xiulei; Nazar, Linda F. Journal of Materials Chemistry, Vol. 20, Issue 44, p. 9821-9826 https://doi.org/10.1039/b925751a	journal	January 2010
Metallic anodes for next generation secondary batteries Kim, Hansu; Jeong, Goojin; Kim, Young-Ugk Chemical Society Reviews, Vol. 42, Issue 23 https://doi.org/10.1039/c3cs60177c	journal	January 2013
Dendrite-Free Lithium Deposition via Self-Healing Electrostatic Shield Mechanism Ding, Fei; Xu, Wu; Graff, Gordon L. Journal of the American Chemical Society, Vol. 135, Issue 11, p. 4450-4456 https://doi.org/10.1021/ja312241y	journal	March 2013
Selective deposition and stable encapsulation of lithium through heterogeneous seeded growth Yan, Kai; Lu, Zhenda; Lee, Hyun-Wook Nature Energy, Vol. 1, Issue 3, Article No. 16010 https://doi.org/10.1038/nenergy.2016.10	journal	February 2016
Design principles for electrolytes and interfaces for stable lithium-metal batteries Tikekar, Mukul D.; Choudhury, Snehashis; Tu, Zhengyuan Nature Energy, Vol. 1, Issue 9 https://doi.org/10.1038/nenergy.2016.114	journal	September 2016
An Artificial Solid Electrolyte Interphase with High Li-Ion Conductivity, Mechanical Strength, and Flexibility for Stable Lithium Metal Anodes Liu, Yayuan; Lin, Dingchang; Yuen, Pak Yan Advanced Materials, Vol. 29, Issue 10 https://doi.org/10.1002/adma.201605531	journal	December 2016
Fluoroethylene Carbonate Additives to Render Uniform Li Deposits in Lithium Metal Batteries Zhang, Xue-Qiang; Cheng, Xin-Bing; Chen, Xiang Advanced Functional Materials, Vol. 27, Issue 10 https://doi.org/10.1002/adfm.201605989	journal	January 2017
Opportunities and challenges for a sustainable energy future Chu, Steven; Majumdar, Arun Nature, Vol. 488, Issue 7411, p. 294-303 https://doi.org/10.1038/nature11475	journal	August 2012
A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries Suo, Liumin; Hu, Yong-Sheng; Li, Hong Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms2513	journal	February 2013
Li–O₂ and Li–S batteries with high energy storage Bruce, Peter G.; Freunberger, Stefan A.; Hardwick, Laurence J. Nature Materials, Vol. 11, Issue 1, p. 19-29 https://doi.org/10.1038/nmat3191	journal	January 2012
High-Performance Lithium Metal Negative Electrode with a Soft and Flowable Polymer Coating Zheng, Guangyuan; Wang, Chao; Pei, Allen ACS Energy Letters, Vol. 1, Issue 6 https://doi.org/10.1021/acsenergylett.6b00456	journal	November 2016
Lithium metal anodes for rechargeable batteries Xu, Wu; Wang, Jiulin; Ding, Fei Energy Environ. Sci., Vol. 7, Issue 2 https://doi.org/10.1039/C3EE40795K	journal	January 2014
Lithium Metal Anodes with an Adaptive “Solid-Liquid” Interfacial Protective Layer Liu, Kai; Pei, Allen; Lee, Hye Ryoung Journal of the American Chemical Society, Vol. 139, Issue 13 https://doi.org/10.1021/jacs.6b13314	journal	March 2017
Layered reduced graphene oxide with nanoscale interlayer gaps as a stable host for lithium metal anodes Lin, Dingchang; Liu, Yayuan; Liang, Zheng Nature Nanotechnology, Vol. 11, Issue 7 https://doi.org/10.1038/nnano.2016.32	journal	March 2016
Coated Lithium Powder (CLiP) Electrodes for Lithium-Metal Batteries Heine, Jennifer; Krüger, Steffen; Hartnig, Christoph Advanced Energy Materials, Vol. 4, Issue 5 https://doi.org/10.1002/aenm.201300815	journal	November 2013
Core–Shell Nanoparticle Coating as an Interfacial Layer for Dendrite-Free Lithium Metal Anodes Liu, Wei; Li, Weiyang; Zhuo, Denys ACS Central Science, Vol. 3, Issue 2 https://doi.org/10.1021/acscentsci.6b00389	journal	January 2017
Interconnected hollow carbon nanospheres for stable lithium metal anodes Zheng, Guangyuan; Lee, Seok Woo; Liang, Zheng Nature Nanotechnology, Vol. 9, Issue 8 https://doi.org/10.1038/nnano.2014.152	journal	July 2014
Stable lithium electrodeposition in liquid and nanoporous solid electrolytes Lu, Yingying; Tu, Zhengyuan; Archer, Lynden A. Nature Materials, Vol. 13, Issue 10 https://doi.org/10.1038/nmat4041	journal	August 2014
High rate and stable cycling of lithium metal anode Qian, Jiangfeng; Henderson, Wesley A.; Xu, Wu Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7362	journal	February 2015
Artificial Protection Film on Lithium Metal Anode toward Long-Cycle-Life Lithium-Oxygen Batteries Liu, Qing-Chao; Xu, Ji-Jing; Yuan, Shuang Advanced Materials, Vol. 27, Issue 40 https://doi.org/10.1002/adma.201504429	journal	October 2015
Decoupling the origins of irreversible coulombic efficiency in anode-free lithium metal batteries Huang, Chen-Jui; Thirumalraj, Balamurugan; Tao, Hsien-Chu Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-21683-6	journal	March 2021
Stable Lithium Electrodeposition in Liquid and Nanoporous Solid Electrolytes Lu, Yingying; Tu, Zhengyuan; Archer, Lynden arXiv https://doi.org/10.48550/arxiv.1404.6177	text	January 2014
Future prospects of the lithium metal anode Takehara, Zen-ichiro Journal of Power Sources, Vol. 68, Issue 1 https://doi.org/10.1016/s0378-7753(96)02546-3	journal	September 1997

Cited By (41)

A Game Changer: Functional Nano/Micromaterials for Smart Rechargeable Batteries Ryu, Jaegeon; Song, Woo‐Jin; Lee, Sangyeop Advanced Functional Materials, Vol. 30, Issue 2 https://doi.org/10.1002/adfm.201902499	journal	August 2019
Constructing a High‐Strength Solid Electrolyte Layer by In Vivo Alloying with Aluminum for an Ultrahigh‐Rate Lithium Metal Anode Lu, Ziyang; Li, Wantang; Long, Yu Advanced Functional Materials, Vol. 30, Issue 7 https://doi.org/10.1002/adfm.201907343	journal	December 2019
Lithium Silicide Surface Enrichment: A Solution to Lithium Metal Battery Tang, Wei; Yin, Xuesong; Kang, Sujin Advanced Materials, Vol. 30, Issue 34 https://doi.org/10.1002/adma.201801745	journal	July 2018
A Hierarchical Silver-Nanowire-Graphene Host Enabling Ultrahigh Rates and Superior Long-Term Cycling of Lithium-Metal Composite Anodes Xue, Pan; Liu, Shuiren; Shi, Xinlei Advanced Materials, Vol. 30, Issue 44 https://doi.org/10.1002/adma.201804165	journal	September 2018
A Lightweight 3D Cu Nanowire Network with Phosphidation Gradient as Current Collector for High‐Density Nucleation and Stable Deposition of Lithium Zhang, Chen; Lyu, Ruiyang; Lv, Wei Advanced Materials, Vol. 31, Issue 48 https://doi.org/10.1002/adma.201904991	journal	September 2019
Improving a Mg/S Battery with YCl ₃ Additive and Magnesium Polysulfide Xu, Yan; Zhou, Guangmin; Zhao, Shuyang Advanced Science https://doi.org/10.1002/advs.201800981	journal	December 2018
Superlithiophilic Amorphous SiO ₂ –TiO ₂ Distributed into Porous Carbon Skeleton Enabling Uniform Lithium Deposition for Stable Lithium Metal Batteries Xue, Pan; Sun, Chuang; Li, Hongpeng Advanced Science, Vol. 6, Issue 18 https://doi.org/10.1002/advs.201900943	journal	July 2019
The Synergistic Effect of Cation and Anion of an Ionic Liquid Additive for Lithium Metal Anodes Yoo, Dong-Joo; Kim, Ki Jae; Choi, Jang Wook Advanced Energy Materials, Vol. 8, Issue 11 https://doi.org/10.1002/aenm.201702744	journal	January 2018
Dendrite-Free Metallic Lithium in Lithiophilic Carbonized Metal-Organic Frameworks Zhu, Mengqi; Li, Bin; Li, Songmei Advanced Energy Materials, Vol. 8, Issue 18 https://doi.org/10.1002/aenm.201703505	journal	March 2018
Enabling Stable Lithium Metal Anode via 3D Inorganic Skeleton with Superlithiophilic Interphase Fan, Lei; Li, Siyuan; Liu, Lei Advanced Energy Materials, Vol. 8, Issue 33 https://doi.org/10.1002/aenm.201802350	journal	October 2018
An Interconnected Channel-Like Framework as Host for Lithium Metal Composite Anodes Wang, Hansen; Lin, Dingchang; Xie, Jin Advanced Energy Materials, Vol. 9, Issue 7 https://doi.org/10.1002/aenm.201802720	journal	January 2019
Uniform High Ionic Conducting Lithium Sulfide Protection Layer for Stable Lithium Metal Anode Chen, Hao; Pei, Allen; Lin, Dingchang Advanced Energy Materials, Vol. 9, Issue 22 https://doi.org/10.1002/aenm.201900858	journal	April 2019
Fast‐Charging and Ultrahigh‐Capacity Lithium Metal Anode Enabled by Surface Alloying Xu, Tianhui; Gao, Peng; Li, Peirong Advanced Energy Materials, Vol. 10, Issue 8 https://doi.org/10.1002/aenm.201902343	journal	January 2020
Structure Design and Composition Engineering of Carbon‐Based Nanomaterials for Lithium Energy Storage Geng, Hongya; Peng, Yan; Qu, Liangti Advanced Energy Materials, Vol. 10, Issue 10 https://doi.org/10.1002/aenm.201903030	journal	March 2020
Halogenid‐basierte Materialien und Chemie für wiederaufladbare Batterien Zhao, Xiangyu; Zhao‐Karger, Zhirong; Fichtner, Maximilian Angewandte Chemie, Vol. 132, Issue 15 https://doi.org/10.1002/ange.201902842	journal	January 2020
Graphitic Carbon Nitride (g‐C ₃ N ₄ ): An Interface Enabler for Solid‐State Lithium Metal Batteries Huang, Ying; Chen, Bo; Duan, Jian Angewandte Chemie, Vol. 132, Issue 9 https://doi.org/10.1002/ange.201914417	journal	January 2020
Halide‐Based Materials and Chemistry for Rechargeable Batteries Zhao, Xiangyu; Zhao‐Karger, Zhirong; Fichtner, Maximilian Angewandte Chemie International Edition, Vol. 59, Issue 15 https://doi.org/10.1002/anie.201902842	journal	January 2020
Graphitic Carbon Nitride (g‐C ₃ N ₄ ): An Interface Enabler for Solid‐State Lithium Metal Batteries Huang, Ying; Chen, Bo; Duan, Jian Angewandte Chemie International Edition, Vol. 59, Issue 9 https://doi.org/10.1002/anie.201914417	journal	January 2020
Low-Weight 3D Al ₂ O ₃ Network as an Artificial Layer to Stabilize Lithium Deposition Tian, Ran; Feng, Xiaoqian; Duan, Huanan ChemSusChem, Vol. 11, Issue 18 https://doi.org/10.1002/cssc.201801234	journal	August 2018
Boosting the Reversibility of Sodium Metal Anode via Heteroatom‐Doped Hollow Carbon Fibers Zheng, Xueying; Li, Peng; Cao, Zhang Small, Vol. 15, Issue 41 https://doi.org/10.1002/smll.201902688	journal	August 2019
Chemical Confinement and Utility of Lithium Polysulfides in Lithium Sulfur Batteries Tang, Tianyu; Hou, Yanglong Small Methods, Vol. 4, Issue 6 https://doi.org/10.1002/smtd.201900001	journal	April 2019
Stable Li‐Metal Deposition via a 3D Nanodiamond Matrix with Ultrahigh Young's Modulus Zhang, Weidong; Fan, Lei; Tong, Zheming Small Methods, Vol. 3, Issue 11 https://doi.org/10.1002/smtd.201900325	journal	May 2019
Multifunctionality of Carbon-based Frameworks in Lithium Sulfur Batteries Tang, Tianyu; Hou, Yanglong Electrochemical Energy Reviews, Vol. 1, Issue 3 https://doi.org/10.1007/s41918-018-0016-x	journal	August 2018
Lithium Metal Anode Materials Design: Interphase and Host Wang, Hansen; Liu, Yayuan; Li, Yuzhang Electrochemical Energy Reviews, Vol. 2, Issue 4 https://doi.org/10.1007/s41918-019-00054-2	journal	October 2019
Two-dimensional molecular brush-functionalized porous bilayer composite separators toward ultrastable high-current density lithium metal anodes Li, Chuanfa; Liu, Shaohong; Shi, Chenguang Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09211-z	journal	March 2019
Rational design of spontaneous reactions for protecting porous lithium electrodes in lithium–sulfur batteries Ren, Y. X.; Zeng, L.; Jiang, H. R. Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-11168-y	journal	July 2019
Anode interfacial layer formation via reductive ethyl detaching of organic iodide in lithium–oxygen batteries Zhang, Xiao-Ping; Sun, Yi-Yang; Sun, Zhuang Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-11544-8	journal	August 2019
Fluorinated hybrid solid-electrolyte-interphase for dendrite-free lithium deposition Pathak, Rajesh; Chen, Ke; Gurung, Ashim Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-019-13774-2	journal	January 2020
Solid-state polymer electrolytes with in-built fast interfacial transport for secondary lithium batteries Zhao, Qing; Liu, Xiaotun; Stalin, Sanjuna Nature Energy, Vol. 4, Issue 5 https://doi.org/10.1038/s41560-019-0349-7	journal	March 2019
AlF ₃ -Modified carbon nanofibers as a multifunctional 3D interlayer for stable lithium metal anodes Guo, Cheng; Yang, Huijun; Naveed, Ahmad Chemical Communications, Vol. 54, Issue 60 https://doi.org/10.1039/c8cc04422h	journal	January 2018
Ionic liquid functionalized electrospun gel polymer electrolyte for use in a high-performance lithium metal battery Cheng, Yuanyuan; Zhang, Lan; Xu, Song Journal of Materials Chemistry A, Vol. 6, Issue 38 https://doi.org/10.1039/c8ta06338a	journal	January 2018
A 3D conductive scaffold with lithiophilic modification for stable lithium metal batteries Song, Rensheng; Wang, Bo; Xie, Ying Journal of Materials Chemistry A, Vol. 6, Issue 37 https://doi.org/10.1039/c8ta06775a	journal	January 2018
A facile annealing strategy for achieving in situ controllable Cu ₂ O nanoparticle decorated copper foil as a current collector for stable lithium metal anodes Zhang, Qi; Luan, Jingyi; Tang, Yougen Journal of Materials Chemistry A, Vol. 6, Issue 38 https://doi.org/10.1039/c8ta07612j	journal	January 2018
Stable lithium–sulfur full cells enabled by dual functional and interconnected mesocarbon arrays Cao, Daxian; Jiao, Yucong; Cai, Qingfu Journal of Materials Chemistry A, Vol. 7, Issue 7 https://doi.org/10.1039/c8ta10351h	journal	January 2019
Low-volume-change, dendrite-free lithium metal anodes enabled by lithophilic 3D matrix with LiF-enriched surface Feng, Yangyang; Zhang, Chaofan; Li, Bing Journal of Materials Chemistry A, Vol. 7, Issue 11 https://doi.org/10.1039/c8ta10779c	journal	January 2019
Expanded-graphite embedded in lithium metal as dendrite-free anode of lithium metal batteries Zhao, Qiang; Hao, Xiaoge; Su, Shiming Journal of Materials Chemistry A, Vol. 7, Issue 26 https://doi.org/10.1039/c9ta04240g	journal	January 2019
In situ formation of a LiF and Li–Al alloy anode protected layer on a Li metal anode with enhanced cycle life Wang, Lili; Fu, Shiyang; Zhao, Teng Journal of Materials Chemistry A, Vol. 8, Issue 3 https://doi.org/10.1039/c9ta10965j	journal	January 2020
Review—Li Metal Anode in Working Lithium-Sulfur Batteries Cheng, Xin-Bing; Huang, Jia-Qi; Zhang, Qiang Journal of The Electrochemical Society, Vol. 165, Issue 1 https://doi.org/10.1149/2.0111801jes	journal	June 2017
Synthesis of Spherical Fluorine Modified Gradient Li-Ion Battery Cathode Material LiNi _0.80 Co _0.15 Al _0.05 O ₂ by Simple Solid Phase Method Xia, Shubiao; Li, Fushao; Cheng, Feixiang Journal of The Electrochemical Society, Vol. 165, Issue 5 https://doi.org/10.1149/2.1021805jes	journal	January 2018
Mechanical rolling formation of interpenetrated lithium metal/lithium tin alloy foil for ultrahigh-rate battery anode Wan, Mintao; Kang, Sujin; Wang, Li Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-14550-3	journal	February 2020
An ultrastable lithium metal anode enabled by designed metal fluoride spansules Yuan, Huadong; Nai, Jianwei; Tian, He Science Advances, Vol. 6, Issue 10 https://doi.org/10.1126/sciadv.aaz3112	journal	March 2020

Similar Records

Transforming from planar to three-dimensional lithium with flowable interphase for solid lithium metal batteries

Journal Article · Sun Oct 01 00:00:00 EDT 2017 · Science Advances · OSTI ID:1389865

Liu, Yayuan; Lin, Dingchang; Jin, Yang; +5 more

Stitching h-BN by atomic layer deposition of LiF as a stable interface for lithium metal anode

Journal Article · Wed Nov 29 00:00:00 EST 2017 · Science Advances · OSTI ID:1389865

Xie, Jin; Liao, Lei; Gong, Yongji; +9 more

An Interconnected Channel-Like Framework as Host for Lithium Metal Composite Anodes

Journal Article · Wed Jan 02 00:00:00 EST 2019 · Advanced Energy Materials · OSTI ID:1389865

Wang, Hansen; Lin, Dingchang; Xie, Jin; +11 more

Related Subjects

36 MATERIALS SCIENCE

Title: Ultrahigh–current density anodes with interconnected Li metal reservoir through overlithiation of mesoporous AlF3 framework

Citation Formats

References (45)

Cited By (41)

Similar Records

Related Subjects

Title: Ultrahigh–current density anodes with interconnected Li metal reservoir through overlithiation of mesoporous AlF₃ framework