Surface Immobilization of Molecular Electrocatalysts for Energy Conversion

Bullock, R. Morris; Das, Atanu K.; Appel, Aaron M.

doi:10.1002/chem.201605066

Title: Surface Immobilization of Molecular Electrocatalysts for Energy Conversion

Journal Article · Tue Feb 28 00:00:00 EST 2017 · Chemistry - A European Journal

DOI:https://doi.org/10.1002/chem.201605066· OSTI ID:1388883

^[1]; Das, Atanu K. ^[1];

^[1]

Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Center for Molecular Electrocatalysis

Electrocatalysts are critically important for a secure energy future, as they facilitate the conversion between electrical energy and chemical energy. Molecular catalysts offer precise control of their structure, and the ability to modify the substituents to understand structure-reactivity relationships that are more difficult to achieve with heterogeneous catalysts. Molecular electrocatalysts can be immobilized on surfaces by covalent bonds or through non-covalent interactions. Advantages of surface immobilization include the need for less catalyst, avoidance of bimolecular decomposition pathways, and easier determination of catalyst lifetime. Copper-catalyzed click reactions are often used to form covalent bonds to surfaces, and pi-pi stacking of pyrene substituents appended to the ligand of a molecular complex is a frequently used method to achieve non-covalent surface immobilization. This mini-review highlights surface confinement of molecular electrocatalysts for reduction of O2, oxidation of H2O, production of H2, and reduction of CO2.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Molecular Electrocatalysis (CME); Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1388883

Alternate ID(s):: OSTI ID: 1843409

Report Number(s):: PNNL-SA-121541

Journal Information:: Chemistry - A European Journal, Vol. 23, Issue 32; Related Information: CME partners with Pacific Northwest National Laboratory (lead); University of Illinois, Urbana-Champaign; Pennsylvania State University; University of Washington; University of Wyoming; ISSN 0947-6539

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 137 works

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
catalysis (homogeneous)
catalysis (heterogeneous)
solar (fuels)
bio-inspired
energy storage (including batteries and capacitors)
hydrogen and fuel cells
charge transport
materials and chemistry by design
synthesis (novel materials)
attachment
confinement
electrocatalysis
immobilization
surface

Title: Surface Immobilization of Molecular Electrocatalysts for Energy Conversion

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